Search Results (44)

With the rapid development of the automotive industry, particularly the year-on-year growth in sales of new energy vehicles, automobile outer panel materials have shown a trend toward high-strength lightweight solutions. Regarding steel for outer panels, existing research has paid less attention to the UF steel that has entered the market in recent years. Moreover, studies on the similarities and differences in deformation behavior among various outer panel steels are lacking. In this study, room-temperature tensile tests at 5% and 8% strain were conducted in accordance with the stamping deformation range on commonly used ultra-low carbon automotive outer panel steels of comparable strength grades, namely, UF340, HC180BD, and DX53D+Z. Prior to deformation, the three materials exhibited similar texture components, predominantly characterized by the γ-fiber texture beneficial for deep drawing, and their room-temperature tensile deformation behaviors were fundamentally identical. After transverse tensile deformation, the textures concentrated towards {111}<112> texture. After 8% deformation, UF340 demonstrated a more rapid stress increase and a higher degree of work hardening. This phenomenon is attributed to the presence of the precipitate free zone (PFZ) near grain boundaries in the UF340, which facilitates the continuous generation of dislocations at grain boundaries during deformation, leading to a rapid increase in dislocation density within the grains. Consequently, this induces accelerated work hardening under small-strain conditions. This mechanism enables UF steels to achieve a strength level comparable to that of bake-hardened (BH) steels, exhibiting a significant performance advantage. Full article

The growing environmental and economic impacts of carbon-based fuels have accelerated the search for sustainable alternatives, with hydrogen (H₂) emerging as a clean and efficient energy carrier. Sodium borohydride (NaBH₄) is a promising hydrogen storage compound, due to its high hydrogen content (10.6 wt%) and stability under ambient conditions. However, its hydrolysis with water proceeds slowly without an effective catalyst. In this study, gold nanoparticle-decorated spherical carbon (AuSC) composites were synthesized and evaluated as catalysts for NaBH₄ hydrolysis. The spherical carbon support, prepared via a glucose-mediated route, provided a high-surface-area and conductive matrix that dispersed and stabilized Au nanoparticles, preventing agglomeration. Catalyst morphology and composition were characterized using XRD, TEM, SEM, and EDS analyses. The AuSC catalyst exhibited excellent catalytic activity, producing 21.8 mL of H₂ at pH 7, 303 K, and 835 μmol NaBH₄. The activation energy (E_a) was determined to be 51.6 kJ mol⁻¹, consistent with a heterolytic B–H bond cleavage mechanism at the Au–C interface. The TON (2.82 × 10⁴) and TOF (1.41 × 10⁴ h⁻¹) values confirmed high intrinsic catalytic efficiency. These results demonstrate that Au-decorated spherical carbon composites are efficient, stable, and promising catalysts for hydrogen generation from NaBH₄ hydrolysis under mild conditions. Full article

The electronic effects of Lewis acids (LAs) in reducing the activation energies of Alder-ene (AE) reactions have been studied within the Molecular Electron Density Theory (MEDT). To this end, the AE reactions of 2-methylbutadiene (2MBD) with formaldehyde (CHO) in the presence of three LAs with increasing acidic character, BH₃, BF₃, and AlCl₃, have been studied. Topological analysis of the electron density and the evaluation of the DFT-based reactivity indices indicate that LAs do not modify the electronic structure of the carbonyl group but markedly increase the electrophilic character of CHO. LAs not only strongly accelerate the AE reactions, but also modify the molecular mechanisms, changing them from a non-concerted two-stage one-step mechanism to a two-step one. Topological analyses of the electron density at the transition state structures (TSs) indicate that while the formation of the new C-C single bond has begun, the departure of the hydrogen has not yet started. A Relative Interacting Atomic Energy (RIAE) analysis of the activation energies allows the establishment of the electronic effects of LAs on the AE reactions. LAs increase the global electron density transfer (GEDT) occurring in polar AE reactions; this phenomenon markedly stabilizes the CHO framework at the TSs, decreasing the RIAE relative energies. Full article

RMB₆-TMB₂ (RM = rare earth elements, TM = transition metal elements) composites retain superior field emission properties of RMB₆ while addressing its inherent mechanical limitations by constructing a eutectic structure with TMB₂. Herein, an in situ route for synthesizing RMB₆-TMB₂ composite nanopowders with homogeneous phase distribution using reduction reactions was proposed. The LaB₆-ZrB₂ composite nanopowders were synthesized in situ for the first time using sodium borohydride (NaBH₄) as both a reducing agent and boron source, with lanthanum oxide (La₂O₃) and zirconium dioxide (ZrO₂) serving as metal sources. The effects of the synthesis temperature on phase compositions and microstructure of the composites were systematically investigated. The LaB₆-ZrB₂ system with a eutectic weight ratio exhibited an accelerated reaction rate, achieving a complete reaction at 1000 °C, 300 °C lower than that of single-phase ZrB₂ synthesis. The composite phases were uniformly distributed even at nanoscale. The composite powder displayed an average particle size of ~170 nm when synthesized at 1300 °C. With the benefit of the in situ synthesis method, LaB₆-TiB₂, CeB₆-ZrB₂, and CeB₆-TiB₂ composite powders were successfully synthesized. This process effectively addresses phase separation and contamination issues typically associated with traditional mixing methods, providing a scalable precursor for high-performance RMB₆-TMB₂ composites. Full article

