Search Results (21,218)

As freshwater resources become increasingly scarce, seawater and brackish water represent alternative sources for crop irrigation, particularly in systems such as saltwater aquaponics. Red orache (Atriplex hortensis var. rubra) is a halophyte with high antioxidant content but also accumulates antinutrients like nitrate (NO₃⁻) and oxalate. Oxalate helps plants cope with salinity stress but can cause health issues in humans. This study examined the growth of red orache baby greens in saline and nitrogen-limited hydroponic solutions to assess its adaptability and nutritional quality, focusing on the impact of salinity and reduced nitrogen on antinutrient levels. Four nutrient solutions differing in NaCl (0 or 428 mM) and NO₃⁻ (10 or 1 mM) were tested. Salinity significantly reduced red orache yield (by 75.5%), pigment levels, antioxidants, and nutrient uptake, while increasing leaf Na and oxalate concentration, ethylene production, and succulence. Salinity decreased NO₃⁻ concentration and oxalate oxidase (OxO) activity but boosted total ascorbic acid and oxalate accumulation. Low NO₃⁻ mildly reduced yield (by 25.7%), leaf area, and NO₃⁻ concentration in leaves, but had no effect on leaf moisture content, succulence, antioxidant capacity, and the concentration of antioxidants, pigments, and total oxalate. In addition, low NO₃⁻ increased OxO activity, only under non-saline conditions. The high salinity typical of aquaculture effluents strongly reduced red orache baby greens yield and quality to a greater extent than low NO₃⁻ levels. Both salinity and low NO₃⁻ reduced NO₃⁻ concentration in leaves, while salinity increased oxalate concentration, probably due to the reduced activity of OxO. Full article

In this study, two novel hybrid monomers (4BD-EDOT and 3BD-EDOT) containing a biphenyl group and a 3,4-ethylenedioxythiophene (EDOT) unit were synthesized and polymerized electrochemically in a CH₂Cl₂-Bu₄NPF₆ electrolyte solution. Characterizations of the resulting P4BD-EDOT and P3BD-EDOT were studied by CV, scanning electron microscopy (SEM), and spectroelectrochemistry in order to examine the effect of different substitution positions of biphenyl on the electrochromic performance of the resultant hybrid polymers. Both polymers have favorable redox activity (a distinct redox peak) and good redox stability (55–49% electroactivity was retained after 1000 cycles). The spectro-electrochemistry study found that both show a distinct color change from reddish brown to blue/purple for P4BD-EDOT with a lower band gap (1.54 eV) and from transparent color to light blue for P3BD-EDOT with a larger band gap (1.73 eV). These electrochromic polymer films also have fast switching speed (0.5–0.2 s), with the favorable optical contrast (22.6% at 1100 nm for P4BD-EDOT) and decent coloration efficiency (250.4 cm² C⁻¹ at 780 nm for P3BD-EDOT). All these results show that both monomers have important values related to the electrochromic field. This work also shows that the different substitution positions of the biphenyl unit affect the spectroelectrochemistry and electrochromic characteristics of the resultant hybrid polymers. Full article

Insufficient harvesting of visible photons, limited adsorption, and fast recombination of photogenerated electron-hole pairs restrict the application of graphitic carbon nitride (g-C₃N₄). Here, we propose a straightforward solid-phase synthesis method for fabricating 2D/2D graphitic carbon nitride/reduced graphene oxide (SCN/GR) hybrid photocatalysts. The synthesis process involves the thermal condensation of three precursors: dicyandiamide (as the g-C₃N₄ source), NH₄Cl (as a pore-forming agent), and graphene oxide (GO, which is in situ reduced to rGO during thermal treatment). The incorporation of reduced graphene oxide (rGO) into the g-C₃N₄ matrix not only narrows the bandgap of the material but also expedites the separation of photogenerated carriers. The photocatalytic activity of the SCN/GR hybrid was systematically evaluated by degrading ciprofloxacin in aqueous solution under different light conditions. The results demonstrated remarkable degradation efficiency: 72% removal within 1 h under full-spectrum light, 81% under UV light, and 52% under visible light. Notably, the introduction of rGO significantly improved the visible light absorption capacity of g-C₃N₄. Additionally, SCN/GR exhibits exceptional cyclic stability, maintaining its structural integrity and photocatalytic properties unchanged across five successive degradation cycles. This study offers a simple yet effective pathway to synthesize 2D/2D composite photocatalysts, which hold significant promise for practical applications in water treatment processes. Full article

