Search Results (884)

The development of non-noble metal catalysts provides a cost-effective and sustainable route for glucose oxidation to gluconic acid. In this study, a series of catalysts based on inexpensive transition metals (Cr, Cu, Ni, Fe) and/or Au were synthesized using siliceous supports (SiO₂ and MCM-41) and systematically evaluated. The aim was to partially or fully replace noble metals with lower-cost alternatives, while maintaining high catalytic performance. Comprehensive characterization—including ICP-AES for composition, N₂ adsorption–desorption for porosity, XRD for structure, H₂-TPR for reducibility, and NH₃-TPD for acidity—was conducted to establish structure–property relationships. Among the tested catalysts, Ni- and Fe-based systems exhibited superior stability, with NiO/SiO₂ achieving gluconic acid yields comparable to Au. The bimetallic Au–Ni/SiO₂ catalyst displayed enhanced metal–support interactions and minimal leaching (<2%), while Au–Fe/SiO₂ improved selectivity, yielding up to 23% gluconic acid, surpassing 5Fe/SiO₂ (18%) and 0.3Au/SiO₂ (15%), albeit with lower stability. These results highlight the potential of low-cost transition-metal and bimetallic catalysts as efficient and economically viable systems for selective glucose oxidation, providing insights for rational catalyst design in sustainable carbohydrate valorization. Full article

The degradation of mercapto organic contaminants is highly important for safety and environmental protection since the specific chemical properties and the strong nature of S-containing bonds can make them less susceptible to traditional degradation mechanisms compared to other types of organic bonds. Thus, degradation of mercapto organic contaminants often requires catalysts with specific bandgap properties to ensure efficient generation of reactive species and appropriate redox potential alignment. Hence, in this work, we prepared bandgap-engineered semiconductor photocatalysts based on nanoparticles of different silica-doped spinel cobalt ferrite [SiO₂/CoFe₂O₄] (abbreviated as SiMCoF) [SiMCoF-1, SiMCoF-2, and SiMCoF-3] and characterized them by different analytical techniques. Since the dopant composition in a heterogeneous semiconductor material has important effects on its photocatalytic efficiency because adjusting the dopant profile can modulate impurity bands and enhance optical properties, which is crucial for the oxidative degradation of organic pollutants. Results from TEM, SEM, and their EDS analysis revealed that increased SiO₂ content showed improved surface area in the matrix, facilitating the increased absorption of oxygen impurities. This is further observed by the higher R_max values presented in AFM of SiMCoF-3 (139 nm) compared to SiMCoF-2 (116 nm) and SiMCoF-1 (8.78 nm), depicting its larger effective surface area (100 µm²), which in turn increases the active binding sites in the matrix. The Raman spectrum and XRD pattern of SiMCoF-3 showed various crystal planes with different atomic arrangements and a smaller crystallite size, leading to varying affinities for oxygen impurities. As a result, the optical bandgap decreased from 3.42 eV to 2.89 eV for SiMCoF-3, which is attributed to the quantum confinement effects caused by the smaller particle size and the dispersion of silica particles in the cobalt ferrite matrix. Thus, SiMCoF-3 showed elevated degradation performance without using any potential oxidants over the degradation of mercapto organic contaminants such as 2-mercaptobenzothiazole, 2-mercaptobenzimidazole, and thiophenol under sunlight irradiation compared to other ferrites, and showed better results than Fenton’s reagent. Full article