Particle Swarm Optimization (PSO) is a metaheuristic optimization technique based on population behavior, inspired by the movement of a flock of birds or a school of fish. In this method, particles move in a search space to find the global minimum of an objective function. In this work, a modified PSO algorithm written in Fortran 90 is proposed. The optimized structures obtained with this algorithm are compared with those obtained using the basin-hopping (BH) method written in Python (3.10), and complemented with density functional theory (DFT) calculations using the Gaussian 09 software. Additionally, the results are compared with the structural parameters reported from single crystal X-ray diffraction data for carbon clusters ${\mathrm{C}}_n$(n = 3–5), and tungsten–oxygen clusters, ${\mathrm{WO}}_n^{m-}$(n = 4–6, $m=2,4,6$). The PSO algorithm performs the search for the minimum energy of a harmonic potential function in a hyperdimensional space $\in {\mathbb{R}}^{3N}$ (where N is the number of atoms in the system), updating the global best position ( $g_{best}$) and local best position ( $p_{best}$), as well as the velocity and position vectors for each swarm cluster. A good approximation of the optimized structures and energies of these clusters was obtained, compared to the geometric optimization and single-point electronic energies calculated with the BH and DFT methods in the Gaussian 09 software. These results suggest that the PSO method, due to its low computational cost, could be useful for approximating a molecular structure associated with the global minimum of potential energy, accelerating the prediction of the most stable configuration or conformation, prior to ab initio electronic structure calculation. Full article

Active galactic nuclei (AGNs) often exhibit broad-line regions (BLRs), populated by high-velocity clouds in approximately Keplerian orbits around the central supermassive black hole (SMBH) at subparsec scales. During episodes of intense accretion at super-Eddington rates, the accretion disk can launch a powerful, radiation-driven wind. This wind may overtake the BLR clouds, forming bowshocks around them. Two strong shocks arise: one propagating into the wind, and the other into the cloud. If the shocks are adiabatic, electrons and protons can be efficiently accelerated via a Fermi-type mechanism to relativistic energies. In sufficiently dense winds, the resulting high-energy photons are absorbed and reprocessed within the photosphere, while neutrinos produced in inelastic $pp$ collisions escape. In this paper, we explore the potential of super-accreting AGNs as neutrino sources. We propose a new class of neutrino emitter: an AGN lacking jets and gamma-ray counterparts, but hosting a strong, opaque, disk-driven wind. As a case study, we consider a supermassive black hole with $M_{\mathrm{BH}}={10}^6{M}_{\odot }$ and accretion rates consistent with tidal disruption events (TDEs). We compute the relevant cooling processes for the relativistic particles under such conditions and show that super-Eddington accreting SMBHs can produce detectable neutrino fluxes with only weak electromagnetic counterparts. The neutrino flux may be observable by the next-generation IceCube Observatory (IceCube-Gen2) in nearby galaxies with a high BLR cloud filling factor. For galaxies hosting more massive black holes, detection is also possible with moderate filling factors if the source is sufficiently close, or at larger distances if the filling factor is high. Our model thus provides a new and plausible scenario for high-energy extragalactic neutrino sources, where both the flux and timescale of the emission are determined by the number of clouds orbiting the black hole and the duration of the super-accreting phase. Full article

Lonicera japonica Thunb. is a traditional Chinese medicinal herb whose floral buds are the primary source of pharmacological compounds that require manual harvesting. As a result, its floral bud duration, determined by the opening time, is a key determinant of both quality and economic value. However, the genetic mechanisms controlling floral bud duration remain poorly understood. In this study, we employed population structure analysis and molecular experiments to identify candidate genes associated with this trait. The improved cultivar Beihua No. 1 (BH1) opens its floral buds significantly later than the landrace Damaohua (DMH). Exogenous application of methyl jasmonate (MeJA) to BH1 indicated that jasmonate acts as a negative regulator of floral bud duration by accelerating floral bud opening. A genome-wide selection scan across 35 germplasms with varying floral bud durations identified the transcription factor LjWRKY50 as the causative gene influencing this trait. The dual-luciferase reporter assay and qRT-PCR experiments showed that LjWRKY50 activates the expression of the jasmonate biosynthesis gene, LjAOS. A functional variant within LjWRKY50 (Chr7:24636061) was further developed into a derived cleaved amplified polymorphic sequence (dCAPS) marker. These findings provide valuable insights into the jasmonate-mediated regulation of floral bud duration, offering genetic and marker resources for molecular breeding in L. japonica. Full article

