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  • Article
  • Open Access
151 Views
23 Pages

Effects of PDADMAC Solution Pretreatment on Beech Wood—Waterborne Coating Interaction

  • Tanja Palija,
  • Daniela Djikanović,
  • Milica Rančić,
  • Marko Petrič and
  • Matjaž Pavlič

22 January 2026

This study builds on previous research into the surface modification of beech wood with polyethyleneimine (PEI) prior to finishing it with a waterborne coating. Poly(diallyldimethylammonium chloride) (PDADMAC) is introduced as an alternative cationic...

  • Article
  • Open Access
14 Citations
6,078 Views
13 Pages

21 April 2022

Polyelectrolyte complex (PEC) hydrogel, formed via physically electrostatic crosslinks between polyanion and polycation, is an interesting hydrogel in terms of its nontoxicity and solvent-free technique. In this work, poly (sodium 4-styrenesulfonate)...

  • Article
  • Open Access
10 Citations
3,990 Views
22 Pages

Complexation in Aqueous Solution of a Hydrophobic Polyanion (PSSNa) Bearing Different Charge Densities with a Hydrophilic Polycation (PDADMAC)

  • Nouha Jemili,
  • Martin Fauquignon,
  • Etienne Grau,
  • Nicolas Fatin-Rouge,
  • François Dole,
  • Jean-Paul Chapel,
  • Wafa Essafi and
  • Christophe Schatz

14 June 2022

In this work the electrostatic complexation of two strong polyelectrolytes (PEs) was studied, the hydrophilic and positively charged poly (diallyldimethylammonium chloride) (PDADMAC) and the hydrophobic and negatively charged poly (styrene-co-sodium...

  • Article
  • Open Access
83 Citations
12,428 Views
17 Pages

Adsorption of Polyelectrolyte onto Nanosilica Synthesized from Rice Husk: Characteristics, Mechanisms, and Application for Antibiotic Removal

  • Tien Duc Pham,
  • Thu Thuy Bui,
  • Van Thanh Nguyen,
  • Thi Kieu Van Bui,
  • Thi Thuy Tran,
  • Quynh Chi Phan,
  • Tien Dat Pham and
  • Thu Ha Hoang

23 February 2018

Adsorption of the polyelectrolyte polydiallyldimethylammonium chloride (PDADMAC) onto nanosilica (SiO2) fabricated from rice husk was studied in this work. Nanosilica was characterized by X-ray diffraction, Fourier-transform infrared spectroscopy (FT...

  • Article
  • Open Access
1 Citations
2,467 Views
18 Pages

A Comparison of Interpolyelectrolyte Complexes (IPECs) Made from Anionic Block Copolymer Micelles and PDADMAC or q-Chitosan as Polycation

  • Özge Azeri,
  • Dennis Schönfeld,
  • Bin Dai,
  • Uwe Keiderling,
  • Laurence Noirez and
  • Michael Gradzielski

6 May 2023

Block copolymers synthesized via Atom Transfer Radical Polymerization from alkyl acrylate and t-butyl acrylate and the subsequent hydrolysis of the t-butyl acrylate to acrylic acid were systematically varied with respect to their hydrophobic part by...

  • Article
  • Open Access
19 Citations
3,656 Views
13 Pages

Adsorptive Removal of Anionic Azo Dye New Coccine Using Silica and Silica-gel with Surface Modification by Polycation

  • Tien Duc Pham,
  • Viet Phuong Bui,
  • Thuy Nga Pham,
  • Thi Mai Dung Le,
  • Kim Thuy Nguyen,
  • Van Hoi Bui and
  • The Dung Nguyen

11 May 2021

In the present work, adsorption of anionic azo dye, new coccine (NCC) on silica and silica-gel in an aquatic environment was discovered. Effective conditions such as adsorption time, pH, the influence of dosage on NCC adsorption using strong polycati...

  • Article
  • Open Access
1 Citations
1,677 Views
14 Pages

21 August 2024

Mercury (Hg) is a toxic element which impacts on biological systems and ecosystems. Because the toxicity of Hg species is highly dependent on their concentration levels and chemical forms, the sensitive identification of the chemical forms of Hg&mdas...

