Search Results (436)

The valorization of biomass waste into advanced electrode materials presents a promising pathway toward sustainable electrochemical energy storage. Herein, a silicon-doped carbon material (Si-CTS-Carbon) is synthesized from chitosan via an in situ reaction with silicon tetrachloride (SiCl₄) and subsequent controlled pyrolysis. When evaluated as an anode for lithium-ion batteries (LIBs), Si-CTS-Carbon exhibits a high reversible capacity of 509.2 mAh g⁻¹ with 99% capacity retention after 100 cycles at 0.05 A g⁻¹. For sodium-ion battery (SIB) applications, it achieves a stable reversible capacity of 155.4 mAh g⁻¹ under identical conditions. Structural and electrochemical analyses reveal that the robust C–O–Si covalent network effectively accommodates volume variation of silicon and enhances structural integrity during cycling. Furthermore, the hierarchically porous architecture shortens ion diffusion pathways, leading to improved Li⁺/Na⁺ transport kinetics. This work demonstrates a viable strategy for fabricating high-performance battery anodes by synergistically doping silicon into biomass-derived carbon, enabling practical biowaste valorization for energy storage. Full article

Under the conditions of laser power of 1500 W, scanning speed of 5 mm/s, spot diameter of 3.5 mm, and powder feeding rate of 10 r/min, this study systematically investigated the influence of different tempering temperatures (200 °C and 600 °C) on the microstructure, friction and wear properties, and corrosion resistance of laser cladding Ni25 coatings, as well as the underlying mechanisms. The phase composition, microstructure, chemical composition, wear resistance, and corrosion resistance of the coatings were characterized and analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), pin-on-disk friction and wear tests, and electrochemical workstations. The results showed that the as-clad coating was composed of γ-Ni supersaturated solid solution and various metastable borides/carbides (such as Cr₃B₄), presenting fine-grained and non-equilibrium features. Tempering at 200 °C mainly achieved stress relaxation, enhancing and shifting the diffraction peaks to the left without changing the phase composition, while tempering at 600 °C drove significant diffusion-type phase transformation, leading to the decomposition of metastable Cr₃B₄ and the precipitation of stable phases such as Ni₂Si, accompanied by grain growth and microstructure coarsening. Friction tests indicated that the coating tempered at 600 °C exhibited the lowest average friction coefficient (0.679) and wear volume (0.0582 mm³) due to stable microstructure and hard phase strengthening, demonstrating the best wear resistance. However, electrochemical tests revealed a “trade-off” effect: the fine-grained microstructure of the as-clad coating, with its uniform composition, had the lowest corrosion current density (8.10 × 10⁻⁵ A/cm²) in 3.5% NaCl solution, showing the best resistance to uniform corrosion, while tempering, especially at 600 °C, caused grain growth, coarsening of the second phase, and micro-galvanic effects, slightly reducing the anodic dissolution resistance and increasing the corrosion current. This study clarified that heat treatment can significantly enhance the mechanical and tribological properties of Ni25 coatings by regulating their transformation from metastable to stable states, but at the potential cost of some corrosion resistance, providing a theoretical basis for optimizing post-treatment processes for different service conditions (wear resistance or corrosion resistance). Full article

This study reports the room-temperature, one-pot, rapid alkalide reduction synthesis of germanium metal nanoparticles on multilayer graphene nanoshells (MGNSs) at a high yield (97%), as well as their electrochemical performance as a Li-ion battery anode. Ge metal’s theoretical gravimetric capacity is second only, and its volumetric capacity nearly equal, to that of Si which possesses the highest capacities of any lithium alloying metal. An MGNS is a carbon net-negative material composed of nested graphene sheets with high surface area, good electrical conductivity and excellent electrochemical stability. When cycling from 1.5 to 0.02 V vs. Li, a stable capacity of ~750 mAh/g Ge/MGNS composite electrode was obtained with an average capacity fade of 0.014% per cycle, maintaining 85% of the original capacity after 600 cycles. Full article

