Search Results (726)

Single memristive nanowire networks have emerged as a promising pathway for energy-efficient neuromorphic computing, owing to their intrinsic nonlinearity, high dimensionality, fading memory and volatile switching dynamics relevant to physical reservoir computing. While prior works focused on oxide- or silver-based network systems, these approaches face trade-offs between operating voltage, cost, stability, and scalability. This work presents a proof-of-concept demonstration of stochastic polyvinylpyrrolidone (PVP)-coated nickel nanowire networks as low-cost and scalable memristive platforms, exhibiting low-voltage resistive switching (1–2 V). The electrical characterization reveals predominantly volatile resistive switching combined with nonvolatile behavior, consistent with a filamentary conduction mechanism at nanowire junctions. The switching dynamics are governed by the polymer coating thickness, with an intermediate PVP concentration (Ni@PVP = 1:25) showing optimal performance, with a resistance ratio of ~200, stable retention over 1 h, and a reproducible endurance of over 45 cycles. These results establish Ni@PVP nanowire networks as promising memristive platforms for neuromorphic hardware applications and physical reservoir computing, with relevant properties such as fading memory and nonlinear dynamics. Full article

This study aims to develop high-performance hybrid nanocomposites for solid-state energy conversion. We achieved this by improving charge transport and thermoelectric efficiency through the interaction of polymers, nanoparticles, and ionic liquids. Nickel oxide nanoparticles (NiO NPs) were synthesized via a sonochemical route using a novel ionic liquid, 1,2-(propan). In our recent work, this approach enabled the formation of a hybrid [NiO NPs + IL] system, which was subsequently incorporated at different loadings (8, 15, and 30 wt.%) and coated with polyethylene glycol (PEG). The resulting nanocomposites were investigated to elucidate charge-transport mechanisms and assess the influence of the polymer coating on their optical, electrical, and thermal transport properties. Optical measurements showed a shift in the band gap due to π–π* electronic transitions. This effect indicates strong interface interactions. The PEG-coated [NiO NPs + IL] nanocomposites exhibited significantly enhanced charge-carrier mobility, resulting in improved electrical conductivity. Remarkably, a high Seebeck coefficient of 720 μV/K and an electrical conductivity of 0.35 S/cm were achieved, resulting in a maximum power factor of 24.74 μW/m·K², surpassing many recently reported polymer-based nanocomposites. PEG-coated [NiO NPs + IL] systems offer tunable optical properties and superior thermoelectric performance. Consequently, they are a promising alternative to conventional nanocomposites for sustainable energy conversion. Full article

MoS₂ acts as a high-performance lubricant, enhancing friction material stability, reducing wear and noise under extreme conditions, and preserving friction pair performance. However, its tendency to decompose and poor matrix wettability make surface modification essential for effective use in Cu-based composites. In this study, comprehensive investigations combining macro-scale and micro-scale friction experiments were conducted to examine the interfacial friction behavior of MoS₂ with different coatings and its tribological effects on copper-based composites under varying braking energy densities. The results indicate that the nickel coating suppressed MoS₂ decomposition, forming a high-strength diffusion interface with the matrix. This enhances the frictional stability and suppresses interfacial defect formation during micro-friction tests. However, the copper coating formed a poor-strength diffusion-reacting interface with matrix, leading to unstable friction at the interface and interface failure. Coating-dependent interfacial properties and micro-friction behaviors lead to varying tribological performance in Cu-based composites with MoS₂ during macro-friction tests. Nickel-plated MoS₂ (MoS₂@Ni) exhibits superior lubrication and frictional stability. The friction coefficients of Cu-based composites with MoS₂@Ni under low, medium and high working conditions are 0.36, 0.3 and 0.24, respectively, which are 6%, 12% and 13% lower than those of copper-plated MoS₂ (MoS₂@Cu). Meanwhile, its friction stability is 0.8, 0.6 and 0.58, respectively. With rising braking energy density, wear in Cu-based composites transitions from ploughing to oxidation and then to delamination. Defective MoS₂@Cu/matrix interfaces intensify delamination wear caused by the unstable fracture of subsurface plastic deformation layer cracks at higher energy density. Full article

