Search Results (891)

The effects of trace Ce on the microstructure and texture of non-oriented silicon steel during recrystallization and grain growth were examined using X-ray diffraction and electron backscatter diffraction. Additionally, this study focused on investigating the mechanisms by which trace Ce influences the evolution of the {114} <481> and γ-fiber textures. During the recrystallization process, as the recrystallization fraction of annealed sheets increased, the intensity of α-fiber texture decreased, while the intensities of α*-fiber and γ-fiber textures increased. The {111} <112> grains preferentially nucleated in the deformed γ-grains and their grain-boundary regions and tended to form a colony structure with a large amount of nucleation. In addition, the {100} <012> and {114} <481> grains mainly nucleated near the deformed α-grains, which were evenly distributed but found in relatively small quantities. The hindering effect of trace Ce on dislocation motion in cold-rolled sheets results in a 2–7% lower recrystallization ratio for the annealed sheets, compared to conventional annealed sheets. Trace Ce suppresses the nucleation and growth of γ-grains while creating opportunities for α*-grain nucleation. During grain growth, trace Ce reduces γ-grain-boundary migration rate in annealed sheets, providing growth space for {114} <418> grains. Consequently, the content of the corresponding {114} <481> texture increased by 6.4%, while the γ-fiber texture content decreased by 3.6%. Full article

The surface topography of the rolls used in skin-pass cold rolling determines the surface finish of rolled sheets. In this sense, work rolls can be intentionally textured to produce certain topographical features on the final sheet surface. The maskless electrochemical texturing method (MECT) is a potential candidate for industrial-scale application due to its reduced texturing cost and time when compared to traditional texturing methods. However, there are few studies in the literature that address the MECT method applied to the topography control of cold rolling work rolls. The present work aims to analyze the viability of surface texturing via MECT of work rolls used in skin-pass cold rolling. In this study, we first investigated how texturing occurs for tool steel using flat textured samples to facilitate the understanding of the dissolution mechanisms involved. In this case, a specially designed texturing chamber was built to texture flat samples extracted from an actual work roll. The results indicated that the anodic dissolution involved in tool steel texturing occurs preferentially in the metallic matrix around the primary carbides. Then, we textured a work roll used in pilot-scale rolling tests, which required the development of a special prototype to texture cylindrical surfaces. After texturing, the texture transfer from the work roll to the sheets was investigated. Rolling tests showed that the work roll surface textured with a dimple pattern generated a pillar-shaped texture pattern on the sheet surface, possibly due to a reverse extrusion mechanism. Full article

This study explores the feasibility of generating a globular microstructure in situ during the thixotropic 3D printing of the EN AW-4043 alloy, starting from a conventional cold-rolled wire. Thermodynamic simulations using Thermo-Calc software were first conducted to identify the semi-solid processing window of the alloy, based on the evolution of liquid and solid fractions as a function of temperature. Guided by these results, thermal treatments were performed on cold-rolled wires to promote the formation of a globular microstructure. A laboratory-scale printing head prototype was then designed and built to test continuous heating and deposition conditions representative of a thixotropic additive manufacturing process. The results showed that a globular microstructure could be achieved in the cold-rolled EN AW-4043 wires by heating them at 590 °C for 5 min in a static muffle furnace. A similar effect was observed when continuously heating the wire while it flowed through the heated printing head. Preliminary deposition tests confirmed the viability of this approach and demonstrated that thixotropic 3D printing of EN AW-4043 alloy is achievable without the need for pre-globular feedstock. Full article

