Search Results (15)

The assessment of surface water quality of the Danube River and Black Sea was performed taking into account the amounts determined for heavy metals (As, Cd, Cr, Cu, Hg, Mn, Ni, Pb, Zn), nutrients (compounds of N and P, chlorophyll a), emerging contaminants (CECs) (pharmaceutics and endocrine disruptors—19 quantified compounds, out of 30 targeted chemicals), heterotrophic bacteria and total coliforms, in thirty-two locations from the lower Danube sector (starting with km 375 up to the river mouths), the Danube Delta Biosphere Reserve (three Danube branches—Chilia, Sulina, and Sf. Gheorghe) and the Romanian coastal area of the Black Sea. The heavy metals levels were found in the following ranges: 3.0–6.5 μg/L As; 0.51–1.32 μg/L Cd; 21.6–61.2 μg/L Cr; 10.2–28.6 μg/L Cu; 196–351 μg/L Mn; 12.3–47.67 μg/L Ni; 5.2–15.5 μg/L Pb; 44–74 μg/L Zn; 0.01–0.08 μg/L Hg. The nutrient concentrations vary in the intervals: 0.04–0.45 mg/L N-NH₄; 0.01–0.06 mg/L N-NO₂; 0.07–1.9 mg/L N-NO₃; 1.0–3.2 mg/L N total; 0.01–0.05 mg/L P-PO₄; 0.02–0.27 mg/L P total, and 0.8–17.3 μg/L chlorophyll a. The concentrations of CECs from various classes (sulfamethoxazole, trimethoprim, ciprofloxacin, flumequine, amoxicillin, cefuroxime, dicloxacillin, carbamazepine, pravastatin, erythromycin, piroxicam, ketoprofen, diclofenac, naproxen, enilconazole (imazalil), clotrimazole, drospirenone, 17α-ethinylestradiol, and bisphenol A) were compared with values reported for European rivers and the Danube River water in various river sectors. The highest detection frequencies were registered for bisphenol A (100%), sulfamethoxazole (96%), carbamazepine and diclofenac (87%), trimethoprim (78%), pravastatin (46%), and imazalil (34%). Bisphenol A exhibited the largest concentrations (342 ng/L), followed by diclofenac (132 ng/L), carbamazepine (38 ng/L), and sulfamethoxazole (36 ng/L). For most of the contaminants, Black Sea coastal water showed lower concentrations than the Danube water and good ecological status for surface water. Correlations between CECs and total coliforms suggest insufficient treated wastewater effluents as a common contamination source and possible use of CECs as indirect fecal pollution indicator in aquatic systems. This is the first study carried out in the connected system Danube River–Danube Delta–Black Sea for a large palette of toxicants classes and microbial pollutants, which will serve as a baseline for future monitoring of water quality in the region. Full article

Microplastic pollution has gained attention in recent years due to its adverse impact on the environment. As a major threat to marine ecosystems and biota, the accumulation of microplastics along coastlines has become a growing concern. This study focused on quantifying and characterizing the presence, distribution, and composition of microplastics along the beaches of Romania and Bulgaria. Microplastics were extracted from beach sand samples using a saturated NaCl solution. The particles were then analyzed through FT-IR and DSC spectral analyses to identify their chemical composition. Sampling was conducted across several resorts along the Romanian and Bulgarian coastlines. The findings revealed varying concentrations of microplastics across different beaches, with Romanian beaches showing concentrations of between 40 and 213 particles per sample (470–2500 microplastics/kg), which were notably higher in areas like Mamaia and Costinești. On Bulgarian beaches, the average concentrations reached up to 137 particles per sample (1612 microplastics/kg), particularly in areas like Sunny Beach and Nessebar. Polyethylene (PE) was identified as the most prevalent polymer (55%), followed by polyamide (PA), polypropylene (PP), polyethylene terephthalate (PET), and polyurethane (PU). These polymers were linked to common sources such as packaging, textiles, and industrial products. Microscopic examination, combined with FT-IR and DSC spectral analysis, confirmed the plastic nature of the particles, revealing distinct chemical structures characteristic of each material type. This study underscores the widespread contamination of Romanian and Bulgarian beaches with microplastics, emphasizing the environmental risks to coastal ecosystems. The presence of synthetic polymers highlights the urgent need for policies targeting plastic waste management to mitigate the growing pollution in marine environments. Full article