This paper analyzes the potential of hydrogen technologies in transport, placing it within the context of global environmental and energy challenges. Its primary purpose is to evaluate the prospects for the implementation of these technologies at international and national levels, including Poland. This study utilizes a literature review and an analysis of the results of a highly limited, exploratory pilot survey measuring public perception of hydrogen technology in transport. It is critical to note that the survey was conducted on a small, non-representative sample and exhibited a strong geographical bias, primarily collecting responses from Europe (50 people) and North America (30 people). This study also details hydrogen vehicle types (FCEV, HICE) and the essential infrastructure required (HRS). Despite solid technological foundations, the development of hydrogen technology heavily relies on non-technical factors, such as infrastructure development, support policy, and social acceptance. Globally, the number of vehicles and stations is growing but remains limited, with the pace of development correlating with the involvement of countries. The pilot survey revealed a generally positive perception of the technology (mainly due to environmental benefits) but highlighted three key barriers: limited availability of refueling infrastructure—51.5% of respondents strongly agreed on this obstacle, high purchase and maintenance costs, and insufficient public awareness. Infrastructure subsidies and tax breaks were identified as effective incentives. Hydrogen technology offers a potentially competitive and sustainable transport solution, but it demands significant systemic support, intensive investment in large-scale infrastructure expansion, and comprehensive educational activities. Further governmental engagement is crucial. The severe limitations resulting from the pilot nature of the survey should be rigorously taken into account during interpretation. Full article

Ladle slag (LF slag) is a by-product of secondary steelmaking that presents unique valorization challenges compared to BOF or EAF slags due to its distinctive chemical composition (high Al₂O₃ and CaO content) and uncontrolled hydraulic activity. While other steelmaking slags can be reused as supplementary cementitious materials or aggregates, LF slag is predominantly landfilled, with over 2 million tons discarded annually in Europe alone. This study introduces a novel pyrometallurgical valorization strategy that, unlike conventional approaches focused solely on mineral recovery, simultaneously recovers both metallic and mineral value through aluminothermic reduction. This process utilizes end-of-waste aluminum scrap rather than virgin materials to reduce Fe and Si oxides, creating a circular economy solution that addresses two waste streams simultaneously. The process generates two valuable products with low liquidus temperatures: a ferrosilicon alloy (FeSi15-50 grade) and a residual oxide rich in calcium and magnesium aluminates suitable for cementitious or ceramic applications. Through the integration of FactSage thermodynamic simulations with experimental validation, it is possible to predict and control phase evolution during equilibrium cooling, an approach not previously applied to LF slag valorization. Experimental validation using industrial slags confirms the theoretical predictions and demonstrates the process operates in a near-energy-neutral, self-sustaining mode by recovering both chemical and sensible thermal energy (50–100 kWh per ton of slag). This represents approximately 90% lower energy consumption compared to conventional ferrosilicon production. The work provides a comprehensive and scalable approach to transform a problematic waste material into valuable products, supporting circular economy principles and low-carbon metallurgy objectives. Full article

