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22 pages, 1066 KB  
Article
PFAD: Parameter-Efficient Framework for Cross-Domain Anomaly Detection for Sustainable Manufacturing
by Bokuk Joo and Hail Jung
Sustainability 2026, 18(13), 6684; https://doi.org/10.3390/su18136684 - 1 Jul 2026
Viewed by 575
Abstract
Deploying visual anomaly detection in industrial production requires retraining models for each product domain, leading to substantial costs in data collection, computational resources, and energy consumption that scale poorly across diverse manufacturing environments. This paper proposes PFAD, a parameter-efficient framework for cross-domain anomaly [...] Read more.
Deploying visual anomaly detection in industrial production requires retraining models for each product domain, leading to substantial costs in data collection, computational resources, and energy consumption that scale poorly across diverse manufacturing environments. This paper proposes PFAD, a parameter-efficient framework for cross-domain anomaly detection without retraining, enabling the direct deployment of a source model trained on a benchmark dataset to unseen industrial settings in a zero-shot manner. PFAD leverages a frozen vision transformer backbone and introduces Soft Anomaly-Aware Feature Selection (Soft AFS), which assigns continuous weights to feature channels based on anomaly discriminability, preserving information while enhancing cross-domain generalization without relying on synthetic anomalies or target-domain data. Extensive experiments on both public benchmarks and real-world industrial datasets demonstrate that PFAD achieves strong cross-domain performance, including an image-level AUROC of 0.945 for semiconductor PCB inspection using only a public dataset for training. Furthermore, PFAD supports an optional one-shot inference extension, where a single normal reference image improves detection performance in scenarios with large domain gaps (up to +10.4 pp), most effectively when zero-shot transfer leaves meaningful headroom. These results demonstrate that PFAD provides a practical and scalable solution for industrial anomaly detection by eliminating repeated retraining cycles and reducing associated computational and energy overhead, while maintaining high performance across heterogeneous domains. Full article
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24 pages, 1031 KB  
Article
Flood Management Framework for Local Government at Shah Alam, Malaysia
by Haziq Sarhan Rosmadi, Minhaz Farid Ahmed, Neyara Radwan, Mazlin Bin Mokhtar, Chen Kim Lim, Bijay Halder, Miklas Scholz, Fahad Alshehri and Chaitanya Baliram Pande
Water 2025, 17(4), 513; https://doi.org/10.3390/w17040513 - 11 Feb 2025
Cited by 2 | Viewed by 12443
Abstract
Flood disasters are common events in Malaysia, particularly during the monsoon seasons. Hence, disaster management in Malaysia is based on the framework following “Directive 20” by the National Security Council (MKN). This study gathered qualitative information in Shah Alam Municipality through informal interviews [...] Read more.
Flood disasters are common events in Malaysia, particularly during the monsoon seasons. Hence, disaster management in Malaysia is based on the framework following “Directive 20” by the National Security Council (MKN). This study gathered qualitative information in Shah Alam Municipality through informal interviews with 20 informants following the quadruple-helix multi-stakeholders model in 2023 for flood disaster management (FDM). Thematic analysis of the qualitative information was conducted following the four main priority of action themes of the Sendai Framework for United Nations Disaster Risk Reduction (2015–2030) using the Taguette software. This study found coordination and inter-agency data sharing are two major issues in Shah Alam that require immediate attention for FDM. Thus, this study suggests improving district-level flood management guidelines, especially the involvement of the National Disaster Management Agency (NADMA). The NADMA should have a close look at the flood management plan, which acts as Malaysia’s main disaster management coordinator, as they are usually the first agency on the scene when a disaster occurs. Hence, to prevent and lessen flood disaster impact, disaster risk preparedness and individual management through customized training are crucial in combining non-structural and structural measures for FDM. Full article
(This article belongs to the Special Issue Recent Advances in Flood Risk Assessment and Management)
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22 pages, 8248 KB  
Article
Integrating Water Quality Index and Advanced Geographic Information System for Groundwater Quantity and Quality Mapping: Insights from Islamabad’s Aquifer
by Hina Basharat, Toqeer Ahmed, Sheikh Saeed Ahmad, Muhammad Zahir and Miklas Scholz
Sustainability 2025, 17(4), 1373; https://doi.org/10.3390/su17041373 - 7 Feb 2025
Cited by 8 | Viewed by 5237
Abstract
Groundwater management (quantity and quality) is a pressing concern in Islamabad amid the challenges posed by climate change and urbanization. This study leverages the Water Quality Index (WQI), coupled with advanced remote sensing (RS) and geographic information system (GIS) applications, to provide a [...] Read more.
