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Search Results (1,322)

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24 pages, 3953 KiB  
Article
A New Signal Separation and Sampling Duration Estimation Method for ISRJ Based on FRFT and Hybrid Modality Fusion Network
by Siyu Wang, Chang Zhu, Zhiyong Song, Zhanling Wang and Fulai Wang
Remote Sens. 2025, 17(15), 2648; https://doi.org/10.3390/rs17152648 - 30 Jul 2025
Abstract
Accurate estimation of Interrupted Sampling Repeater Jamming (ISRJ) sampling duration is essential for effective radar anti-jamming. However, in complex electromagnetic environments, the simultaneous presence of suppressive and deceptive jamming, coupled with significant signal overlap in the time–frequency domain, renders ISRJ separation and parameter [...] Read more.
Accurate estimation of Interrupted Sampling Repeater Jamming (ISRJ) sampling duration is essential for effective radar anti-jamming. However, in complex electromagnetic environments, the simultaneous presence of suppressive and deceptive jamming, coupled with significant signal overlap in the time–frequency domain, renders ISRJ separation and parameter estimation considerably challenging. To address this challenge, this paper proposes a method utilizing the Fractional Fourier Transform (FRFT) and a Hybrid Modality Fusion Network (HMFN) for ISRJ signal separation and sampling-duration estimation. The proposed method first employs FRFT and a time–frequency mask to separate the ISRJ and target echo from the mixed signal. This process effectively suppresses interference and extracts the ISRJ signal. Subsequently, an HMFN is employed for high-precision estimation of the ISRJ sampling duration, offering crucial parameter support for active electromagnetic countermeasures. Simulation results validate the performance of the proposed method. Specifically, even under strong interference conditions with a Signal-to-Jamming Ratio (SJR) of −5 dB for deceptive jamming and as low as −10 dB for suppressive jamming, the regression model’s coefficient of determination still reaches 0.91. This result clearly demonstrates the method’s robustness and effectiveness in complex electromagnetic environments. Full article
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20 pages, 3139 KiB  
Article
Intelligent Recognition and Parameter Estimation of Radar Active Jamming Based on Oriented Object Detection
by Jiawei Lu, Yiduo Guo, Weike Feng, Xiaowei Hu, Jian Gong and Yu Zhang
Remote Sens. 2025, 17(15), 2646; https://doi.org/10.3390/rs17152646 - 30 Jul 2025
Abstract
To enhance the perception capability of radar in complex electromagnetic environments, this paper proposes an intelligent jamming recognition and parameter estimation method based on deep learning. The core idea of the method is to reformulate the jamming perception problem as an object detection [...] Read more.
To enhance the perception capability of radar in complex electromagnetic environments, this paper proposes an intelligent jamming recognition and parameter estimation method based on deep learning. The core idea of the method is to reformulate the jamming perception problem as an object detection task in computer vision, and we pioneer the application of oriented object detection to this problem, enabling simultaneous jamming classification and key parameter estimation. This method takes the time–frequency spectrogram of jamming signals as input. First, it employs the oriented object detection network YOLOv8-OBB (You Only Look Once Version 8–oriented bounding box) to identify three types of classic suppression jamming and five types of Interrupted Sampling Repeater Jamming (ISRJ) and outputs the positional information of the jamming in the time–frequency spectrogram. Second, for the five ISRJ types, a post-processing algorithm based on boxes fusion is designed to further extract features for secondary recognition. Finally, by integrating the detection box information and secondary recognition results, parameters of different ISRJ are estimated. In this paper, ablation experiments from the perspective of Non-Maximum Suppression (NMS) are conducted to simulate and compare the OBB method with the traditional horizontal bounding box-based detection approaches, highlighting OBB’s detection superiority in dense jamming scenarios. Experimental results show that, compared with existing jamming detection methods, the proposed method achieves higher detection probabilities under the jamming-to-noise ratio (JNR) ranging from 0 to 20 dB, with correct identification rates exceeding 98.5% for both primary and secondary recognition stages. Moreover, benefiting from the advanced YOLOv8 network, the method exhibits an absolute error of less than 1.85% in estimating six types of jamming parameters, outperforming existing methods in estimation accuracy across different JNR conditions. Full article
(This article belongs to the Special Issue Array and Signal Processing for Radar (Second Edition))
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10 pages, 1357 KiB  
Article
Design of Balanced Wide Gap No-Hit Zone Sequences with Optimal Auto-Correlation
by Duehee Lee, Seho Lee and Jin-Ho Chung
Mathematics 2025, 13(15), 2454; https://doi.org/10.3390/math13152454 - 30 Jul 2025
Abstract
Frequency-hopping multiple access is widely adopted to blunt narrow-band jamming and limit spectral disclosure in cyber–physical systems, yet its practical resilience depends on three sequence-level properties. First, balancedness guarantees that every carrier is occupied equally often, removing spectral peaks that a jammer or [...] Read more.