The catalytic hydrogenation of carbon dioxide (CO₂) represents a transformative approach for reducing greenhouse gas emissions while producing sustainable fuels and chemicals, with ethanol being particularly promising due to its compatibility with existing energy infrastructure. Despite significant progress in converting CO₂ to C₁ products (e.g., methane, methanol), selective synthesis of C₂₊ compounds like ethanol remains challenging because of competing reaction pathways and byproduct formation. Recent advances in thermo-catalytic CO₂ hydrogenation have explored diverse catalyst systems including noble metals (Rh, Pd, Au, Ir, Pt) and non-noble metals (Co, Cu, Fe), supported on zeolites, metal oxides, perovskites, silica, metal–organic frameworks, and carbon-based materials. These studies reveal that catalytic performance hinges on the synergistic effects of multimetallic sites, tailored support properties and controlled reaction micro-environments to optimize CO₂ activation, controlled hydrogenation and C−C coupling. Mechanistic insights highlight the critical balance between CO₂ reduction steps and selective C−C bond formation, supported by thermodynamic analysis, advanced characterization techniques and theoretical calculations. However, challenges persist, such as low ethanol yields and undesired byproducts, necessitating innovative catalyst designs and optimized reactor configurations. Future efforts must integrate computational modeling, in situ/operando studies, and renewable hydrogen sources to advance scalable and economically viable processes. This review consolidates key findings, proposes potential reaction mechanisms, and outlines strategies for designing high-efficiency catalysts, ultimately providing reference for industrial application of CO₂-to-ethanol technologies. Full article

The conventional treatment of high-concentration volatile organic compounds (VOCs) relies on energy-intensive dilution to avoid explosion risks. This study proposes an efficient catalytic combustion process treating VOCs directly within the explosive range while recovering reaction heat using Pt/γ-Al₂O₃-based catalysts promoted with La and Ce. Catalysts (0.05–0.5 wt% Pt) were synthesized via impregnation and characterized using FE-SEM, BET, and XRD. Catalytic combustion experiments at VOC concentrations up to 13,000 ppm showed combustion initiation below 200 °C, achieving 83–99% conversions at 300 °C with complete oxidation to CO₂. Although 5 vol.% moisture significantly inhibited low-temperature activity through competitive adsorption, La and Ce promoters (10 wt%) effectively overcame this limitation by increasing surface area (up to 194.93 m²/g) and oxygen mobility. The Ce-promoted catalyst demonstrated superior water tolerance, achieving complete conversion at 200–210 °C due to its high Oxygen Storage Capacity (OSC). Bench-scale validation using a 1 Nm³/h system confirmed industrial feasibility. Operating at 220 °C with 13,000 ppm toluene for 100 h, the catalyst maintained >99.98% conversion with negligible deactivation and THC emissions below 2 ppm. The double-jacket heat exchanger effectively managed reaction heat (limiting temperature rise to ~20 °C) and recovered it as steam. Compared to Regenerative Thermal Oxidation, this Regenerative Catalytic Oxidation approach reduced emissions and energy consumption. This work demonstrates a robust “combustion-with-recovery” strategy for high-concentration VOC treatment, offering a sustainable alternative with high efficiency, stability, and safe energy-integrated operation. Full article

A series of catalytic oxides (Fe₂O₃, CuO, ZnO, and Cu₂O) were investigated as prospective additives shaping the thermal features of a model solid rocket propellant (SRP) formulation utilising ammonium nitrate as the oxidising agent. An extensive investigation of the thermal behaviour (DSC and ignition/explosion temperature studies) of the model and catalyst-bearing SRP formulations was conducted, providing insights into both the thermodynamics and mechanism of combustion of these systems. XRD analysis of post-combustion residues was used to validate the mechanistic claims, as well as to provide information about the behaviour of copper oxides in the SRP system. In addition, the linear combustion velocity was experimentally determined, and the power output was estimated from density, linear combustion velocity and DSC data, in order to assess the potential motor performance of the tested formulations. The obtained results show that the utilisation of metal oxides significantly improves the combustion performance of ammonium nitrate-based SRP formulations relative to the unmodified ammonium nitrate-based propellants. Full article

To improve the efficiency of CO₂ hydrogenation, it is essential to develop new catalysts as well as new methods of producing them. In our work, we propose a new Fe-, Co-, Cu-containing catalyst preparation technique based on depositing the active component through urea hydrolysis using microwave heating. We also compare catalysts produced with microwave synthesis to samples obtained through traditional synthesis methods, including impregnation and thermal deposition. The obtained catalysts were characterized by XRD, low-temperature N₂ adsorption, SEM., and UV-VIS methods. The catalytic properties of the catalysts depend not only on the nature of the active component, but also on the preparation method. The best results for CO₂ hydrogenation were achieved with Ni-containing catalysts produced by the impregnation method and microwave synthesis. Full article