This study investigates the influence of plastic deformation and temperature on the formation of mechanically induced martensite and the associated changes in hardness in AISI 304 austenitic stainless steel. Cold rolling was performed at three temperatures (20 °C, 0 °C, and −196 °C) and various degrees of deformation (10–70%). Microstructural changes, including the formation of ε and α′ martensite, were characterized using X-ray diffraction (XRD) and electron backscatter diffraction (EBSD). The results confirm that martensitic transformation proceeds via the γ → ε → α′ sequence, with transformation rates and martensite fractions increasing at lower temperatures and higher strains. The stacking fault energy of 25.9 mJ/m² favors this transformation pathway. Transformation rates of α′ martensite fractions significantly increased at lower temperatures and higher strains, 91.8% α′ martensite was observed at just 30% deformation at −196 °C. Hardness measurements revealed a strong correlation with martensite content: strain hardening dominated at lower deformations, while martensite formation became the primary hardening mechanism at higher deformations, especially at cryogenic temperatures. The highest hardness (551 HV) was observed in samples deformed to 70% at −196 °C. The findings provide insights into optimizing the mechanical properties of AISI 304 stainless steel through controlled deformation and temperature conditions. Full article

This study investigates the fabrication and residual stress behavior of a 0.5 wt.% graphene-reinforced AA2195 aluminum matrix composite, developed for advanced aerospace structural applications. The composite was synthesized via squeeze casting, followed by a multi-pass hot rolling process and subsequent T8 heat treatment. The evolution of residual stress was systematically examined after each rolling pass and during thermal treatments. The successful incorporation of graphene into the matrix was confirmed through Energy-Dispersive Spectroscopy (EDS) analysis. Residual stress measurements after each pass revealed a progressive increase in compressive stress, reaching a maximum of −68 MPa after the fourth hot rolling pass. Prior to the fifth pass, a solution treatment at 530 °C was performed to dissolve coarse precipitates and relieve internal stresses. Cold rolling during the fifth pass reduced the compressive residual stress to −40 MPa, and subsequent artificial aging at 180 °C for 48 h further decreased it to −23 MPa due to recovery and stress relaxation mechanisms. Compared to the unreinforced AA2195 alloy in the T8 condition, which exhibited a tensile residual stress of +29 MPa, the graphene-reinforced composite in the same condition retained a compressive residual stress of −23 MPa. This represents a net improvement of 52 MPa, highlighting the composite’s superior capability to retain compressive residual stress. The presence of graphene significantly influenced the stress distribution by introducing thermal expansion mismatch and acting as a barrier to dislocation motion. Overall, the composite demonstrated enhanced residual stress characteristics, making it a promising candidate for lightweight, fatigue-resistant aerospace components. Full article

Thermomechanical processing has a significant impact on the porosity and mechanical properties of AISI 316L stainless steel produced by laser powder bed fusion (L-PBF). This work evaluated the effect of three heat treatment conditions: as-built (HT0), annealed at 650 °C for 3 h with air cooling (HT1), and annealed at 1050 °C for 1 h followed by water quenching (HT2), combined with cold and hot rolling at different strain levels. The most pronounced improvement was observed after 20% hot rolling followed by water quenching (HR + WQ), which reduced porosity to 0.05% and yielded the most spherical pores, with a circularity factor ($f_{circle}$) of 0.90 and an aspect ratio (AsR) of 1.57. At elevated temperatures, the matrix becomes more pliable, which promotes pore closure and helps reduce stress concentrations. On the other hand, applying heat treatment without causing deformation resulted in the pores growing and increasing porosity in the build direction. The fractography supported these findings, showing a transition from brittle to more ductile fracture surfaces. Heat treatment combined with plastic deformation effectively reduced internal defects and improved both structural integrity and strength. Full article

