Search Results (135)

Precise Re-Os isotopic ages of the Jinduicheng and Donggou Mo deposits in the East Qinling orogenic belt can shed light on the controversies about multiple-stage pulses of mineralization and further elucidate the genesis and metallogenic process of the deposits. In this study, we propose two major events of Mo mineralization in this orogenic belt occurring during the Late Mesozoic: the early stage of 156–130 Ma and late stage of 122–114 Ma. Results of molybdenite Re-Os isotopic analysis reveal that the Jinduicheng deposit formed at 139.2 ± 2.9 Ma, while the Donggou deposit exhibited two-stage mineralization at 115.4 ± 1.6 Ma and 111.9 ± 1.3 Ma. These isotopic ages align with the spatiotemporal evolution of coeval ore-barren granites exposed in eastern Qinling, pointing to a close genetic relationship between the magmatism and mineralization that was controlled by the same tectonic activity, likely in a post-collisional setting. This highlights the multiple-stage Mo mineralization and provides evidence for further understanding the geodynamics and metallogenic process in the eastern Qinling orogenic belt. Full article

Recent updates to the reconstructions of Cenozoic environmental changes (global sea level, temperature, and atmospheric carbon dioxide content) have made it intriguing to compare them to paleontological records for original interpretations. Paleogene brachiopods have remained in the shadow of their Paleozoic–Mesozoic predecessors, and the reactions of their diversity to the Earth’s dramatic changes are poorly understood. The present work aims to fill this gap via a comparison of several diversity and paleoenvironmental curves. The generic diversity was established by stages with two essentially different paleontological datasets, and several fresh paleoenvironmental reconstructions were adopted. It was observed that neither Paleogene eustatic fluctuations nor changes in the atmospheric carbon dioxide content correspond well to the generic diversity dynamics of brachiopods. The changes in the total number of genera and the global temperatures demonstrate similarity at the Danian–Ypresian interval, but not later. The fluctuations in the brachiopod diversity are near the same level during the Eocene–Oligocene, despite strong paleoenvironmental changes, implying the intrinsic resistivity of these organisms to external influences. Additionally, the Cretaceous/Paleogene mass extinction, the Paleocene–Eocene thermal maximum, and the Early Eocene optimum could enhance the diversity dynamics together with the long-term temperature changes. In contrast, the influences of the Late Danian warming event and the Oi-1 glaciation were not observed. Full article

The Erentaolegai silver deposit is located within the Derbugan metallogenic belt in the eastern segment of the Central Asia–Mongolia giant orogenic belt. The ore bodies are primarily hosted in the volcanic rocks of the Middle Jurassic Tamulangou Formation of the Mesozoic. The mineralization process of the deposit is divided into three stages: Stage I: Pyrite–Quartz Stage; Stage II: Sulfide–Quartz Stage; Stage III: Quartz–Manganese Carbonate Stage. This paper discusses the ore-forming fluids, ore-forming materials, and deposit genesis of the Erentaolegai silver deposits using fluid inclusions microthermometry, laser Raman spectroscopy, and H-O-S isotope analyses. Fluid inclusion microthermometry and laser Raman spectroscopy analyses indicate that the Erentaolegai silver deposit contains exclusively fluid-rich two-phase fluid inclusions, all of which belong to the H₂O-NaCl system. Homogenization temperatures of fluid inclusions in the three stages (from early to late) ranged from 257 to 311 °C, 228 to 280 °C, and 194 to 238 °C, corresponding to salinities of 1.91 to 7.86 wt%, 2.07 to 5.41 wt%, and 0.70–3.55 wt% NaCl equivalent, densities of 0.75 to 0.83 g/cm⁻³, 0.80 to 0.86 g/cm⁻³ and 0.85 to 0.89 g/cm⁻³. The mineralization pressure ranged from 12.2 to 29.5 MPa, and the mineralization depth was 0.41 to 0.98 km, indicating low-pressure and shallow-depth mineralization conditions. H-O isotope results indicate that the ore-forming fluid is a mixture of magmatic fluids and meteoric water, with meteoric contribution dominating in the late stage. The δ³⁴S values of metallic sulfides ranged from −1.8 to +4.0‰, indicating that the metallogenic material of the Erentaolegai silver deposit was dominated by a deep magmatic source. This study concludes that meteoric water mixing and subsequent fluid cooling served as the primary mechanism for silver mineral precipitation. The Erentaolegai silver deposit is classified as a low-sulfidation epithermal silver deposit. Full article

