Search Results (349)

This study evaluates the efficiency of sub-stoichiometric Ti₄O₇ titanium oxide anodes for the electrochemical degradation of glyphosate, a persistent herbicide classified as a probable carcinogen by the World Health Organization. After optimizing the process operating parameters (pH and current density), the mineralization efficiency and fate of degradation by-products of the treated solution were determined using a total organic carbon (TOC) analyzer and HPLC/MS, respectively. The results showed that at pH = 3, glyphosate degradation and mineralization are enhanced by the increased generation of hydroxyl radicals (^●OH) at the anode surface. A current density of 14 ${\mathrm{mA} \mathrm{cm}}^{-2}$ enables complete glyphosate removal with 77.8% mineralization. Compared with boron-doped diamond (BDD), ${\mathrm{Ti}}_4{\mathrm{O}}_7$ shows close performance for treatment of a concentrated glyphosate solution (0.41 mM), obtained after nanofiltration of a synthetic ionic solution (0.1 mM glyphosate), carried out using an NF-270 membrane at a conversion rate (Y) of 80%. At 10${ \mathrm{mA} \mathrm{cm}}^{-2}$ for 8 h, ${\mathrm{Ti}}_4{\mathrm{O}}_7$ achieved 81.3% mineralization with an energy consumption of 6.09 ${\mathrm{kWh} \mathrm{g}}^{-1}$ TOC, compared with 90.5% for BDD at 5.48 ${\mathrm{kWh} \mathrm{g}}^{-1}$ TOC. Despite a slight yield gap, ${\mathrm{Ti}}_4{\mathrm{O}}_7$ demonstrates notable efficiency under demanding conditions, suggesting its potential as a cost-effective alternative to BDD for glyphosate electro-oxidation. Full article

This study investigates the dynamic relationship between bearing gearbox condition indicators (BGCIs) and the lubrication oil temperature within the framework of health and usage monitoring system (HUMS) applications. Using the dynamic autoregressive distributed lag (DARDL) simulation model, we quantified both the short- and long-term responses of condition indicators to shocks in oil temperature, offering a robust framework for a counterfactual analysis. To complement the time-domain perspective, we applied a wavelet coherence analysis (WCA) to explore time–frequency co-movements and phase relationships between the condition indicators under varying operational regimes. The DARDL results revealed that the ball energy, cage energy, and inner and outer race indicators significantly increased in response to the oil temperature in the long run. The WCA results further confirmed the positive association between oil temperature and the condition indicators under examination, aligning with the DARDL estimations. The DARDL model revealed that the ball energy and the inner race energy have statistically significant long-term effects on the oil temperature, with p-values < 0.01. The adjusted R² of 0.785 and the root mean square error (MSE) of 0.008 confirm the model’s robustness. The wavelet coherence analysis showed strong time–frequency correlations, especially in the 8–16 scale range, while the frequency-domain causality (FDC) tests confirmed a bidirectional influence between the oil temperature and several condition indicators. The FDC analysis showed that the oil temperature significantly affected the BGCIs, with evidence of feedback effects, suggesting a mutual dependency. These findings contribute to the advancement of predictive maintenance frameworks in HUMSs by providing practical insights for enhancing system reliability and optimizing maintenance schedules. The integration of dynamic econometric approaches demonstrates a robust methodology for monitoring critical mechanical components and encourages further research in broader aerospace and industrial contexts. Full article

The hydrosystem composed of Lake Togo, Lagoon of Togoville, and Lagoon of Aného is located in the coastal zone of Togo and receives important and different kinds of mining waste that cause its degradation. This study aims to evaluate the physicochemical and metallic quality of these waters and determine the possible sources of these contaminants using geostatistical, multivariate, and special analysis methods. These waters were very mineralized according to the average conductivity (15.51 mS/cm). Average contents (μg/L) in trace elements varied from 2.46 μg/L for As to 141.63 μg/L for Pb. Average levels of Cd, Pb, Cr, and Ni were significantly higher than the WHO standards. Trace elements and physicochemical parameters showed strong spatial variations with the highest values recorded downstream of the hydrosystem. The main possible source of trace element pollution was the intrusion of seawater loaded with phosphate effluent, followed by atmospheric deposition and soil leaching. This hydrosystem, therefore, deserves special attention for better planning its management. Full article