This study presents a straightforward strategy for producing novel, effective and inexpensive functional non-noble metal-supported carbon materials made from abundant natural biomass. These materials offer a cost-effective alternative to noble metals for the oxidation of hydrazine (HzOR) and demonstrate the potential for widespread adoption of green, energy-saving hydrazine-based technologies in energy applications. Highly efficient and cost-effective iron (Fe) and manganese–iron (MnFe)-supported nitrogen-doped carbon (N–C) materials were developed using hydrothermal synthesis. Meanwhile, the N–C material was obtained from biomass—birch-wood chips—using hydrothermal carbonisation (HTC), followed by activation and nitrogen doping of the resulting hydrochar. The morphology, structure, and composition of the MnFe, MnFe/N–C, and Fe/N–C catalysts were determined using scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive X-ray spectroscopy (EDS). The activity of the catalysts for HzOR in an alkaline medium was evaluated using cyclic voltammetry (CV). Depositing MnFe particles onto N–C was shown to significantly enhance electrocatalytic activity for HzOR compared to the Fe/N–C catalyst and especially to the MnFe particles catalyst in terms of highly developed porous structure, which offers the largest surface area, lowest onset potential, and highest current density response, resulting in the strongest catalytic activity. These results suggest that the MnFe/N–C catalyst could be a highly promising anode material for HzOR in direct hydrazine fuel cells (DHFCs). Full article

Double complex salts (DCSs) of the composition [Co(NH₃)₆][Fe(CN)₆] are a promising precursor for the preparation of catalysts for the hydrogenation of carbon oxides (CO and CO₂) by Fischer–Tropsch synthesis. The specific surface area is an important parameter for catalysts. Our article investigates the influence of mechanochemical activation (MCA) on this DCS in order to determine the conditions for obtaining the largest specific surface area of the intermetallic compound, a product of the DCS thermolysis. In this work, the effect of MCA on the physicochemical properties of the DCS [Co(NH₃)₆][Fe(CN)₆] and the products of its thermal decomposition in an argon atmosphere were investigated. It was shown that MCA leads to partial reduction of Fe⁺³ to Fe⁺², changes in the coordination of ammonia, amorphization of the structure and a decrease in the thermal stability of DCS. Thermolysis at 650 °C of samples subjected to MCA for 10 min results in the formation of nanocrystalline intermetallic compound Co_0.5Fe_0.5. The results demonstrate the potential of using MCA to control the properties of functional materials based on DCS. Full article

Direct hydroxylation of benzene to phenol using hydrogen peroxide is a cornerstone of sustainable green chemistry. This paper presents the results of a stability study of an iron-containing mordenite catalyst in the liquid-phase hydroxylation of benzene to phenol with a 30% aqueous hydrogen peroxide solution. The study utilizes a combination of catalytic activity measurements, dynamic light scattering (DLS), and electron paramagnetic resonance (EPR) spectra. The system is initially shown to exhibit high phenol selectivity; however, over time, DLS measurements indicate aggregation of the catalyst particles with an increase in the average particle diameter from 1.8 to 2.6 μm and the formation of byproducts–dihydroxybenzenes. Iron is present predominantly as magnetite nanoparticles (Fe₃O₄) ~10 nm in diameter, stabilized on the outer surface of mordenite, with minor leaching (<10%) due to the formation of iron ion complexes with ascorbic acid as a result of the latter’s interaction with magnetite particles. Using a thermodynamic approach based on the Ulich formalism (first and second approximations), it is shown that the reaction of benzene hydroxylation H₂O₂ in the liquid phase is thermodynamically quite favorable (ΔG° = −(289–292) kJ·mol⁻¹ in the range of 293–343 K, K = 1044–1052). It is shown that ascorbic acid acts as a redox mediator (reducing Fe³⁺ to Fe²⁺) and a regulator of the catalytic medium activity. The stability of the catalytic system is examined in terms of the Lyapunov criterion: it is shown that the total Gibbs free energy (including the surface contribution) can be considered as a Lyapunov functional describing the evolution of the system toward a steady state. Ultrasonic (US) treatment of the catalytic system is shown to redisperse aggregated particles and restore its activity. It is established that the catalytic activity is due to nanosized Fe₃O₄ particles, which react with H₂O₂ to form hydroxyl radicals responsible for the selective hydroxylation of benzene to phenol. Full article