Frequency-hopping multiple access is widely adopted to blunt narrow-band jamming and limit spectral disclosure in cyber–physical systems, yet its practical resilience depends on three sequence-level properties. First, balancedness guarantees that every carrier is occupied equally often, removing spectral peaks that a jammer or energy detector could exploit. Second, a wide gap between successive hops forces any interferer to re-tune after corrupting at most one symbol, thereby containing error bursts. Third, a no-hit zone (NHZ) window with a zero pairwise Hamming correlation eliminates user collisions and self-interference when chip-level timing offsets fall inside the window. This work introduces an algebraic construction that meets the full set of requirements in a single framework. By threading a permutation over an integer ring and partitioning the period into congruent sub-blocks tied to the desired NHZ width, we generate balanced wide gap no-hit zone frequency-hopping (WG-NHZ FH) sequence sets. Analytical proofs show that (i) each sequence achieves the Lempel–Greenberger bound for auto-correlation, (ii) the family and zone sizes satisfy the Ye–Fan bound with equality, (iii) the hop-to-hop distance satisfies a provable WG condition, and (iv) balancedness holds exactly for every carrier frequency. Full article
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18 pages, 2466 KiB  
Article
An Anti-Range-Deception-Jamming Method for Networked Moving Radar Based on Trajectory Optimization
by Xiaofei Han, Huafeng He, Chuan He, Qi Zhang, Liyuan Wang, Tao Zhou and Xin Zhang
Sensors 2025, 25(15), 4675; https://doi.org/10.3390/s25154675 - 29 Jul 2025
Viewed by 44
Abstract
Aiming at the problem that the anti-range-deception-jamming effect of a networked moving radar system is severely affected by the spatial distribution of each radar, an anti-range-deception-jamming method for networked moving radar based on trajectory optimization is proposed. Firstly, the anti-jamming method of networked [...] Read more.
Aiming at the problem that the anti-range-deception-jamming effect of a networked moving radar system is severely affected by the spatial distribution of each radar, an anti-range-deception-jamming method for networked moving radar based on trajectory optimization is proposed. Firstly, the anti-jamming method of networked moving radar considering the radar position error (RPE) is proposed. Then, the theoretical expression for the false target (FT) misjudgment probability of networked moving radar is deduced. Based on the theoretical expression, a trajectory optimization model is formulated to minimize FT misjudgment probability. Simulation experiments validate both the correctness of the derived probability expression and the significant influence of the radar spatial distribution position on the FT misjudgment probability. Moreover, the simulation results verify that the proposed anti-jamming method can effectively reduce the FT misjudgment probability of networked moving radar under the condition of a high discrimination probability of the physical target (PT). Full article
(This article belongs to the Section Radar Sensors)
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13 pages, 2541 KiB  
Article
Multiantenna Synthetic Interference Technology Using Phase Comparison Method
by Xin Zhou, Mengxia Yu and Maoyan Wang
Aerospace 2025, 12(8), 671; https://doi.org/10.3390/aerospace12080671 - 27 Jul 2025
Viewed by 237
Abstract
Based on the theoretical framework of the phase comparison method and the computational analysis of the interference model calculation analysis, this paper designs, implements, establishes, calibrates, and verifies an interference experimental platform. The proposed methodology validates the effectiveness and practical feasibility of multiantenna [...] Read more.