The Caucasian Sea was among the vast tropical water masses that existed on Earth in the Mesozoic. The knowledge of Kimmeridgian–Hauterivian deposits from the central Western Caucasus can facilitate the understanding of the Caucasian paleogeography at the Jurassic–Cretaceous transition. Taking into account the scale of the study area and its geological complexity, a generalized synthesis of the published information seems to be an appropriate option to propose a tentative paleogeographical model. Some original field and laboratory studies, including the examination of the composition of Hauterivian alluvial sandstones, contribute to this model. Kimmeridgian–Hauterivian deposits crop out in the northern, western, and southern domains of the study area, but older rocks are exposed in its central and eastern parts. The Caucasian Sea covered the study area in the early Kimmeridgian, but a large land appeared in the late Kimmeridgian and existed until the end of the Hauterivian despite certain shoreline shifts. The land was eroded deeply, with exposure of pre-Upper Jurassic rocks, including Precambrian–Paleozoic crystalline complexes, and the sedimentary material was delivered to an alluvial plain on its periphery. The registered sea–land interplay was controlled tectonically. Full article

Late Paleozoic to Early Mesozoic granitoids in the East Kunlun Orogenic Belt (EKOB) provide critical insights into the complex and debated relationship between Paleo–Tethyan magmatism and tectonics. This study presents integrated bulk-rock geochemical and zircon isotopic data for the Xingshugou monzogranite (MG) to address these controversies. LA-ICP-MS zircon U-Pb dating constrains the emplacement age of the MG to 247.1 ± 1.5 Ma. The MG exhibits a peraluminous and low Na₂O A₂-type granite affinity, characterized by high K₂O (4.69–6.80 wt.%) and Zr + Nb + Ce + Y (>350 ppm) concentrations, coupled with high Y/Nb (>1.2) and A/CNK ratios (1.54–2.46). It also displays low FeO^T, MnO, TiO₂, P₂O₅, and Mg^# values (26–49), alongside pronounced negative Eu anomalies (Eu/Eu* = 0.37–0.49) and moderately fractionated rare earth element (REE) patterns ((La/Yb)_N = 3.30–5.11). The MG exhibits enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs; such as Sr and Ba), and depletion in high field strength elements (HFSEs; such as Nb, Ta, and Ti), collectively indicating an arc magmatic affinity. Zircon saturation temperatures (T_Zr = 868–934 °C) and geochemical discriminators suggest that the MG was generated under high-temperature, low-pressure, relatively dry conditions. Combined with positive zircon ε_Hf(t) (1.8 to 4.7) values, it is suggested that the MG was derived from partial melting of juvenile crust. Synthesizing regional data, this study suggests that the Xingshugou MG was formed in an extensional tectonic setting triggered by slab rollback of the Paleo-Tethys Oceanic slab. Full article

The North China Craton (NCC) experienced extensive destruction and modification of its subcontinental lithospheric mantle during the Mesozoic, a period marked by intensive tectonism, magmatism, and mineralization. Among the key manifestations of this event are the Shizhuzi magmatic complex (SMC) and related Mo-Cu-Au deposits in the Liaodong Peninsula. This study presents new zircon U-Pb ages and Hf isotope data, along with whole-rock major and trace element geochemical data. Meanwhile, by incorporating published datasets, the magmatism and mineralization of the SMC are discussed. Two-stage magmatic activity is identified in the SMC as follows: (1) Stage I (130–126 Ma) associated with mineralization, and (2) Stage II (121–117 Ma), both corresponding to the peak destruction of the NCC. The mineralized granitoids exhibit I-type affinities and formed in an extension setting. Quartz diorites within this suite were derived from the partial melting of an enriched mantle source, and the high-temperature thermal underplating associated with this process subsequently triggered partial melting of the basaltic lower crust, leading to the generation of granodiorites and monzonitic granites. These rocks experienced limited fractional crystallization (dominated by plagioclase + biotite) and are linked to Mo-Cu-Au mineralization. In contrast, the non-mineralized granitoids are high-K calc-alkaline, peraluminous A-type granites, which developed in an extremely extensional tectonic setting. They were derived from partial melting of ancient lower crust and display characteristics of highly fractionated granites, having undergone extensive crystallization differentiation involving plagioclase + K-feldspar during magmatic evolution. The mineralized and non-mineralized granitoids exhibit distinct differences in lithology, major/trace element characteristics, Hf isotopes, and degree of fractional crystallization. Our proposed two-stage magmatic model—coupled with a mineralization phase—provides significant insights into both magmatic processes and metallogenesis in the Liaodong Peninsula. It further offers key perspectives into the Early Cretaceous decratonization of the NCC in terms of its tectonic–magmatic–mineralization evolution. Full article