In the present study, the electrodeposition of thin Ni–Fe films obtained from aqueous electrolytes containing nickel (II) and iron (II) sulfates and chlorides is investigated. The study particularly emphasizes the influence of electrolyte additives—boric acid, chloride ions, and Na₂EDTA—on the electrochemical behavior, microstructure, and magnetic properties of the deposited layers. Cyclic voltammetry revealed a partial alignment of the reduction potentials of nickel and iron and the suppression of the hydrogen evolution side reaction up to −1 V. Electrodeposition in galvanostatic mode in the range of 0.5 to 1.0 A/dm² allows the formation of layers with iron contents between 20.5 wt. % to 41.4 wt. % and coating thickness from 1.3 to 3.0 µm. SEM and AFM observations demonstrated a pronounced dependence of the surface morphology on the current density, with higher current densities promoting the formation of dendritic structures. X-ray diffraction confirmed the dominance of a face-centered cubic (FCC) Ni-based solid solution, accompanied by minor contributions from non-stoichiometric Fe_1−xO. All the obtained Fe-Ni films have soft magnetic properties. Increasing the current density and the boric acid concentration causes the coercive force and isotropy of the layers to improve. The results demonstrate that thin Ni-Fe films with controlled structure and morphology, with favorable soft ferromagnetic properties suitable for functional applications, could be electrodeposited from complex chloride–sulfate electrolytes by adjusting the current density. Full article

Engineering carbon nanostructures directly on carbon fiber fabrics offers an effective route to constructing hierarchical multifunctional coating systems. In this study, methane-based chemical vapor deposition (CVD) was employed to investigate nanocarbon coating formation on woven carbon fabrics supported by electrodeposited Ni catalysts. Catalyst morphology was systematically engineered through surface pretreatment, electric-field configuration, and pulse electrodeposition. At 700 °C, methane activation was insufficient to sustain continuous nanocarbon growth, indicating a temperature-dependent activation threshold. Raising the growth temperature to 900 °C enabled sustained methane decomposition and produced dense nanocarbon coatings; hydrogen assistance suppressed amorphous deposition and promoted more ordered nanofilament features. Pulse electrodeposition refined Ni catalyst dispersion and nucleation density, improving coating uniformity compared with direct-current deposition. Structural ordering was further supported by Raman spectroscopy (D and G bands with an average ID/IG of 0.678 ± 0.068 for methane-grown samples versus 0.798 ± 0.011 for electrodeposition-only controls) and by HRTEM revealing multi-layer graphitic walls (~0.34 nm interlayer spacing). Together, the results support a methane-derived dissolution–diffusion–precipitation growth pathway governed by catalyst morphology, temperature, and gas composition. This controllable, textile-compatible catalyst engineering approach provides a scalable route to hierarchical graphitic coatings for carbon-fabric-based composites, electromagnetic interference shielding, and thermal management applications. Full article

The antimicrobial activity of multicomponent, magnetron-sputtered glass coatings was evaluated against phytopathogenic fungi (Botrytis cinerea, Fusarium oxysporum, Cladosporium fulvum, Alternaria solani) and the chromista Phytophthora infestans, with Aspergillus fumigatus included as a model opportunistic pathogen. Fourteen Cu-based multicomponent coatings were deposited on glass using multi-alloy targets composed of Sn, Zn, Al, Ni, Fe, Ti, Mn, Nb, or Co in two high-transmittance variants (≥85% and ≥88%). Antimicrobial activity was assessed in two assays: (A) spore survival after 24–72 h contact, and (B) hyphal growth over 7 days following coating exposure under light and dark conditions. Spore viability decreased after incubation on high-Cu coatings, which showed inhibition for most strains, particularly B. cinerea, F. oxysporum, and P. infestans. The effects on spore germination were independent of the direct transmittance value of the coated glass. Hyphal growth was generally less affected by a high Cu content for most strains. Hyphal growth of F. oxysporum, C. fulvum, A. solani and B. cinerea was reduced by up to 30% on selected multicomponent coatings. For most strains, hyphal growth showed no inhibition after light incubation on coatings. However, light-dependent effects were observed for A. solani, A. fumigatus and P. infestans, while B. cinerea and C. fulvum showed reduced sensitivity during the first two days. High-Cu coatings were most effective at inhibiting spore germination, whereas hyphal growth on multicomponent coatings may respond to different ions. Therefore, high-Cu, two-component coatings may be recommended for practical greenhouse applications. Full article

Thermal barrier coatings (TBCs) are an effective means of providing thermal insulation and protecting the hot-section components of gas turbine engines. Their quality and performance characteristics largely depend on the microstructural features and the bond strength between the bonding layer and the substrate. The present study aims to determine the optimal plasma spraying parameters that ensure the formation of NiCrAlY coatings with superior microstructural integrity and adhesion strength. The objective of the study is a thermally sprayed nickel–chromium–aluminum–yttrium (NiCrAlY) bond coat deposited onto an Inconel 718 nickel-based superalloy, which is widely used in aircraft gas turbine engines due to its high strength and excellent oxidation resistance at elevated temperatures. It was found that the coating produced under the optimized conditions exhibited a significantly higher adhesion strength compared with the samples obtained under other spraying regimes. The results confirm that a precise adjustment of the atmospheric plasma spraying (APS) process parameters, taking into account the equipment configuration, allows for a substantial improvement in coating quality and performance. Full article