This study assesses the spatial distribution and contamination levels of some heavy metals (HMs), i.e., cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), and lead (Pb), in seawater and surface sediments along the Romanian Black Sea coast (RBSC). Sampling was conducted at 40 stations across 12 transects during May–June 2021, and the measured levels of HM concentrations were compared with Environmental Quality Standards (EQS), i.e., maximum allowable concentration (MAC) values, for seawater and effects range-low (ERL) thresholds for sediments. HM concentrations were measured using high-resolution continuum source atomic absorption spectrometry (HR-CS AAS). In seawater, the levels of Cd, Cu, and Pb concentrations exceeded the MAC values at three stations located in areas influenced by the Danube River or anthropogenic activities. In sediments, exceedances of ERL thresholds were found for Ni at 11 stations, for Cu at three stations, and for Pb at one station. HM contamination of sediment samples collected from these stations can be caused by both natural and anthropogenic sources, e.g., the Danube River, rock/soil weathering and erosion, agricultural runoff, port and construction activities, maritime and road transport, coastal tourism, petrochemical industry, wastewater discharges, offshore oil and gas extraction. Principal Component Analysis (PCA) provided valuable information about the relationships between relevant variables, including water depth and HM concentrations in seawater and sediments, and potential sources of contamination. The results highlight the influence of fluvial inputs and localized human activities on HM contamination. While the overall chemical status of Romanian Black Sea waters and sediments remains favorable, targeted management strategies are needed to address localized pollution hotspots and mitigate potential ecological risks. These findings provide valuable insights for environmental monitoring and sustainable coastal management. Full article

Coastal erosion affects all coastal areas with different intensities, and its effects may be severe. This is the case of the Black Sea sandy beaches on the Romanian coast, where the beaches have been used for tourism since the mid-19th century. In 2012, a project was launched to reduce erosion and protect the Romanian Black Sea coast from its destructive effects. By the 2021 tourist season, the completed works in Mamaia resort resulted in beaches exceeding, in some cases, 300 m in width. However, while these efforts successfully curtailed erosion, they also brought unintended consequences. The imported coarse sand and increased seawater depth canceled the resort’s traditional advantages, raising concerns among both tourists and local stakeholders. The purpose of our article was twofold—to present the case of the Mamaia resort and the expansion works conducted and to present the results of an exploratory study highlighting the tourists’ perceptions regarding the beach extensions, as well as their motivations, preferences, and expectations for the development of a modern beach. Our results suggest that while the beach extension works were necessary and long-awaited, they inadvertently caused dissatisfaction among tourists, leading to shifts in tourist flows and financial losses for local tourism operators. Data visualization techniques were employed to explore the complex relationships between tourist satisfaction with the extension works (in both 2021 and 2022) and factors influencing their comfort and overall experience. Additionally, the extraction of millions of cubic meters of sediment for the extensions disrupted marine habitats, raising ecological concerns. Future coastal protection efforts should balance erosion mitigation, ecological sustainability, and tourism needs by adopting environmentally sensitive methods, preserving marine ecosystems, and engaging stakeholders to align projects with tourists’ expectations, thus ensuring the long-term viability of popular tourist destinations like Mamaia. Full article

This study provides a comprehensive evaluation of contamination levels in the Romanian Black Sea within the framework of the Marine Strategy Framework Directive (MSFD). Over the course of five oceanographic expeditions between 2020 and 2022, data were gathered from 70 stations in transitional, coastal, shelf, and offshore waters of the Black Sea. Analyses were conducted on water, sediment, and biota samples for key contaminants: heavy metals (HMs), polycyclic aromatic hydrocarbons (PAHs), and persistent organic pollutants (POPs) such as organochlorinated pesticides (OCPs) and polychlorinated biphenyls (PCBs). The assessment identified contamination hotspots near riverine inputs, urban runoff, harbor activities, and industrial discharges. Offshore waters also showed measurable pollutant levels, likely from diffuse sources and atmospheric deposition. The key findings reveal the widespread contamination of HMs, PAHs, and POPs across the Romanian Black Sea, with concentrations in certain areas exceeding acceptable environmental thresholds, highlighting ongoing challenges for regional pollution management. PAHs were prevalent in both nearshore and offshore regions, while OCPs and PCBs were detected across various matrices, with significant concentrations observed in water and biota samples. The study emphasizes the importance of integrated assessments within the MSFD framework, suggesting that future evaluations should complement the “one out-all out” (OOAO) approach with multi-metric tools, to enhance the robustness of pollution status reporting. Despite improvements in some areas, contamination remains a critical challenge, requiring strengthened regulations, improved waste management, and increased regional cooperation to mitigate the ongoing risks to marine ecosystems. The findings provide valuable data for the upcoming national MSFD assessment cycle (2018–2023) and highlight the need for sustained monitoring and coordinated efforts to ensure long-term marine sustainability. Full article

