Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (80)

Search Parameters:
Keywords = UHMWPE fibers

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
19 pages, 5806 KB  
Article
Ballistic Failure Analysis of Hybrid Natural Fiber/UHMWPE-Reinforced Composite Plates Using Experimental and Finite Element Methods
by Eduardo Magdaluyo, Ariel Jorge Payot, Lorenzo Matilac and Denisse Jonel Pavia
J. Manuf. Mater. Process. 2026, 10(1), 33; https://doi.org/10.3390/jmmp10010033 - 13 Jan 2026
Viewed by 313
Abstract
This study evaluated the ballistic performance and failure mechanisms of epoxy-based hybrid laminates reinforced with abaca/UHMWPE and pineapple leaf fiber (PALF)/UHMWPE fabrics fabricated by using vacuum-assisted hand lay-up. Ballistic tests utilized 9 mm full metal jacket (FMJ) rounds (~426 m/s impact velocity) under [...] Read more.
This study evaluated the ballistic performance and failure mechanisms of epoxy-based hybrid laminates reinforced with abaca/UHMWPE and pineapple leaf fiber (PALF)/UHMWPE fabrics fabricated by using vacuum-assisted hand lay-up. Ballistic tests utilized 9 mm full metal jacket (FMJ) rounds (~426 m/s impact velocity) under NIJ Standard Level IIIA conditions (44 mm maximum allowable BFS). This experimental test was complemented by finite element analysis (FEA) incorporating an energy-based bilinear fracture criterion to simulate matrix cracking and fiber pull-out. The results showed that abaca/UHMWPE composites exhibited lower backface signature (BFS) and depth of penetration (DOP) values (~23 mm vs. ~42 mm BFS; ~7 mm vs. ~9 mm DOP) than PALF/UHMWPE counterparts, reflecting superior interfacial adhesion and more ductile failure modes. Accelerated weathering produced matrix microcracking and delamination in both systems, reducing overall ballistic resistance. Scanning electron microscopy confirmed improved fiber–matrix bonding in abaca composites and interfacial voids in PALF laminates. The FEA results reproduced major failure modes, such as delamination, fiber–matrix debonding, and petaling, and identified stress concentration zones that agreed with experimental observations, though the extent of delamination was slightly underpredicted. Overall, the study demonstrated that abaca/UHMWPE hybridcomposites offer enhanced ballistic performance and durability compared with PALF/UHMWPE laminates, supporting their potential as sustainable alternatives for lightweight protective applications. Full article
Show Figures

Figure 1

22 pages, 4661 KB  
Article
Investigation of Constant Shear Rate and Sample Configuration for Shear Characterization of a UHMWPE Unidirectional Cross-Ply Material System
by Kari D. White and James A. Sherwood
J. Compos. Sci. 2025, 9(12), 685; https://doi.org/10.3390/jcs9120685 - 10 Dec 2025
Viewed by 385
Abstract
In-plane shear is the dominant deformation mode during thermoforming of fiber-reinforced composites, and accurate characterization of shear behavior is essential for reliable forming simulations. The present work investigates the shear response of a unidirectional cross-ply UHMWPE material system (DSM Dyneema® HB210) using [...] Read more.
In-plane shear is the dominant deformation mode during thermoforming of fiber-reinforced composites, and accurate characterization of shear behavior is essential for reliable forming simulations. The present work investigates the shear response of a unidirectional cross-ply UHMWPE material system (DSM Dyneema® HB210) using the picture-frame test, with emphasis on sample configuration, normalization methods, and shear rate effects. Three cruciform sample sizes were tested at 120 °C, along with a configuration in which cross-arm material was removed to isolate the gage region. Finite element analyses using LS-DYNA® were performed to evaluate the shear rate distribution during forming and to validate the experimental characterization. To maintain a constant shear rate during testing, a decreasing crosshead speed profile was implemented in the test software. Results showed that normalizing by the full specimen area yielded consistent shear stiffness curves across sample sizes, indicating that the arm region contributes equally to the load. Samples with cross-arm material removed exhibited greater scatter than those specimens without cross-arm material removed, confirming that preparation of cross-arm removal complicates repeatability. Rate dependence was observed at room temperature but not at elevated processing temperatures, suggesting that rate-dependent shear models are unnecessary for forming simulations of this material system. These findings provide a practical methodology for shear characterization of UHMWPE cross-ply laminates suitable for thermoforming analyses. Full article
Show Figures