Increasing the use of healthcare facilities has resulted in the growing production of biomedical waste, which poses health risks to users, health professionals, and the environment. The aim of this research is to study the correlation between governance in Togo’s public health facilities and the quality of biomedical waste management within these facilities. Methods: This was a cross-sectional, descriptive, and analytical study conducted from September to December 2024. It involved 264 public health facilities of all types in all health regions of Togo. Health facilities were selected using the simple random selection technique. Healthcare providers were selected using the reasoned choice technique. The statistical tests used were the chi-square test and logistic regression, which enabled proportions to be compared and confounding factors to be eliminated, respectively. Results: Multivariate analysis revealed a statistically significant association between the organization and training component of governance and the quality of biomedical waste management (BMWM) in health facilities (OR = 3.79; 95% CI [1.79–8.03]; p < 0.001). This relationship suggests that health facilities with functional infection prevention and control (ICP) or BMWM committees, trained staff at all levels (nursing, technical, and administrative), and dedicated waste management personnel are more likely to implement compliant waste management practices. Analyses of the data also revealed that, among the criteria for assessing the quality of biomedical waste management (BMWM), the most significant were sorting (OR = 1.482; 95% CI [1.286; 1.708]), quantification (OR = 2.026; 95% CI [1.491; 2.753]), transportation (OR = 1.403; 95% CI [1.187; 1.66]), and disposal infrastructure (OR = 1.604; 95% CI [1.298; 1.982]). The application of this grid shows that 17.8% of the health facilities surveyed had a score equal to or above 80% on all the criteria used to assess the quality of biomedical waste management, and they were therefore managing waste in an “acceptable” manner. The study highlights key findings in biomedical waste management practices, providing actionable insights for improving public health safety. Full article

This study presents the influence of pH control agents and pH value on the physical properties of ZnO thin films obtained by chemical bath deposition. ZnO thin films were synthesized on glass substrates using precursor solutions of different pHs prepared from two bases: sodium hydroxide (NaOH) and ammonia (NH₃). The effect of pH values on the morphological, structural, and optical properties of ZnO thin films was investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and UV–Visible spectroscopy. XRD results showed that all the synthesized ZnO thin films are polycrystalline and crystallize in a hexagonal wurtzite structure. The crystallite size, calculated using the Debye–Scherrer formula, varied from 10.50 nm to 11.69 nm for ZnO thin films obtained with NH₃ and from 20.79 nm to 27.76 nm for those obtained with NaOH. FTIR analysis confirmed the presence of functional groups. SEM images indicated that not only the base but also the pH affects the morphology of the films, giving rise to different granular shapes. Overall, the ZnO thin films obtained with NaOH looked more mesoporous compared to those obtained with NH₃. Optical characterization results showed that whatever the base used, the pH of the precursor solution affected the ZnO thin film transmittance. Films synthesized with NH₃ exhibited the best transmittance (80%) at pH 8.5, while the best transmittance (81%) of films synthesized with NaOH was obtained at pH 8 in the visible region. Based on optical and morphological properties, ZnO films obtained from NH₃ at pH 8.5 are found to be more suitable as photoanodes in dye-sensitized solar cells. Full article

Previous studies have consistently reported the detrimental impact of dam construction on natural populations of softshell turtles across East and Southeast Asia, with particularly severe effects on large-bodied species. The Wattle-necked Softshell Turtle (Palea steindachneri), a large-sized and Critically Endangered member of the family Trionychidae, remains poorly documented throughout much of its native range in Southeast Asia. In this study, we present new field data from the Đà River basin in northern Vietnam, encompassing areas both upstream and downstream of the Sơn La Dam. Data were obtained through a combination of direct field observations, camera trap monitoring, and semi-structured interviews with local fishers and traders. Two individuals of P. steindachneri—including a juvenile—were recorded, providing the first confirmed evidence of ongoing natural reproduction in the region. Additionally, we documented 102 individuals of Pelodiscus sp., encompassing all life stages and indicating a stable, reproducing local population. Despite overlapping in macrohabitat use along the river, the two species were spatially segregated, with a minimum interspecific distance of 8.2 km, suggesting broad sympatry without syntopy, potentially due to microhabitat partitioning. These findings underscore the persistence and likely reproductive viability of P. steindachneri in modified riverine systems affected by dams, and have broader conservation implications for other threatened taxa with similar ecologies, such as Rafetus swinhoei. Urgent conservation actions, including habitat protection, community-based monitoring, and strengthened regulation of the wildlife trade, are essential to ensure the survival of remaining wild populations. Full article

