Search Results (17)

The Carajás Mineral Province hosts one of the world’s most extensive sulfide-bearing copper belts. These deposits are typically covered by thick regolith, including gossans, laterites, colluviums, and soil, which can be used as important exploration indicators. In some cases, these covers can be mined alongside the parent hypogene ore. Therefore, accurate identification of copper-bearing minerals is essential for selecting the most appropriate metallurgical techniques. This study investigated the saprolite horizon overlying the Alvo 118 deposit, where the parent rocks are chloritites hosting copper-bearing hypogene sulfides, partially altered to an immature gossan. Saprolite formation was primarily controlled by the weathering of chlorite, mostly converted into kaolinite, with smectite and vermiculite serving as intermediates, forming a typical lower saprolite association. During weathering, iron released from chlorite and indirectly by vermiculite and smectite contributed to the formation of ferrihydrite, goethite, and hematite. Magnetite octahedrons, relics of the hypogene ore, pseudomorphic phases, are embedded in the clay mineral matrix. While FTIR analysis of kaolinite showed no evidence of copper retention, Mössbauer spectroscopy enabled the quantification of iron-bearing minerals, revealing a strong correlation between CuO contents and goethite and ferrihydrite. These results suggest that goethite and ferrihydrite may be the main copper carriers in the deposit, consistent with findings from similar deposits. Weak acid leaching is proposed as the most effective technique for copper extraction from this mineralization type. Full article

The connection between crustal anatexis and magmatism is key to understanding the mechanisms that drive the evolution of the continental crust. Isotope geology and lithochemistry are important tools for reconstructing links between these processes, as field evidence of their connection is often obliterated by deformation in high-grade terrains. Thus, this study proposes new insights into the connection between the Mesoarchean regional metamorphism, crustal anatexis, and plutonism in the northern sector of the Carajás Province (i.e., Carajás Domain), in the Amazonian Craton, around 2.89 to 2.83 Ga. The widespread crustal anatexis in the Carajás Domain involved the water-fluxed melting of banded orthogneisses of the Xingu Complex and Xicrim-Cateté Orthogranulite (crystallization age at ca. 3.06–2.93 Ga), producing metatexites and diatexites with stromatic, net, schollen, and schlieren morphologies and coeval syntectonic leucosomes with composition similar to tonalites, trondhjemites, and granites. These leucosomes yielded crystallization ages of 2853 ± 5 Ma (MSWD: 0.61), 2862 ± 13 Ma (MSWD: 0.1), and 2867 ± 7 Ma (MSWD: 1.3). Their lithochemical data are similar to those of several diachronous Mesoarchean granitoids of the Carajás Domain in terms of major, minor, and trace elements and magmatic affinity. In addition, binary log–log vector diagrams (e.g., La vs. Yb; Rb vs. Yb), Sr/Y vs. Y, and Eu/Eu* vs. Yb plots indicate that plagioclase fractionation preceded melt extraction, establishing evolving source-to-sink trends between leucosomes and granites. These results show that the interplay between high-grade metamorphism, crustal anatexis, and magmatism may have shaped the evolution of the Mesoarchean continental crust in the Carajás Province, developing a petrotectonic assemblage associated with collisional orogens. The Mesoarchean geodynamic setting played a critical role in the development of coeval ca. 2.89 Ga magmatic–hydrothermal copper deposits in the Carajás Province, as well as Neoarchean world-class iron oxide–copper–gold deposits linked to post-orogenic extensional rebound. Full article

The Brazilian Amazon presents several artisanal and industrial Cu mines that generate significant amounts of waste. The objective of this study was to evaluate the risks to the environment and human health based on the bioavailable and bioaccessible concentrations of potentially toxic elements (PTEs; Ba, Co, Cr, Cu, Mo, Ni, Pb, and Zn) in artisanal and industrial Cu mining areas in the Carajás Mineral Province (CMP), eastern Amazon. For this purpose, samples (0–20 cm depth) were collected from natural forest soils (considered as a reference), as well as areas where artisanal mining wastes (artisanal overburden–AO and artisanal rock waste–AR) and industrial mining tailings (IT) were deposited. Total PTE concentrations were obtained via acid digestion, bioavailable concentrations were obtained via sequential extraction, and oral bioaccessible concentrations were obtained via the simple bioaccessibility extraction test. Environmental indices were obtained from PTE concentrations. The results indicated contamination by elements such as Mo, Cr, Ni, and Cu, mainly in AR, which had the highest contamination levels. Sequential extraction revealed that most PTEs are in residual form, suggesting low environmental risk from the bioavailable fraction. The bioaccessible concentrations of Cr and Ni were associated with health risks for children in AR. The results of this study will be important for protecting the environment and public health in artisanal mining areas in the region. Full article