Figure 1

17 pages, 5734 KB  
Article
Experimental Investigation of Equivalent Friction Coefficient Between Rope–Drum Mechanism and Pulley Transmission Loss for High-Altitude Wind Power Generation Systems
by Dong Liang, Wei Shuai, Ao Song, Xiangyang Xu, Hanjie Jia and Jiayuan Luo
Energies 2025, 18(23), 6079; https://doi.org/10.3390/en18236079 - 21 Nov 2025
Viewed by 564
Abstract
This paper presents the design and experimental investigation of a multifunctional friction test bench, aiming to characterize the frictional and transmission efficiency of rope–drum systems in high-altitude wind power generation. The study addresses a critical gap in the experimental validation of key components [...] Read more.
This paper presents the design and experimental investigation of a multifunctional friction test bench, aiming to characterize the frictional and transmission efficiency of rope–drum systems in high-altitude wind power generation. The study addresses a critical gap in the experimental validation of key components for this demanding application. The test bench, comprising loading, power, test, and data acquisition modules, was designed to measure the equivalent friction coefficient (a comprehensive macro-parameter, not the traditional material friction coefficient) between an ultra-high-molecular-weight polyethylene (UHMWPE) fiber rope and a drum, as well as the transmission efficiency of pulleys. Key parameters, including contact angle, gasket material (steel vs. polyamide (PA)), groove type (U vs. V), and rotational speed, were systematically tested using tension and speed and torque sensors for data acquisition. Experimental results show that the equivalent friction coefficient initially increased and then decreased with the contact angle, reaching a maximum of approximately 0.15 at 100°. The coefficient was positively correlated with rotational speed, increasing by about 40% for steel and 10% for PA linings as speed rose from 25 to 100 rpm. Steel linings exhibited a significantly higher equivalent friction coefficient (0.14–0.17) than PA linings (0.10–0.13). Similarly, in transmission tests, steel pulleys demonstrated superior efficiency compared to PA pulleys, while V-grooves slightly reduced efficiency compared to U-grooves. Furthermore, pulley misalignment was found to decrease transmission efficiency. This work provides essential experimental data and a robust testing platform, laying a foundation for optimizing the efficiency and reliability of high-altitude wind energy systems. Full article
(This article belongs to the Section A3: Wind, Wave and Tidal Energy)
Show Figures

Figure 1

21 pages, 4727 KB  
Article
The Effect of Material Arrangement Order on Ballistic Resistance of Ceramic Composite Armor Structure
by Yu Liang Chen, Cheng Kun Chu and Ya Chih Chang
Solids 2025, 6(4), 64; https://doi.org/10.3390/solids6040064 - 17 Nov 2025
Viewed by 1309
Abstract
This study investigates the ballistic performance and energy-absorption behavior of advanced multilayer ceramic composite armor systems composed of silicon carbide (SiC) ceramics, composite metal foam (CMF), rolled homogeneous armor (RHA), ultra-high-molecular-weight polyethylene (UHMWPE), aluminum, and rubber interlayers. The objective is to enhance impact [...] Read more.
This study investigates the ballistic performance and energy-absorption behavior of advanced multilayer ceramic composite armor systems composed of silicon carbide (SiC) ceramics, composite metal foam (CMF), rolled homogeneous armor (RHA), ultra-high-molecular-weight polyethylene (UHMWPE), aluminum, and rubber interlayers. The objective is to enhance impact resistance and optimize energy dissipation efficiency against armor-piercing (AP) projectiles. Ballistic tests were performed following the NIJ Standard 0101.06 Level IV specifications using .30” caliber AP M2 rounds with an impact velocity of 784–844 m/s. Experimental results revealed that the SiC front layer effectively fragmented the projectile and dispersed its kinetic energy, while the CMF and UHMWPE layers were the primary energy absorbers, dissipating approximately 70% of the total impact energy (≈3660 J). The aluminum and RHA layers provided additional reinforcement, and the rubber interlayer significantly reduced stress-wave propagation and suppressed crack growth in the ceramic. The most efficient configuration 0.5 mm RHA + 7 mm SiC + 7 mm EPDM + 7 mm CMF + 5 mm UHMWPE achieved an areal density absorption of 77.2 J·m2/kg and a unit thickness absorption of 190.6 J/mm. These findings establish a quantitative layer-wise energy dissipation framework, highlighting the synergistic interaction between brittle, porous, and ductile layers. This work provides practical design principles for developing lightweight, high-efficiency composite armor systems applicable to defense, aerospace, and personal protection fields. Moreover, this study not only validates the NIJ Standard 0101.06 ballistic performance experimentally but also establishes a reproducible methodology for quantitative, layer-wise energy analysis of hybrid ceramic-CMF-fiber armor systems, offering a scientific framework for future model calibration and optimization. Full article
Show Figures

