Search Results (596)

Polyethylene is the most used plastic in the world, and over 90% of this plastic is ultimately disposed of in landfills or released into the environment, leading to severe ecological implications. In this research, the technoeconomic feasibility of upcycling low-density polyethylene (LDPE) to produce ethylene is studied. The catalytic conversion of LDPE to ethylene is considered in microwave heating mode and Joule heating mode. Experimental data is obtained under conditions where most of the upcycled products are in the gas phase. A flowsheet is developed that produces industrial quantities of ethylene for both heating modes. A technoeconomic analysis and a life cycle analysis are conducted and compared with the traditional ethane cracking process for producing ethylene. Simulation results indicate that the upcycling system exhibits a lower capital expenditure and a comparable operating expenditure relative to conventional ethane steam cracking while generating additional valuable co-products, such as propylene and aromatic hydrocarbons, leading to a higher net present value potential. Sensitivity analyses reveal that the electricity price has the most significant impact on both the net present value and levelized cost of production, followed by the low-density polyethylene feedstock cost. Life-cycle assessment reveals a substantial reduction in greenhouse-gas emissions in the upcycled process compared to the fossil-based ethane steam-cracking route, primarily due to the use of renewable electricity, the lower reaction temperature that reduces utility demand, and the use of plastic waste as the feedstock. Overall, the proposed process demonstrates strong potential for the sustainable production of ethylene from waste LDPE. Full article

A knowledge of the process–structure–property correlation and underlying deformation mechanisms of material under a coupled electro-thermal–mechanical field is crucial for developing novel electrically assisted forming techniques. In this work, numerical simulation and experimental analyses were carried out to study the non-uniform deformation behaviors and microstructure evolution of Ti₂AlNb-based alloy stiffened panels in different characteristic deformation regions during electrically assisted press bending (EAPB). The quantitative relationships between electro-thermal–mechanical routes, microstructural features, and mechanical properties of EAPBed stiffened panels were initially established, and the underlying mechanisms of electrically induced phase transformation and morphological transformation were unveiled. Results show that the temperature of the panel first increases then deceases with forming time in most regions, but it increases monotonically and reaches its peak value of 720.1 °C in the web region close to the central transverse rib. The higher accumulated strain and precipitation of the acicular O phase at mild temperature leads to strengthening of the longitudinal ribs at near blank holder regions, resulting in an ideal microstructure of 3~4% blocky α₂ phase + a dual-scale O structure in a B2 matrix with a maximal hardness of 389.4 ± 7.2 HV_0.3. While the dissolution of the α₂ phase and the spheroidization and coarsening of the O phase bring about softening (up to 9.29%) of the lateral ribs and web near the center region, the differentiated evolution of microstructure and the mechanical property in EAPB results in better deformation coordination and resistance to wrinkling and thickness variation in the rib–web structure. The present work will provide valuable references for achieving shape-performance coordinated manufacturing of Ti₂AlNb-based stiffened panels. Full article

This work introduces ultrafast high-temperature graphitization (UHG) as an effective method to synthesize graphite with significantly reduced processing times of about 100 s and reduced consumed energy, as opposed to conventional methods that require several days at 2800 K. This novel process achieves graphitization of up to 90% within a few minutes due to the accelerated kinetics occurring at temperatures as high as 3400 K. Samples processed using UHG attained stable cyclic capacities of 350 mAh/g, which is fully comparable to commercially available graphite. Finite Element Simulations were also used to calculate the energy consumption for a scaled-up configuration, and it was found that the UHG approach reaches ultra-low energy consumption, requiring only 2.4 MJ/kg for the direct conversion of coke into graphite. By minimizing the duration of high-temperature processing and employing localized heating, UHG is envisioned to mitigate some of the challenges associated with traditional Acheson furnaces that have been in use for more than a century. Full article