  • Article
  • Open Access
8 Citations
10,552 Views
18 Pages

Towards a Sustainable Water Supply: Humic Acid Removal Employing Coagulation and Tangential Cross Flow Microfiltration

  • Mohammed Wali Hakami,
  • Abdullah Alkhudhiri,
  • Myrto-Panagiota Zacharof and
  • Nidal Hilal

8 October 2019

Synthetic solutions assimilating irrigated groundwater containing varying concentrations of humic acid (10 mg/L), saline (10–35 g/L) and metal agents (5–10 mg/L), were processed through a ceramic microfiltration membrane (Sterilox Ltd., 0...

  • Article
  • Open Access
8 Citations
7,453 Views
11 Pages

Poly-diallyldimethylammonium (PDADMAC) chloride is a flocculant agent extensively used in water clarification treatments. Commercial polyelectrolyte formulations often contain residual monomer (DADMAC), reaction by-products and other reactants as con...

  • Article
  • Open Access
17 Citations
7,116 Views
16 Pages

The Effect of Temperature Treatment on the Structure of Polyelectrolyte Multilayers

  • Maximilian Zerball,
  • André Laschewsky,
  • Ralf Köhler and
  • Regine Von Klitzing

2 April 2016

The study addresses the effect of thermal treatment on the internal structure of polyelectrolyte multilayers (PEMs). In order to get insight into the internal structure of PEMs, Neutron Reflectometry (NR) was used. PEMs with a deuterated inner block...

  • Article
  • Open Access
849 Views
10 Pages

Polymer Electrolyte-Gated Organic Electrochemical Transistors for Bioinspired Neuromorphic Computing

  • Banghua Wu,
  • Lin Gao,
  • Yujie Peng,
  • Changjian Liu,
  • Canghao Xu,
  • Haihong Guo,
  • Yong Huang and
  • Junsheng Yu

Organic electrochemical transistors (OECTs) are compelling artificial synapses because mixed ionic–electronic coupling and transport enables low-voltage, analog weight updates that mirror biological plasticity. Here, we engineered solid-state,...

  • Article
  • Open Access
8 Citations
4,292 Views
16 Pages

PDADMAC/PSS Oligoelectrolyte Multilayers: Internal Structure and Hydration Properties at Early Growth Stages from Atomistic Simulations

  • Pedro A. Sánchez,
  • Martin Vögele,
  • Jens Smiatek,
  • Baofu Qiao,
  • Marcello Sega and
  • Christian Holm

17 April 2020

We analyze the internal structure and hydration properties of poly(diallyl dimethyl ammonium chloride)/poly(styrene sulfonate sodium salt) oligoelectrolyte multilayers at early stages of their layer-by-layer growth process. Our study is based on larg...

  • Article
  • Open Access
3 Citations
2,268 Views
12 Pages

28 March 2023

Aqueous formulations based on anionic butadiene-styrene microspheres (BSMs) and cationic poly(diallyldimethylammonium chloride) (PDADMAC) with the weight PDADMAC fraction from 0 to 1 were studied as the stabilizers of loose sandy soils. In general, t...

  • Article
  • Open Access
14 Citations
2,759 Views
14 Pages

21 November 2022

Carrageenan is a polysaccharide of a plant origin, commonly used as a thickening and gelling agent in the food, pharmaceutical, and cosmetic industries. Due to the negative charges of its sulfate groups, carrageenan macromolecules strongly interact w...

  • Article
  • Open Access
8 Citations
4,382 Views
18 Pages

Determination of SLES in Personal Care Products by Colloid Titration with Light Reflection Measurements

  • Dorota Ziółkowska,
  • Iryna Syrotynska,
  • Alexander Shyichuk and
  • Jan Lamkiewicz

The method of colloid titration with poly(diallyldimethylammonium) chloride has been improved to detect the endpoint with an off-vessel light reflectance sensor. The digital color sensor used measures light reflectance by means of light guides, with...

  • Article
  • Open Access
11 Citations
2,874 Views
15 Pages

Pattern Formation upon Evaporation of Sessile Droplets of Polyelectrolyte/Surfactant Mixtures on Silicon Wafers

  • Lionel Perrin,
  • Andrew Akanno,
  • Eduardo Guzman,
  • Francisco Ortega and
  • Ramon G. Rubio

The formation of coffee-ring deposits upon evaporation of sessile droplets containing mixtures of poly(diallyldimethylammonium chloride) (PDADMAC) and two different anionic surfactants were studied. This process is driven by the Marangoni stresses re...