One of the most important and efficient sources of green electricity is catching air currents through wind turbine technology. Wind power plants are located in areas where the energy potential of the wind is high but it varies. The time variation of the wind generates fluctuations in the power produced by the wind farms that is injected into the grid. This elevates, depending on the intensity, problems of network stability and the need for balancing energy, thus raising both technical and cost issues. The present paper analyzes the behavior of a wind turbine (WT) over time in varying wind speed conditions, highlighting that without automation algorithms, a WT is far from the operation at the maximum power point (MPP). However, even when it is brought to operate at MPP, there are still significant variations in the power injected into the network. These power variations can be compensated if the wind system has energy storage facilities for the captured wind. All of these assumptions are analyzed using improved mathematical models and processed in simulations, with experimental data used as input from a wind turbine with an installed power of 2.5 [MW] in operation on the Romanian Black Sea coastal area. Consequently, the paper demonstrates that during an operation in the optimal area, from an energy perspective, the wind turbine’s maximum power point requires a storage system for the captured wind energy. Full article

Based on molecular and morphological characters, we describe a new species of monothalamous foraminifera, Psammophaga secriensia sp. nov., that was sampled from two coastal locations (48 m and 53 m depth) on the Romanian Black Sea continental shelf. Molecular data further confirm its presence in the northeastern part of the Black Sea (Balaklava Bay, 5–10 m depth). Specimens of Psammophaga secriensia sp. nov. are characterized by an elongate to broadly pyriform test and a simple rounded aperture. The wall is translucent and the cytoplasm contains mineral grains of different sizes. The genus Psammophaga, including Psammophaga simplora and several undetermined morphotypes, has been reported from different areas of the Black Sea. Previous research using an integrative taxonomic approach has identified two additional species (Psammophaga zirconia; Psammophaga sp., Gooday et al., 2011) occurring in the Black Sea. Monothalamids are an important part of the meiobenthos in the Black Sea and our results increase the knowledge of foraminiferal diversity in this marginal sea. Full article

Three green algae, collected from the Romanian Black Sea coast, are studied: Ulva lactuca, Enteromorpha intestinalis, and Cladophora vagabunda, which were collected from six different coastal areas. This paper aims to identify the bioactive compounds of these green algae and their beneficial properties, in order to use them as potential nutraceuticals using different analytical methods. Pharmacognostic, microbiological, and physico-chemical methods used for the analysis of algal materials revealed a rich and diverse array of biocompounds with nutritional value. In the case of green algae, a high percentage of sulphates, carbohydrates and dietary fibers were identified. Moisture, ash, total nitrogen, protein and lipid contents were determined. The contents of pigments, vitamins, and metals determined complement the nutritional qualities of the three seaweed species studied as future nutraceuticals. The content of flavonoid and phenolic compounds identified in the composition of seaweeds justifies their antioxidant and antimicrobial properties. The antioxidant capacity was tested by means of DPPH, reducing power, and TEAC methods, and the algae studied exhibit important antioxidant properties that can be used to enhance their potential as nutraceuticals. The studied algae show good antibacterial activity on both Gram (+) and Gram (−) bacteria, with slightly better activity on Gram (−) bacteria. Biocompounds from green algae from the Black Sea coast may represent an important source of marine nutraceuticals with medical and nutritional potential. Full article