Cu-Ni-Si is a prominent example of a high-end lead frame copper alloy. The enhancement of strength without compromising electrical conductivity has emerged as a prominent research focus. The evolution of the precipitates exerts a significant influence on the strength and electrical conductivity of Cu-Ni-Si-Co-Mg alloys. In this paper, the effects of aging treatment and Mg addition on the properties and precipitates of cold-rolled Cu-Ni-Si-Co alloys were studied. The precipitate was (Ni, Co)₂Si and was in a strip shape. During aging, precipitation and coarsening of the (Ni, Co)₂Si precipitates were observed. In the early stage of aging, a significant number of fine (Ni, Co)₂Si precipitates were formed. These fine precipitates could not only have a better effect of precipitation strengthening, but also impeded the dislocation movement, thus increasing the dislocation density and improving the dislocation strengthening effect. However, the coarsening of the precipitates became dominant with increasing aging times. Therefore, the strengthening effect was weakened. The addition of 0.12% Mg promoted finer and more diffuse precipitates, which not only improving the tensile strength by 100–200 MPa, but also exhibiting a smaller effect on the electrical conductivity. However, further increases in Mg contents resulted in a significant decrease in electrical conductivity, with little change in the tensile strength. The optimum amount of added Mg was 0.12%, and the aging parameters were 300 °C and 20 min. Full article

This study investigates the mechanical behavior and deformation mechanisms of Fe-30Mn-0.05C (30Mn0.05C) and Fe-34Mn-0.7C (34Mn0.7C) steels at room temperature (RT) and liquid nitrogen temperature (LNT). The 30Mn0.05C sample exhibited a significant enhancement in both strength and ductility at LNT, achieving a total elongation of 85%. In contrast, the 34Mn0.7C sample demonstrated superior ductility (90%) at RT, with a marginal reduction in plasticity but a remarkable increase in strength (>1100 MPa) at LNT. Compared to the 30Mn0.05C, the 34Mn0.7C, characterized by higher carbon content, displayed more pronounced dynamic strain aging (DSA) effects. Additionally, a greater density of deformation twins was activated at LNT, revealing a strong correlation between deformation twinning and DSA effects. This interplay accounts for the simultaneous strength improvement and ductility reduction observed in the 34Mn0.7C at LNT. Furthermore, the 34Mn0.7C sample exhibited a significantly refined grain structure after rolling, contributing to a substantial strength increase (approaching 1500 MPa) at the expense of ductility. This trade-off can be attributed to the pre-introduction of a higher density of dislocations and deformation twins during rolling, which facilitated strengthening but limited further plastic deformation. Full article

Aluminum and its alloy magnetron sputtering targets, owing to their superior electrical/thermal conductivity and robust substrate adhesion, serve as critical materials in advanced electronics and information technologies. It is known that the microstructure of the target, including grain uniformity and crystallographic texture, directly affects the sputtering performance and the quality of the deposited thin film. Despite extensive research efforts, the review paper focused on the microstructure of aluminum target materials is still absent. In that context, the recent progress on the Al alloy target is reviewed, focusing on grain refinement and texture control strategies. The roles of alloying elements, such as Si, Cu, and rare-earth Sc and Nd, are described first. The two conventional manufacturing techniques of fabricating Al targets, including melting and powder metallurgy, are introduced. Then, studies on grain refinement by thermomechanical processing routes (hot/cold rolling, annealing and forging) are summarized. Lastly, texture engineering through deformation and heat treatment protocols (unidirectional/multidirectional rolling, deformation thickness, and composite deformation modes) is reviewed. By establishing the relationship between thermomechanical processing and microstructure, this review provides insights for designing high-performance aluminum targets tailored to next-generation advanced thin-film applications. Full article

In this work, we report the identification of a novel quaternary intermetallic phase (Al₂₁GdCrTi) formed during the solidification of a novel Al-Gd-Cr-Ti alloy, which has not been previously documented in the literature to the best of our knowledge. The study also provides a detailed analysis of microstructure evolution, texture behavior, and the mechanical strengthening effect of rolling processes, along with neutron absorption performance. XRD analysis reveals that the intensity of (022), (113) planes of the as-hot-cold-rolled sample is higher than that of the as-cast due to the change in the direction of some grains in these planes during rolling. The results indicate that the studied alloys scatter neutrons about 100 times less than a nearly pure aluminum alloy. The hardness of the as-cast alloy increased from 36 to 53 HV after cold rolling and to 50 HV after hot rolling-cold rolling. Hot-cold-rolled alloy has a yield strength of 160 MPa and an ultimate tensile strength of 181 MPa, while maintaining an elongation of 11.3%. The studied alloys, containing 4.2 wt.% of the alloying elements 3.8Gd, 0.2Cr, and 0.2Ti (Al-3.8Gd-0.2Cr-0.2Ti), exhibited a yield strength 28 MPa higher than those containing 21 wt.% of the alloying elements 5Cu, 6Gd, and 8Bi (Al-5Cu-6Gd-8Bi). The studied alloys form the basis for the development of high-technology Al-Gd alloys for neutron shielding. Full article