  • Article
  • Open Access
20 Citations
3,753 Views
12 Pages

19 March 2022

Polymer coatings based on polycations represent a perspective class of protective antimicrobial coatings. Polydiallyldimethylammonium chloride (PDADMAC) and its water-soluble complexes with sodium polystyrenesulfonate (PSS) were studied by means of d...

  • Article
  • Open Access
3 Citations
1,967 Views
19 Pages

A modified activated carbon (AC) was developed by modifying with poly(diallyldimethylammonium) chloride (PDADMAC) to enhance its adsorption performance for water treatment applications. Different PDADMAC concentrations were explored and evaluated usi...

  • Article
  • Open Access
18 Citations
4,085 Views
15 Pages

Interfacial Behavior of Solid- and Liquid-like Polyelectrolyte Complexes as a Function of Charge Stoichiometry

  • Hongwei Li,
  • Martin Fauquignon,
  • Marie Haddou,
  • Christophe Schatz and
  • Jean-Paul Chapel

7 November 2021

We systematically investigate in this work the surface activity of polyelectrolyte complex (PECs) suspensions as a function of the molar charge ratio Z (= [-]/[+]) from two model systems: the weakly and strongly interacting poly (diallyldimethylammon...

  • Article
  • Open Access
3 Citations
1,267 Views
16 Pages

10 February 2025

A novel, eco-friendly and cost-effective adsorbent, poly(diallyldimethylammonium) chloride (PDADMAC)-modified clay was developed to enhance its efficacy in removing Methyl Red (MR) from water. Different concentrations of PDADMAC solutions were evalua...

  • Communication
  • Open Access
3 Citations
2,770 Views
9 Pages

2 March 2023

Biocidal compositions based on interpolyelectrolyte complexes and a low molecular weight antibiotic can become a promising material for creating biocidal coatings, as they combine wash-off resistance and dual biocidal action due to the biocide and th...

  • Article
  • Open Access
7 Citations
2,917 Views
16 Pages

Model Surfaces for Paper Fibers Prepared from Carboxymethyl Cellulose and Polycations

  • Cassia Lux,
  • Thomas Tilger,
  • Ramsia Geisler,
  • Olaf Soltwedel and
  • Regine von Klitzing

29 January 2021

For tailored functionalization of cellulose based papers, the interaction between paper fibers and functional additives must be understood. Planar cellulose surfaces represent a suitable model system for studying the binding of additives. In this wor...

  • Article
  • Open Access
1 Citations
1,832 Views
14 Pages

Ag2O-Containing Biocidal Interpolyelectrolyte Complexes on Glass Surfaces—Adhesive Properties of the Coatings

  • Vladislava A. Pigareva,
  • Oleg S. Paltsev,
  • Valeria I. Marina,
  • Dmitrii A. Lukianov,
  • Andrei V. Moiseenko,
  • Nikita M. Shchelkunov,
  • Andrey A. Fedyanin and
  • Andrey V. Sybachin

13 December 2023

Biocidal coatings are of great interest to the healthcare system. In this work, the biocidal activity of coatings based on a complex biocide containing polymer and inorganic active antibacterial components was studied. Silver oxide was distributed in...

  • Feature Paper
  • Article
  • Open Access
31 Citations
4,031 Views
16 Pages

Two Different Scenarios for the Equilibration of Polycation—Anionic Solutions at Water–Vapor Interfaces

  • Eduardo Guzmán,
  • Laura Fernández-Peña,
  • Andrew Akanno,
  • Sara Llamas,
  • Francisco Ortega and
  • Ramón G. Rubio

The assembly in solution of the cationic polymer poly(diallyldimethylammonium chloride) (PDADMAC) and two different anionic surfactants, sodium lauryl ether sulfate (SLES) and sodium N-lauroyl-N-methyltaurate (SLMT), has been studied. Additionally, t...

  • Article
  • Open Access
1 Citations
1,980 Views
14 Pages

The in situ synthesis of Fe0 particles using poly-(acrylic acid) (PAA) is an effective tool for fabricating catalytic membranes relevant to advanced oxidation processes (AOPs). Through their synthesis in polyelectrolyte multilayer-based nanofiltratio...