Achieving a balanced combination of mechanical performance and corrosion resistance remains a critical challenge restricting the broader application of Al–Zn–Mg–Cu alloys in aerospace, marine, and transportation industries. In this investigation, the addition of Si significantly enhances the mechanical properties of the alloy. Among them, the alloy containing 0.35Si has the best corrosion resistance, which is closely related to the transformation of precipitates. A non-monotonic relationship between Si content and corrosion resistance was observed. At low Si levels, the simultaneous precipitation of η, T, and GPB-II phases leads to a large electrochemical potential difference among these phases, which promotes micro-galvanic corrosion. With increasing Si content, the microstructure evolves toward the dominance of GPB-II precipitates, thereby reducing the internal potential difference and improving corrosion resistance. However, excessive addition of Si will lower the equilibrium solid phase temperature, resulting in overburning during the solid solution treatment process and a significant decrease in corrosion resistance. In addition, lowering the solution treatment temperature effectively improves corrosion resistance by suppressing the formation of remelted spheres and low-melting-point brittle phases along grain boundaries. These phases can form strong micro-galvanic couples with the matrix, accelerating anodic dissolution. Therefore, by adding an appropriate amount of Si and optimizing the solid solution temperature, a corrosion-resistant high-strength Al-Zn-Mg-Cu-Si alloy can be obtained. This strategy also provides a broader compositional and heat-treatment design window, which could be further expanded through the incorporation of rare-earth (RE) elements. Full article

In this study, first-principles calculations were employed to systematically investigate the adsorption of Cl⁻ on Al₂Cu(110) surfaces, clean Al(111)/Al₂Cu(110) interfaces, and Fe/Si-doped interfaces, as well as the influence of strain on interfacial electronic structure and corrosion activity. When Cl⁻ is adsorbed on Al sites, the bonding between Cl and Al exhibits strong ionic characteristics with localized charge transfer, while adsorption on Cu sites is characterized by more delocalized, covalent interactions. This competition dictates the site-dependent stability of adsorption. Through geometric–electronic synergy, the interface functions as both a “Cl⁻ enrichment zone” and an “activity source,” significantly favoring Cl⁻ adsorption at high-activity anodic sites such as Al-hole and Al-bridge. Conversely, Cu-top sites maintain a high work function and an inert cathodic nature, facilitating the formation of efficient micro-galvanic couples across the interface. Moreover, Fe/Si doping further modulates the interfacial electronic landscape: Si serves as an effective strengthening element due to its low substitution energy and high stability, while Fe primarily forms a solid solution on the Al side, potentially introducing galvanic corrosion risks. Stress analysis indicates that tensile strain systematically enhances surface activity by lowering the work function, while compressive strain non-monotonically influences corrosion through a three-stage mechanism involving the “densification–cracking–plastic relaxation” of the passive film. These findings elucidate the atomistic origins of corrosion initiation at Cu–Al composite interfaces and provide a theoretical foundation for enhancing corrosion resistance through alloy design and strain engineering. Full article

Silicon-based materials offer exceptional theoretical capacity for lithium-ion batteries (LIBs), but their practical application remains severely hindered by large volume expansion, low electrical conductivity, and unstable solid electrolyte interphase (SEI) formation during cycling. Herein, a binder-free silicon-containing carbon composite anode (denoted as CP-Si@C-4, where CP represents the conductive carbon paper substrate) is designed: carbon constitutes the structural and conductive framework, while silicon nanoparticles serve as a functional alloying component contributing characteristic lithiation/delithiation behavior. This framework comprises a conductive carbon paper (CP) scaffold, a resin-derived carbon matrix for homogeneous silicon dispersion, an interconnected carbon nanotube (CNT) network enabling long-range electron transport, and a conformal chemical vapor deposition (CVD) carbon layer for interfacial stabilization. Rather than simply increasing the overall carbon content, a series of control electrodes with distinct carbon configurations are deliberately designed to decouple the respective roles of bulk stress buffering and particle-level interfacial stabilization during cycling. The results indicate that functionally differentiating and coordinately regulating these two functions is critical for achieving durable binder-free silicon-containing carbon composite anodes. Benefiting from this cooperative multidimensional carbon architecture, the optimized CP-Si@C-4 anode delivers an initial Coulombic efficiency (ICE) of 86.3% and maintains a reversible capacity of ~990 mA h g⁻¹ at 2 A g⁻¹ after 1000 cycles. This work provides a structural design concept for improving long-term stability in binder-free silicon-containing carbon composite anodes. Full article