Background/Objectives: The nutritional importance of grain-based foods (GBFs) and whole grains (WGs) is underscored by their central position in dietary guidance worldwide. Many jurisdictions recommend consumers increase WG intake because they are associated with multiple health benefits, with evidence quality rated as moderate to high. High intakes of ultra-processed foods (UPFs), as defined by NOVA that classifies food by level of processing, are associated with numerous negative health outcomes, with evidence less convincing than for WGs. Yet, some dietary guidance recommends consumers to avoid UPFs. This creates two divergent guidelines since NOVA designates most commonly eaten grain-based foods (GBFs) as UPFs. These contradictory guidelines fail to comply with recommended principles of dietary guidance and generate questions about underlying assumptions and definitions that classify WG staples and colas together. Methods: Definitions and assumptions for systems ostensibly categorizing foods by level of processing were evaluated for validity by various methods. Special attention was paid to the ability of different classifications to differentiate between WGs, RGs staples, and indulgent GBFs. Findings from meta-analyses associating high intakes of WGs with numerous health benefits were compared with those associating high intakes of UPFs. Menus and modeling studies were assessed for ability to meet recommendations for WGs and the grain food group with customary GBFs while avoiding UPFs. Advice to “avoid UPFs” was tested against principles for effective dietary guidance. Results: Definitions and categorizations of foods by levels of processing vary markedly. Assumptions for NOVA and other systems are questionable. While meta-analyses consistently show high intakes of UPFs are associated with adverse health outcomes, high intake of WG foods, nearly all designated as UPFs, are associated with better health outcomes, although evidence quality for the latter is rated stronger. These findings add to the body of evidence suggesting flawed assumptions behind categorizing WG staples in terms of level of processing. Conclusions: NOVA deems 90% of WGs as UPFs. Adding statements to dietary guidance to “Avoid UPFs”, while asking consumers to increase WG intakes, confuses. Further, it jeopardizes efforts to increase intake of fiber and WG foods because it excludes top sources of fiber and WG-based breads, rolls, tortillas, or cold cereals in Western diets. NOVA advice to avoid UPFs challenges principles for usable dietary guidance and the construction of culturally appropriate, healthy dietary patterns containing WG staples from all levels of processing. Full article

This study signifies the development and characterization of a composite material with a metallic matrix of aluminum reinforced with a steel mesh, utilizing centrifugal casting technology. An evaluation was conducted to ascertain the influence of the formulation process and the presence of the insert on the mechanical behavior with regard to tensile strength. The aluminum matrix was obtained from commercial and scrap alloys, elaborated by advanced methods of degassing and chemical modification. Meanwhile, the steel mesh reinforcement was cleaned, copper plated, and preheated to optimize wetting and, consequently, adhesion. The structural characterization was performed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy analyses (EDX), which highlighted a well-defined interface and uniform copper distribution. The composite was produced by means of horizontal-axis centrifugal casting in a fiberglass mold, followed by cold rolling to obtain flat specimens. A total of eight tensile specimens were examined, with measured ultimate tensile strengths ranging from 78.5 to 119.8 (MPa). A thorough examination of the fractured specimens revealed a brittle fracture mechanism, devoid of substantial plastic deformation. The onset of failures was frequently observed at the interface between the aluminum matrix and the steel mesh. The use of SEM and EDX investigations led to the confirmation of the uniformity of the copper coating and the absence of significant porosity or interfacial defects. A bimodal distribution of tensile strength values was observed, a phenomenon that is likely attributable to variations in mesh positioning and local differences in solidification. A correlation was established between the experimental results and an analytical polynomial model, thereby confirming a reasonable fit. In sum, the present study provides a substantial foundation for the development of metal matrix composites with enhanced performance, specifically designed for challenging structural applications. This method also demonstrates potential for recycling aluminum scrap into high-performance composites with controlled microstructure and mechanical integrity. Full article