Graphical abstract

18 pages, 4680 KB  
Article
Multi-Objective Optimization Design of Hybrid Fiber-Reinforced ECC Based on Box–Behnken and NSGA-II
by Xiao Wang, Haowen Jing, Hongkui Chen, Sen Zheng, Fei Yang and Jinggan Shao
Materials 2025, 18(21), 4914; https://doi.org/10.3390/ma18214914 - 27 Oct 2025
Viewed by 596
Abstract
To enhance the effectiveness and precision of design and to produce more low-carbon and high-performance Engineered Cementitious Composites (ECCs), novel hybrid fiber-reinforced high-ductility cementitious composites developed by incorporating a combination of ultra-high-molecular-weight polyethylene fibers (UHMWPE) and basalt fibers (BFs) into the cementitious matrix. [...] Read more.
To enhance the effectiveness and precision of design and to produce more low-carbon and high-performance Engineered Cementitious Composites (ECCs), novel hybrid fiber-reinforced high-ductility cementitious composites developed by incorporating a combination of ultra-high-molecular-weight polyethylene fibers (UHMWPE) and basalt fibers (BFs) into the cementitious matrix. Building upon the Box–Behnken design model from Response Surface Methodology (RSM), this study investigates the effects of different water-to-binder ratios and fiber contents on the mechanical properties of hybrid fiber-reinforced ECC. Analysis of variance (ANOVA) was used to validate the regression models. Furthermore, multi-objective optimization of the ECC mix proportion was achieved by employing the NSGA-II algorithm in conjunction with the TOPSIS comprehensive evaluation method. The results indicate that UHMWPE and BFs exhibited a significant positive hybrid effect. The order of factor significance was as follows: The content of ultra-high-molecular-weight polyethylene is greater than that of basalt fiber, and the content of basalt fiber is greater than that of the water–binder ratio. The results of variance analysis show that the regression model has high fitting accuracy. Furthermore, the algorithmic optimization yielded an optimal mix proportion: a water-to-binder ratio of 0.21, UHMWPE fiber content of 1.51%, and BF content of 0.85%. This study provides a valuable reference for the multi-objective optimization design of ECC mix proportions targeting diverse strength and toughness requirements. Full article
(This article belongs to the Section Construction and Building Materials)
Show Figures