Molybdenum disulfide (MoS₂)-based composite systems are widely used as solid lubricating coatings. However, further optimization towards lower friction and higher wear resistance remains necessary to meet the extreme operating conditions and high reliability requirements of next-generation aerospace equipment. This study investigated the tribological performance of MoS₂/epoxy composite coatings by comparing the effects of individual and combined additions of nano nickel (Ni) and magnesium silicate hydroxide (MSH). The coating preparation process adopted in this study is the bonding method. Experimental results showed that, under a load of 2 N and a rotational speed of 500 r/min, the coating containing 0.3 g Ni and 0.1 g MSH (labeled W03Ni01MSH) achieved a 22% reduction in wear scar width compared to the coating with only Ni, demonstrating a distinct synergistic effect. This is attributed to the complementary roles of the two additives: Ni promotes the formation of flaky wear debris, facilitating rapid formation and stabilization of a transfer film, thereby reducing friction; MSH enhances the load carrying capacity of the coating and suppresses wear propagation, thereby improving wear resistance. Furthermore, this composite coating exhibited optimal performance under the conditions of 500 r/min and 2 N. The results of this study significantly improved the friction-reducing and wear-resistant properties of the MoS₂/epoxy composite coating. This provides a new strategy for the formulation design of high-performance solid lubricating coatings. Full article

The control of cladding layer morphology is crucial in laser cladding technology. However, traditional process parameter-based regulation suffers from parameter coupling issues, and previous nanosecond laser pretreatment is prone to causing uneven substrate morphology due to significant thermal effects. This study proposes a novel substrate pretreatment method using femtosecond laser etching, employing 45 steel as the substrate and Ni45 powder as the cladding material to investigate its regulatory effect on cladding layer morphology. The results show that femtosecond laser etching enables a good linear correlation between substrate roughness and laser power, forming uniform grid-like microgrooves without the spherical remelted structures observed in nanosecond laser treatment, thus achieving superior regulatory stability. With the increase in substrate roughness, the contact angle and dilution rate of the cladding layer decrease, while the cladding height and width increase, with the optimal cladding quality obtained in the roughness range of 4~7 μm. This study reveals the intrinsic mechanism by which femtosecond laser regulates molten pool behavior through mechanical anchoring and groove guiding effects, providing a more stable technical pathway for the preparation of high-quality cladding coatings. Full article

An innovative preparation route for iron-based soft magnetic materials is presented, focusing on the influence of the mechanical surface treatment of powder particles on their structural and magnetic properties. High-purity Fe (99.98% purity) and FeNiMo (supermalloy) powders were mechanically milled (ball-to-powder ratio of 6:1; 120 min), surface-treated by controlled milling, coated with an inorganic SiO₂ insulating layer, and subsequently compacted into ring-shaped specimens. Structural characterization was carried out using optical microscopy and scanning electron microscopy. Magnetic properties were evaluated by hysteresis loop measurements, initial magnetization curves, and coercivity analysis at 200 K. The results demonstrate that mechanical surface treatment improves the homogeneity and continuity of the SiO₂ insulating layer. This improvement leads to reduced coercivity from 2100 to 1980 A·m⁻¹ for Fe powders, while FeNiMo powders showed a decrease from 1990 to 1910 A·m⁻¹, along with lower energy losses. The proposed method provides a laboratory-scale approach for studying the influence of powder surface treatment on the magnetic behavior of Fe-based soft magnetic composites. Full article

The generation of high-purity hydrogen via chemical reaction from hydrogen-rich materials is one of the ways in the alternative energy industry. In this approach, the utilization of catalytic materials that possess the capacity to initiate the decomposition of the starting material and the subsequent release of hydrogen is of paramount importance. In this study, nickel/cobalt-plated copper catalysts (NiCo/Cu) are presented, comprising from 4 to 90 wt.% of cobalt as catalytic materials for hydrogen generation via sodium borohydride (NaBH₄) hydrolysis reaction. The NiCo/Cu catalysts were synthesized via electroless deposition from glycine-based baths, utilizing Ni²⁺ and Co²⁺ ions as metal sources and morpholine borane (MB) as the reducing compound. The catalytic performance in alkaline NaBH₄ hydrolysis was found to correlate with the cobalt loading in the coating. The maximum rate of hydrogen production, which was determined to be 14.22 L min⁻¹ gcat⁻¹, was achieved at 343 K for a catalyst composed of 90 wt.% Co. The reaction proceeded with the activation energy of 52.5 kJ mol⁻¹, while the catalyst exhibited high durability, preserving nearly 88% of its initial activity after five successive reaction cycles. The combination of nickel and cobalt, along with their synergistic effect and high efficiency in the borohydride hydrolysis reaction, makes them promising catalysts. Full article

