Search Results (101)

Coastal ecosystems of the tropical Atlantic and the Mexican Caribbean have experienced recurrent massive influxes of pelagic brown macroalgae, Sargassum natans and Sargassum fluitans, generating severe environmental, social, and economic impacts. While the accumulation of this biomass poses a significant waste management challenge, it also represents an underexploited renewable resource aligned with circular economy and sustainability principles. This study investigated the valorisation of Sargassum spp. through comprehensive physicochemical characterisation and multiple value-added applications. The biomass collected in Tulum, Quintana Roo, Mexico, was analysed to determine its chemical composition, including lignin, holocellulose, α-cellulose, ash, and moisture content, using standardised methods of the Technical Association of the Pulp and Paper Industry (TAPPI). For mechanical testing, methods from the American Society for Testing and Materials (ASTM) were used. The biomass was subjected to controlled pretreatment and thermochemical conversion processes. Evaluated valorisation pathways included: (1) taxonomic identification and physicochemical characterisation, (2) polymer composites, (3) reinforcement in construction materials such as unfired clay bricks, and (4) biochar and activated carbon production for contaminant adsorption. The results demonstrated that Sargassum spp. biomass can be transformed from an environmental nuisance into a multifunctional, high-value biomaterial, providing scalable solutions that mitigate waste disposal challenges and contribute to climate and resource sustainability. Full article

Kiln-fired clay bricks are energy-intensive and carbon-heavy. This study develops and validates kiln-free, pressure-free, and ambient-cured geopolymer (GPM) bricks made from uncalcined clay and Class F fly ash. A two-stage experimental program screened 33 mixes (12–16 M NaOH and 396 cubes tested at 14–90 days) and then scaled six optimized mixes to 90 full-size bricks for mechanical, durability, and microstructural evaluation. Bricks with an optimal mix of 20–30% clay and 70–80% fly ash achieved a compressive strength of up to 32.5 MPa, satisfying ASTM C62 (for severe weathering) requirements. Relative to fired clay units, GPM bricks delivered +61% average compressive strength (up to +91%), +56.5% average modulus of rupture (up to +103%), 6–29% lower water absorption, and 42–84% higher UPV while their strength losses after 28-day immersion in 5% H₂SO₄ or 3.5% NaCl were only ~3–5%. SEM confirmed a dense N-A-S-H gel matrix with reduced porosity. Eco-efficiency analysis showed ~95% lower embodied CO₂ (0.26–0.31 vs. 5.5 kg eCO₂ per brick) and ~35% lower cost per MPa of strength than fired clay bricks. The findings demonstrate a practical, low-carbon brick manufactured without mechanical pressing or heat curing, delivering verified performance and durability under ambient conditions. Full article

The disposal of industrial waste poses a significant environmental challenge, often leading to pollution and degradation of surrounding and terrestrial ecosystems. This study investigates the sustainable valorization of such wastes through the development of one-part geopolymer mortars. Solid sodium silicate was employed as a dry alkali activator for binary blends comprising ground granulated blast-furnace slag (GGBS), clay brick powder (CBP), steel slag (SS), and fly ash (FA), with all mixtures cured under ambient conditions. The mortars were evaluated in terms of fresh properties (flow and setting time) and hardened characteristics, including compressive strength, density, water absorption, and porosity. Durability performance was assessed through mass loss, visual degradation, and compressive strength retention following exposure to acidic (H₂SO₄, HCl) and sulfate environments. Microstructural characterization using XRD, SEM, and FTIR provided insight into the mechanisms of gel formation and degradation in aggressive media. The results revealed that incorporating 5% FA into GGBS-based mortars enhanced 28-day compressive strength by 21.7% compared with the control mix. The inclusion of industrial by-products promoted the formation of C–S–H and C–(A)–S–H gels, contributing to a denser and more refined microstructure. Overall, the findings demonstrate that one-part geopolymer mortars offer a promising, eco-efficient, and durable alternative to traditional cementitious systems, while also addressing safety and handling concerns associated with liquid alkaline activators used in conventional two-part geopolymer formulations. Full article

The re-valorisation of oyster-shell waste offers a sustainable pathway for producing eco-efficient construction materials. This study investigates the physical, mechanical, and durability performance of natural hydraulic lime (NHL) mortars incorporating oyster shells (OSs), applied to solid bricks representative of historical masonry. Two formulations were developed: one with 24% replacement of NHL by oyster-shell powder (OSP, <150 µm) and another with 30% substitution of sand by oyster-shell aggregate (OSA, 0–4 mm), both compared with a control mortar. Mortars were tested in standard molds and directly applied to bricks, including under accelerated aging conditions (temperature and humidity cycles). Results revealed that shell-incorporated mortars applied to bricks exhibited higher bulk density and compressive strength, and lower porosity, capillary water absorption, and water vapor permeability, compared with mold-cast samples. The performance for the shell-based mortars highlights the substrate–mortar interaction, consistent with the behavior of traditional lime-based systems, and the microscope characterization (poro-Hg and X-ray tomography). Shell-incorporated mortars retained stable properties after aging, with variations below 10% compared to unaged mortars. These findings demonstrate the feasibility of oyster shells as partial replacements for lime and sand, confirming its potential as an eco-efficient strategy for sustainable mortars in conserving and rehabilitating historic masonry buildings. Full article