  • Article
  • Open Access
6 Citations
2,884 Views
19 Pages

Enhanced Coagulation for Algae Removal Using Composite Al-Based Coagulants: Collaborative Optimization Mechanism of Aluminum Morphology

  • Yangyuan Zhou,
  • Dawei Zhang,
  • Guosheng Zhang,
  • Weiying Li,
  • Ningzheng Zhu,
  • Jinpei Bo,
  • Xiangzhou Meng,
  • Yao Chen,
  • Yu Qin and
  • Huajie Liu

The main purpose of this paper was to reveal the effect of aluminum (Al)-based coagulants on enhanced coagulation for the removal of algae and the synergistic optimization mechanism among different Al species. The formation, breakage, and regrowth pr...

  • Article
  • Open Access
5 Citations
2,762 Views
16 Pages

Biocidal Coatings against Gram-Positive Bacteria from Linear and Branched Polycations: The Decisive Role of the Diffusion Coefficients of Macromolecules

  • Vladislava A. Pigareva,
  • Valeria I. Marina,
  • Anastasia V. Bolshakova,
  • Anna K. Berkovich,
  • Oksana A. Kuznetsova,
  • Anastasia A. Semenova,
  • Yulia K. Yushina,
  • Dagmara S. Bataeva,
  • Maria A. Grudistova and
  • Andrey V. Sybachin

10 June 2023

Positively charged polyelectrolytes hold significant potential as materials for creating antibacterial coatings. We examined the physicochemical and mechanical properties of the macromolecules in water solutions and in coatings for the series of bran...

  • Article
  • Open Access
26 Citations
4,646 Views
16 Pages

23 September 2019

The bulk and interfacial properties of solutions formed by a polycation (i.e., poly(diallyl-dimethylammonium chloride), PDADMAC) and two different zwitterionic surfactants (i.e., coco-betaine (CB) and cocoamidopropyl-betaine (CAPB)) have been studied...

  • Article
  • Open Access
21 Citations
3,857 Views
13 Pages

28 November 2018

Sequential adsorption of polyelectrolytes on nanoparticles is a popular method to obtain thin films after deposition. However, the effect of polyelectrolyte multilayer formation on the colloidal stability of the nanoparticles has not been studied in...

  • Feature Paper
  • Article
  • Open Access
20 Citations
7,177 Views
13 Pages

19 April 2016

Quantifying the effect that nanofiber mat chemistry and hydrophilicity have on microorganism collection and inactivation is critical in biomedical applications. In this study, the collection and inactivation of Escherichia coli K12 was examined using...

  • Article
  • Open Access
3 Citations
2,487 Views
15 Pages

6 March 2024

Swine wastewater (SW) was treated using industrial wastes as raw materials in a pre-treatment process (coagulation or adsorption), followed by a continuous heterogeneous Fenton reaction. Before the treatment conducted as a continuous operation, two d...

  • Feature Paper
  • Article
  • Open Access
2 Citations
3,641 Views
18 Pages

Positively charged water-solid interfaces are prepared by adsorption of a cationic polyelectrolyte poly(diallyldimethylammonium chloride) (PDADMAC) from aqueous solutions to planar silica substrates. These substrates are characterized by atomic force...

  • Article
  • Open Access
9 Citations
4,010 Views
13 Pages

A Comparative Study on the Flocculation of Silica and China Clay with Chitosan and Synthetic Polyelectrolytes

  • Konstantin B. L. Borchert,
  • Christine Steinbach,
  • Simona Schwarz and
  • Dana Schwarz

10 February 2021

Flocculation is still one of the most important and efficient processes for water treatment. However, most industrial processes, such as in water treatment plants, still use huge amounts of synthetic polyelectrolytes for the flocculation process. Her...

  • Article
  • Open Access
10 Citations
4,306 Views
25 Pages

Evaporation of Sessile Droplets of Polyelectrolyte/Surfactant Mixtures on Silicon Wafers

  • Andrew Akanno,
  • Lionel Perrin,
  • Eduardo Guzmán,
  • Sara Llamas,
  • Victor M. Starov,
  • Francisco Ortega,
  • Ramón G. Rubio and
  • Manuel G. Velarde

The wetting and evaporation behavior of droplets of aqueous solutions of mixtures of poly(diallyldimethylammonium chloride) solution, PDADMAC, with two different anionic surfactants, sodium laureth sulfate, SLES, and sodium N-lauroyl N-methyl taurate...