Based on the theoretical framework of the phase comparison method and the computational analysis of the interference model calculation analysis, this paper designs, implements, establishes, calibrates, and verifies an interference experimental platform. The proposed methodology validates the effectiveness and practical feasibility of multiantenna synthetic interference technology in real-world applications. Experimental results demonstrate that the developed system can achieve flexible and arbitrary interference angles with desired distortion characteristics through precise amplitude–phase modulation, enabling dynamic manipulation of phase plane angles. Furthermore, the system successfully synthesizes false target positions at distances exceeding five times the baseline length from the jamming platform center. Both mathematical computations and experimental validations confirm that this multiantenna synthetic interference technology represents an advanced electromagnetic countermeasure characterized by two-dimensional planar interference coverage and robust phase parameter tolerance, while also enabling artificial angular glint generation. This technology exhibits significant potential for practical engineering applications. Full article
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19 pages, 2696 KiB  
Article
Effect of Ultrasound and Chemical Cross-Linking on the Structural and Physicochemical Properties of Malanga (Colocasia esculenta) Starch
by Ana Sofía Martínez-Cigarroa, Guadalupe del Carmen Rodríguez-Jimenes, Alejandro Aparicio-Saguilán, Violeta Carpintero-Tepole, Miguel Ángel García-Alvarado, Ceferino Carrera, Gerardo Fernández Barbero, Mercedes Vázquez-Espinosa and Lucio Abel Vázquez-León
Foods 2025, 14(15), 2609; https://doi.org/10.3390/foods14152609 - 25 Jul 2025
Viewed by 293
Abstract
Starch extracted from malanga (Colocasia esculenta) is a biopolymer with considerable industrial potential thanks to its high starch content (70–80% on a dry basis) and small granule size, which give it distinctive functional properties. To expand its applications in advanced processes [...] Read more.
Starch extracted from malanga (Colocasia esculenta) is a biopolymer with considerable industrial potential thanks to its high starch content (70–80% on a dry basis) and small granule size, which give it distinctive functional properties. To expand its applications in advanced processes such as encapsulation, it is necessary to modify its structural and physicochemical characteristics. This study evaluated the effects of ultrasound (US) and chemical cross-linking (CL) on the properties of this starch. US was applied at various times and amplitudes, while CL was performed using sodium trimetaphosphate and sodium tripolyphosphate, with sodium sulfate as a catalyst. US treatment reduced particle size and increased amylose content, resulting in lower viscosity and gelatinization temperature, without affecting granule morphology. Meanwhile, CL induced phosphate linkages between starch chains, promoting aggregation and reducing amylose content and enthalpy, but increasing the gelatinization temperature. The modified starches exhibited low syneresis, making them potentially suitable for products such as pastas, baby foods, and jams. Additionally, ultrasound modification enabled the production of fine starch microparticles, which could be applied in the microencapsulation of bioactive compounds in the food and pharmaceutical industries. These findings suggest that modified malanga starch can serve as a functional and sustainable alternative in industrial applications. Full article
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20 pages, 3148 KiB  
Article
Dynamic Ultrasonic Jamming via Time–Frequency Mosaic for Anti-Eavesdropping Systems
by Zichuan Yu, Lu Tang, Kai Wang, Xusheng Tang and Hongyu Ge
Electronics 2025, 14(15), 2960; https://doi.org/10.3390/electronics14152960 - 24 Jul 2025
Viewed by 112
Abstract
To combat microphone eavesdropping on devices like smartphones, ultrasonic-based methods offer promise due to human inaudibility and microphone nonlinearity. However, existing systems suffer from low jamming efficiency, poor energy utilization, and weak robustness. Based on these problems, this paper proposes a novel ultrasonic-based [...] Read more.