Electrochemical CO₂ reduction (CO₂RR) is a promising route to transform a major greenhouse gas into value-added fuels and chemicals. However, its deployment is still hindered by the sluggish activation of CO₂, poor selectivity toward multielectron products, and competition with the hydrogen evolution reaction (HER). Single-atom catalysts (SACs) have emerged as powerful materials to address these challenges because they combine maximal metal utilization with well-defined coordination environments whose electronic structure can be precisely tuned through metal–support interactions. This minireview summarizes current understanding of how structural, electronic, and chemical features of SAC supports (e.g., porosity, heteroatom doping, vacancies, and surface functionalization) govern the adsorption and conversion of key CO₂RR intermediates and thus control product distributions from CO to CH₄, CH₃OH and C₂⁺ species. Particular emphasis is placed on selectivity descriptors (e.g., coordination number, d-band position, binding energies of *COOH and *OCHO) and on rational design strategies that exploit curvature, microenvironment engineering, and electronic metal–support interactions to direct the reaction along desired pathways. Representative SAC systems based primarily on N-doped carbons, complemented by selected examples on oxides and MXenes are discussed in terms of Faradaic efficiency (FE), current density and operational stability under practically relevant conditions. Finally, the review highlights remaining bottlenecks and outlines future directions, including operando spectroscopy and data-driven analysis of dynamic single-site ensembles, machine-learning-assisted DFT screening, scalable mechanochemical synthesis, and integration of SACs into industrially viable electrolyzers for carbon-neutral chemical production. Full article

Magnesium hydride (MgH₂) is a promising solid-state hydrogen storage material owing to its high hydrogen capacity and low cost, yet its practical application is limited by sluggish kinetics, high operating temperatures, and poor cycling stability. Among various catalytic approaches, Fe-based catalysts have emerged as attractive candidates due to their abundance, compositional tunability, and effective promotion of hydrogen sorption reactions in MgH₂ systems. This review critically summarizes recent progress in Fe-based catalysts for MgH₂ hydrogen storage, encompassing elemental Fe, iron oxides, Fe-based alloys, and advanced composite catalysts with nanostructured and multicomponent architectures. Mechanistic insights into catalytic enhancement are discussed, with particular emphasis on interfacial electron transfer, catalytic phase evolution, hydrogen diffusion pathways, and synergistic effects between Fe-containing species and MgH₂, supported by experimental and theoretical studies. In addition to catalytic activity, key stability challenges—including catalyst agglomeration, phase segregation, interfacial degradation, and performance decay during cycling—are analyzed in relation to structural evolution and kinetic–thermodynamic trade-offs. Finally, a roadmap for the scalable design of Fe-based catalysts is proposed, highlighting rational catalyst selection, interface engineering, and compatibility with large-scale synthesis. This review aims to bridge fundamental mechanisms with practical design considerations for developing durable and high-performance MgH₂-based hydrogen storage materials. Full article

This work is based on our previous research on sulfur-assisted graphitization of biopitch by focusing on catalyst-driven optimization of biomass-derived pitch (BDP) composites as sustainable alternatives to coal tar pitch (CTP). Biomass from eucalyptus sawdust was pyrolyzed to produce BDP, which was used as a binder for carbon–carbon composites. The properties of BDP/graphite and CTP/graphite composites, including bending strength, electrical conductivity, hardness, density, porosity, mass loss, and shrinkage, were compared. Furthermore, the influence of catalysts (NiSO₄, K₂SO₄, CuSO₄, FeSO₄, and KOH) on composite performance was systematically investigated. Results show that catalyst selection significantly enhances structural, electrical, and mechanical properties, demonstrating the potential of combining eco-friendly materials with strategic catalyst engineering to develop high-performance, sustainable composites. Full article