The analysis of the vulnerability of vernacular buildings to climatic hazards is nowadays a subject of significant importance due to the consequences of climate change. This study assesses the vulnerability of vernacular buildings to three climatic hazards (heavy rains, strong winds and high heat) in the Kara region to identify the vulnerable parts of these constructions that require reinforcement. It is based on PTVA (Papathoma Tsunami Vulnerability Assessment), a multi-hazard analysis methodology, which uses vulnerability indicators. It focuses on the Kabiyè and Nawdeba peoples, who are the major ethnic groups in the region. Focus groups with the population, interviews with professionals and a series of surveys of 125 households in the visited territories enabled us to identify, firstly, the types of vernacular constructions in the region, the climatic hazards that occur there and the indicators that affect the vulnerability of the constructions. Secondly, we calculated the vulnerability index for each type of construction to the three climatic hazards. The vulnerability index of Kabiyè vernacular architecture (KVA) to heavy rain, high heat and strong wind is 0.379, 0.403 and 0.356, respectively. The Nawdéba vernacular architecture (NVA) vulnerability score is 0.359 for heavy rain, 0.375 for high heat, and 0.316 for strong wind. The index of vulnerability to heavy rain, high heat and strong wind for contemporary architecture (CA), as we term the current state of evolution of these two forms of architecture, is 0.499, 0.522 and 0.456, respectively. This study reveals that contemporary architecture (CA) in the Kara region, regardless of the type of hazard considered, is the most vulnerable construction model in the region. It also highlights the indicators that accentuate the vulnerability of vernacular constructions. Regardless of the type of construction, special attention must be paid to features such as roof style (roof slope, shape and material) and building style (form and state of maintenance of the building) to increase the resilience of buildings to climatic hazards. Full article

Climate change and anthropogenic activities, which are central to landscape-related concerns, affect both the well-being of populations and the structure of semi-urban and urban landscapes worldwide. This article aims to assess the environmental impact of landscape modifications across Togo as perceived through the lens of urban ecology. In conjunction with Landsat 8 satellite imagery, data were gathered via questionnaires distributed to stakeholders in urban space development. Four land use classifications are discernible from analyzing the Agoè-Nyivé northern municipalities’ cartography: vegetation, development areas/artificial surfaces, crops and fallows, meadows, and wetlands. Between 2014 and 2022, meadows and wetlands decreased by 57.14%, vegetation cover decreased by 27.77%, and fields and fallows decreased by 15.38%. Development areas/artificial surfaces increased by 40.47% due to perpetual expansion, displacing natural habitats, including wetlands and meadows, where rapid growth results in the construction of flood-prone areas. In wetland ecosystems, 91 plant species were identified and classified into 84 genera and 37 families using a floristic inventory. Typical species included Mitragyna inermis (Willd.) Kuntze; Nymphaea lotus L.; Typha australis Schumach; Ludwigia erecta (L.); Ipomoea aquatica Forssk; Hygrophila auriculata (Schumach.) Heine. This concerning observation could serve as an incentive for policymakers to advocate for incorporating urban ecology into municipal development strategies, with the aim of mitigating the environmental risks associated with rapid urbanization. Full article

The unprecedented development of coastal cities in West Africa is marked by anarchic urbanization accompanied by ineffective environmental management, leading to water pollution. This study is conducted in the southern districts of Lomé, Togo, an area built on sandbars where inappropriate attitudes, behaviors, and inadequate hygiene and sanitation practices prevail. The objective of this study is to characterize the quality of groundwater in the study area. Bacteriological and physicochemical analyses were carried out on 11 wells in 10 districts in the southern districts during the four seasons of the year. The analysis shows that the groundwater is polluted in all seasons. Nitrate concentrations exceed 50 mg/L in 65% of the samples, while chloride levels surpassed 250 mg/L in 18% of the cases. Regardless of the season, the dominant facies is sodium chloride and potassium chloride. In all districts, the analysis of microbiological parameters including total germs (30 °C, 100/mL), total coliforms (30 °C, 0/mL), Escherichia coli (44 °C, 2/250 mL), fecal streptococci (0/100 mL), and anaerobic sulfite reducers (44 °C, 2/20 mL) reveals values exceeding the European Union standards (2007). Groundwater contamination is facilitated by the sandy nature of the soil, which increases its vulnerability to various pollutants. Togo continues to experience cholera outbreaks, aggravated by poor sanitation infrastructure and limited vaccination coverage. Public health efforts are directed toward improving sanitation and raising awareness about waterborne and non-communicable diseases. Full article