Groundwater management (quantity and quality) is a pressing concern in Islamabad amid the challenges posed by climate change and urbanization. This study leverages the Water Quality Index (WQI), coupled with advanced remote sensing (RS) and geographic information system (GIS) applications, to provide a comprehensive assessment of groundwater dynamics in the city. Groundwater samples from 40 tube wells were analyzed using standard methods, and spatial distribution patterns of water quality variables were mapped applying an integrated GIS framework. Geological and hydrological data collected from the Capital Development Authority (CDA) supported the mapping of water table depths, bore depths, and water quality features. Key findings revealed significant hydrogeological variations, with sectors G-8, G-7, G-9, and G-11 exhibiting elevated electrical conductivity (EC) levels, peaking at 1054.5 µS/cm, surpassing permissible limits. The WQI indicated excellent to good quality of all the collected samples except one found unfit for drinking. Land use and land cover (LULC) analysis revealed extensive urbanization, exacerbating groundwater contamination risks. This study underscores the interconnectedness of urban growth, geological features, groundwater quality deterioration, and sustainability. The findings provide actionable insights for policymakers and urban planners to mitigate groundwater contamination and ensure sustainable resource management in Islamabad. Full article
(This article belongs to the Section Sustainable Water Management)
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23 pages, 3668 KB  
Article
Optimization of Selected Parameters in Vertical, Horizontal, and Hybrid Surface Flow Constructed Wetland Systems for Improving the Treatment Efficiency of Textile and Sewage Effluents
by Faisal Javeed, Firdaus-e-Bareen, Muhammad Shafiq, Aisha Nazir and Miklas Scholz
Water 2025, 17(3), 402; https://doi.org/10.3390/w17030402 - 1 Feb 2025
Cited by 12 | Viewed by 4080
Abstract
Constructed wetland systems (CWSs) can offer cost-effective wastewater treatment in developing countries like Pakistan. This study focused on optimizing design and operational parameters of CWSs in horizontal surface flow (HSF), vertical surface flow (VSF), and hybrid mesocosms for treating sewage and textile effluents [...] Read more.
Constructed wetland systems (CWSs) can offer cost-effective wastewater treatment in developing countries like Pakistan. This study focused on optimizing design and operational parameters of CWSs in horizontal surface flow (HSF), vertical surface flow (VSF), and hybrid mesocosms for treating sewage and textile effluents using local hydrophytes: Lemna minor, Typha latifolia, and Eichhornia crassipes. Pollutants and heavy metals (Cd, Cr, Cu, Pb, Ni, and Zn) were removed under different flow configurations, bedding materials, hydrophyte species, and hydraulic retention times (HRT) to optimize the overall contaminant removal efficiency (RE). Key findings indicated that the hybrid CWS achieved a maximum RE of 63.62% for total suspended solids (TSS) and 57.9% for biochemical oxygen demand (BOD) at an HRT of 3 days, with efficiencies declining at longer retention times. Additionally, the hybrid system showed maximum metal removal, with Cd and Cr RE reaching 75.2% and 70.5%, respectively. The study also highlighted the critical role of hydrophyte species and HRT in optimizing RE. Furthermore, the choice of hydrophyte species significantly influenced pollutant removal, with treatment cells containing mixed hydrophytes achieving the highest removal efficiencies (63.62%), followed by Eichhornia crassipes with high Cd (643.33 mgkg−1) and Cr (1103.72 mgkg−1) uptake. A lower HRT of 3 days resulted in the highest overall removal efficiency of 57.5%, which decreased with longer HRTs (from 6 to 9 days). Optimizing design and operational parameters is crucial for maximizing CWS treatment potential. Full article
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28 pages, 3318 KB  
Review
Importance of Geographic Information System (GIS) Application to Reduce the Impact of Flood Disasters in Malaysia: A Meta-Analysis
by Adam Narashman Leeonis, Minhaz Farid Ahmed, Mazlin Bin Mokhtar, Bijay Halder, Chen Kim Lim, Nuriah Abd Majid and Miklas Scholz
Water 2025, 17(2), 181; https://doi.org/10.3390/w17020181 - 10 Jan 2025
Cited by 12 | Viewed by 10338
Abstract
Malaysia can accurately analyse flood patterns and susceptible forecast areas and allocate resources as efficiently as possible by leveraging geographic information systems (GIS). Authorities can execute data-driven plans for robust flood control and quick catastrophe response because of this technology. However, in Malaysia, [...] Read more.