To combat microphone eavesdropping on devices like smartphones, ultrasonic-based methods offer promise due to human inaudibility and microphone nonlinearity. However, existing systems suffer from low jamming efficiency, poor energy utilization, and weak robustness. Based on these problems, this paper proposes a novel ultrasonic-based jamming algorithm called the Time–Frequency Mosaic (TFM) technique, which can be used for anti-eavesdropping. The proposed TFM technique can generate short-time, frequency-coded jamming signals according to the voice frequency characteristics of different speakers, thereby achieving targeted and efficient jamming. A jamming prototype using the Time–Frequency Mosaic technique was developed and tested in various scenarios. The test results show that when the signal-to-noise ratio (SNR) is lower than 0 dB, the text Word Error Rate (WER) of the proposed method is basically over 60%; when the SNR is 0 dB, the WER of the algorithm in this paper is on average more than 20% higher than that of current jamming algorithms. In addition, when the jamming system maintains the same distance from the recording device, the algorithm in this paper has higher energy utilization efficiency compared with existing algorithms. Experiments prove that in most cases, the proposed algorithm has a better jamming effect, higher energy utilization efficiency, and stronger robustness. Full article
(This article belongs to the Topic Addressing Security Issues Related to Modern Software)
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18 pages, 1090 KiB  
Article
Enhancing Soy Yogurt with Microencapsulated Limosilactobacillus reuteri: Viability and Sensory Acceptability
by Ricardo H. Hernández-Figueroa, Yani D. Ramírez, Aurelio López-Malo and Emma Mani-López
Fermentation 2025, 11(8), 423; https://doi.org/10.3390/fermentation11080423 - 22 Jul 2025
Viewed by 434
Abstract
This study aimed to microencapsulate Limosilactobacillus reuteri DSM 17938 to enrich soy yogurt flavored with peach jam. The effect of three concentrations of alginate and coating chitosan were evaluated in terms of probiotic viability, and the physicochemical and sensory properties of soy yogurt. [...] Read more.
This study aimed to microencapsulate Limosilactobacillus reuteri DSM 17938 to enrich soy yogurt flavored with peach jam. The effect of three concentrations of alginate and coating chitosan were evaluated in terms of probiotic viability, and the physicochemical and sensory properties of soy yogurt. Lim. reuteri was microencapsulated in alginate (1, 2, and 3%) and coated with chitosan (0, 0.4, and 0.8%). Soymilk was fermented using Lactobacillus bulgaricus and Streptococcus thermophilus. Soy yogurt was combined with probiotic beads and peach jam and stored for 27 days at 4 °C. The pH, titratable acidity, and probiotic viability of probiotic peach soy yogurt (PPSY) were determined during storage. Alginate at 3% and alginate (2%) coated with 0.4% chitosan maintained probiotic counts at 8 and 7.5 log CFU/g after 27 days. The pH of PPSY decreases rapidly and drastically during storage when probiotic-free cells are added. The PPSY containing alginate (3%) beads, alginate (2%) coated with chitosan (0.4%), and probiotic-free cells had a similar level of acceptance in color, texture, and odor (p > 0.05), while flavor and overall acceptability were significantly higher (p < 0.05) in PPSY with probiotic beads. These findings support the use of microencapsulation strategies in developing functional plant-based probiotic foods. Full article
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19 pages, 4782 KiB  
Article
PD Detection and Analysis Triggered by Metal Protrusion in GIS Through Various Methods
by Weifeng Xin, Wei Song, Manling Dong, Xiaochuan Huang, Xiaoshi Kou, Zhenyu Zhan, Xinyue Shi and Xutao Han
Appl. Sci. 2025, 15(14), 8113; https://doi.org/10.3390/app15148113 - 21 Jul 2025
Viewed by 247
Abstract
Defects in GIS can be effectively detected by detecting the partial discharge (PD). The common methods of detecting partial discharge are pulse current, ultrasonic and UHF (ultra-high frequency). However, the results of different methods may be different due to the different physical quantities [...] Read more.