Figure 1

25 pages, 15459 KB  
Article
Effect of Fiber Type on the Thermomechanical Performance of High-Density Polyethylene (HDPE) Composites with Continuous Reinforcement
by José Luis Colón Quintana, Scott Tomlinson and Roberto A. Lopez-Anido
J. Compos. Sci. 2025, 9(8), 450; https://doi.org/10.3390/jcs9080450 - 20 Aug 2025
Viewed by 2065
Abstract
The thermal, thermomechanical, and viscoelastic properties of continuous unidirectional (UD) glass fiber/high-density polyethylene (GF/HDPE) and ultra-high-molecular-weight polyethylene/high-density polyethylene (UHMWPE/HDPE) tapes are characterized in this paper in order to support their use in extreme environments. Unlike prior studies that focus on short-fiber composites or [...] Read more.
The thermal, thermomechanical, and viscoelastic properties of continuous unidirectional (UD) glass fiber/high-density polyethylene (GF/HDPE) and ultra-high-molecular-weight polyethylene/high-density polyethylene (UHMWPE/HDPE) tapes are characterized in this paper in order to support their use in extreme environments. Unlike prior studies that focus on short-fiber composites or limited thermal conditions, this work examines continuous fiber architectures under five operational environments derived from Army Regulation 70-38, reflecting realistic defense-relevant extremes. Differential scanning calorimetry (DSC) was used to identify melting transitions for GF/HDPE and UHMWPE/HDPE, which guided the selection of test conditions for thermomechanical analysis (TMA) and dynamic mechanical analysis (DMA). TMA revealed anisotropic thermal expansion consistent with fiber orientation, while DMA, via strain sweep, temperature ramp, frequency sweep, and stress relaxation, quantified their temperature- and time-dependent viscoelastic behavior. The frequency-dependent storage modulus highlighted multiple resonant modes, and stress relaxation data were fitted with high accuracy (R2 > 0.99) to viscoelastic models, yielding model parameters that can be used for predictive simulations of time-dependent material behavior. A comparative analysis between the two material systems showed that UHMWPE/HDPE offers enhanced unidirectional stiffness and better low-temperature performance. At the same time, GF/HDPE exhibits lower thermal expansion, better transverse stiffness, and greater stability at elevated temperatures. These differences highlight the impact of fiber type on thermal and mechanical responses, informing material selection for applications that require directional load-bearing or dimensional control under thermal cycling. By integrating thermal and viscoelastic characterization across realistic operational profiles, this study provides a foundational dataset for the application of continuous fiber thermoplastic tapes in structural components exposed to harsh thermal and mechanical conditions. Full article
Show Figures

Figure 1

26 pages, 14840 KB  
Article
Experimental Investigation of Ultra-High Molecular Weight Polyethylene Fibers and Fabric for Flexural Reinforcement in Ultra-High-Performance Concrete
by Zengrui Pan, Faning Dang, Rabin Tuladhar, Shi Yin, Feng Shi, Peter To and Zisheng Tang
Materials 2025, 18(9), 2002; https://doi.org/10.3390/ma18092002 - 28 Apr 2025
Cited by 1 | Viewed by 1179
Abstract
This study investigates the use of Ultra-High Molecular Weight Polyethylene (UHMWPE) fibers and fabric to enhance the flexural performance of Ultra-High-Performance Concrete (UHPC). A total of 45 specimens were tested to examine the effects of fiber type, fabric material, adhesive, and various combined [...] Read more.
This study investigates the use of Ultra-High Molecular Weight Polyethylene (UHMWPE) fibers and fabric to enhance the flexural performance of Ultra-High-Performance Concrete (UHPC). A total of 45 specimens were tested to examine the effects of fiber type, fabric material, adhesive, and various combined strengthening techniques. The main findings are that incorporating UHMWPE fiber into the ultra-high-strength mortar (HSM) matrix provides superior performance compared to steel fiber, particularly in enhancing crack resistance and energy absorption. UHMWPE fiber-reinforced UHPC achieved a flexural toughness of 307 KJ/m3, over three times higher than that of steel fiber-reinforced UHPC (98 KJ/m3). The use of UHMWPE fabrics was more effective in improving the ductility and toughness of the composites than the use of glass fabrics. The bonding effect of using epoxy resin with UHMWPE fabric is better than using magnesium phosphate cement (MPC). Increasing the number of fabric layers improved the flexural properties of externally bonded fabric but had no impact on internal reinforcement techniques. The best strengthening method in this study was a combination of incorporating UHMWPE fiber internally and externally bonded fabric on a concrete surface, yielding the highest toughness of 580 KJ/m3. Full article
(This article belongs to the Special Issue Study on Mechanical Properties of Concrete Structures and RC Beams)
Show Figures