The central singularity present in black hole (BH) spacetimes arising in the general theory of relativity (GR) can be avoided by using various methods. In the present work we have investigated the gravitational effect of one of such spacetime known as a black-bounce-Reissner–Nordström spacetime. We revisited its horizon structure along with first integrals of its geodesic equations. We derived the expressions for Newtonian radial acceleration for freely infalling neutral test particles. For the description of tidal effects, the geodesic deviation equations are derived and solved analytically as well as numerically. To be specific, in the numerical approach, we have opted for two initial conditions to elaborate on the evolution of geodesic deviation vectors in radial and angular directions. The corresponding nature of geodesic deviation vectors in radial and angular directions is then compared with the standard results such as Schwarzschild and Reissner–Nordström BHs in order to figure out the differences. Full article

Copper nanoparticles (CuNPs) have attracted attention due to their low cost and high specific surface area. In this work, a simple and inexpensive two-step synthesis method was proposed to prepare highly stable and well-dispersed spherical CuNPs in solution with a particle size of approximately 37 nm. Synthesis of CuNPs was carried on in the presence of complexing agent trisodium citrate (TSC), while for the chemical reduction step, sodium borohydride (NaBH₄) was used. Taking into account the potential of this type of nanoparticles, their synthesis and characterization represent a current and relevant topic in the field. The ability to control the size, shape and properties of CuNPs by adjusting the synthesis parameters (pH, precursor:stabilizer:reductant ratio, homogenization time, temperature) offers extraordinary flexibility in the development of these materials. The combination of characterization techniques such as SEM, EDX, UV–Vis, Raman, FT-IR and AFM provides a thorough understanding of the structure and properties of CuNPs, allowing the modulation of the properties of the obtained nanoparticles in the desired direction. Based on the studies, the copper reduction mechanism was proposed. For the theoretical verification of the size of the experimentally obtained spherical CuNPs, Mie theory was applied. A stability study of the synthesized CuNPs in optimal conditions was performed using UV–Vis analysis at specific time intervals (1, 3, 30 and 60 days), the sample being kept in the dark, inside a drawer at 25 °C. The CuNPs obtained after setting the optimal synthesis parameters (Cu(II):TSC:${\mathrm{B}\mathrm{H}}_4^{+}$ = 1:1:0.2, pH = 5, homogenization time 60 min and temperature 25 °C) were then tested to highlight their antibacterial effect on some reference bacterial strains. The obtained CuNPs demonstrated very good antimicrobial efficacy compared to traditional antimicrobials, for both Gram-negative and Gram-positive bacteria. This may reduce the development of antimicrobial resistance, an urgent medical issue. After evaluating the cytotoxic effects of CuNPs on the SKBR3 cancer cell line, a significant decrease in cell proliferation was observed at the 0.5 mg/mL concentration, with a reduction of 89% after 60 h of cultivation. Higher concentrations of CuNPs induced a more rapid cytotoxic effect, leading to an accelerated decline in cell viability. Full article

The relativistic jets of gamma-ray bursts (GRBs) might be powered by a black-hole (BH) hyperaccretion system. The inherent asymmetry in these jets generates recoil forces, inducing oscillations and positional deviations of the BH from equilibrium. In this study, we explore the influence of different initial BH mass, spin, and mass accretion rate, as well as their evolutions on the dynamical properties of BH under the effect of asymmetric jets. Our results reveal that the initial mass and accretion rate significantly impact the BH’s acceleration, velocity, and displacement, while the different initial spin plays a negligible role in shaping the overall dynamical evolution. Additionally, we calculate the gravitational wave (GW) strains associated with the asymmetric jets, finding that the resulting GW signals are too weak to be detected, even for nearby GRBs. These findings provide critical insights into the dynamical response of BHs to asymmetric jets and the associated GW radiation, advancing our understanding of BH physics in GRBs. Full article