Phosphorus is an essential resource for numerous industrial applications. However, its uneven global distribution makes Europe heavily dependent on imports. Recovering phosphorus from waste streams is therefore crucial for improving resource security. The FlashPhos project addresses this challenge by developing a process to recover phosphorus from sewage sludge, in which phosphorus-rich slag is produced in a flash reactor and subsequently reduced in a Submerged Arc Furnace (SAF). In this process, approximately 250 kg/h of sewage sludge is converted into slag, which is further processed in the SAF to recover about 8 kg/h of white phosphorus. This work focuses on the development of a computational model of the SAF, with particular emphasis on slag behaviour. Due to the extreme operating conditions, which severely limit experimental access, a numerically efficient three-dimensional CFD model was developed to investigate the internal flow of the three-phase, AC-powered SAF. The model accounts for multiphase interactions, dynamic bubble generation and energy sinks associated with the reduction reaction, and Joule heating. A temperature control loop adjusts electrode currents to reach and maintain a prescribed target temperature. To further reduce computational cost, a novel simulation approach is introduced, achieving a reduction in simulation time of up to 300%. This approach replaces the solution of the electric potential equation with time-averaged Joule-heating values obtained from a preceding simulation. The system requires transient simulation and reaches a pseudo-steady state after approximately 337 s. The results demonstrate effective slag mixing, with gas bubbles significantly enhancing flow velocities compared to natural convection alone, leading to maximum slag velocities of 0.9–1.0 m/s. The temperature field is largely uniform and closely matches the target temperature within ±2 K, indicating efficient mixing and control. A parameter study reveals a strong sensitivity of the flow behaviour to the slag viscosity, while electrode spacing shows no clear influence. Overall, the model provides a robust basis for further development and future coupling with the gas phase. Full article

The present studies focus on the analysis of the inherent differences between temperature- and pyrolysis-based models and foster a rational and comprehensive understanding of numerical models for lightning strike damage in laminated composites. A systematic methodology combining numerical simulation and pyrolysis kinetics analysis has been developed to examine the inherent differences in damage area and depth, damage threshold, electrical conductivity characteristics, and Joule energy between temperature- and pyrolysis-based models. The results indicate that the pyrolysis-based model demonstrates closer agreement with experimental data in terms of both damage area and damage depth predictions compared to the temperature-based model. The two damage thresholds (500 °C and pyrolysis degree of 0.1) yield equivalent predictions of overall damage, but the temperature-based criterion neglects localized heating rate effects. The pyrolysis-based model exhibits significantly delayed through-thickness conductivity development during initial current conduction compared to the temperature-based model due to the influence of heating rate. This lag results in the pyrolysis-based model predicting larger damage areas and shallower penetration depths. Joule heating analysis further confirms that the pyrolysis-based model exhibits higher overall electrical resistance than the temperature-based model. Through a systematic comparison of temperature- and pyrolysis-based models, this research holds the significance of enhancing the understanding of lightning strike damage mechanisms and advancing the development of high-fidelity numerical models for predicting lightning strike damage in laminated composite. Full article

The utilization and transformation of heat have played pivotal roles in numerous significant stages of human societal evolution and advancement. Recently, more rigorous and precise requirements have been imposed on thermal functional materials for applications including microelectronic device cooling, personal thermal regulation in extreme environments, green building initiatives, flexible wearable electronics, and solar thermal collection. Thermal functional fibers offer advantages such as lightweight construction, versatile functional design, and integrated manufacturing capabilities. By modifying the composition, structure, and fabrication techniques of fibers, control over heat transfer, storage, and conversion processes can be optimized. This review underscores the latest developments in thermal functional fibers, emphasizing high thermal conductivity fibers, thermal insulation fibers, thermal radiation regulation fibers, phase-change thermal storage fibers, thermoelectric fibers, Joule heating fibers, photothermal conversion fibers, thermally actuated fibers, and multifunctional composite fibers. It elucidates how these various fibers enhance thermal performance through innovative material selection, fabrication methods, and structural design. Finally, the review discusses prevailing developmental trends, current challenges, and future directions in the design and fabrication of thermal functional fibers. Full article