Figure 1

12 pages, 10201 KB  
Article
Effect of Resin Parameters on the Consistency and Mechanical Properties of Ultra-High-Molecular-Weight Polyethylene Fiber
by Cheng Yan, Tiantian Yan, Tianhong Dong, Mingxin Xia, Yumin Xia and Yong He
Polymers 2025, 17(8), 1109; https://doi.org/10.3390/polym17081109 - 19 Apr 2025
Viewed by 1265
Abstract
Maintaining the consistency of linear density in ultra-high-molecular-weight polyethylene (UHMWPE) fiber has been a critical challenge in the production of UHMWPE fibers. However, there has been limited research focusing on the impact of UHMWPE resin parameters on the consistency in fiber linear density. [...] Read more.
Maintaining the consistency of linear density in ultra-high-molecular-weight polyethylene (UHMWPE) fiber has been a critical challenge in the production of UHMWPE fibers. However, there has been limited research focusing on the impact of UHMWPE resin parameters on the consistency in fiber linear density. In this study, a series of UHMWPE fibers were produced through wet spinning using UHMWPE resins with varying parameters. The effects of molecular weight, molecular weight distribution, particle size, and particle size distribution of UHMWPE resins on the consistency of linear density and the mechanical properties of UHMWPE fibers were systematically investigated. The experimental findings revealed that narrowing the molecular weight distribution and particle size distribution of ultra-high molecular weight polyethylene (UHMWPE) resin precursors significantly enhanced the consistency of resultant UHMWPE fibers, concurrently improving their tensile strength and elastic modulus. Notably, while the absolute molecular weight of the resin demonstrated no statistically significant correlation with fiber consistency, an optimal molecular weight range was identified to maximize the mechanical performance of UHMWPE fibers. Specifically, fibers synthesized from resin precursors within this molecular weight window exhibited peak values in both strength and modulus, suggesting a critical balance between molecular chain entanglement and processability. Full article
(This article belongs to the Section Polymer Analysis and Characterization)
Show Figures

Figure 1

20 pages, 19814 KB  
Article
Cutting Feature Extraction Method for Ultra-High Molecular Weight Polyethylene Fiber-Reinforced Concrete Based on Feature Classification and Improved Hilbert–Huang Transform
by Shanshan Hu, Jinzhao Feng, Hui Liu, Guoxin Tang, Geng’e Zhang, Fali Xiong, Shirun Zhong and Yilong Huang
Buildings 2025, 15(8), 1272; https://doi.org/10.3390/buildings15081272 - 13 Apr 2025
Viewed by 784
Abstract
Ultra-high molecular weight polyethylene (UHMWPE) fiber-reinforced concrete (UHMWPE-FRC) is a hard–soft multiphase hybrid composite with exceptional toughness and impact resistance compared to conventional concrete. However, its cutting characteristics and processing performance have not been sufficiently investigated, potentially causing accelerated saw blade wear, higher [...] Read more.
Ultra-high molecular weight polyethylene (UHMWPE) fiber-reinforced concrete (UHMWPE-FRC) is a hard–soft multiphase hybrid composite with exceptional toughness and impact resistance compared to conventional concrete. However, its cutting characteristics and processing performance have not been sufficiently investigated, potentially causing accelerated saw blade wear, higher energy consumption, and poor cutting quality, thus increasing project costs and duration. In order to intelligently evaluate the performance of diamond saw blades when cutting UHMWPE-FRC, a feature extraction method, based on feature classification and an improved Hilbert–Huang transform (HHT), is proposed, which consider Improved Complete Ensemble Empirical Mode Decomposition with Adaptive Noise (ICEEMDAN) and wavelet threshold de-noising. By conducting the cutting experiments, the cutting force was analyzed by the improved HHT, in terms of noise reduction and time-frequency. Five types of characteristics were preliminarily screened, including depth of cut (ap), cutting speed (Vc), feed rate (Vf), concrete strength, and the type of concrete. A feature correlation analysis method for UHMWPE-FRC cutting, based on feature classification, is proposed. The five features were classified into continuous variable features and unordered categorical variable features; correlation analyses were carried out by Spearman correlation coefficient testing and Kruskal–Wallis and Dunn’s testing, respectively. It was found that the ap and concrete strength exhibited a strong positive correlation with cutting force, making them the primary influencing factors. Meanwhile, the influence of aggregates on cutting force can be identified in the low-frequency range, while the influence of fibers can be identified in the high-frequency range. The feature classification-based correlation analysis effectively distinguishes the influence of Vc on cutting force. Full article
(This article belongs to the Section Building Structures)
Show Figures