The aim of this paper is to highlight the state of development of tourist ports in the Romanian Black Sea coastal area and their implications for the sustainable provision of quality recreational transport. As indicated by the collected data, both locals and tourists are showing a growing interest in nautical sports and maritime recreational activities, and there are plans to upgrade existing marinas and build new ones. Although the boating activity in the Romanian Black Sea coastal area is not as developed and popular as that in other areas of the Balkan Peninsula, it has particular advantages due to its geographical position close to the Danube and its delta, as well as its historical and cultural heritage. Between 2014 and 2019, the south marinas of Romania’s Black Sea coast experienced a 65% increase in the number of visiting boats. Despite some decreases in traffic during the pandemic, the general trend continues to be upward. An evaluation of the operational capacities and policies implemented by tourist ports and relevant stakeholders identifies the strengths and weaknesses of the current system and provides insights into the current activity and implemented policies of the four most known and developed marinas along the Romanian Black Sea coast. The study’s main objective is to assess sustainable practices in relation to the environmental, social, and economic systems, with a focus on environmental protection, the use of renewable energy sources, and the implementation of quality management standards. The study uses a mix of qualitative and quantitative analyses to achieve this. Interviews with representatives of the four coastal marinas helped gather the data. The size of boat traffic was evaluated by taking into consideration the data from the local harbor master. The research identified gaps and highlighted areas that require improvement, subsequently providing recommendations to enhance sustainability. The findings can guide policymakers and stakeholders in developing practices that can promote the growth of recreational nautical transport in Romania while ensuring the sustainable development of the sector. Full article

In the context of the European Green Deal implementation, it is expected that there will be an increase in number of the wind farms located near the coastal areas in order to support this initiative. The Black Sea represents an important source of wind energy, and as a consequence, in the present work the regional wind resources (onshore and offshore) are evaluated by considering a total of 20 years of ERA5 wind data covering the 20-year time interval from January 2002 to December 2021. From a general perspective, it is clear that the offshore areas (100 km from the shoreline) are defined by much higher wind speed values than in the onshore, reaching an average of 8.75 m/s for the points located on the western sector. During the winter, these values can go up to 8.75 m/s, with the mention that the northern sectors from Ukraine and Russia may easily exceed 8 m/s. In terms of the wind turbines’ selection, for the offshore areas defined by consistent wind resources, generators will be considered that are defined by a rated wind speed of 11 m/s. Finally, we can mention that a theoretical offshore wind turbine of 20 MW can reach a capacity factor located between 20.9 and 48.3%, while a maximum annual electricity production of 84.6 GWh may be obtained from the sites located near the Romanian and Ukrainian sectors, respectively. Full article

To meet the global challenges of climate change and human activity pressure on biodiversity conservation, it has become vital to map such pressure hotspots. Large areas, such as nation-wide regions, are difficult to map from the point of view of the resources needed for such mapping (human resources, hard and soft resources). European biodiversity policies have focused on restoring degraded ecosystems by at least 10% by 2020, and new policies aim to restore up to 30% of degraded ecosystems by 2030. In this study, methods developed and applied for the assessment of the degradation state of the ecosystems in a semi-automatic manner for the entire Romanian territory (238,391 km²) are presented. The following ecosystems were analyzed: forestry, grassland, rivers, lakes, caves and coastal areas. The information and data covering all the ecoregions of the Romania (~110,000 km²) were analyzed and processed, based on GIS and remote sensing techniques. The largest degraded areas were identified within the coastal area (49.80%), grassland ecosystems (38.59%) and the cave ecosystems (2.66%), while 27.64% of rivers ecosystems were degraded, followed by 8.52% of forest ecosystems, and 14.05% of lakes ecosystems. This analysis can contribute to better definition of the locations of the most affected areas, which will yield a useful spatial representation for future ecological reconstruction strategy. Full article

The European offshore wind market is continuously expanding. This means that, together with significant technological developments, new coastal environments should be considered for the implementation of the wind farms, as is the case of the Black Sea, which is targeted in the present work. From this perspective, an overview of the wind energy potential in the Romanian exclusive economic zone (EEZ) in the Black Sea is presented in this work. This is made by analyzing a total of 20 years of wind data (corresponding to the time interval 2000–2019) coming from different sources, which include ERA5 reanalysis data and satellite measurements. Furthermore, a direct comparison between these datasets was also carried out. Finally, the results of the present work indicate that the Romanian offshore areas can replicate the success reported by the onshore wind projects, of which we can mention the Fantanele-Cogealac wind farm with an operating capacity of 600 MW. Full article