The ongoing global warming threatens the Greenland Ice Sheet (GIS), which has exhibited an overall mass loss since 1990. This loss varies annually and interannually, reflecting the intricate interactions between the ice sheet and atmospheric and oceanic circulations. We investigate GIS mass balance variations (2002–2024) using data from the Gravity Recovery and Climate Experiment (GRACE) and its Follow-On (GRACE-FO) missions. Monthly mass anomalies from the International Combination Service for Time-variable Gravity Fields (COST-G) solution are compared with cumulative climate indices (North Atlantic Oscillation—NAO, Greenland Blocking Index—GBI, Atlantic Multidecadal Oscillation—AMO) and meteorological parameters (temperature, precipitation, surface albedo). Empirical Orthogonal Function analysis reveals five principal modes of variations, the first capturing annual and interannual frequencies (4–7 and 11 years), while subsequent modes only describe interannual frequencies. Wavelet analysis shows significant annual correlations between GIS mass changes and temperature (r = −0.88), NAO (r = 0.74), and GBI (r = −0.85). An annual cycle connects GIS mass changes, climatic indices, and meteorological parameters, while interannual variations highlight the role of the AMO and the NAO. The presence of an 11-year periodicity with the mass variations for NAO, GBI, and temperature strongly correlates with solar activity. Full article

Fruit tree image segmentation is an essential problem in automating a variety of agricultural tasks such as phenotyping, harvesting, spraying, and pruning. Many research papers have proposed a diverse spectrum of solutions suitable for specific tasks and environments. The review scope of this paper is confined to the front views of fruit trees, and 207 relevant papers proposing tree image segmentation in an orchard environment are collected using a newly designed crawling review method. These papers are systematically reviewed based on a four-tier taxonomy that sequentially considers the method, image, task, and fruit. This taxonomy will assist readers to intuitively grasp the big picture of these research activities. Our review reveals that the most noticeable deficiency of the previous studies was the lack of a versatile dataset and segmentation model that could be applied to a variety of tasks and environments. Six important future research topics, such as building large-scale datasets and constructing foundation models, are suggested, with the expectation that these will pave the way to building a versatile tree segmentation module. Full article

Deaf-blindness, particularly in progressive conditions such as Usher syndrome, presents profound challenges to communication, independence, and access to information. Existing tactile communication technologies for individuals with Usher syndrome are often limited by the need for close physical proximity to trained interpreters, typically requiring hand-to-hand contact. In this study, we introduce a novel, cloud-based, AI-assisted gesture recognition and haptic communication system designed for long-term use by individuals with Usher syndrome, whose auditory and visual abilities deteriorate with age. Central to our approach is a wearable haptic interface that relocates tactile input and output from the hands to an arm-mounted sleeve, thereby preserving manual dexterity and enabling continuous, bidirectional tactile interaction. The system uses surface electromyography (sEMG) to capture user-specific muscle activations in the hand and forearm and employs lightweight, personalized convolutional neural networks (CNNs), hosted on a centralized server, to perform real-time gesture classification. A key innovation of the system is its ability to adapt over time to each user’s evolving physiological condition, including the progressive loss of vision and hearing. Experimental validation using a public dataset, along with real-time testing involving seven participants, demonstrates that personalized models consistently outperform cross-user models in terms of accuracy, adaptability, and usability. This platform offers a scalable, longitudinally adaptable solution for non-visual communication and holds significant promise for advancing assistive technologies for the deaf-blind community. Full article

Background: Glioma remains an intractable and highly aggressive brain tumor, mainly due to the daunting obstacle presented by the blood–brain barrier (BBB). To overcome this challenge and enhance therapeutic efficacy, a dual-drug delivery system was engineered. This system co-encapsulated curcumin, a nutraceutical with multitargeted anticancer potential, with atorvastatin calcium, a repurposed anticancer agent, within lipidic nanocapsules (LNCs). Methods: LNCs were prepared via the phase inversion temperature method and optimized using a Box–Behnken design. The optimized LNCs were subsequently functionalized with folic acid (FA) to enable active targeting. FA-LNCs were characterized using XPS, TEM, in vitro release, and MTT cytotoxicity assays. Atorvastatin and curcumin were radiolabeled separately with iodine-131 to evaluate the in vivo pharmacokinetics in a glioma-bearing mouse model. Results: The optimized LNCs and FA-LNCs displayed a mean particle size of 97.98 ± 2.27 nm and 181.60 ± 2.83 nm, a polydispersity index of 0.32 ± 0.07 and 0.40 ± 0.02, and a zeta potential of −15.85 ± 1.35 mV and −11.90 ± 2.80, respectively. XPS and FTIR analyses verified FA conjugation. Both LNCs and FA-LNCs enhanced the in vitro cytotoxicity compared to free drugs; however, the most pronounced effect of FA functionalization was observed in vivo. Most significantly, FA-LNCs achieved markedly greater glioma accumulation than non-functionalized LNCs, with AUC values 2.0-fold higher for atorvastatin and 2.6-fold higher for curcumin. When compared to the free drug solutions, this efficiency was even more pronounced, with atorvastatin and curcumin showing enhancements of 8.2 and 12.4 times, respectively. Conclusions: FA-LNCs markedly improved glioma targeting efficiency and reduced systemic clearance, which underscores the therapeutic potential of integrating nutraceuticals with repurposed agents to achieve effective glioma therapy. Full article