Figure 1

21 pages, 11881 KB  
Article
Analysis of Water-Based Polyurethane Properties in the Ballistic Behavior of Ultra-High Molecular Weight Polyethylene Fiber Composites
by Shuhao Yang, Shumao Zhai, Mingxing Piao, Xiao Wang, Haofei Shi and Chaolong Li
Polymers 2025, 17(7), 837; https://doi.org/10.3390/polym17070837 - 21 Mar 2025
Cited by 1 | Viewed by 2303
Abstract
The ballistic performance of fiber-reinforced polymer composites (FRPC) is influenced by the adhesive’s mechanical properties, such as stiffness, toughness, and energy dissipation. However, the specific contributions of these properties remain unclear. This study explores how varying the hard segment (HS) content in water-based [...] Read more.
The ballistic performance of fiber-reinforced polymer composites (FRPC) is influenced by the adhesive’s mechanical properties, such as stiffness, toughness, and energy dissipation. However, the specific contributions of these properties remain unclear. This study explores how varying the hard segment (HS) content in water-based polyurethane (WPU) impacts the thermal, mechanical, and ballistic performance of FRPCs. By increasing HS content, the storage modulus and tensile strength of WPU improved, while elongation at break decreased, transitioning the adhesive from soft and ductile to rigid and brittle. Quasi-static tests, ballistic experiments, and SEM analysis were conducted on UHMWPE fiber-reinforced WPU-HS% composites. Results reveal that adhesives with high hardness and modulus hinder fiber deformation, reducing energy dissipation and causing severe delamination, which diminishes ballistic performance. Conversely, soft and ductile adhesives allow deformation alongside fibers during bullet impact, suppress delamination, and absorb more kinetic energy while transferring load. Among the tested formulations, WPU with 45% HS content exhibited the best balance of mechanical properties, achieving the most significant improvement in ballistic performance by enhancing energy absorption and minimizing damage. This study establishes a clear relationship between WPU properties and composite protective behavior, providing insights for designing high-performance ballistic materials. Full article
(This article belongs to the Section Polymer Analysis and Characterization)
Show Figures

Figure 1

14 pages, 3160 KB  
Article
Influence of Fabric Characteristics on Mechanical Performances of Protective Gloves
by Ali Afzal, Shahbaz Ahmad, Sheraz Ahmad, Muhammad Irfan, Liliana Indrie, Faheem Ahmad and Mariana Rațiu
Coatings 2025, 15(3), 285; https://doi.org/10.3390/coatings15030285 - 28 Feb 2025
Viewed by 1911
Abstract
In this study, high-performance gloves were developed from core–sheath yarn. Different materials were used in the core, while Kevlar fibers were used in the sheath. The filaments used in the core included glass, ultra-high-molecular-weight polyethylene (UHMWPE), and stainless steel filaments with 100D and [...] Read more.
In this study, high-performance gloves were developed from core–sheath yarn. Different materials were used in the core, while Kevlar fibers were used in the sheath. The filaments used in the core included glass, ultra-high-molecular-weight polyethylene (UHMWPE), and stainless steel filaments with 100D and 200D linear densities. Seamless gloves were developed from these yarns with varying characteristics to observe their effect on the performance of seamless gloves. The factors examined were the areal density (GSM) of the gloves, linear density of sheath fibers, core material, and plied structure. The mechanical behavior of the gloves was evaluated by different tests such as blade cut resistance, coupe cut resistance, tear resistance, and puncture resistance. The results demonstrated that the sheath fiber characteristics, core material type, yarn’s plied structure, and fabric’s areal density are statistically significant factors affecting the properties of gloves in relation to mechanical risk. The selection of appropriate levels of these parameters is crucial for better achievement of desired properties in workwear protection applications. Full article
Show Figures