Defects in GIS can be effectively detected by detecting the partial discharge (PD). The common methods of detecting partial discharge are pulse current, ultrasonic and UHF (ultra-high frequency). However, the results of different methods may be different due to the different physical quantities detected. It is important to research the differences between the PD detection methods for the PD detection and analysis. In this study, we designed metal protrusion defects in GIS, including protrusion on the conductor and enclosure. Then, we detected the PD of defects using pulse current, UHF and ultrasonic methods at the same time. The PRPD patterns, maximum discharge amplitude of different defects and PD inception voltage (PDIV) detected by the three methods were analyzed. The PRPD patterns and discharge amplitude of the different methods were very similar to each other, but the PDIVs were different. It can be concluded that the process from the PD inception to breakdown can be divided into four sections based on the PRPD and the maximum discharge amplitude. The similarity between the three methods is because their signals are all related to the pulse current during the PD process, and differences in their PDIVs are caused by the differences in sensitivity. The sensitivity of the pulse current is the lowest among the three methods due to its poor anti-jamming capability. The sensitivity of UHF is higher, and that of ultrasonic is the highest. Full article
(This article belongs to the Special Issue Advances in Monitoring and Fault Diagnosis for Power Equipment)
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18 pages, 3678 KiB  
Article
Performance Degradation in Monopulse Angle Measurement of Planar Phased-Array Due to Cross-Polarization Component
by Yunhui Zhang, Bo Pang, Dahai Dai, Bo Chen and Zhengkuan Tan
Remote Sens. 2025, 17(14), 2454; https://doi.org/10.3390/rs17142454 - 15 Jul 2025
Viewed by 234
Abstract
Due to the high-precision angle measurement performance, the monopulse technique plays a key role in fields such as remote sensing and space surveillance. The accuracy of monopulse angle measurement depends on the received amplitude and phase information, which is sensitive to the polarization [...] Read more.
Due to the high-precision angle measurement performance, the monopulse technique plays a key role in fields such as remote sensing and space surveillance. The accuracy of monopulse angle measurement depends on the received amplitude and phase information, which is sensitive to the polarization component. Previous research has demonstrated that the performance of monopulse radar equipped with a parabolic antenna suffers from the cross-polarization component. However, it is not clear whether phased arrays (PAs) with higher degrees of freedom will also be affected by the cross-polarization component, and the parameter tolerance for performance degradation remains uncertain. In this paper, we establish a mathematical model of monopulse angle measurement in PA radar, which provides a comprehensive consideration of the cross-polarization component. Then, the received amplitude and phase patterns of PA radar are analyzed, and the theoretical angle errors caused by the cross-polarization jamming are derived. The experiments are conducted based on the measured amplitude-phase patterns of both co-polarization and cross-polarization. Experimental results are consistent with the theoretical analysis: the angle errors caused by cross-polarization jamming can reach half of the beamwidth in both azimuth and elevation dimensions, provided that the power of the cross-polarization and co-polarization components at the receiver is equal. Full article
(This article belongs to the Special Issue Recent Advances in SAR: Signal Processing and Target Recognition)
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28 pages, 1727 KiB  
Article
Detecting Jamming in Smart Grid Communications via Deep Learning
by Muhammad Irfan, Aymen Omri, Javier Hernandez Fernandez, Savio Sciancalepore and Gabriele Oligeri
J. Cybersecur. Priv. 2025, 5(3), 46; https://doi.org/10.3390/jcp5030046 - 15 Jul 2025
Viewed by 311
Abstract
Power-Line Communication (PLC) allows data transmission through existing power lines, thus avoiding the expensive deployment of ad hoc network infrastructures. However, power line networks remain vastly unattended, which allows tampering by malicious actors. In fact, an attacker can easily inject a malicious signal [...] Read more.
Power-Line Communication (PLC) allows data transmission through existing power lines, thus avoiding the expensive deployment of ad hoc network infrastructures. However, power line networks remain vastly unattended, which allows tampering by malicious actors. In fact, an attacker can easily inject a malicious signal (jamming) with the aim of disrupting ongoing communications. In this paper, we propose a new solution to detect jamming attacks before they significantly affect the quality of the communication link, thus allowing the detection of a jammer (geographically) far away from a receiver. We consider two scenarios as a function of the receiver’s ability to know in advance the impact of the jammer on the received signal. In the first scenario (jamming-aware), we leverage a classifier based on a Convolutional Neural Network, which has been trained on both jammed and non-jammed signals. In the second scenario (jamming-unaware), we consider a one-class classifier based on autoencoders, allowing us to address the challenge of jamming detection as a classical anomaly detection problem. Our proposed solution can detect jamming attacks on PLC networks with an accuracy greater than 99% even when the jammer is 68 m away from the receiver while requiring training only on traffic acquired during the regular operation of the target PLC network. Full article
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24 pages, 4085 KiB  
Article
A Joint Optimization Method for Power and Array of Multi-Point Sources System
by Zhihao Cai, Shiqi Xing, Xinyuan Su, Junpeng Wang, Weize Meng and Ziwen Xiao
Remote Sens. 2025, 17(14), 2445; https://doi.org/10.3390/rs17142445 - 14 Jul 2025
Viewed by 230
Abstract
In a multi-point source system, increasing the jamming power can expand the distribution area of the equivalent radiation center, but significantly increases the system exposure risk. Therefore, in order to achieve an optimal balance between the two, this paper proposes a joint optimization [...] Read more.