Relatively uniform consumption of a large amount of electrical energy intended for the current operation of the equipment of multi-story student dormitories indicates several actions aimed at renovation of these dormitories using photovoltaic installations producing electricity to replace the energy supplied from external networks. The research allowed for parameterization of input and output data, defining several innovative parametric and discrete models used in modernization processes and constituting the basis for optimizing energy renovations in terms of the substitutability of grid energy, payback periods, and investment costs. A new method developed to renovate dormitories was supported by an application elaborated in the visual parametric Rhino/Grasshopper design environment. This application enables automatic uploading of various meteorological data files and programming the loads, properties, and operation of the designed photovoltaic installation. This method results in a single optimal solution concerning a building renovation process, which allows for fully automated execution of the above activities. The developed models were configured based on a real renovated multi-story residence student hall located on the Central European Plain, for which a 34.3% balance of the replaced grid energy was carried out. The optimizing processes concerning the geometric properties and orientation of photovoltaic panels resulted in −30° of azimuth, 210 m² of total surface area, and 14° of tilt of photovoltaic panels distributed on the south façade, with 193 m² of surface area, 42° of tilt of panels arranged on the east façade, and an optimal payback period of 99 months. The invented algorithm, parametric models, computer programs, simulations, and optimizing calculations fill the gap in variant-optimized modelling and simplify the design processes of renovations of multi-story residence halls. These objects provide a basis for expanding the method to include other types of dormitory modernizations. Full article

The development of mineral resources in China is increasingly targeting the recovery of residual ore bodies, which significantly elevates geotechnical risks, including goaf collapse and pillar instability. To address these challenges, this study developed an integrated ground pressure control system that coordinates mining, backfilling, and support technologies. The system is dynamically optimized through a microseismic monitoring-based feedback mechanism, forming a closed-loop disaster management framework. Based on a two-year microseismic monitoring campaign (October 2012–September 2014), which captured 103 located events, a strong spatial clustering of seismic activity was observed, with over 7% of event pairs occurring within 20 m, particularly at the abutment of the syncline ore body. A zonal early-warning model was established using key parameters (event rate ratio ≥ 3, cluster density ≥ 15 events/10,000 m³, energy ratio ≥ 4). The effectiveness of the control system was validated by a 5.9% reduction in located events and a decrease in maximum magnitude from 0.3 to −0.2, despite a 34% year-on-year increase in ore production in 2019. These results demonstrate that the integrated approach provides a reliable and adaptive solution for ground pressure disaster prevention during residual ore recovery. Full article

Synthesis of anionic metal–organic framework Na[Ce(BDC)₂(DMF)₂] based on cerium (III)–sodium terephthalate was performed. The crystal structure, studied by the Rietveld method, consists of anionic [Ce(BDC)₂]⁻ layers, connected by interlayer sodium cations in a 3D network. Variable-temperature PXRD, total X-ray scattering with pair distribution function analysis, and DFT calculations revealed framework structure stability upon DMF elimination and thermal treatment up to 300 °C. Modification with copper cations was performed using wetness impregnation with a Cu(NO₃)₂ methanol solution to obtain a catalyst for carbon monoxide oxidation. Cu²⁺@Na[Ce(BDC)₂(DMF)₂] in situ decomposition leads to the catalytic activity of the resulting CuO/CeO₂ composite during CO gas oxidation by air. Full article