Figure 1

31 pages, 6533 KB  
Article
Enhancing Interfacial Adhesion in Kevlar and Ultra-High Molecular Weight Polyethylene Fiber-Reinforced Laminates: A Comparative Study of Surface Roughening, Plasma Treatment, and Chemical Functionalization Using Graphene Nanoparticles
by Feyi Adekunle, Jan Genzer and Abdel-Fattah M. Seyam
Fibers 2025, 13(2), 19; https://doi.org/10.3390/fib13020019 - 11 Feb 2025
Cited by 6 | Viewed by 3515
Abstract
This study investigates the impact of mechanical and chemical surface treatments on the interfacial adhesion and mechanical properties of Kevlar and ultra-high molecular weight polyethylene (UHMWPE) fiber-reinforced laminates (FRLs). Various treatments, including surface roughening, plasma exposure, NaOH and silane coupling, and graphene nanoparticle [...] Read more.
This study investigates the impact of mechanical and chemical surface treatments on the interfacial adhesion and mechanical properties of Kevlar and ultra-high molecular weight polyethylene (UHMWPE) fiber-reinforced laminates (FRLs). Various treatments, including surface roughening, plasma exposure, NaOH and silane coupling, and graphene nanoparticle (NP) incorporation, were conducted to enhance the fiber–matrix bonding within thermoplastic polyurethane (TPU) and ethylene-vinyl acetate (EVA) matrices. Results demonstrated that treatment efficacy highly depends on fiber type and matrix material, with chemical modifications generally outperforming the physical treatment (surface roughness). Plasma treatment significantly enhanced adhesion for UHMWPE, increasing yarn pullout force by 188.1% with TPU. While combining plasma with graphene slightly improved performance, it did not exceed plasma-only results due to potential surface functionalization losses during wet graphene application. For Kevlar, the combination of NaOH, silane, and graphene NP (NSG) treatment yielded the highest adhesion, showing increases of 76.6% with TPU and 95.4% with EVA, underscoring the synergy between chemical coupling and nanomaterial reinforcement. This study’s insights align with previous research, expanding the knowledge base by investigating graphene’s role independently and alongside established methods. Full article
Show Figures

Figure 1

19 pages, 5154 KB  
Review
Single-Site Catalyst for the Synthesis of Disentangled Ultra-High-Molecular-Weight Polyethylene
by Jian Chen, Shuzhang Qu, Xinwei Li, Yiming Wei, Qian Li, Zhao Wen and Zifang Guo
Polymers 2025, 17(1), 95; https://doi.org/10.3390/polym17010095 - 1 Jan 2025
Cited by 3 | Viewed by 2762
Abstract
Disentangled ultra-high-molecular-weight polyethylene (d-UHMWPE) solves the problem of the difficult processing of traditional UHMWPE caused by entanglements between molecular chains. In this review, we look into the innovative realm of nascent disentangled UHMWPE, concentrating on the recent advances achieved through the [...] Read more.
Disentangled ultra-high-molecular-weight polyethylene (d-UHMWPE) solves the problem of the difficult processing of traditional UHMWPE caused by entanglements between molecular chains. In this review, we look into the innovative realm of nascent disentangled UHMWPE, concentrating on the recent advances achieved through the in situ polymerization of ethylene by single-site catalysts. The effect of single-site catalysts and polymerization conditions on the molecular characteristics is discussed in detail from the perspective of mechanism and DFT calculations. The key factors to low entanglement are revealed, which have instructive implications for the development of new single-site catalytic systems that can generate d-UHMWPE more efficiently and become closer to industrial production. The progress in the preparation for nascent d-UHMWPE with homogeneous and heterogeneous single-site catalysts is systematically reviewed. Rheology and DSC can be used to characterize the degree of entanglement. High-modulus and high-strength biaxial films, tapes, and fibers are obtained by the solid-state processing of these nascent d-UHMWPE. Full article
(This article belongs to the Section Polymer Chemistry)
Show Figures