The development of efficient and stable oxygen evolution reaction (OER) electrocatalysts based on non-precious metals is pivotal for advancing sustainable energy conversion technologies. We present a facile and green strategy for synthesizing a high-performance HO-CDs-FeOOH/NF(D) composite catalyst by leveraging a synergistic system of FeCl₃/urea deep eutectic solvent (DES) and hydroxyl-functionalized carbon dots (HO-CDs). This system orchestrates the rapid, in situ growth of FeOOH on nickel foam (NF) via simple immersion, wherein the DES acts as both an etchant and an iron source, while the HO-CDs induce a morphological transformation from sheet-like to granular stacking, thereby constructing highly active interfaces and increasing the density of accessible catalytic sites. The optimized catalyst exhibits exceptional OER performance, requiring an overpotential of only 251 mV to achieve 50 mA cm⁻², with a Tafel slope of 55.4 mV dec⁻¹. Moreover, it demonstrates outstanding stability, maintaining 98% of its initial current density after 24 h of continuous operation and showing negligible performance decay after 3000 cycles. This work presents a straightforward approach for designing high-performance Fe-based electrocatalysts through carbon dot-mediated morphology control via a facile DES-based impregnation strategy. Full article

The widespread application of Rhodamine B (RhB) poses a serious threat to the aquatic environment. ZnFe₂O₄, as a catalyst material, can effectively activate persulfate (PMS) and respond to visible light, thus effectively degrading RhB with the joint assistance of sunlight and PMS. This study recovered Fe₂O₃ from high-iron coal gangue through an activating–acid leaching–extracting–back-extracting process and synthesized ZnFe₂O₄ catalysts (CG-ZFO) using coal gangue back-extraction liquid as the Fe source by a hydrothermal method and cetyltrimethylammonium bromide (CTAB)-assisted hydrothermal method. The characterization results of X-ray diffraction (XRD), scanning electron microscopy (SEM), and diffuse reflectance spectroscopy (DRS) showed that the CG-ZFO has a pure crystal phase, and the addition of CTAB can effectively improve the photoelectric performance of the catalyst. The synthesized CG-ZFO can produce a significant synergistic effect with simulated sunlight (SS) and PMS, and the constructed SS/CG-ZFO/PMS system had a good degradation effect on RhB. Based on the conclusions of free radical-quenching experiments, electron paramagnetic resonance (EPR) spectroscopy, and X-ray photoelectron spectroscopy (XPS), the main active species in the SS/CG-ZFO/PMS system was identified as ₁O², and the degradation mechanism of RhB was elucidated. CG-ZFO prepared from coal gangue holds promising potential for application in the remediation of organic dye wastewater, and this study also provides a new approach for the resource regeneration of high-iron coal gangue. Full article

The development of sustainable catalysts from renewable resources is a key challenge for reducing the cost of industrial catalytic processes and waste valorization. In this work, low-cost heterogeneous active catalysts were prepared based on pyrolyzed forest residues, forming valuable porous support materials (Biochar) able to efficiently accommodate the highly active heteropolyacid HPW₁₂. Further, magnetic functionality was incorporated in the novel catalytic materials by the impregnation of NiFe₂O₄. The resulting magnetic composites were characterized by FTIR-ATR, SEM-EDS, ICP-OES, BET, XRD, potentiometric titration and magnetometry. The novel HPW₁₂@NiFe₂O₄@Biochar composites were able to valorize the glycerol to produce the fuel additive solketal with high conversion and high selectivity after only 3 h of reaction via acetalization reaction with acetone. The biochar catalytic composite prepared from cork presented higher pore size than the same prepared from forest biomass. This property was crucial to achieve the best conversion (89%) and the highest solketal selectivity (96%). Additionally, reusability capacity was verified, supporting the potential of the cork-pyrolyzed-based composites as potential low-cost catalytic material to produce fuel additives, such as solketal, under sustainable conditions. This may contribute one step further toward a future with greener energy, increasing the viability of biodiesel industry waste. Full article