Transparent conductive materials (TCMs) are essential for optoelectrical devices ranging from smart windows and defogging films to soft sensors, display technologies, and flexible electronics. Materials, such as indium tin oxide (ITO) and silver nanowires (AgNWs), are commonly used and offer high optical transmittance and electrical conductivity, but suffer from brittleness, oxidation susceptibility, and require high-cost materials, greatly limiting their use. Carbon nanotube (CNT) networks provide a promising alternative, featuring mechanical compliance, chemical robustness, and scalable processing. This study reports an aqueous ink formulation composed of ultra-long mix-walled carbon nanotubes (UL-CNTs), compatible with the flow coating process, yielding uniform transparent conductive films (TCFs) on polyethylene terephthalate (PET), glass, and polycarbonate (PC). The resulting films exhibit tunable transmittance (85%–88% for single layers; ~57% for three layers at 550 nm) and sheet resistance of 7.5 kΩ/□ to 1.5 kΩ/□ accordingly. These TCFs maintain stable sheet resistance for over 5000 bending cycles and show excellent mechanical durability with negligible effects on heating performance. Post-deposition treatments, including nitric acid vapor doping or flash photonic heating (FPH), further reduce sheet resistance by up to 80% (7.5 kΩ/□ to 1.2 kΩ/□). X-ray photoelectron spectroscopy (XPS) results in reduced surface oxygen content after FPH. The photonic-treated heaters attain ~100 °C within 20 s at 100 V. This scalable, water-based process provides a pathway toward low-cost, flexible, and stretchable devices in a variety of fields, including printed electronics, optoelectronics, and thermal actuators. Full article

The development of economical and scalable methods for synthesizing high-quality graphene remains a pivotal challenge in materials science. This study presents an efficient approach for synthesizing turbostratic graphene with micron-sized domains from an accessible bioprecursor-activated charcoal—using fast Joule heating. We demonstrate that ultra-rapid thermal annealing (~16.2 kJ/g, up to 3000 K) triggers a phase transition from amorphous carbon to a highly graphitized structure. Comprehensive characterization via SEM, AFM, Raman spectroscopy, and XRD revealed the formation of large flakes with lateral dimensions up to 1.5 µm and thicknesses ranging from 4 to 200 nm. Raman mapping further uncovered a heterogeneous structure with alternating regions exhibiting different degrees of interlayer coupling, characteristic of turbostratic stacking. The key feature of the material is its turbostratic layer stacking, confirmed by the combination of XRD data showing an interlayer distance of 3.436 Å and Raman spectra characteristic of decoupled graphene layers. The synthesized material exhibits excellent electrical transport properties, with a bulk resistivity of 0.51 Ω·cm—an order of magnitude lower than that of the initial charcoal. These findings highlight the potential of the developed method for producing electrode materials for energy storage devices and conductive composites. Full article

Electromigration (EM) presents a major reliability challenge in advanced electronic packaging as device scaling and rising power demands lead to higher current densities in solder joints. While eutectic Sn-58Bi solder is widely adopted as a low-temperature alternative for its energy efficiency and compatibility with heat-sensitive substrates, its heterogeneous microstructure renders it vulnerable to EM-induced degradation. This review summarizes recent progress in understanding the EM behavior of Sn-Bi solder joints. We first introduce lifetime prediction models based on Black’s law, emphasizing the influences of current density, Joule heating, and thermomigration. Subsequently, the microstructural mechanisms accelerating degradation, including phase segregation and the coarsening of intermetallic compounds (IMCs), are examined. Various alloying strategies are evaluated for their effectiveness in strengthening the solder matrix and suppressing atomic diffusion to improve EM resistance. The critical role of substrate metallization is also discussed, comparing how different surface finishes affect interfacial reactions and joint lifetimes. Additionally, operational methods such as current polarity reversal are explored as potential pathways to mitigate degradation. Finally, we conclude that the EM reliability of Sn-Bi solder joints depends on the combined effects of alloy chemistry, interfacial reactions, and operating conditions, and we suggest future research directions in advanced modeling and material design for next-generation electronic applications. Full article