In a multi-point source system, increasing the jamming power can expand the distribution area of the equivalent radiation center, but significantly increases the system exposure risk. Therefore, in order to achieve an optimal balance between the two, this paper proposes a joint optimization method for jamming power and an array of multi-point source systems. First, based on determining the spatial geometric relationship between the triplet antenna and the target, the distribution law of the equivalent radiation center of the triplet antenna under the condition of the target echo is derived. Second, by introducing the angle factor, the jamming power and equivalent radiation center distribution area are combined to construct the joint optimization model of jamming power and array in omnidirectional and non-omnidirectional situations. Third, based on the non-dominated sorting whale optimization algorithm (NSWOA), an adaptive inertia weight based on the cosine function and logistic chaotic map is introduced to obtain the optimal arrangement. The experimental results show that in the omnidirectional case, when the average jamming-to-signal ratio is 13.83 dB, the equilateral triangle array can achieve the goal of protecting the target while avoiding the exposure of the triplet antenna position. In the non-omnidirectional case, when the average jamming-to-signal ratio is 13.90 dB, the equilateral triangle array can achieve the optimal balance between the jamming power and the area of the distribution area of the equivalent radiation center, and control the distribution of the equivalent radiation center to strictly meet the preset angular domain constraints. Furthermore, the optimal JSR value was reduced by an average of 1.14 dB compared with that of the conventional selection scheme. Full article
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21 pages, 887 KiB  
Article
Enhanced Mainlobe Jamming Suppression in Distributed Array Radar via Joint Optimization of Radar Positions and Subpulse Frequencies
by Weiming Pu, Kewei Feng, Xiaoping Wang, Zhennan Liang, Xinliang Chen and Quanhua Liu
Remote Sens. 2025, 17(14), 2423; https://doi.org/10.3390/rs17142423 - 12 Jul 2025
Viewed by 238
Abstract
This study presents a joint optimization framework for radar positions and subpulse carrier frequencies to address mainlobe jamming suppression in a distributed array radar system with one main and multiple auxiliary radars. Accounting for gain and aperture differences between the main and auxiliary [...] Read more.
This study presents a joint optimization framework for radar positions and subpulse carrier frequencies to address mainlobe jamming suppression in a distributed array radar system with one main and multiple auxiliary radars. Accounting for gain and aperture differences between the main and auxiliary radars, the grating lobe effect on jamming suppression performance is analyzed. Unlike conventional sparse array design approaches, this work introduces an architecture leveraging subpulses at distinct carrier frequencies to enhance grating lobe suppression and jamming suppression. A specific joint optimization method for radar positions and subpulse frequencies is then established. With jamming suppression performance as the objective function, the method first maps the variations induced by a range of candidate frequencies onto a single representative frequency point. This mapping enables efficient optimization of radar positions across the designated frequency band. Subsequently, a sequential scheme selects specific carrier frequencies for the subpulses. In practical anti-jamming operations, the optimal frequency for the current scenario is determined by analyzing the suppression results from these subpulses. The main radar then transmits pulses at this optimal frequency, thereby reducing both system complexity and pulse accumulation difficulty. Simulation results demonstrate that the proposed method achieves a reduction of over 3 dB in grating lobe suppression compared to conventional sparse array design methods, while enhancing the output signal-to-jamming and noise ratio by nearly 3 dB after jamming suppression. Full article
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17 pages, 2732 KiB  
Article
Influence of Cellulose Nanocrystals and Surfactants on Catastrophic Phase Inversion and Stability of Emulsions
by Daniel Kim and Rajinder Pal
Colloids Interfaces 2025, 9(4), 46; https://doi.org/10.3390/colloids9040046 - 11 Jul 2025
Viewed by 228
Abstract
This study presents the first quantitative comparison of catastrophic phase inversion behavior of water-in-oil emulsions stabilized by nanocrystalline cellulose (NCC) and molecular surfactants with different headgroup charge types: anionic (sodium dodecyl sulfate referred to as SDS), cationic (octadecyltrimethylammonium chloride referred to as OTAC), [...] Read more.