CoFe-based catalysts have shown excellent activity for the oxygen evolution reaction (OER), with the oxidation states of the active sites playing a crucial role in determining catalytic performance. However, how to effectively increase the oxidation state of these active sites remains a key challenge. In this work, a facile treatment with NaBH₄ solution was employed to modulate the surface state of CoFeO_xH_y catalysts, inducing an enhanced OER activity. The overpotential at 10 mA cm⁻² for the NaBH₄-treated CoFe catalyst was reduced to 270 mV, indicating improved OER activity. X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS) results reveal that NaBH₄ treatment induced a phase reconstruction of the CoFe oxalate framework, a critical step in enhancing its catalytic properties. The strong reducing ability of NaBH₄ strengthened the Co-Fe interaction, allowing the retention of low-valence Co species while facilitating the formation of high-valence Fe sites. This dual modulation of Co and Fe oxidation states significantly accelerated charge transfer kinetics, ultimately boosting OER performance. These findings highlight the importance of improving the oxidation states of active sites in CoFe-based catalysts, providing insights for developing efficient catalysts for electrochemical water splitting. Full article

Urea shows promise as an alternative substrate to water oxidation in electrolyzers, and replacing OER with the Urea Oxidation Reaction (UOR, theoretical potential of 0.37 V vs. RHE) can significantly increase hydrogen production efficiency. Additionally, the decomposition of urea can help reduce environmental pollution. This paper improves the inherent activity of catalytic materials through morphology and electronic modulation by incorporating tungsten (W), which accelerates electron transfer, enhances the electronic structure of neighboring atoms to create a synergistic effect, and regulates the adsorption process of active sites and intermediates. NiCoW catalytic materials with an ultra-thin nanosheet structure were prepared using an ultrasonic-assisted NaBH₄ reduction method. The results show that during the OER process, NiCoW catalytic materials have a potential of only 1.53 V at a current density of 10 mA/cm², while the UOR process under the same conditions requires a lower potential of 1.31 V, demonstrating superior catalytic performance. In a mixed electrolyte of 1 M KOH and 0.5 M urea, overall water splitting also shows excellent performance. Therefore, the designed NiCoW electrocatalyst, with its high catalytic activity, provides valuable insights for enhancing the efficiency of water electrolysis for hydrogen production and holds practical research significance. Full article

We analyze a rotating black hole (BH) in a four-dimensional space-time embedded in five-dimensional flat bulk. In Boyer–Lindquist coordinates, we use a generic extension of the Kerr metric by the line element of Gürses–Gürsey metric. We discuss their horizon properties and shadow cast which is tailored by the influence of the extrinsic curvature. By means of the model based on the Nash–Greene theorem, we analyze the Gürses–Gürsey metric embedded in five dimensions acting as a rotating “charged” BH which may be regarded as a source of ultrahigh-energy cosmic rays (UHECRs). We also show that this type of BH presents a different structure of the accretion disk which is modified by the extrinsic curvature leading to an enlargement of the photons ring and an increase in the BH’s inner shadow. In the presence of a magnetic field, our initial results suggest that such BHs may be efficient free-test particle accelerators orbiting the inner stable circular orbit (ISCO). Full article

The dimensional accuracy and microstructure affect the service performance of parts fabricated by wire arc additive manufacturing (WAAM). Regulating the geometry and microstructure of such parts presents a challenge. The coupling method of an artificial neural network and finite element (FE) is proposed in this research for this purpose. Back-propagating neural networks (BPNN) based on optimization algorithms were established to predict the bead width (BW) and height (BH) of the deposited layers. Then, the bead geometry was modeled based on the predicted dimension, and 3D FE heat transfer simulation was performed to investigate the evolution of temperature and microstructure. The results showed that the errors in BW and BH were less than 6%, and the beetle antenna search BPNN model had the highest prediction accuracy compared to the other models. The simulated melt pool error was less than 5% with the experimental results. The decrease in the ratio of the temperature gradient and solidification rate induced the transition of solidified grains from cellular crystals to columnar dendrites and then to equiaxed dendrites. Accelerating the cooling rate increased the primary dendrite arm spacing and δ-ferrite content. These results indicate that the coupling model provides a pathway for regulating the dimensions and microstructures of manufactured parts. Full article

The accelerated expansion of the Universe is impressively well described by a cosmological constant. However, the observed value of the cosmological constant is much smaller than expected based on quantum field theories. Recent efforts to achieve consistency in these theories have proposed a relationship between Dark Energy and the most compact objects, such as black holes (BHs). However, experimental tests are very challenging to devise and perform. In this article, we present a testable model with no cosmological constant in which the accelerated expansion can be driven by black holes. The model couples the expansion of the Universe (the Friedmann equation) with the mass function of cosmological halos (using the Press–Schechter formalism). Through the observed link between halo masses and BH masses, one thus gets a coupling between the expansion rate of the Universe and the BHs. We compare the predictions of this simple BH model with SN1a data and find poor agreement with observations. Our method is sufficiently general to allow us to also test a fundamentally different model, also without a cosmological constant, where the accelerated expansion is driven by a new force proportional to the internal velocity dispersion of galaxies. Surprisingly enough, this model cannot be excluded using the SN1a data. Full article