Malaysia can accurately analyse flood patterns and susceptible forecast areas and allocate resources as efficiently as possible by leveraging geographic information systems (GIS). Authorities can execute data-driven plans for robust flood control and quick catastrophe response because of this technology. However, in Malaysia, public authorities adequately apply GIS, researchers often limit the use of GIS applications to study natural disasters, and communities find GIS challenging to learn and adopt. By producing flood risk mapping using GIS applications that make it easy for the communities to understand the situation, the government and communities can implement programs to mitigate the impacts of natural hazards. Reviewing the available literature on the use of GIS applications in assessing natural hazards, this study found that GIS applications effectively provide flood risk mapping and positively impact natural disaster management to ensure that the worst impacts of natural hazards can be avoided. Moreover, this study revealed the importance of GIS applications and technologies in managing natural hazards in communities to make them better prepared for disaster management. Based on the scientific research, 12 articles were identified to analyse flood management activities in Malaysia. Therefore, the government and relevant agencies should take advantage of the appropriate use of GIS in managing natural disasters and educate the population about applying GIS so that present and future generations can gain this knowledge earlier and use it better in mitigating disaster risks. Full article
(This article belongs to the Special Issue Advances in Crisis and Risk Management of Extreme Floods)
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13 pages, 1067 KB  
Article
Novel Approach to Diagnose Safe Electrical Power Distribution
by Lars Braun, Minh Le, Jürgen Motz and Kai Peter Birke
Energies 2024, 17(22), 5685; https://doi.org/10.3390/en17225685 - 14 Nov 2024
Viewed by 1521
Abstract
The integrity of the 12Vdc power distribution system on a vehicle is essential to guarantee continuous power supply to safety-relevant consumers. Safety-relevant consumers are critical loads, for example, electric power steering, braking systems with functionalities like Anti-Lock Braking or Electronic Stability [...] Read more.
The integrity of the 12Vdc power distribution system on a vehicle is essential to guarantee continuous power supply to safety-relevant consumers. Safety-relevant consumers are critical loads, for example, electric power steering, braking systems with functionalities like Anti-Lock Braking or Electronic Stability Control, and autonomous drive systems. To prevent insufficient power supply for safety-relevant consumers due to an increased wiring harness resistance, a novel diagnostic approach is developed to determine the condition of the power distribution, especially the electrical resistance. The influence of measurement errors and bus commutation on the estimation is investigated by using a simulation. By using the diagnostic, a resistance determination in the milliohm range with a standard deviation of σ=0.3mΩ can be achieved under realistic conditions. This ensures that failures in the wiring harness can be identified, avoiding cascading effects and minimizing recalls. Compared to the state of the art, redundancies, costs, and weight can be saved with the proposed diagnostic system based on electrical resistance estimation. Full article
(This article belongs to the Section F1: Electrical Power System)
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2 pages, 131 KB  
Abstract
Hybrid Paper–Fabric Sandwich Structure-Based Micro-Analytical Device for Detection of Iodine
by Lingadharini Parameswaran, Shreya Paul, Purbita Nag, Sakthivel Jagannathan and Debashis Maji
Proceedings 2024, 104(1), 10; https://doi.org/10.3390/proceedings2024104010 - 28 May 2024
Viewed by 921
Abstract
This study presents a novel method for manufacturing microfluidic paper–fabric hybrid analytical devices (μPFADs), which play a vital role in conducting diagnostic tests at the point of care (POC), especially in resource-limited environments. By circumventing the need for complex machinery or highly skilled [...] Read more.