The Cenozoic Nankang Basin in China records a complex series of tectonic, magmatic, metamorphic, and sedimentary events associated with the surrounding Shiwanshan, Liuwanshan, and Yunkaishan orogenic systems. The Nankang Basin is a critical location for studying the Cenozoic tectono–sedimentary evolution and strategic mineral resources of the southern Cathaysia Block. We used core samples from multiple boreholes and regional geological survey data to analyze the rock assemblages, sediment types, and sedimentary facies of the Nankang Basin. In addition, we analyzed the detrital zircon U–Pb geochronology, sandstone detrital compositions, heavy mineral assemblages, and major element geochemistry. The detrital zircon grains from Cenozoic sandstones in the Nankang Basin have age peaks at 2500–2000, 1100–900, 500–400, and 300–200 Ma, with most grains having ages of 500–400 or 300–200 Ma. The provenance analysis indicates that the 300–200 Ma zircon grains originated mainly from the Liuwanshan pluton; the 500–400 Ma zircon grains originated from the Ningtan pluton; and the 2500–2000 and 1100–900 Ma zircon grains originated from the Lower Silurian Liantan Formation and Middle Devonian Xindu Formation. This indicates that the provenance of Cenozoic sandstones in the Nankang Basin primarily originates from Paleozoic–Early Mesozoic igneous in the surrounding area, while the regional old sedimentary rocks possibly serve as intermediate sedimentary reservoirs. The detrital compositions of the sandstones and heavy mineral assemblages indicate a change in the tectonic setting during the deposition of the Nankang and Zhanjiang Formations, with a change in the source of the sediments due to the uplift of the Shizishan. During the deposition of the Nankang Formation, the sediment transport direction was to the NNW, whereas during the deposition of the Zhanjiang Formation, it was to the NNE. The uplift of the Shizishan most probably occurred during the late Neogene and early Quaternary, separating the Hepu and Nankang Basins. Full article

Regolith-hosted rare-earth element (REE) deposits are some of the most important types of REE deposits. The relationship between Late Paleozoic and Early Mesozoic granite and regolith-hosted REE deposits is still poorly studied. Detailed geochronology, geochemistry, and rare-earth mineralogy analyses of Early Triassic granite in the South China Block were conducted. The geochronological results showed that four representative granite samples yielded formation ages of 245 ± 1 Ma, 244 ± 1 Ma, 244 ± 1 Ma, and 244 ± 2 Ma, respectively. The granites show geochemical affinity to A-type granite. They are characterized by enrichment in Rb, Th, and U, are depleted in Ba, Sr, P, and Ti, and show obvious negative Nb and Ta anomalies. They have high light rare-earth element (LREE) and low heavy rare-earth element (HREE) contents, with obvious negative Eu anomalies. They were derived from the partial melting of a sediment source and underwent intense fractional crystallization during the magma evolution process. They contain a certain number of rare-earth-element-bearing minerals, such as monazite, xenotime, apatite, and zircon. Their REE compositions and mineral associations are similar to those of the parent rocks from typical regolith-hosted REE deposits in South China. The highly weathered horizon at the ridge of the granite weathering crust profile has the highest REE content. A comprehensive analysis indicated that the degree of magma evolution, geomorphology, and weathering are important factors controlling the formation of regolith-hosted REE deposits in the area. Full article