The photovoltaic industry generates a substantial amount of high-purity waste silicon powder during the diamond-wire saw cutting process, which can serve as an environmentally friendly and cost-effective resource for lithium-ion battery recycling. However, its commercial application is hindered by the surface attachment of silicon dioxide, organic substances, metal impurities, as well as its intrinsic drawbacks such as significant volume expansion (>300%) during lithium (de)intercalation and low electronic conductivity. To address these issues, this study first purifies the waste silicon powder and then designs the structure of the composites. Using a simple ball-milling combined with sol-gel method, a core-shell composite material with a carbon-coated two-dimensional conductive network (FVW-Si/G₅₀₀@C) was synthesized. The two-dimensional conductive network provides sufficient space to accommodate the volume expansion of silicon, while the mesoporous structure on the carbon shell offers a fast transport pathway for Li⁺, thereby enhancing the electrode kinetics. The prepared FVW-Si/G₅₀₀@C electrode maintained a high reversible capacity of 951.8 mAh g⁻¹ after 100 cycles at a current density of 0.2 A g⁻¹. Even at a high current density of 1 A g⁻¹, it retained a reversible capacity of 230.4 mAh g⁻¹. The results indicated that the synergistic effect between graphite sheets and the mesoporous carbon shell significantly improved the rate performance and cycling stability of the FVW-Si/G₅₀₀@C electrode. This study provided a theoretical foundation for the scalable, green, and high-value utilization of waste silicon powder in the photovoltaic industry and offered technical support for sustainable energy development. Full article

Silicon (Si) has attracted extensive attention as a promising anode material for next-generation lithium-ion batteries (LIBs) due to its ultra-high theoretical capacity, low lithiation potential, and economic advantages. However, drastic volume expansion during cycling and slow reaction kinetics severely compromise its structural stability and practical application. Recently, two-dimensional (2D) MXenes have been explored as effective functional components in Si-based electrodes because of their excellent electrical conductivity, high specific surface area, adjustable surface terminations, and mechanical robustness. When integrated with Si, MXenes serve as conductive matrices that alleviate volumetric stress, enhance charge transport, and accelerate electron/ion diffusion. Consequently, Si/MXene nanocomposites (NCs) exhibit significantly improved lithium (Li) storage performance. This review outlines recent advances in Si/MXene NCs, covering fabrication strategies, structural engineering, and various configurations, including particulate materials, three-dimensional (3D) architectures, films, and fibrous systems, and establishes the relationship between structural design and electrochemical behavior. Remaining challenges and prospective research directions are also discussed to guide the development of high-energy-density LIB anodes. Full article

The Probe Of Extreme Multi-Messenger Astrophysics (POEMMA) is a proposed dual-satellite mission to observe Ultra-High-Energy Cosmic Rays (UHECRs), increase the statistics at the highest energies, and observe Very-High-Energy Neutrinos (VHENs) following multi-messenger alerts of astrophysical transient events, such as gamma-ray bursts and gravitational wave events, throughout the universe. POEMMA–Balloon with radio (PBR) is a small-scale version of the POEMMA design, adapted to be flown as a payload on one of NASA’s suborbital Super Pressure Balloons (SPBs) circling over the Southern Ocean for more than 20 days after a launch from Wanaka, New Zealand. The main science objectives of PBR are: (1) to observe UHECRs via the fluorescence technique from suborbital space; (2) to observe horizontal high-altitude air showers (HAHAs) with energies above the cosmic ray knee (E > 3PeV) using optical and radio detection for the first time; and (3) to follow astrophysical event alerts in the search of VHENs. The PBR instrument consists of a 1.1 m aperture Schmidt telescope similar to the POEMMA design, with two cameras on its focal surface: a Fluorescence Camera (FC) and a Cherenkov Camera (CC). In addition, PBR has a Radio Instrument (RI) optimized for detecting EASs (covering the 60–660 Mhz range). The FC observes UHECR-induced EASs in the ultraviolet (UV) spectrum using an array of 9216-pixel Multi-Anode Photo-Multiplier Tubes (MAPMTs) imaged every 1 $\mathsf{\mu }$s. The CC uses a 2048-pixel Silicon Photo-Multiplier (SiPM) imager to observe cosmic-ray-induced HAHAs and search for neutrino-induced upward-going EASs. The CC covers a spectral range of 320–900 nm, with an integration time of 10 ns. This contribution provides an overview of PBR instruments and their current status. Full article