Despite growing interest in positive-energy and net-zero-energy buildings (NZEBs), few studies have addressed the integration of biobased construction with building-integrated photovoltaics (BIPV) under hot–dry climate conditions, particularly in Morocco and North Africa. This study fills this gap by presenting a simulation-based evaluation of energy performance and renewable energy integration strategies for a residential building in the Fes-Meknes region. Two structural configurations were compared using dynamic energy simulations in DesignBuilder/EnergyPlus, that is, a conventional concrete brick model and an eco-constructed alternative based on biobased wooden materials. Thus, the wooden construction reduced annual energy consumption by 33.3% and operational CO₂ emissions by 50% due to enhanced thermal insulation and moisture-regulating properties. Then multiple configurations of the solar energy systems were analysed, and an optimal hybrid off-grid hybrid system combining rooftop photovoltaic, BIPV, and lithium-ion battery storage achieved a 100% renewable energy fraction with an annual output of 12,390 kWh. While the system incurs a higher net present cost of $45,708 USD, it ensures full grid independence, lowers the electricity cost to $0.70/kWh, and improves occupant comfort. The novelty of this work lies in its integrated approach, which combines biobased construction, lifecycle-informed energy modelling, and HOMER-optimised PV/BIPV systems tailored to a hot, dry climate. The study provides a replicable framework for designing NZEBs in Morocco and similar arid regions, supporting the low-carbon transition and informing policy, planning, and sustainable construction strategies. Full article

Saudi Natural Pozzolan (SNP) can be processed and used in construction as a partial replacement for Ordinary Portland Cement (OPC). Its use as a supplementary cementitious material supports more sustainable and eco-friendly building practices. This study investigates various treatment methods for enhancing the reactivity of SNPs, including thermal, mechanical, thermo-mechanical, mechano-thermal, and chemical techniques. The activity of 18 different treated SNP mixtures was evaluated using the Strength Activity Index (SAI). Results identified the optimum conditions for each treatment: thermal treatment at 600 °C, mechanical treatment through 6 h of grinding, and chemical treatment with a 9% addition of hydrated lime. The SAI results demonstrated that a 6 h mechanical treatment was the most effective method for activating the raw pozzolan. X-ray diffraction (XRD) analysis revealed that phases such as quartz, anorthite, and aluminate are significant contributors to pozzolanic activity. The XRD analysis was further supported by scanning electron microscopy (SEM), which examined microstructural changes. This study highlights the potential of maximizing the utilization of extensive pozzolan resources in the Harrat region of the Kingdom of Saudi Arabia. Treated SNP can be applied in various industries, such as mining backfills, brick industry, and pozzolanic concrete, as a sustainable and environmentally friendly material. Full article

The preparation of construction waste into eco-friendly recycled powder (RP), partially replacing cement to produce foam concrete with thermal insulation properties, provides a new approach for the resource utilization of RP. In this study, different components of construction waste were used to prepare recycled paste powder (RPP), recycled brick powder (RBP), and recycled concrete powder (RCP). The effects of RP on the microstructural and macroscopic properties of foam concrete were investigated at replacement rates ranging from 0% to 30%. The research results indicate that the microstructure of all three types of RP exhibits irregular shapes, and their chemical compositions show significant differences. Partial replacement of cement with these RP leads to the deterioration of the matrix microstructure, which negatively affects the workability and mechanical properties of the foam concrete. However, the addition of RP effectively mitigates the drying shrinkage of the foam concrete, with RBP showing particularly outstanding performance in this regard. Specifically, the maximum drying shrinkage rate of F-30RBP is 9.33% and 11.31% lower than that of F-30RPP and F-30RCP, respectively. Furthermore, the incorporation of RP has a minimal effect on the thermal conductivity of the foam concrete, indicating that RP is well-suited for use in foam concrete. Full article