The Heilongjiang Complex provides a crucial geological record of the evolutionary history of the Mudanjiang Ocean, making it significant for understanding the accretion process between the Jiamusi Block and the Songliao Block. In this study, we analyzed samples from the Heilongjiang Complex in the Huanan region using zircon U-Pb and ⁴⁰Ar/³⁹Ar isotopic dating. The LA-ICP-MS U-Pb dating results show that the deposition time of the mica quartz schist is Late Triassic (237–207 Ma), while the protolith age of the amphibolite is Middle Triassic (245.5 ± 1.2 Ma). Detrital zircon ages from the mica quartz schist reveal four groups: 155–229 Ma, 237–296 Ma, 485–556 Ma, and 585–2238 Ma. The provenances are related to the magmatic and metamorphic activities at the junction of the Jiamusi Block and Songliao Block. ⁴⁰Ar/³⁹Ar isotopic dating yielded a plateau age of 183.40 ± 1.83 Ma for phengite in the mica quartz schist, with the metamorphic ages obtained from zircon U-Pb dating. We identify three major metamorphic events in the Heilongjiang Complex: (1) ~229 Ma, marking the earliest tectonic thermal disturbance in the complex; (2) 207–202 Ma, corresponding to the metamorphic event related to the collision between the Jiamusi Block and Songliao Block; and (3) ~183 Ma, indicating the closure of the Mudanjiang Ocean. Integrating these new findings with the results of previous research on magmatism and metamorphism, we reconstruct the tectonic evolution of the Mudanjiang Ocean from the Late Paleozoic to the Mesozoic. During the Early Permian, the Mudanjiang Ocean had already opened. Between the Middle Permian and Middle Triassic, bidirectional subduction occurred. In the Late Triassic, the Mudanjiang Ocean entered a subduction dormancy period. By the Early to Middle Jurassic, the Mudanjiang Ocean closed due to continental collision, leading to the final positioning of the Heilongjiang Complex. Full article

Late Mesozoic magmatism in Southeast China extensively reworked the Cathaysia Block’s crust, linked to the Paleo-Pacific Plate subduction beneath East Asia. The northeastern Cathaysia Block, largely covered by Cretaceous volcanic-sedimentary basins, has limited Jurassic exposure to Early Cretaceous intrusions, which provides critical insights into deep crust-mantle processes. In this study, we present zircon U-Pb geochronology and Hf isotope, whole-rock geochemistry, and Sr-Nd isotopes of the Middle Jurassic syenite-granite suites and Early Cretaceous granites with enclaves in the Qingyuan area (SW Zhejiang Province) to constrain their petrogenesis and tectonic significance. Middle Jurassic syenites and alkali-feldspar granites (169–167 Ma) exhibit calc-alkaline to shoshonitic affinities and weakly peraluminous compositions. Early Cretaceous granites (134 Ma) and their enclaves (136 Ma) are high-K calc-alkaline and weakly peraluminous to metaluminous. All samples show LILE and LREE enrichment, HFSE depletion, and negative Eu and Sr anomalies, with only syenites displaying negative Ce anomalies. We suggest that the Middle Jurassic syenites originated from the partial melting of an enriched lithospheric mantle influenced by subduction-related metasomatism. Alkali-feldspar granites derived from partial melting of the basement of the Cathaysia Block. Early Cretaceous granites formed by partial melting of lower crustal mafic rocks, with enclaves representing earlier crystallization products, which were then mechanically mixed with granites. We propose the NE Cathaysia Block underwent significant reworking from the Middle Jurassic to the Early Cretaceous. Middle Jurassic syenites formed in a compressional setting linked to Paleo-Pacific Plate subduction, while Early Cretaceous magmatism reflects lithospheric extension and crust-mantle interaction triggered by slab rollback. Full article