  • Article
  • Open Access
3 Citations
2,061 Views
15 Pages

Separation of Magnesium and Lithium Ions Utilizing Layer-by-Layer Polyelectrolyte Modification of Polyacrylonitrile Hollow Fiber Porous Membranes

  • Danai Koukoufilippou,
  • Ioannis L. Liakos,
  • George I. Pilatos,
  • Niki Plakantonaki,
  • Alexandros Banis and
  • Nikolaos K. Kanellopoulos

30 November 2024

This study explores the layer-by-layer (LBL) modification of polyacrylonitrile (PAN) hollow fibers for effective Mg2+/Li+ separation. It employs an LBL method of surface modification using polyelectrolytes, specifically aiming to enhance ion selectiv...

  • Article
  • Open Access
1,019 Views
15 Pages

2 August 2025

Silica-modified electrodes possess physicochemical properties that make them valuable in electrochemical sensing and energy-related applications. Although intrinsically insulating, silica thin films can selectively interact with redox species, produc...

  • Article
  • Open Access
9 Citations
3,687 Views
13 Pages

14 September 2020

In order to improve the luminescent stability of water-based anti-counterfeit ink, a new fluorescent material is prepared by doping dye into silica nanoparticles. Water soluble anionic dye 1, 3, 6, 8-pyrenesulfonic acid sodium salt (PTSA) is selected...

  • Article
  • Open Access
11 Citations
5,124 Views
12 Pages

Poly(3,4-Ethylenedioxythiophene) Nanoparticles as Building Blocks for Hybrid Thermoelectric Flexible Films

  • Jose F. Serrano-Claumarchirant,
  • Mario Culebras,
  • Andrés Cantarero,
  • Clara M. Gómez and
  • Rafael Muñoz-Espí

28 December 2019

Hybrid thermoelectric flexible films based on poly(3,4-ethylenedioxythiophene) (PEDOT) nanoparticles and carbon nanotubes were prepared by using layer-by-layer (LbL) assembly. The employed PEDOT nanoparticles were synthesized by oxidative miniemulsio...

  • Article
  • Open Access
6 Citations
3,986 Views
12 Pages

Layer-by-Layer (LbL) Surface Augmented Modification of Poly(Styrene/Divinylbenzene)High Internal Phase Emulsion for Carbon Dioxide Capture

  • Muhammad Imran Azman,
  • Jirasuta Chungprempree,
  • Jitima Preechawong,
  • Pornsri Sapsrithong and
  • Manit Nithitanakul

9 July 2021

In this study, we used amines electrolyte solution with layer-by-layer (LbL) technique to modify and increase the CO2 adsorption capacity of highly porous polymer from high internal phase emulsion template polymer. This perspective presents the extra...

  • Article
  • Open Access
23 Citations
4,991 Views
15 Pages

10 December 2020

The characterization of membranes is suitable to investigate changes in the membrane properties caused by Layer-by-Layer (LbL) modification. Besides permeability, rejection, and molecular-weight cut-off (MWCO), which give information about the modifi...

  • Article
  • Open Access
9 Citations
3,104 Views
18 Pages

10 October 2022

Responsive materials, i.e., smart materials, have the ability to change their physical or chemical properties upon certain external signals. The development of nanofibrous halochromic materials, specifically combining the pH-sensitive functionality a...

  • Article
  • Open Access
123 Citations
17,425 Views
23 Pages

pH and Salt Effects on the Associative Phase Separation of Oppositely Charged Polyelectrolytes

  • Prateek K. Jha,
  • Priyanka S. Desai,
  • Jingyi Li and
  • Ronald G. Larson

16 May 2014

The classical Voorn-Overbeek thermodynamic theory of complexation and phase separation of oppositely charged polyelectrolytes is generalized to account for the charge accessibility and hydrophobicity of polyions, size of salt ions, and pH variations....

  • Article
  • Open Access
8 Citations
3,825 Views
17 Pages

27 April 2021

The plant cell mechanics, including turgor pressure and wall mechanical properties, not only determine the growth of plant cells, but also reflect the functional and structural changes of plant cells under biotic and abiotic stresses. However, there...

  • Proceeding Paper
  • Open Access
83 Views
7 Pages

11 November 2025

Recently, interest in multifunctional materials has increased; therefore, we developed a system that combines biocompatibility, gradient changing, and antibacterial properties. We aim to combine these properties in the development of a biomimetic sys...