This study prepared epoxy–clay nanocomposites (ECNs) by incorporating organophilic clays modified with either non-redox cetyltrimethylammonium bromide (CTAB) or redox-active aniline pentamer (AP), then compared their anticorrosion performance on metal substrates in saline environments. The test solution contained 2 wt% alkaline copper quaternary (ACQ) wood preservatives. Cold-rolled steel (CRS) panels coated with the ECNs were evaluated via electrochemical impedance spectroscopy (EIS) in saline media both with and without ACQ. For CRS coated with unmodified epoxy, the Nyquist plot showed impedance dropping from 255 kΩ to 121 kΩ upon adding 2 wt% ACQ—indicating that Cu²⁺ ions accelerate iron oxidation. Introducing 1 wt% CTAB–clay into the epoxy increased impedance from 121 kΩ to 271 kΩ, while 1 wt% AP–clay raised it to 702 kΩ. This improvement arises because the organophilic clay platelets create a more tortuous path for Cu²⁺ and O₂ diffusion, as confirmed by ICP–MS measurements of Cu²⁺ after EIS and oxygen permeability tests (GPA), thereby slowing iron oxidation. Moreover, ECN coatings containing AP–clay outperformed those with CTAB–clay in corrosion resistance, suggesting that AP not only enhances platelet dispersion but also promotes formation of a dense, passive metal oxide layer at the coating–metal interface, as shown by TEM, GPA, and XRD analyses. Finally, accelerated salt-spray exposure following ASTM B-117 yielded corrosion behavior consistent with the EIS results. Full article

The Charpy impact toughness of single-phase austenitic Fe-32Mn-0.6C steel was systematically investigated across a wide temperature spectrum from 25 °C to −196 °C using Charpy V-notch impact tests. The material exhibited a remarkable temperature dependence of impact energy, decreasing dramatically from 120 J at ambient temperature (25 °C) to 13 J under cryogenic conditions (−196 °C). Notably, a steep transition in impact energy occurred within the critical temperature window of −100 °C to −150 °C. Microstructural analysis revealed that synergistic effects of high strain rates and low temperatures significantly restrict dislocation slip and multiplication mechanisms, while also suppressing deformation twinning activation. This restricted plasticity accommodation mechanism fundamentally differs from the deformation characteristics reported in conventional low-carbon high-manganese steels and other face-centered cubic (FCC) alloy systems. Full article

This study intends to understand the effect of annealing behavior on the microstructure and mechanical and magnetic properties of cold-rolled extra-low-carbon steel. Deformed steel samples are annealed at temperature ranges of 200–690 °C followed by air-cooling. As part of this study, Magnetic Hysteresis loop (MHL) and Barkhausen emission (MBE) measurements are carried out for non-destructive evaluation (NDE) of the mechanical properties that are altered during annealing, viz. recovery and recrystallization. At low annealing temperature ranges 200 < T < 550 °C, the recovery causes no substantial variations in microstructure, hardness value from 191–185 HV, and tensile strength 456–452 MPa, while magnetic coercivity decreases from 293–275 A/m for cold-rolled annealed steels. The microstructural changes due to recovery and recrystallization are examined using transmission electron microscopy and orientation imaging microscopy (OIM) through electron backscattered diffraction (EBSD). Recrystallization is found after annealing at T > 550 °C, confirmed by the lowering of the microstructural KAM value from 0.81° to 0.65° and a hardness drop from 190.02 to 98 HV for cold-rolled extra-low-carbon steel. Full article