The Beishan Orogenic Belt, situated along the southern margin of the Central Asian Orogenic Belt, represents a critical tectonic domain that archives the prolonged subduction–accretion processes and Paleo-Asian Ocean closure from the Early Paleozoic to the Mesozoic. Early Permian magmatism, exhibiting the most extensive spatial-temporal distribution in this belt, remains controversial in its geodynamic context: whether it formed in a persistent subduction regime or was associated with mantle plume activity or post-collisional extension within a rift setting. This study presents an integrated analysis of petrology, zircon U-Pb geochronology, in situ Hf isotopes, and whole-rock geochemistry of Early Permian granites from the Tiancang area in the southern Beishan Orogenic Belt, complemented by regional comparative studies. Tiancang granites comprise biotite monzogranite, monzogranite, and syenogranite. Zircon U-Pb dating of four samples yields crystallization ages of 279.3–274.1 Ma. These granites are classified as high-K calc-alkaline to calc-alkaline, metaluminous to weakly peraluminous I-type granites. Geochemical signatures reveal the following: (1) low total rare earth element (REE) concentrations with light REE enrichment ((La/Yb)_N = 3.26–11.39); (2) pronounced negative Eu anomalies (Eu/Eu* = 0.47–0.71) and subordinate Ce anomalies; (3) enrichment in large-ion lithophile elements (LILEs: Rb, Th, U, K) coupled with depletion in high-field-strength elements (HFSEs: Nb, Ta, P, Zr, Ti); (4) zircon ε_Hf(t) values ranging from −10.5 to −0.1, corresponding to Hf crustal model ages (T_DMC) of 1.96–1.30 Ga. These features collectively indicate that the Tiancang granites originated predominantly from partial melting of Paleoproterozoic–Mesoproterozoic crustal sources with variable mantle contributions, followed by extensive fractional crystallization. Regional correlations demonstrate near-synchronous magmatic activity across the southern/northern Beishan and eastern Tianshan Orogenic belts. The widespread Permian granitoids, combined with post-collisional magmatic suites and rift-related stratigraphic sequences, provide compelling evidence for a continental rift setting in the southern Beishan during the Early Permian. This tectonic regime transition likely began with lithospheric delamination after the Late Carboniferous–Early Permian collisional orogeny, which triggered asthenospheric upwelling and crustal thinning. These processes ultimately led to the terminal closure of the Paleo-Asian Ocean’s southern branch, followed by intracontinental evolution. Full article

The North Caspian Basin, known for its oil and gas potential, was formed because of the evolution of the ancient Tethys Ocean and is also a result of the collision of the East European, Kazakhstania, and Siberian paleocontinents. At the beginning of the Mesozoic Era, it was a part of the northern continental margin of the Neo-Tethys, which formed Eurasia. In the Late Triassic and Early Jurassic, a major restructuring of the North Caspian sedimentary basin occurred, characterized by angular unconformity and the erosion of underlying sediments in the coastal zones of the basin. The sedimentary succession of the depression accumulating in the Mesozoic Era consisted of alternating siliciclastic and carbonate rocks. It began to form due to the destruction of the uplifts formed north and west of the East European craton and Urals, which resulted in coastal clastic material in the Triassic and Jurassic, but by the end of the Jurassic and Cretaceous, when all uplifts existing in the north of Tethys were leveled, it was mostly marine environments that contributed to the accumulation of siliciclastic and carbonate strata. The appearance of a large amount of sedimentary material towards the center of the depression, causing stress, as well as the deflection of the basement, contributed to fault tectonics and the resumption and manifestation of salt tectonics. As a result of the continuous diapirism of salt bodies during the Late Mesozoic, mini basins were formed, in which different sedimentogenesis was manifested. These processes contributed to the redistribution of hydrocarbons from the underlying pre-salt formations to the intermediate depth interval post-salt succession with Permian–Triassic and also near-surface Jurassic–Cretaceous formations. Full article