As the hydrogen economy rapidly expands, carbon-fiber-reinforced polymer composites (Towpreg) have become key materials for next-generation hydrogen pressure vessels, offering superior processability, reproducibility, and storage stability compared to conventional wet-winding composites. Since hydrogen storage vessels are evaluated at three representative service temperatures (−40, 25, and 85 °C), Towpreg materials must maintain consistent mechanical performance across this range to meet certification standards. This study establishes an integrated methodology combining Towpreg panel fabrication, temperature-controlled tensile and fatigue testing, and quantitative assessment of thermo-mechanical stability using DM epoxy resin as the matrix. To address artifacts such as tab slippage at high temperatures and inefficiency at low temperatures, a “Localized Thermal Control” approach was developed. The HY-Mini Heater System enables localized heating at 85 °C, while the HY-Cooler System applies a Joule–Thomson-based Stirling cooler for efficient localized cooling at −40 °C. Quantitative evaluation showed tensile strengths of 2973.3 MPa (RT), 2767.3 MPa (HT, ~7% decrease), and 2907.7 MPa (LT, ~2% decrease). Under R = 0.1 fatigue testing, the Basquin slope (m) was 11.97 (RT), 9.98 (HT), and 10.6 (LT), while the intercept (log b ≈ 3.7) remained nearly constant. These results confirm the excellent thermo-mechanical stability of the carbon-fiber-reinforced polymer composites (Towpreg) for hydrogen tank applications. Full article

Acoustofluidic devices use Surface Acoustic Waves (SAWs) to handle small fluid volumes and manipulate nanoparticles and biological cells with high precision. However, SAWs can cause significant heat generation and temperature rises in acoustofluidic systems, posing a critical challenge for biological and other applications. In this work, we studied temperature distribution in a Standing Surface Acoustic Wave (SSAW)-based PDMS microfluidic device both experimentally and numerically. We investigated the relative contribution of Joule and acoustic dissipation heat sources. We investigated the acoustofluidic device in two heat dissipation configurations—with and without the heat sink—and demonstrated that, without the heat sink the temperatures inside the microchannel increased by 43 °C at 15 V. Adding the metallic heat sink significantly reduced the temperature rise to only 3 °C or less at lower voltages. This approach enabled the effective manipulation and alignment of nanoparticles at applied voltages up to 15 V while maintaining low temperatures, which is crucial for temperature-sensitive biological applications. Our findings provide new insights for understanding the heat generation mechanisms and temperature distribution in acoustofluidic devices and offer a straightforward strategy for the thermal management of devices. Full article

This work investigates the impact of load-dump stress on p-GaN HEMTs under floating gate condition. The experiments show that preconditioning the device with a small load-dump stress (150 V, @t_d = 100 ms and t_r = 8 ms) enhances its robustness against a larger stress (190 V, @t_d = 100 ms and t_r = 8 ms). If a large load-dump stress (≥160 V, @t_d = 100 ms and t_r = 8 ms) is applied directly to the device’s drain, the device will burn out. This occurs because the rapidly changing drain voltage during a load-dump event can generate a capacitive coupling current, leading to transient positive charge accumulation in the gate region. Consequently, the channel under the gate is turned on, allowing a large current to flow through it. The coexistence of high current and high voltage leads to substantial Joule heating within the device, resulting in eventual burnout. When a small load-dump stress is initially applied, the resulting charging of electron traps in the gate region increases the threshold voltage. As a result, the device can withstand a larger load-dump stress before the channel turns on, which explains the device’s enhanced robustness. This work clarifies the failure threshold of p-GaN HEMTs under the load-dump stress, providing key support for improving the devices’ reliability in the practical applications. It can provide a basis for adding necessary protective measures in device circuit design, and clarify the triggering voltage threshold of protective measures to ensure that they can effectively avoid device damage due to the load-dump stress. Full article