This study presents a novel method for manufacturing microfluidic paper–fabric hybrid analytical devices (μPFADs), which play a vital role in conducting diagnostic tests at the point of care (POC), especially in resource-limited environments. By circumventing the need for complex machinery or highly skilled operators, our method presents a practical solution for scaling up these POC devices. The approach involves the utilization of a folded paper structure featuring a specific pattern like a circular well or liner microchannel on either side of the fold as a mirror image, followed by inserting a piece of fabric in between the paper fold, thereby creating a sandwich-like structure. Subsequently, a PDMS (polydimethylsiloxane) elastomer with base and curing agents in a 10:1 ratio would be coated over the entire top paper and allowed to settle, enabling the penetration of PDMS down to the bottom paper through the sandwiched fabric. When sufficient PDMS penetration is achieved through visual changes on the back side of the paper, the sandwiched assembly is heated for polymerization of the PDMS. An embedded fabric-based POC device is obtained within the paper whose structure is defined by the designs on the folded paper itself. This micro paper–fabric hybrid analytical device (μPFAD) offers several noteworthy advantages as it boasts rapid fabrication times and is cost-effective, without the need for any printing machines, thereby further enhancing its suitability for no- or low-resource environments. Experimental studies with these μPFADs were conducted for the colorimetric detection of iodine, whose deficiency is a leading cause of thyroid disorders, particularly hypothyroidism. Here, starch acts as the chromogenic agent, which forms a blue-colored complex that shifts the color from purple to deep blue–black with increasing iodine concentration. The initial experimental results reveal contrasting color changes for varying levels of iodine using the proposed μPFADs, which would be useful for the early diagnosis and management of thyroid disorders. Full article
(This article belongs to the Proceedings of The 4th International Electronic Conference on Biosensors)
13 pages, 985 KB  
Article
Comprehensive Study of Failure Mechanisms of Field-Aged Automotive Lead Batteries
by Rafael Conradt, Philipp Schröer, Martin Dazer, Jonathan Wirth, Florian Jöris, Dominik Schulte and Kai Peter Birke
Batteries 2023, 9(11), 553; https://doi.org/10.3390/batteries9110553 - 13 Nov 2023
Cited by 3 | Viewed by 4276
Abstract
Modern vehicles have increasing safety requirements and a need for reliable low-voltage power supply in their on-board power supply systems. Understanding the causes and probabilities of failures in a 12 V power supply is crucial. Field analyses of aged and failed 12 V [...] Read more.
Modern vehicles have increasing safety requirements and a need for reliable low-voltage power supply in their on-board power supply systems. Understanding the causes and probabilities of failures in a 12 V power supply is crucial. Field analyses of aged and failed 12 V lead batteries can provide valuable insights regarding this topic. In a previous study, non-invasive electrical testing was used to objectively determine the reasons for failure and the lifetime of individual batteries. By identifying all of the potential failure mechanisms, the Latin hypercube sampling method was found to effectively reduce the required sample size. To ensure sufficient confidence in validating diagnostic algorithms and calculating time-dependent failure rates, all identified aging phenomena must be considered. This study presents a probability distribution of the failure mechanisms that occur in the field, as well as provides insights into potential opportunities, but it also challenges diagnostic approaches for current and future vehicles. Full article
(This article belongs to the Special Issue The Precise Battery—towards Digital Twins for Advanced Batteries)
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20 pages, 4018 KB  
Article
Efficient and Stable Rice Husk Bioderived Silica Supported Cu2S-FeS for One Pot Esterification and Transesterification of a Malaysian Palm Fatty Acid Distillate
by Mohammed Yousuf Albalushi, G. Abdulkreem-Alsultan, N. Asikin-Mijan, Mohd Izham bin Saiman, Yen Ping Tan and Y. H. Taufiq-Yap
Catalysts 2022, 12(12), 1537; https://doi.org/10.3390/catal12121537 - 29 Nov 2022
Cited by 7 | Viewed by 3174
Abstract
A novel heterogeneous catalyst composite (CuS-FeS/SiO2) derived from rice husk silica was engineered following pyrolysis, chemical precipitation, and chemical redox technique. The resulting catalyst was applied to the conversion of palm fatty acid distillate to biodiesel. The presence of CuS and [...] Read more.