This study investigates the electrical performance of two 4H-SiC p⁺-i-n⁻ diodes, based on lightly doped epitaxial layers, representative of high-voltage and neutron-detector structures. Each design was implemented in multiple nominally identical devices and characterized over the temperature range 298–623 K, with particular attention to the influence of p⁺ layer fabrication, n-type epitaxial layer thickness, and doping concentration. One diode features an ion-implanted p⁺ layer on a 250 µm thick n-type epitaxial layer, while the other employs an epitaxially grown p⁺ layer on a 100 µm thick n-type epitaxial layer. A comparison of reverse-bias Current–Voltage (I–V) and Capacitance–Voltage (C–V) characteristics indicates that, although both designs exhibit high-quality epitaxial 4H-SiC material, devices with an implanted p⁺ anode tend to show a more pronounced temperature-dependence and degradation of selected electrical parameters in reverse bias than those with an epitaxial p⁺ anode, while forward I–V in the range 298–623 K remains broadly similar for both designs. These observations suggest that anode fabrication and epitaxial design may jointly influence thermal stability, recombination mechanisms, and overall electrical performance, offering guidance for the optimization of 4H-SiC-based power and neutron-detector devices for high-temperature and harsh environments. Full article

Silicon is a well-known anode material for lithium-ion batteries that has attracted a lot of interests because of its high theoretical specific capacity (4200 mAh g⁻¹). However, its severe volume expansion during cycling leads to structural degradation and rapid capacity fading. The design of porous silicon architectures has emerged as a fundamental and effective strategy to mitigate these issues by accommodating mechanical stress and preserving electrode integrity. Concurrently, the development of advanced in situ/operando characterization techniques has shifted the research paradigm, enabling direct observation of dynamic structural and interfacial evolution under operating conditions. This review systematically summarizes recent progress in the rational design of porous Si-based anodes and critically examines how state-of-the-art in situ methods provide direct mechanistic validation of these designs. The work highlights the synergistic interplay between targeted material engineering and in situ/operando characterization, offering a roadmap for the development of high-performance porous silicon anodes. Full article

In silicon–carbon (Si-C) anode materials fabricated via chemical vapor deposition (CVD), the pore size distribution of porous carbon is a critical parameter that strongly affects the overall electrochemical performance. In this study, biomass-derived hard carbon was employed as the precursor, and porous carbon materials with distinct pore size characteristics were prepared via fluidized bed porosimetry after carbonization at different temperatures. Based on these porous carbon substrates, three types of Si-C anodes corresponding to low-, medium-, and high-temperature treatments were synthesized through a combination of SiH₄ deposition and carbon coating processes. Electrochemical evaluation demonstrated that all three Si-C anodes exhibited favorable electrochemical performance and suppressed volume expansion. Among them, the Si-C anode prepared at a medium temperature of 1100 °C, denoted as NT-P-SC, delivered the most balanced performance, achieving an initial coulombic efficiency of 94.47% together with excellent rate capability. Furthermore, when Si-C anodes derived from different porous carbon matrices were blended with graphite to achieve a composite capacity of 500 mAh/g and evaluated in full-cell configurations, the NT-P-SC silicon-based composite exhibited superior cycling stability. The composite delivered an initial discharge capacity of 3.53 mAh and maintained a capacity of 2.74 mAh after 1628 cycles, corresponding to a capacity retention of 77.62%. The improved electrochemical performance of the Si-C anode is primarily attributed to the optimized pore structure of the porous carbon matrix synergistically combined with the carbon coating process. Full article