An enrichment in nickel (Ni) or platinum group elements (PGE) is seldom observed in ores of the iron oxide–copper–gold (IOCG) type. This phenomenon is, however, known from a few deposits and prospects in the Carajás Mineral Province, Brazil. The Ni-PGE enrichment is explained, in part, by the spatial association of the IOCG-type ores with altered mafic-ultramafic lithologies, as well as by reworking and remobilization of pre-existing Ni and PGE during multiple mineralization and tectonothermal events across the Archean-Proterozoic. One such example of this mineralization is the Jatobá deposit in the southern copper belt of the Carajás Domain. This is the first detailed study of the Ni and PGE mineralization at Jatobá, with implications for understanding ore genesis. Petrographic and compositional study of sulfides shows that pyrite is the main Ni carrier, followed by pyrrhotite and exsolved pentlandite. Measurable concentrations of palladium (Pd) and platinum (Pt), albeit never more than a few ppm, are noted in pyrite. More importantly, however, the trace mineral signature of the Jatobá deposit features several platinum group minerals (PGM), including merenskyite, naldrettite, sudburyite, kotulskite, sperrylite, and borovskite. These PGM occur as sub-10 µm-sized grains that are largely restricted to fractures and grain boundaries in pyrite. All Pd minerals reported contain mobile elements such as Te, Bi, and Sb and are associated with rare earth- and U-minerals. This conspicuous mineralogy, differences in sulfide chemistry between the magnetite-hosted ore and stringer mineralization without magnetite, and microstructural control point to a genetic model for the sulfide mineralization at Jatobá and its relative enrichment in Ni and PGE. Observations support two alternative scenarios for ore genesis. In the first, an initial precipitation of disseminated or semi-massive Ni-PGE-bearing sulfides took place within the mafic rock pile, possibly in a VHMS-like setting. Later partial dissolution and remobilization of this pre-existing mineralization by mineralizing fluids of IOCG-type, possibly during the retrograde stage of a syn-deformational metamorphic event, led to their re-concentration within magnetite along structural conduits. The superposition of IOCG-style mineralization onto a pre-existing assemblage resulted in the observed replacement and overprinting in which PGE combined with components of the IOCG fluids like Sb, Bi, and Te. An alternative model involves leaching, by the IOCG-type fluids, of Ni and PGE from komatiites within the sequence or from ultramafic rocks in the basement. The discovery of PGM in Jatobá emphasizes the potential for additional discoveries of Ni-PGE-enriched ores elsewhere in the Carajás Domain and in analogous settings elsewhere. Full article

Knowledge about regions where lightning occurs is important both for understanding storm development and direction. This can assist in very short-term weather forecasts and in developing lightning warning systems, aiming to minimize exposure of people and equipment in the open sky. A survey on the occurrence of lightning in different types of land use and coverage and different elevation strata in the region of the Itacaiúnas River watershed (IRW), located in the Carajás Mineral Province, in the Eastern Amazon, from 2012 to 2021 was conducted. The results showed significant differences in the occurrence of lightning in mining areas and deforested areas. When comparing the large proportion of deforested areas with the mining area, the results suggested that in IRW mining areas, the lightning incidence is expressively higher. The assessment of electrical activity at different elevations in the region suggested that the slope of the terrain and its thermodynamic effects on the formation of storms have more influence than altitude on lightning activity. The results showed the importance of adopting initiatives aimed at protecting both the local population and mining workers, as well as equipment exposed to the open sky in this region. Full article

In the Carajás Mineral Province, gossan formation and lateritization have produced numerous supergene orebodies at the expense of IOCG deposits and host rocks. The Alvo 118 deposit comprises massive and disseminated hypogene copper sulfides associated with gossan and mineralized saprolites. The hypogene reserves are 170 Mt, with 1% Cu and 0.3 ppm Au, while the supergenes are 55 Mt, comprised of 30% gossan and 70% saprolite, with 0.92% Cu and 0.03 ppm Au. The gossan includes goethite, malachite, cuprite, and libethenite zones. The saprolite comprises kaolinite, vermiculite, smectite, and relics of chlorite. In the hypogene mineralization, Ag, Te, Pb, Se, Bi, Au, In, Y, Sn, and U are mainly hosted by chalcopyrite and petzite, altaite, galena, uraninite, stannite, and cassiterite. In the gossan, Ag, Te, Pb, Se, and Bi are hosted by Cu minerals, while Au, In, Y, Sn, and U are associated with iron oxyhydroxides, in addition to Zn, As, Be, Ga, Ga, Mo, Ni, and Sc. As supporting information, δ⁶⁵Cu values indicate that the gossan is immature and, at least partly, not affected by leaching. In the saprolite, Ga, Sc, Sn, V, Mn, Co, and Cr are associated with the iron oxyhydroxides, partially derived from the host rock weathering. The δ⁵⁶Fe values indicate that hypogene low contribution of the hypogene mineralization to the saprolite iron content. The association of Al₂O₃, Hf, Zr, Th, TiO₂, Ce, La, Ba, and Sr represents the geochemical signature of the host rocks, with dominant contributions from chlorites, while In, Y, Te, Pb, Bi, and Se are the main pathfinders of Cu mineralization. Full article