This study presents the first quantitative comparison of catastrophic phase inversion behavior of water-in-oil emulsions stabilized by nanocrystalline cellulose (NCC) and molecular surfactants with different headgroup charge types: anionic (sodium dodecyl sulfate referred to as SDS), cationic (octadecyltrimethylammonium chloride referred to as OTAC), nonionic (C12–14 alcohol ethoxylate referred to as Alfonic), and zwitterionic (cetyl betaine referred to as Amphosol). By using conductivity measurements under controlled mixing and pendant drop tensiometry, this study shows that NCC markedly delays catastrophic phase inversion through interfacial jamming, whereas surfactant-stabilized systems exhibit concentration-dependent inversion driven by interfacial saturation. Specifically, NCC-stabilized emulsions exhibited a nonlinear increase in the critical aqueous phase volume fraction required for inversion, ranging from 0.253 (0 wt% NCC) to 0.545 (1.5 wt% NCC), consistent with enhanced resistance to inversion typically associated with the formation of rigid interfacial layers in Pickering emulsions. In contrast, surfactant-stabilized systems exhibited a concentration-dependent inversion trend with opposing effects. At low concentrations, limited interfacial coverage delayed inversion, while at higher concentrations, increased surfactant availability and interfacial saturation promoted earlier inversion and favored the formation of oil-in-water structures. Pendant drop tensiometry confirmed negligible surface activity for NCC, while all surfactants significantly lowered interfacial tension. Despite its weak surface activity, NCC imparted strong coalescence resistance above 0.2 wt%, attributed to steric stabilization. These findings establish distinct mechanisms for governing phase inversion in particle- versus surfactant-stabilized systems. To our knowledge, this is the first study to quantitively characterize the catastrophic phase inversion behavior of water-in-oil emulsions using NCC. This work supports the use of NCC as an effective stabilizer for emulsions with high internal phase volume. Full article
(This article belongs to the Special Issue Rheology of Complex Fluids and Interfaces: 2nd Edition)
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9 pages, 1521 KiB  
Communication
Dynamic Behaviors of Concentrated Colloidal Silica Suspensions: Dancing, Bouncing, Solidifying, and Melting Under Vibration
by Motoyoshi Kobayashi, Takuya Sugimoto, Ryoichi Ishibashi and Shunsuke Sato
Liquids 2025, 5(3), 18; https://doi.org/10.3390/liquids5030018 - 11 Jul 2025
Viewed by 220
Abstract
Concentrated suspensions exhibit intriguing behaviors under external forces, including vibration and shear. While previous studies have focused primarily on cornstarch suspensions, this paper reports a novel observation that colloidal silica suspensions also exhibit dancing, bouncing, solidification, and melting under vertical vibration. Unlike cornstarch, [...] Read more.
Concentrated suspensions exhibit intriguing behaviors under external forces, including vibration and shear. While previous studies have focused primarily on cornstarch suspensions, this paper reports a novel observation that colloidal silica suspensions also exhibit dancing, bouncing, solidification, and melting under vertical vibration. Unlike cornstarch, silica particles offer high stability, controlled size distribution, and tunable surface properties, making them an ideal system for investigating these phenomena. The 70 wt.% aqueous suspensions of spherical silica particles with a diameter of 0.55 μm were subjected to controlled vertical vibration (60–100 Hz, 100–500 m/s2). High-speed video analysis revealed dynamic transitions, including melting, fingering, squirming, fragmentation, and jumping. The solidified suspension retained its shape after vibration ceased but melted upon weak vibration. This study demonstrates that such dynamic state transitions are not exclusive to starch-based suspensions but can also occur in well-defined colloidal suspensions. Our findings provide a new platform for investigating shear-thickening, jamming, and vibrational solidification in suspensions with controllable parameters. Further work is required to elucidate the underlying mechanisms. Full article
(This article belongs to the Section Physics of Liquids)
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