A novel heterogeneous catalyst composite (CuS-FeS/SiO2) derived from rice husk silica was engineered following pyrolysis, chemical precipitation, and chemical redox technique. The resulting catalyst was applied to the conversion of palm fatty acid distillate to biodiesel. The presence of CuS and FeS on the catalyst was verified using X-ray diffraction and Fourier transform infrared spectroscopy, nitrogen physisorption, scanning electron microscopy (FESEM) with energy dispersive X-ray (EDS) spectroscopy, and temperature-programmed desorption of NH3 (TPD-NH3), inductively coupled plasma-atomic emission spectrometry (ICP-AES), and TGA; a specific surface area of approximately 40 m2·g−1 was identified. The impact of independent variables, i.e., reaction temperature, reaction duration, methanol:oil ratio and catalyst concentration were evaluated with respect to the efficacy of the esterification reaction. The greatest efficiency of 98% with a high productivity rate of 2639.92 µmol·g−1·min−1 with k of 4.03 × 10−6 mole·S−1 was achieved with the following parameters: temperature, 70 °C; duration, 180 min; catalyst loading, 2 wt.%; and methanol to oil ratio, 15:1. The CuS-FeS/SiO2 catalyst showed relatively high stability indicated by its ability to be reused up to five times. Full article
(This article belongs to the Section Biomass Catalysis)
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16 pages, 5823 KB  
Article
Glycerol-Based Retrievable Heterogeneous Catalysts for Single-Pot Esterification of Palm Fatty Acid Distillate to Biodiesel
by Balkis Hazmi, Mahnoush Beygisangchin, Umer Rashid, Wan Nur Aini Wan Mokhtar, Toshiki Tsubota, Ali Alsalme and Chawalit Ngamcharussrivichai
Molecules 2022, 27(20), 7142; https://doi.org/10.3390/molecules27207142 - 21 Oct 2022
Cited by 10 | Viewed by 3958
Abstract
The by-product of the previous transesterification, glycerol was utilised as an acid catalyst precursor for biodiesel production. The crude glycerol was treated through the sulfonation method with sulfuric acid and chlorosulfonic acid in a reflux batch reactor giving solid glycerol-SO3H and [...] Read more.
The by-product of the previous transesterification, glycerol was utilised as an acid catalyst precursor for biodiesel production. The crude glycerol was treated through the sulfonation method with sulfuric acid and chlorosulfonic acid in a reflux batch reactor giving solid glycerol-SO3H and glycerol-ClSO3H, respectively. The synthesised acidic glycerol catalysts were characterised by various analytical techniques such as thermalgravimetric analyser (TGA), infrared spectroscopy, surface properties adsorption-desorption by nitrogen gas, ammonia-temperature programmed desorption (NH3-TPD), X-ray diffraction spectroscopy (XRD), elemental composition analysis by energy dispersive spectrometer (EDX) and surface micrographic morphologies by field emission electron microscope (FESEM). Both glycerol-SO3H and glycerol-ClSO3H samples exhibited mesoporous structures with a low surface area of 8.85 mm2/g and 4.71 mm2/g, respectively, supported by the microscopic image of blockage pores. However, the acidity strength for both catalysts was recorded at 3.43 mmol/g and 3.96 mmol/g, which is sufficient for catalysing PFAD biodiesel at the highest yield. The catalytic esterification was optimised at 96.7% and 98.2% with 3 wt.% of catalyst loading, 18:1 of methanol-PFAD molar ratio, 120 °C, and 4 h of reaction. Catalyst reusability was sustained up to 3 reaction cycles due to catalyst deactivation, and the insight investigation of spent catalysts was also performed. Full article
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16 pages, 2302 KB  
Article
Novel Approach to Ensure Safe Power Supply for Safety-Relevant Consumers
by Lars Braun, Minh Le, Jürgen Motz and Kai Peter Birke
Batteries 2022, 8(5), 47; https://doi.org/10.3390/batteries8050047 - 19 May 2022
Cited by 3 | Viewed by 4275
Abstract
The 12 V powernet in vehicles must fulfill certain safety requirements due to the safety demand of consumers. A potential risk is undervoltage for a safety-relevant consumer, which leads to its fault. Therefore, a novel approach is presented in this study, which can [...] Read more.