The plasma-catalytic conversion of CO₂ is a promising route toward sustainable fuel and chemical production under mild operating conditions. However, many aspects still need to be better understood to improve performance and better understand the catalyst-plasma synergies. Among them, one aspect concerns understanding whether photons emitted by plasma discharges could induce changes in the catalyst, thereby promoting interaction between plasma species and the catalyst. This question was addressed by investigating the CO₂ splitting reaction in a planar dielectric barrier discharge (pDBD) reactor using titania-based catalysts that simultaneously act as discharge electrodes. Four systems were examined feeding pure CO₂ at different flow rates and applied voltage: bare titanium gauze, anodically formed TiO₂ nanotubes (TiNT), TiNT decorated with Ag–Au nanoparticles (TiNTAgAu), and TiNT supporting Ag–Au nanoparticles coated with polyaniline (TiNTAgAu/PANI). The TiNTAgAu exhibited the highest CO₂ conversion (35% at 10 mL min⁻¹ and 5.45 kV) and the most intense optical emission, even in the absence of external light irradiation, suggesting that the improvement is primarily attributed to plasma–nanoparticle interactions and self-induced localized surface plasmon resonance (si-LSPR) rather than conventional photocatalytic pathways. SEM analyses indicated severe plasma-induced degradation of TiNT and TiNTAgAu surfaces, leading to performance decay over time. In contrast, the TiNTAgAu/PANI catalyst retained structural integrity, with the polymeric coating mitigating plasma etching while maintaining competitive efficiency. There is thus a complex behavior with catalytic performance governed by nanostructure stability, plasmonic enhancement, and the interfacial protection. The results demonstrate how integrating plasmonic nanoparticles and conductive polymers can enable the rational design of durable and efficient plasma-photocatalysts for CO₂ valorization and other plasma-assisted catalytic processes. Full article

Silicon oxide/graphite (SiO_x/Gr) anodes are promising candidates for high energy-density lithium-ion batteries. However, their complex multiphysics degradation mechanisms pose challenges for accurately interpreting and predicting capacity fade behavior. In particular, existing multiphysics models typically treat gas generation and solid electrolyte interphase (SEI) growth as independent or unidirectionally coupled processes, neglecting their bidirectional interactions. Here, we develop an electro–thermal–mechanical–gaseous coupled model to capture the dominant degradation processes in SiO_x/Gr anodes, including SEI growth, gas generation, SEI formation on cracks, and particle fracture. Model validation shows that the proposed framework can accurately reproduce voltage responses under various currents and temperatures, as well as capacity fade under different thermal and mechanical conditions. Based on this validated model, a mechanistic analysis reveals two key findings: (1) Gas generation and SEI growth are bidirectionally coupled. SEI growth induces gas release, while accumulated gas in turn regulates subsequent SEI evolution by promoting SEI formation through hindered mass transfer and suppressing it through reduced active surface area. (2) Crack propagation within particles is jointly governed by the magnitude and duration of stress. High-rate discharges produce large but transient stresses that restrict crack growth, while prolonged stresses at low rates promote crack propagation and more severe structural degradation. This study provides new insights into the coupled degradation mechanisms of SiO_x/Gr anodes, offering guidance for performance optimization and structural design to extend battery cycle life. Full article

This study aims to fabricate magnesium-doped SiOx materials through the integrated application of physical vapor deposition and chemical vapor deposition techniques, with the objective of developing high-performance anode materials for lithium-ion batteries. With the macroscopic particle size held constant, this study endeavors to explore the impact of variations in the size of microscopic silicon crystals on the properties of the material. Under the effect of magnesium doping, the influence mechanism of different microscopic grain sizes on the reaction kinetics behavior and structural stability of the material was systematically studied. Based on the research findings, a reasonable control range for the size of silicon crystals will be proposed. The research findings indicate that both relatively small and large silicon crystals are disadvantageous for cycling performance. When the silicon crystal grain size is 5.79 nm, the composite material demonstrates a relatively high overall capacity of 1442 mAh/g and excellent cycling stability. After 100 cycles, the capacity retention rate reaches 83.82%. EIS analysis reveals that larger silicon crystals exhibit a higher lithium ion diffusion coefficient. As a result, the silicon electrodes show more remarkable rate performance. Even under a high current density of 1C, the capacity of the material can still be maintained at 1044 mAh/g. Full article