Gearboxes are autonomous devices essential for power transmission in various mechanical systems. When a failure occurs, it can lead to an inability to perform the required functions, potentially resulting in a complete shutdown of the mechanism and causing significant operational disruptions. Consequently, deploying expert methods for fault detection and diagnosis is crucial to ensuring the reliability and efficiency of these systems. Artificial intelligence (AI) techniques show promise for fault diagnosis, but their accuracy can be hindered by noise and manufacturing imperfections that distort mechanical signatures. Thorough data analysis and preprocessing are vital to preserving these critical features. Validating approaches through numerical simulations before experimentation is essential to identify model limitations and minimize risks. A hybrid approach, combining AI and physics-based models, could provide a robust solution by leveraging the strengths of both domains: AI for its ability to process large volumes of data and physics-based models for their reliability in modeling complex mechanical behaviors. This paper proposes a comprehensive diagnostic methodology. It starts with feature extraction from time-domain analysis, which helps identify critical indicators of gearbox performance. Following this, a feature selection process is applied using the Fisher criterion, which ensures that only the most relevant features are retained for further analysis. These selected features are then employed to train an Adaptive Neuro-Fuzzy Inference System (ANFIS), a sophisticated approach that combines the learning capabilities of neural networks with the reasoning abilities of fuzzy logic. The proposed methodology is evaluated using a dataset of gear faults generated through energy simulations based on a six-degree-of-freedom (6-DOF) model, followed by a secondary validation on an experimental dataset. Full article

Wind power plays a significant role in sustainable energy production, but the reliability of wind turbines depends heavily on the integrity of their gearboxes. Gearbox failures can lead to significant downtime and operational disruption. In this context, this paper provides an overview of the evolution of gearbox monitoring techniques, culminating in the emergence of digital twin (DT) technology. We explore the application of DT technology to gearbox condition monitoring, focusing on two critical components: bearings and gears. This includes a comprehensive review of methodologies involving model-based approaches and data-driven techniques using signal processing (SP) and artificial intelligence (AI) algorithms. We address the challenges of “learning with minimal knowledge” and propose a framework for the effective application of DT technology. Finally, we discuss future research directions and potential contributions to advancing the field of gearbox condition monitoring through the continued development and implementation of DT-based solutions. Full article

The effects of germination (fresh germinated soybean [SG1F]) and post-germination drying (dried germinated soybean [SG1S]) on the crude protein (CP) levels, aflatoxin content, survival, and growth performance of Nile tilapia fry (Oreochromis niloticus) were evaluated. Raw soybean (SC) and roasted soybean (ST) served as controls. Laboratory analyses revealed CP contents of 11.74%, 38.72%, 38.42%, and 34.72% for SG1F, SG1S, RT, and RS, respectively. Aflatoxin levels were 2.3 µg/kg for SG1S, 1.66 µg/kg for RS, 1.60 µg/kg for RT, and 0.00 µg/kg for SG1F. Experimental diets, formulated to be isoproteic (35.44%) and isolipidic (8.73%), were prepared using flour from these soybean treatments and tested on tilapia fry with an average initial weight of 11.86 ± 2.15 g. The study was conducted in a completely randomized design with three replicates in 1 m³ tanks stocked at 35 fry per tank over 56 days. Weight gains were 23.40 ± 10.21 g, 18.93 ± 8.67 g, 16.30 ± 9.92 g, and 16.07 ± 5.55 g for RT, RS, SG1S, and SG1F, respectively. Survival rates were 100%, 90.67%, 89.33%, and 88% for SG1F, RS, RT, and SG1S, respectively. Daily growth rates showed a consistent upward trend for all diets from the start to the end of the experiment. Full article