The 12 V powernet in vehicles must fulfill certain safety requirements due to the safety demand of consumers. A potential risk is undervoltage for a safety-relevant consumer, which leads to its fault. Therefore, a novel approach is presented in this study, which can predict the minimum terminal voltage for consumers. This consists of diagnostics of the wiring harness and of the lead-acid battery as well as predefined consumer currents. Using simulation, first the beginning of a drive cycle is simulated to determine the state of the powernet, and afterwards a critical driving maneuver is simulated to validate the predicted minimum terminal voltage. It demonstrates that the novel approach is able to predict a fault due to undervoltage. In addition to fulfilling safety requirements, the novel approach could be used to achieve additional availability and miniaturization of powernet components compared to the state of the art. Full article
(This article belongs to the Special Issue The Precise Battery—towards Digital Twins for Advanced Batteries)
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13 pages, 2176 KB  
Article
Sustainable Diesel from Pyrolysis of Unsaturated Fatty Acid Basic Soaps: The Effect of Temperature on Yield and Product Composition
by Endar Puspawiningtiyas, Oki Muraza, Hary Devianto, Meiti Pratiwi, Subagjo, Tirto Prakoso, Krisnawan, Usamah Zaki, Lidya Elizabeth, Tatang H. Soerawidjaja, Yohanes Andre Situmorang and Antonius Indarto
Molecules 2022, 27(3), 667; https://doi.org/10.3390/molecules27030667 - 20 Jan 2022
Cited by 7 | Viewed by 4697
Abstract
The production of sustainable diesel without hydrogen addition remains a challenge for low-cost fuel production. In this work, the pyrolysis of unsaturated fatty acid (UFA) basic soaps was studied for the production sustainable diesel (bio-hydrocarbons). UFAs were obtained from palm fatty acids distillate [...] Read more.
The production of sustainable diesel without hydrogen addition remains a challenge for low-cost fuel production. In this work, the pyrolysis of unsaturated fatty acid (UFA) basic soaps was studied for the production sustainable diesel (bio-hydrocarbons). UFAs were obtained from palm fatty acids distillate (PFAD), which was purified by the fractional crystallization method. Metal hydroxides were used to make basic soap composed of a Ca, Mg, and Zn mixture with particular composition. The pyrolysis reactions were carried out in a batch reactor at atmospheric pressure and various temperatures from 375 to 475 °C. The liquid products were obtained with the best yield (58.35%) at 425 °C and yield of diesel fraction 53.4%. The fatty acids were not detected in the pyrolysis liquid product. The gas product consisted of carbon dioxide and methane. The liquid products were a mixture of hydrocarbon with carbon chains in the range of C7 and C20 containing n-alkane, alkene, and iso-alkane. Full article
(This article belongs to the Section Applied Chemistry)
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10 pages, 4282 KB  
Article
Conversion of Waste Polyethylene Terephthalate (PET) Polymer into Activated Carbon and Its Feasibility to Produce Green Fuel
by Firdous Ahmad Ahangar, Umer Rashid, Junaid Ahmad, Toshiki Tsubota and Ali Alsalme
Polymers 2021, 13(22), 3952; https://doi.org/10.3390/polym13223952 - 16 Nov 2021
Cited by 38 | Viewed by 8206
Abstract
In this study, a novel idea was proposed to convert the polyethylene terephthalate (PET) waste drinking-water bottles into activated carbon (AC) to use for waste cooking oil (WCO) and palm fatty acid distillate (PFAD) feasibility to convert into esters. The acidic and basic [...] Read more.
In this study, a novel idea was proposed to convert the polyethylene terephthalate (PET) waste drinking-water bottles into activated carbon (AC) to use for waste cooking oil (WCO) and palm fatty acid distillate (PFAD) feasibility to convert into esters. The acidic and basic char were prepared by using the waste PET bottles. The physiochemical properties were determined by employing various analytical techniques, such as field emission scanning electron microscopy (FESEM), thermogravimetric analysis (TGA), Fourier transform infrared (FTIR), Brunauer–Emmett–Teller (BET) and temperature-programmed desorption – ammonia/carbon dioxide (TPD-NH3/CO2). The prepared PET H3PO4 and PET KOH showed the higher surface area, thus illustrating that the surface of both materials has enough space for impregnation of foreign precursors. The TPD-NH3 and TPD-CO2 results depicted that PET H3PO4 is found to have higher acidity, i.e., 18.17 mmolg−1, due to the attachment of phosponyl groups to it during pretreatment, whereas, in the case of PET KOH, the basicity increases to 13.49 mmolg−1. The conversion results show that prepared materials can be used as a support for an acidic and basic catalyst for the conversion of WCO and PFAD into green fuel. Full article
(This article belongs to the Special Issue Advance in Bioplastics)
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15 pages, 2112 KB  
Article
Bioreactor Rhamnolipid Production Using Palm Oil Agricultural Refinery By-Products
by Mohd Nazren Radzuan, James Winterburn and Ibrahim Banat
Processes 2021, 9(11), 2037; https://doi.org/10.3390/pr9112037 - 14 Nov 2021
Cited by 14 | Viewed by 4289
Abstract
Palm fatty acid distillate (PFAD) and fatty acid methyl ester (FAME) are used by P. aeruginosa PAO1 to produce rhamnolipid biosurfactant. The process of fermentation producing of biosurfactant was structured in a 2 L bioreactor using 2% of PFAD and FAME as carbon [...] Read more.