This study utilized oscillating laser cladding technology to fabricate nickel-based composite coatings, systematically investigating the influence of varying laser powers on their morphology, microstructure, and properties. The results indicate that as laser power increases from 800 W to 1400 W, the dilution rate of the coating exhibits a non-monotonic change, reaching a maximum at an intermediate laser power due to the competing effects of enhanced substrate melting and melt-pool instability. The microstructure of the coatings is primarily composed of dendritic and equiaxed crystals. Elemental analysis revealed that Ni is predominantly enriched within the dendritic regions, whereas Cr segregates toward the grain boundary areas. Furthermore, the microhardness of the coating, as well as its anti-wear and anti-corrosion properties, are positively correlated with the laser power. When the power reaches the maximum value of 1400 W studied, the performance of the coating significantly improves. The average hardness is 482 HV, and the relative wear resistance is approximately 1.8 times that of the coating when the power is 800 W. The corrosion current density is 9.04 × 10⁻⁷ A/cm². Full article

Electroless Ni–P coatings are widely used for corrosion and wear protection, yet their ability to deliver water-based superlubricity and the role of phosphorus content remain insufficiently understood. Here, electroless Ni–P coatings with four P contents (3.4, 6.4, 9.0, and 12.4 wt%) were deposited on GCr15 steel with nearly constant thickness and comparable initial roughness, and were tested against Si₃N₄ balls in neutral 0.5 M NaH₂PO₂ solution. Friction measurements, together with surface topography characterization and tribofilm analysis, were used to link P content with tribofilm chemistry and superlubricity. All coatings achieved macroscale superlubricity, exhibiting steady-state friction coefficients below 0.01, while the running-in time decreased markedly as P content increased. During sliding, the wear tracks underwent mechano-chemical polishing to Sa ≈ 11–12 nm and formed phosphate–silicate tribofilms enriched in P–O and Si–O species on both the coating and the counterface. These findings establish a composition–tribofilm–superlubricity relationship in the Ni–P/NaH₂PO₂ system and demonstrate that P-content optimization is an effective internal design lever to accelerate running-in, mitigate wear, and achieve robust superlubricity under neutral aqueous lubrication. Full article

In the present work, the effect of the composition of the metal binder (Co–Cr, Ni, and NiCr) on the structure and performance properties of WC-based coatings obtained by detonation spraying is investigated. The coatings were characterized using microstructural analysis, EDS mapping, microhardness measurements, tribological testing, and corrosion analysis. The results show that changing the type of binder significantly affects the porosity, distribution of the WC phase, hardness, and tribological behavior of the coatings. The best combination of properties—the lowest coefficient of friction, highest hardness, and the highest corrosion resistance—was obtained for the WC–Co–Cr coating. These results indicate the potential of these coatings for extending the service life of pipeline fittings and equipment in the oil and gas sector. Full article

High-entropy coatings based on CoCrFeNiMn obtained by thermal spraying have demonstrated the potential to improve the wear resistance of traditional materials used in extreme conditions. The aim of the work was to study the effect of the oxygen/fuel ratio when using kerosene as fuel in the HVOF process on the microstructural characteristics of CoCrFeNiMn coatings, including phase composition, microhardness, elastic modulus, and wear resistance. Phase and microstructural transformations in gas-atomized powder during HVOF spraying were analyzed using XRD, SEM, and EDS methods. The tribological and mechanical properties of the coatings obtained were also evaluated. The results obtained are consistent with thermodynamic predictions based on the Scheil model for non-equilibrium conditions. The data obtained indicate the high potential of high-entropy CoCrFeNiMn alloys for use as protective coatings for industrial purposes. In addition, the results of the study emphasize the promise of using thermodynamic prediction of high-entropy alloys using Thermo-Calc software. The best mechanical and tribological properties were obtained in the HVOF 1 regime, which provided a maximum microhardness of 783.8 HV and a minimum wear rate of 7.45 × 10⁻⁵ mm³ × N⁻¹ × m⁻¹. Full article