Figure 1

20 pages, 4196 KB  
Article
In Situ Polymerization and Synthesis of UHMWPE/Carbon Fiber Composites
by Elena Fedorenko and Gerrit A. Luinstra
Polymers 2025, 17(1), 90; https://doi.org/10.3390/polym17010090 - 1 Jan 2025
Cited by 4 | Viewed by 2727
Abstract
Carbon-fiber-reinforced composites of ultra-high-molecular-weight polyethylene (UHMWPE) are not easily prepared because of their high viscosity, although they can be advantageous in advanced engineering applications due to their superior mechanical properties in combination with their low specific weight and versatility. Short polyacrylonitrile-based carbon-fiber-reinforced UHMWPE [...] Read more.
Carbon-fiber-reinforced composites of ultra-high-molecular-weight polyethylene (UHMWPE) are not easily prepared because of their high viscosity, although they can be advantageous in advanced engineering applications due to their superior mechanical properties in combination with their low specific weight and versatility. Short polyacrylonitrile-based carbon-fiber-reinforced UHMWPE composites with fiber contents of 5, 10, and 15 wt.% could easily be prepared using in situ ethylene polymerization. Therefore, MgCl2 was generated at the Brønsted acidic groups of the fiber surface by employing a reaction between the co-catalysts Mg(C4H9)2 and AlEt2Cl. Titanation with TiCl4 resulted in a catalyst directly on the fiber surface. The catalyst polymerized ethylene (2 bar pressure at 50 °C), forming a UHMWPE matrix near the surface; its fragmentation led to polymer particles associated with the fiber. The catalyst activity on the fiber surface of untreated (CF-Pr, 3.48 ± 0.24 wt.%) and oxidized fibers (CF-Ox, 7.41 ± 0.03 wt.%) was 20% lower. CF-Pr compression-molded samples showed tensile strengths of up to 50.4 ± 1.3 MPa, while CF-Ox samples reached 39.1 ± 0.6 MPa, surpassing the performance of composites prepared by melt compounding. The stiffness of 1.58 ± 0.17 GPa for a melt-compounded material was lower than the 3.24 ± 0.10 GPa for CF-Pr and 2.19 ± 0.07 GPa for CF-Ox composites. A fracture examination showed fiber pull-outs, matrix residues on the fibers, and the formation of some extensional polymer fibrils. The latter explains the higher stress at yield and the breakage of the CF-Pr based composites in particular. The potential of in situ polymerized UHMWPE composites for the utilization in high-performance structural applications is thus demonstrated. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
Show Figures

Figure 1

15 pages, 6889 KB  
Article
Quaternized and Hyperbranched Amidoxime-Modified Ultra-High-Molecular-Weight Polyethylene Fiber for Uranium Extraction from Seawater
by Lijun Hu, Hongwei Han, Xuanzhi Mao, Xinxin Feng, Yulong He, Jiangtao Hu and Guozhong Wu
Polymers 2024, 16(23), 3310; https://doi.org/10.3390/polym16233310 - 27 Nov 2024
Cited by 1 | Viewed by 1768
Abstract
The most promising material for uranium extraction from saltwater is generally acknowledged to be fibrous adsorbents. An irradiation-modified anti-biofouling ultra-high-molecular-weight polyethylene (UHMWPE-g-PGAO) fibrous adsorbent with a hyperbranched structure was synthesized. It exhibited adsorption capacities of 314.8 mg-U/g-Ads in aqueous solution and [...] Read more.
The most promising material for uranium extraction from saltwater is generally acknowledged to be fibrous adsorbents. An irradiation-modified anti-biofouling ultra-high-molecular-weight polyethylene (UHMWPE-g-PGAO) fibrous adsorbent with a hyperbranched structure was synthesized. It exhibited adsorption capacities of 314.8 mg-U/g-Ads in aqueous solution and 4.04 mg-U/g-Ads in simulated seawater over a 28-day period. The ultra-high-molecular-weight polyethylene (UHMWPE) fiber was functionalized by covalently linking hyperbranched polyethyleneimine (h-PEI) to facilitate the migration of uranyl ions within the fibers. Additionally, amidoxime and quaternary ammonium groups were immobilized on the fiber surface to enhance uranium affinity and provide defense against marine organisms. This three-dimensional design of amidoxime and h-PEI-modified UHMWPE fiber retained more than 91.0% of its maximum adsorption capacity after undergoing five adsorption-desorption cycles. The UHMWPE-g-PGAO adsorbent exhibits significant antibacterial activity against Escherichia coli and Staphylococcus aureus, achieving an inactivation efficiency of over 99.9%. It is proved to be an innovative fiber adsorbent for uranium extraction from seawater for its biofouling resistance, robustness, and reusability. Full article
Show Figures

Graphical abstract

Back to TopTop