The growing demand for eco-efficient construction materials has driven the development of low-clinker cement systems incorporating recycled mineral additives. Finely ground brick powder represents one of such materials with high pozzolanic potential. This article presents an experimental study on the effect of partially replacing slag cement CEM III and ordinary rapid-hardening cement CEM I with brick powder waste of different chemical compositions and fineness levels (63, 32, and 15 µm) on the physical and mechanical properties of blended cement mortars. Compressive and flexural strengths were determined at 2, 7, and 28 days, along with the strength activity index (SAI). Additionally, the setting times and standard consistency were investigated, with the latter showing a correlation with the workability of fresh mortars. Comprehensive microstructural analysis (TGA, SEM, EDX) confirmed the pozzolanic activity of the brick powder, which was manifested by the formation of C-S-H and C-A-S-H phases. The highest strength characteristics were achieved with a 15% replacement of cement by brick powder with a fineness of 32 μm and an increased SiO₂ content (63.06%). Comparative analysis with fly ash- and silica fume-modified mortars revealed that brick powder exhibits comparable performance, confirming its suitability as an active mineral additive. Full article

Biodeterioration represents a major threat to cultural heritage, as microbial colonization can cause both esthetic and structural damage. The use of conventional chemical biocides raises concerns due to environmental and health risks, potential substrate deterioration, and the emergence of resistant strains. In this study, an ozone-loaded bacterial cellulose (OBC) hydrogel was investigated as an eco-friendly, broad-spectrum antimicrobial treatment in the case study of the Cryptoporticus of the Baths of Trajan (Rome, Italy), a hypogean archeological site where some structures are severely affected by phototrophic biofilms. Microorganisms isolated from a colonized wall were employed in laboratory assays. OBC hydrogel exhibited strong antimicrobial activity, with >90% bacterial mortality within 10 min, complete inhibition of fungal spore germination after 24 h, and a marked reduction in microalgal chlorophyll fluorescence comparable to heat-killed controls. Furthermore, tests on Carrara marble and brick specimens artificially contaminated with microalgae confirmed the removal of green staining, restoring surface chromatic parameters (ΔE* < 5) comparable to those obtained with a commercial biocide. In situ applications demonstrated significant suppression of green biofilm for at least two months. These findings support OBC hydrogel as a sustainable, effective, and non-toxic alternative to conventional biocides for controlling microbial and microalgal colonization on cultural heritage surfaces. Full article

In response to escalating environmental concerns, the construction industry is under growing pressure to adopt sustainable practices. As a major consumer of natural resources and a significant emitter of greenhouse gases, it paradoxically holds the potential to become a leader in green transformation. This study investigates the development of innovative, fire-resistant, and alkali-activated hybrid binder foams incorporating recycled materials: fly ash, coal slag, and ground brick waste, as sustainable alternatives to traditional building materials. The fire resistance performance at a technical scale and the thermal behavior of fiber-reinforced, alkali-activated hybrid binder foams synthesized from recycled aluminosilicate precursors were determined. The properties of unreinforced composite were compared with the composites reinforced with merino wool, basalt fibers, polypropylene fibers, and coconut fiber. Small-scale fire-resistance tests revealed that merino wool-reinforced composites exhibited the best thermal insulation performance, maintaining structural integrity, that is, retaining shape and continuity without delamination or collapse for 83 min under fire exposure. Analyses combining chemical characterization (X-ray fluorescence) with microstructural methods (computed tomography and colorimetry) confirmed that fire performance is strongly influenced not only by fiber type but also by pore distribution, phase composition, and oxide migration under thermal loading. These findings demonstrate the potential of fiber-reinforced foamed, alkali-activated hybrid binder as eco-efficient, printable materials for fire-safe and thermally demanding construction applications. Full article

Plastic waste, particularly polyethylene terephthalate (PET), poses a growing environmental challenge. This study investigates the feasibility of incorporating recycled PET into clay bricks as a sustainable alternative in construction. Bricks were fabricated with 0%, 5%, 10%, and 15% PET content. Clay characterization included particle size distribution, Atterberg limits, and moisture content. Physical and mechanical tests evaluated dimensional variability, void percentage, warping, water absorption, suction, unit compressive strength ($f_b^{\prime }$), and prism compressive strength ($f_m^{\prime }$). Statistical analysis (Shapiro–Wilk, p < 0.05) validated the results. PET addition improved physical properties—reducing water absorption, suction, and voids—while slightly compromising mechanical strength. The 15% PET mix showed the best overall performance ($f_b^{\prime }$ = 24.00 kg/cm²; $f_m^{\prime }$ = 20.40 kg/cm²), with uniform deformation and lower absorption (18.7%). Recycled PET enhances key physical attributes of clay bricks, supporting its use in eco-friendly construction. However, reduced compressive strength limits its structural applications. Optimizing PET particle size, clay type, and firing conditions is essential to improve load-bearing capacity. Current formulations are promising for non-structural uses, contributing to circular material strategies. Full article