This study investigates the influence of gender in the bioconcentration of essential and nonessential elements in different parts of Black Sea turbot (Psetta maxima maeotica) body, from an area considered under high anthropogenic pressure (the Constanta City Black Sea Coastal Area in Romania). A number of 13 elements (Ca, Mg, Na, K, Fe, Zn, Mn, Cu, Ni, Cr, As, Pb and Cd) were measured in various sample types: muscle, stomach, stomach content, intestine, intestine content, gonads, liver, spleen, gills and caudal fin. Turbot adults (4–5 years old) were separated, according to their gender, into two groups (20 males, 20 females, respectively), and a high total number of samples (1200 from both groups) were prepared and analyzed, in triplicate, with Flame Atomic Absorption Spectrometry and High-Resolution Continuum Source Atomic Absorption Spectrometry with Graphite Furnace techniques. The results were statistically analyzed in order to emphasize the bioconcentration of the determined elements in different tissues of wild turbot males vs. females, and also to contribute to an upgraded characterization of the Romanian Black Sea Coast, around Constanta City, in terms of heavy metals pollution. The essential elements Mg and Zn have different roles in the gonads of males and females, as they were the only elements with completely different patterns between the analyzed groups of specimens. The concentrations of studied elements in muscle were not similar with the data provided by literature, suggesting that chemistry of the habitat and food plays a major role in the availability of the metals in the body of analyzed fish species. The gender influenced the bioaccumulation process of all analyzed elements in most tissues since turbot male specimens accumulated higher concentration of metals compared to females. The highest bioaccumulation capacity in terms of Ca, Mg, Na, Ni, As, Zn and Cd was registered in caudal fin, liver and intestine tissues. Also, other elements such as K, Fe, Cu and Mn had the highest bioaccumulation in their muscle, spleen, liver and gills tissues. The concentrations of toxic metals in Black Sea turbot from this study were lower in the muscle samples compared with the studies conducted in Turkey, suggesting that the anthropogenic activity in the studied area did not pose a major impact upon the habitat contamination. Full article

At the European level, offshore wind projects are already considered a competitive market. Nevertheless, this is not yet the case of the enclosed sea basins, such as the Black Sea, where no offshore wind farm is operating at this moment. From this perspective, the objective of the present work is to identify the most suitable sites where a wind project can be developed in the Romanian coastal areas. Various parameters, such as wind speed, water depth, distance to shore, and turbine performance, are considered. A picture of the local wind characteristics is first provided considering 20 years of reanalysis data, which cover the time interval from January 1998 to December 2017. The results indicated that the best sites to implement a wind project are located in the northern sector of the Black Sea, close to the Danube Delta. It was also noticed an important variation of the wind speed between onshore and 20 km offshore, for which an increase of about 55% was estimated. Full article

The most relevant patterns of the wave energy propagation in the western side of the Black Sea were assessed in the present work. The emphasis was put on the western side because this is also the most energetic part of the Black Sea. The assessments performed relate some recent results provided by a numerical wave modeling system based on the spectrum concept. The SWAN model (acronym for Simulating Waves Nearshore) was considered. This was implemented over the entire sea basin and focused with increasing resolution in the geographical space towards the Romanian nearshore. Furthermore, some data assimilation techniques have also been implemented, such that the results provided are accurate and reliable. Special attention was paid to the high, but not extreme, winter wave energy conditions. The cases considered are focused on the coastal waves generated by distant storms, which means the local wind has not very high values in the targeted areas. This also takes into account the fact that the configuration of the environmental matrix in the Black Sea is currently subjected to significant changes mainly due to the climate change. From this perspective, the present work illustrates some of the most recent patterns of wave energy propagation in the western side of the Black Sea, considering eight different SWAN computational domains. According to most of the recent evaluations, the nearshore of the Black Sea is characterized by an average wave power lower than 6 kW/m. The results of the present work show that there is a real tendency of the wave energy enhancement. This tendency, especially concerns the western side of the basin, where in the high conditions considered, values of the wave power about 10 times greater than the average have been noticed. Full article