The article presents a numerical model of a high-temperature superconducting (HTS) transformer rated at 13.8 kVA, equipped with windings made of 2G ReBCO tapes. The model was developed to analyze the coupled electromagnetic and thermal phenomena occurring during the inrush current period of transformer energization. It describes the dynamic processes of critical current exceedance, resistive zone formation, and local temperature rise within the superconducting tape structure under realistic operating conditions. The geometry of the ReBCO tape is represented with its active superconducting layer and metallic stabilizer layers. Temperature-dependent material properties of each layer, such as electrical resistivity, thermal conductivity, and specific heat capacity, are incorporated into the model. This approach enables a detailed analysis of the temperature distribution across all layers of the superconducting tape. The results indicate that the highest thermal stress occurs during the first inrush current peak, whose amplitude exceeds the critical current of the winding. At this stage, a distinct temperature rise is observed in the stabilizer layers, followed by gradual cooling in subsequent cycles of operation. The simulated current and temperature waveforms show good agreement with experimental measurements performed on a liquid-nitrogen-cooled transformer prototype. The developed model enables quantitative evaluation of local overheating risks, analysis of Joule loss distribution, and assessment of the influence of supply parameters and circuit impedance on the thermal stability of the system. Its application supports the optimization of HTS transformer design and provides valuable insight into the reliability of superconducting windings under transient inrush current conditions. Full article

To address the degradation of O-ring material properties and reduced dynamic seal reliability caused by excessive hydrogen temperature rise in a Type IV hydrogen cylinder due to constant-flow filling strategies, this study systematically investigates the coupled mechanism by which a linearly decreasing flow filling strategy maintains sealing performance through temperature rise regulation. By establishing a fluid–thermal–solid coupled mathematical model that comprehensively considers the Joule–Thomson effect, compression heat, gas swelling, and material nonlinear behavior, combined with numerical simulation methods, the sealing performance of the linear decreasing and constant-flow filling strategies was systematically compared across three key dimensions: temperature field distribution, evolution of seal ring material properties, and contact stress at the sealing interface. Results demonstrate that the linear decrease filling strategy effectively suppresses hydrogen temperature rise, achieving a 4.6% lower temperature increase at completion compared to the constant-flow strategy. Concurrently, this strategy mitigates thermally induced degradation of seal material properties, reducing contact stress fluctuations by 5% and significantly enhancing dynamic seal reliability. This research provides theoretical foundations and design support for optimizing filling protocols in high-performance hydrogen storage vessels. Full article

The development of electro-thermal textiles has attracted growing interest as a promising approach for active thermal management in wearable systems. Metallic-coated fabrics can efficiently generate heat through the Joule effect; however, their long-term performance and safety are severely limited under perspiration due to metal ion release and corrosion. To overcome these challenges, this study introduces a Parylene-C encapsulation strategy for copper-coated polyethylene terephthalate nonwovens (CuPET) using a chemical vapor deposition (CVD) process. The conformal, biocompatible Parylene-C films (thickness 4–16 μm) act as effective protective barriers while preserving the porous textile structure. Morphological and comfort analyses demonstrate a controlled reduction in air permeability from 3100 to 1100 L·m⁻²·s⁻¹, maintaining acceptable breathability. Electro-thermal measurements reveal rapid and uniform heating, reaching 40–45 °C within 2 min at 2 V, and the addition of a thermal insulation layer further enhances the Joule heating efficiency, increasing the steady-state temperature by approximately 6 °C. ICP–OES results show an ≈80% reduction in copper ion release (from 28.34 mg·L⁻¹ to 5.80 mg·L⁻¹) after artificial sweat exposure. This work demonstrates a scalable encapsulation route that effectively balances sweat protection, electrical stability, and thermal performance, paving the way for safe, durable, and actively heated smart textiles for advanced thermal insulation applications. Full article