Palm fatty acid distillate (PFAD) and fatty acid methyl ester (FAME) are used by P. aeruginosa PAO1 to produce rhamnolipid biosurfactant. The process of fermentation producing of biosurfactant was structured in a 2 L bioreactor using 2% of PFAD and FAME as carbon sources in minimal medium and with a nitrogen concentration of 1 g L−1. Mass spectrometry results show the crude biosurfactant produced was predominantly monorhamnolipid (Rha-C10-C10) and dirhamnolipid (Rha-Rha-C10-C10) at 503 and 649 m/z value for both substrates. Maximum production of crude rhamnolipid for PFAD was 1.06 g L−1 whereas for FAME it was 2.1 g L−1, with a reduction in surface tension of Tris-HCl pH 8.0 solution to 28 mN m−1 and a critical micelle concentration (CMC) of 26 mg L−1 measured for both products. Furthermore, the 24 h emulsification indexes in kerosene, hexadecane, sunflower oil, and rapeseed oil using 1 g L−1 of crude rhamnolipid were in the range 20–50%. Consequently, PFAD and FAME, by-products from the agricultural refining of palm oil, may result in a product that has a higher added-value, rhamnolipid biosurfactant, in the process of integrated biorefinery. Full article
(This article belongs to the Topic Bioreactors: Control, Optimization and Applications)
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17 pages, 7718 KB  
Article
Renewable Diesel Production from Palm Fatty Acids Distillate (PFAD) via Deoxygenation Reactions
by Brenda Fernanda Honorato de Oliveira, Luiz Ferreira de França, Nádia Cristina Fernandes Corrêa, Nielson Fernando da Paixão Ribeiro and Mauricio Velasquez
Catalysts 2021, 11(9), 1088; https://doi.org/10.3390/catal11091088 - 9 Sep 2021
Cited by 16 | Viewed by 6120
Abstract
The reactions to produce liquid biofuels from a palm fatty acid distillate (PFAD) under hydrogen absence were carried out using 10 wt% NiO/zeolite (Ni/Zeo), 10 wt% Co3O4/zeolite (Co/Zeo), and 10 wt% (NiO + Co3O4)/zeolite (NiCo/Zeo) [...] Read more.
The reactions to produce liquid biofuels from a palm fatty acid distillate (PFAD) under hydrogen absence were carried out using 10 wt% NiO/zeolite (Ni/Zeo), 10 wt% Co3O4/zeolite (Co/Zeo), and 10 wt% (NiO + Co3O4)/zeolite (NiCo/Zeo) as catalysts. The zeolite was synthesized by a thermal and chemical treatment from natural clay, obtaining a zeolite A and sodalite mixture. Catalytic activity was evaluated as a function of reaction temperature (250, 300, and 350 °C) during 0.5 h and using 5 wt% of catalyst. The reaction products were classified as organic liquid products (OLPs), gaseous products, and solid waste. The OLPs fractions were separated by fractional distillation, and the products were identified and quantified using gas chromatography coupled to a mass spectrometer detector (GC-MS). The results showed yields to OLPs above 50% for all catalysts and temperatures. However, the highest yield to OLPs of 67.9% was reached with a NiCoZeo catalyst at 300 °C. In this reaction, a higher yield to hydrocarbons was obtained (84.8%), indicating a cooperative effect between Ni and Co in the catalyst. Hydrocarbons such as heptadecane (C17H36), pentadecane (C15H26), and other alkanes-alkenes with lower carbon chains were the main products. Therefore, deoxygenation of PFAD using a low-cost Ni-Co catalyst was shown to be an economic and viable way to produce diesel-type biofuels. Full article
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