Antimicrobial resistance (AMR) poses an escalating global health crisis, projected to cause up to 10 million deaths annually by 2050. Conventional antibiotics are increasingly ineffective due to microbial adaptation, overuse, and disruption of gut microbiota. Nanotechnology offers promising alternatives, but traditional nanoparticle synthesis often relies on toxic chemicals and energy-intensive processes. This review explores mushroom-derived nanoparticles (myco-NPs) as sustainable, eco-friendly antimicrobials. Edible and medicinal mushrooms contain bioactive compounds, including polysaccharides, flavonoids, and proteins, that act as reducing and stabilizing agents in nanoparticle biosynthesis. Myco-NPs exhibit antimicrobial activity through membrane disruption, oxidative stress, immune modulation, and biofilm inhibition, while also demonstrating synergistic effects with antibiotics and potential roles in regulating the gut microbiota. Recent advances highlight their potential applications in medicine, food safety, and environmental protection. However, challenges remain regarding standardization, safety evaluation, and large-scale production. We emphasize interdisciplinary collaboration as essential to translating mushroom-based nanotechnology into effective clinical and industrial solutions. Full article

The standard motion analysis systems are limited to laboratory settings; therefore, an individual’s gait may not be realistic, as it is removed from the day-to-day environment in which people ambulate. The modern world and advanced technologies have driven portable, affordable, and wearable sensors for real-world gait assessment that can be used outside the laboratory and during day-to-day activities. Wearable sensors offer a promising solution; however, despite that, the reliability of many wearable systems, especially under unsupervised and real-world-like conditions, remains insufficiently validated. This study aimed to establish intra- and inter-rater reliability of the inertial sensors as a tool used in gait analysis in a quasi-real-world environment. Ninety-eight healthy participants (52% females) aged 19–33 years took part in this reliability study. The research procedures included two separate measurements of gait analysis at participants’ preferred walking speed, conducted by two raters assessing selected spatiotemporal parameters. The reliability was calculated using intraclass correlation coefficients (ICC), and the bias was assessed using the Bland–Altman method. The analysis of intraclass correlation coefficients (ICC) revealed excellent, or near-excellent, reliability for walking speed, cadence, and stride length between raters (ICC = 0.932–0.941, 0.950–0.957, and 0.916–0.938, respectively) and between measurements (ICC = 0.916–0.928, 0.934–0.938, and 0.888–0.906, respectively). Bland–Altman plots confirmed minimal systematic bias for both inter- and intra-rater assessments, with differences in walking speed below 0.038 km/h, cadence below 0.283 steps/min, and stride length below 0.827 cm. The examined sensors are reliable tools for walking speed, cadence, and stride length in a quasi-real-world environment gait assessment. Future studies should include gait analysis involving random path and direction changes, turns, uneven or slippery surfaces, and natural environments. Additionally, research should consider individuals ambulating with various walking aids, or those with unilateral disorders, such as stroke. Full article

In this study, thermodynamic properties such as water activity, osmotic coefficient, and saturation points of the aqueous mixture in the system D-Sucrose + Water + ammonium nitrate (AN) were determined at 298.15 K. The measurements were carried out on the mixtures of concentrations of NH₄NO₃ (ranging from 0.1 to 6 mol·kg⁻¹) and D-sucrose (from 0.1 to 4 mol·kg⁻¹) using our hygrometric method. Powder X-ray diffraction (XRD) and attenuated total reflection–Fourier transform infrared (ATR-FTIR) spectroscopy were used to characterize the solid phases crystallized during the supersaturation of the solution. Other thermodynamic quantities such as the solute activity coefficients, excess Gibbs energies, transfer energies, and solute solubilities were calculated using the Pitzer–Simonson–Clegg (PSC) model. The results obtained indicate that at an AN concentration lower than 1 mol·kg⁻¹, the system exhibits increasingly negative deviations from ideality, and that NH₄NO₃ promotes the salting-out effect of sucrose. Full article