The technological potential and sustainability of red clays from the Taveiro region (Coimbra, Portugal) for structural ceramic applications have been investigated. Thirteen representative samples granulometric, mineralogical, chemical analysis, and technological characterization were conducted to determine the suitability for extrusion-based ceramics, aligned with circular economy and climate goals (e.g., PNEC2030, RNC2050). The samples exhibited a high fine fraction content (<0.002 mm up to 76%) and plasticity index (PI; up to 41%), associated with significant smectite, illite, and kaolinite content. Bulk mineralogy was dominated by Σ phyllosilicates (up to 77%) and quartz (12%–29%), while chemical analyses showed high SiO₂ and Al₂O₃ content, moderate Fe₂O₃, and low CaO/MgO, typical of aluminosilicate clays for red ceramics. High cation exchange capacity (CEC; up to 49 meq/100 g) and specific surface area (SSA; up to 83 m²/g) reflected smectite-rich samples. Firing tests at 900 and 1000 °C demonstrated decreasing water absorption and shrinkage with increased temperature, with some samples yielding lower porosity and higher strength (~12 MPa), confirming suitability for bricks and tiles. Two samples showed higher plasticity but greater shrinkage and porosity, suggesting applicability in porous ceramics or blends. This work highlights the role of mineralogical and technological indicators in guiding the eco-efficient use of georesources for ceramic manufacturing. Full article

This study investigates the synergistic modification of cement–soil using waste brick powder (WBP) and polyvinyl alcohol (PVA) fibers to address the growing demand for sustainable construction materials and recycling of demolition waste. An orthogonal experimental design was employed with 5% WBP (by mass) and PVA fiber content (0–1%), evaluating mechanical properties based on unconfined compressive strength (UCS) and splitting tensile strength (STS) and microstructure via scanning electron microscopy (SEM) across 3–28 days of curing. The results demonstrate that 0.75% PVA optimizes performance, enhancing UCS by 28.3% (6.87 MPa) and STS by 34.6% (0.93 MPa) at 28 days compared to unmodified cement–soil. SEM analysis revealed that PVA fibers bridged microcracks, suppressing propagation, while WBP triggered pozzolanic reactions to densify the matrix. This dual mechanism concurrently improves mechanical durability and valorizes construction waste, offering a pathway to reduce reliance on virgin materials. This study establishes empirically validated mix ratios for eco-efficient cement–soil composites, advancing scalable solutions for low-carbon geotechnical applications. By aligning material innovation with circular economy principles, this work directly supports global de-carbonization targets in the construction sector. Full article

This study investigates the use of gypsum waste from civil construction as a partial substitute for cement in soil–cement formulations, aiming to produce eco-friendly bricks aligned with circular economy principles. Formulations were prepared using a 1:8 cement–soil ratio, with gypsum replacing cement in proportions ranging from 5% to 40%. The raw materials were characterized in terms of chemical composition, crystalline phases, plasticity, and thermal behavior. Specimens, molded by uniaxial pressing into cylindrical bodies and cured for either 7 or 28 days, were evaluated for compressive strength, water absorption, durability, and microstructure. Water absorption remained below 20% in all samples, with an average value of 16.20%. Compressive strength after 7 days exhibited a slight reduction with increasing gypsum content, ranging from 16.36 MPa (standard formulation) to 13.74 MPa (40% gypsum), all meeting the quality standards. After 28 days of curing, the formulation containing 10% gypsum achieved the highest compressive strength (26.7 MPa), surpassing the reference sample (25.2 MPa). Mass loss during wetting–drying cycles remained within acceptable limits for formulations incorporating up to 20% gypsum. Notably, samples with 5% and 10% gypsum demonstrated superior mechanical performance, while the 20% formulation showed performance comparable to the standard formulation. These findings indicate that replacing up to 20% of cement with gypsum waste is a technically and environmentally viable approach, supporting sustainable development, circular economy, and reduction of construction-related environmental impacts. Full article

This study presents the development and characterization of sustainable bio-bricks incorporating agricultural residues—specifically coffee husks and bovine excreta—as partial substitutes for cement. A mixture design optimized through response surface methodology (RSM) identified the best-performing formulation, namely 960 g of cement, 225 g of lignin (extracted from coffee husks), and 315 g of bovine excreta. Experimental evaluations included compressive and flexural strength, water absorption, density, thermal conductivity, transmittance, admittance, and acoustic transmission loss. The optimal mixture achieved a compressive strength of 1.70 MPa and a flexural strength of 0.56 MPa, meeting Colombian technical standards for non-structural masonry. Its thermal conductivity (~0.19 W/(m×K)) and transmittance (~0.20 W/(m²×K)) suggest good insulation performance. Field tests in three Colombian climate zones confirmed improved thermal comfort compared to traditional clay brick walls, with up to 8 °C internal temperature reduction. Acoustic analysis revealed higher sound attenuation in bio-bricks, especially at low frequencies. Chemical and morphological analyses (SEM-EDS, FTIR, and TGA) confirmed favorable thermal stability and the synergistic interaction of organic and inorganic components. The findings support bio-bricks’ potential as eco-efficient, low-carbon alternatives for sustainable building applications. Full article