The water contents and geochemical evidence of nominally anhydrous minerals in peridotite xenoliths provide critical insights into lithospheric mantle features, offering a deep understanding of cratonic destruction and mantle evolution processes. Damaping, located in the central part of the intra-North China Craton, hosts abundant mantle peridotite xenoliths’ samples, providing new constraints on lithospheric mantle evolution. In this study, spinel lherzolite samples from Damaping Cenozoic basalts were analyzed for major and trace elements, water content, and oxygen isotope to investigate the factors controlling mantle water distribution and lithospheric mantle modification. The olivines of Damaping spinel lherzolite have a range of Mg# values from 89.73 to 91.01, indicating moderately refractory mantle characteristics. Clinopyroxenes display an LREE-depleted pattern, suggesting a consistency with 1–6% of batch partial melting and 1–5% fractional partial melting. The high (La/Yb)_N (0.20–0.73) and low Ti/Eu (3546.98–5919.48) ratios of Damaping clinopyroxenes reveal that the lithosphere mantle beneath the Damaping has undergone silicate metasomatism. The water contents of Damaping clinopyroxenes and orthopyroxenes range from 13.39 to 19.46 ppm and 4.60 to 7.82 ppm, respectively. The water contents of the olivines are below the detection limit (<2 ppm). The whole-rock water contents can be estimated based on the mineral modes and partition coefficients, with values ranging from 3.21 to 5.44 ppm. Partial melting indicators (Mg# in Ol and Yb_n in Cpx) correlate with the water content in clinopyroxenes and orthopyroxenes but show no correlation with the redox state (Fe³⁺/∑Fe ratios in spinel) or metasomatism ((La/Yb)_N in clinopyroxene). These results suggest that the degree of partial melting primarily controls the heterogeneous water distribution in Damaping spinel lherzolite, rather than the redox state or metasomatism. The δ¹⁸O values of clinopyroxenes from Damaping spinel lherzolites (5.27–5.59‰) fall within the range of mid-ocean ridge basalts (MORB), indicating a mantle source characterized by MORB-like isotopic signatures. The low whole-rock water contents are attributed to lithospheric reheating resulting from asthenospheric upwelling during the Late Mesozoic–Early Cenozoic. Therefore, the lithosphere is predominantly composed of ancient Proterozoic residues, with localized contributions of younger asthenospheric material near deep faults. Full article

The widespread occurrence of Mesozoic ocean island basalt (OIB)-like igneous rocks in the Southern Tibetan Himalayan Belt provides important constraints on the rifting of East Gondwana. This study undertook a petrological, geochronological, and geochemical investigation of mafic intrusive rocks in the Cuona area of the eastern Tethyan Himalayan Belt. The mafic intrusions have OIB-type geochemical signatures, including diabase porphyrite, gabbro, and diabase. Zircon U–Pb dating indicates that the diabase porphyrite formed at 135.0 ± 1.6 Ma. The diabase porphyrite and gabbro are enriched in high-field-strength elements (Nb and Ti) and large-ion lithophile elements (Sr and Pb) and experienced negligible lithospheric mantle or crustal contamination. The diabase is enriched in large-ion lithophile elements (LILEs, e.g., La and Ce) and depleted in high-field-strength elements (HFSEs, e.g., Ru, Zr and Ti). In general, the mafic intrusions exhibit significant light REE enrichment and heavy REE depletion and have no Eu anomalies. Whole-rock neodymium (ε_Nd(t) = 1.55) and zircon Hf (ε_Hf(t) = 0.60–3.73) isotopic compositions indicate derivation of the magma from enriched type I mantle. We propose that the diabase porphyrite and diabase formed in a continental margin rift setting, influenced by the Kerguelen mantle plume, and represent magmatism related to the breakup of East Gondwana. However, the gabbro formed in a relatively stable continental intraplate environment, likely derived from deep magmatic processes associated with the Kerguelen mantle plume. Our results provide new constraints on the early activity of the Kerguelen mantle plume and offer insights into the breakup and tectonic evolution of East Gondwana. Full article

The possible uplift of a plateau in eastern China during the Mesozoic was closely associated with variations in crustal thickness. High-Sr and low-Y granites, regarded as products of thickened lower crust melting, have been used to infer the evolution of the plateau, but their formation conditions and implications remain debated. We trained a crustal thickness estimation model by employing machine learning methods and integrating multiple geochemical features. The model achieved an R² of 0.87 on the test set and was consistent with previous crustal thickness constraints in external validations in the Gangdese orogen and Andes arc. Based on the model and igneous rock data from the North China Craton and its surrounding orogenic belts, we reveal that crustal thickening during the Middle Jurassic facilitated the uplift of a proto-plateau centered on the Jiaodong–Liaoning region. By the Late Jurassic, the plateau matured, with a crustal thickness of 55 ± 3 km, a paleo-elevation of ~4.2 km, and likely coverage spanning the entirety of the studied areas in eastern China. During the Early Cretaceous, extensional tectonics led to the plateau’s collapse, ultimately evolving into plains. This study provides new evidence for the existence and evolution of the Mesozoic plateau in eastern China. Full article