Background/Objectives: Taeniasis, a zoonotic infection, is a common foodborne disease. Niclosamide and praziquantel have proven to be effective in treating it, but the use of the same drugs can lead to resistance, so alternative drugs need to be explored. This study investigated the anthelmintic potential of derived fractions from hydroethanolic extracts (HEs) of Aframomum melegueta (AM) and Xylopia aethiopica (XA), two medicinal plants known for their diverse bioactive properties. Methods: AM-HE fractions (dichloromethane fraction (DCMF), ether fraction (EF), aqueous fraction (AF)) and XA-HE fractions (chloroform fraction (CF), ether fraction (EF), and aqueous fraction (AF)) were used, and in vitro anthelmintic activity was assessed against Taenia spp. by using an adult motility assay for the worm’s paralysis time determination. The parasiticidal and parasitostatic activity was also tested on Taenia spp. adult worms. Cell viability was further evaluated using propidium iodide (PI) staining, with albendazole (20 mg/mL) as the reference drug. Results: The three fractions of each plant exhibited significant, dose-dependent anthelmintic activity, with AM-HE and XA-CF showing the greatest effects at 20 mg/mL. AM-EF demonstrated significant activity at 0.4% and 0.8%. Irreversibility tests revealed that most of the treated worms remained paralysis, except those exposed to the AF of both plants. PI staining confirmed the dose-dependent mortality of Taenia cells treated with HE, DCMF, and AF of AM. Conclusions: These results underscore the potential of AM and XA extracts and fractions as alternative treatments for helminth infections. Further, in vivo studies are warranted to confirm their safety and therapeutic efficacy. Full article

Historically protected by cultural traditions, sacred forests are now increasingly threatened by anthropogenic pressures, particularly in West Africa, where natural areas and wildlife populations have dwindled as human populations have increased exponentially. Residents in the vicinity of sacred forests play critical roles in conservation success or failure, but few studies have investigated their views. We surveyed 281 residents representing ~100% of households surrounding the sacred forest of Nakpadjoak, a 50-hectare remnant of Sudan-Guinea woodland savanna in northern Togo that is now surrounded by human-dominated landscapes. The majority of residents believe that the sacred forest should be protected (92%) and that access to the forest should be prohibited (55%). Most residents own livestock (93%) and reported that the forest has become a pasture for domestic animals (70%) while wildlife populations have declined (79%). Two-thirds of residents (64%) reported that the forest has changed due to wood cutting, a practice that occurs despite being banned. Most (96%) residents use wood as their primary source of domestic energy, but 90% would switch to alternative fuels, such as natural gas, if available. Unfortunately, despite residents’ desire to protect the forest and external funding for its protection and restoration, Nakpadjoak forest has become increasingly degraded due to ongoing exploitation and conflicts of interest surrounding its use. We recommend bolstering local prohibitions on sacred forest exploitation as well as government interventions such as subsidizing natural gas as an alternative to wood fuel to support the conservation of this and other protected areas in the region, which may otherwise be destroyed. Full article

It has been demonstrated that organic fertilisers could be a source of microplastics (MPs) in agricultural soils. These organic fertilisers comprise a diverse array of matrices including organic waste and by-products. Currently, there is no established methodology for the extraction of MP from these matrices. The present article aims to validate a standardised protocol for the extraction of MPs from a diverse range of complex, organic-rich samples. The protocol has been developed to ensure a high recovery of MPs, to preserve their integrity, and to eliminate organic particles that interfere with FTIR analyses. Spiked MPs sized 315–5000 µm were subjected to a two-step process involving chemical digestion (H₂O₂, 30% (w/v), 53 °C) and density separation (NaI, >1.60 g·cm⁻³). This resulted in a mean extraction rate exceeding 95%, with undigested matter remaining below 5%. No evidence of fragmentation was observed. Furthermore, the chemical nature of spiked microplastics is still perfectly interpretable from the FTIR spectra despite the different chemical treatments undergone. These findings thus validate the method for the microplastic range 315–5000 µm. However, a new method for reanalysing the project’s data produced contrasting results, suggesting a significant drop in recovery rates for size ranges below 250 µm. This reanalysis approach constitutes the second innovation of this protocol, and enables a more critical analysis of the results obtained in publications on microplastics. Full article