Since the start-up of the Sossego copper concentrator, located in the Carajás Mineral Province in the southeast of Para State, Brazil, the low-grade ore (~0.34% Cu) has been stockpiled, as defined in the long-term mine plan, to be reclaimed at the end of the mine life. Given this imminent need to process around 40 Mt of this low-grade ore, questions have been raised related to the extent of oxidation that might have occurred in this stockpiled ore. In this context, a study was designed to characterize the stockpiled ore and assess the effect of the ore oxidation on its flotation response. A sampling campaign of the stockpiled ore was carried out to analyze the main variables that could influence the level of oxidation, and, consequently, copper recovery, such as stockpiling time, depth, and particle size. The results showed that there are two main factors negatively impacting the copper recovery of the low-grade stockpiled ore: the surface oxidation and the level of liberation of the copper mineral. Depth and period of stockpiling were not found to influence the level of oxidation, nor the flotation response. An empirical model was proposed for the copper recovery in the rougher stage, which resulted in a predicted value of 90.7%, which was lower than that for the fresh (and higher copper content) ore fed to the plant (93%). Full article

Brownfield areas are important targets of exploration; however, the extensive drilling present in these areas has not fully exploited their prospective potential. The appropriate use of drill hole cores in these areas can play an important role in deep exploration. We present a case study of iron oxide-copper-gold (IOCG) Furnas Southeast deposit, located in the Carajás Mineral Province, Brazil. This deposit has disseminated chalcopyrite, bornite and gold mineralization associated with a silicic (Si), potassic (K), calcic (Na), sodic-calcic (Na-Ca) hydrothermal alteration, and intense iron metasomatism with massive magnetite (Fe) alteration. Petrophysical hand-held equipment measurements were carried out on drill core samples with the purpose of studying the potential roles that magnetic susceptibility properties can play in high-grade mineralization. The results indicate that the geological complexity of the IOCG deposit is readily reflected in the extensive variation of the measurements. The statistical analysis shows how the detailed characterization of this physical property carried out for this mineral association could effectively define and describe ore, and the magnetic susceptibility footprints of hydrothermal alteration zones. Furthermore, we were able to perform a magnetic susceptibility 3D modeling of diamagnetic, paramagnetic, and ferrimagnetic responses strictly correlated with known orebody. Thus, petrophysical analyses can form a quantitative geological criterion for ore delineation. Full article

Currently, most mining companies conduct chemical analyses by X-ray fluorescence performed in the laboratory to evaluate the quality of Fe ore, where the focus is mainly on the Fe content and the presence of impurities. However, this type of analysis requires the investment of time and money, and the results are often available only after the ore has already been sent by the processing plant. Reflectance spectroscopy is an alternative method that can significantly contribute to this type of application as it consists of a nondestructive analysis technique that does not require sample preparation, in addition to making the analyses available in more active ways. Among the challenges of working with reflectance spectroscopy is the large volume of data produced. However, one way to optimize this type of approach is to use machine learning techniques. Thus, the main objective of this study was the calibration and evaluation of models to analyze the quality of Fe from Sinter Feed collected from deposits in the Carajás Mineral Province, Brazil. To achieve this goal, machine learning models were tested using spectral libraries and X-ray fluorescence data from Sinter Feed samples. The most efficient models for estimating Fe were the Adaboost and support vector machine and our results highlight the possibility of application in the samples without the need for preparation and optimization of the analysis time, providing results in a timely manner to contribute to decision-making in the production chain. Full article

The most frequent crystallographic preferred orientations developed during the progressive phase transformation of magnetite-hematite-goethite are described and analyzed in two natural samples of banded iron formations from Carajás Mineral Province. Microtextures of martitized grains containing the three phases and the microplaty matrix were analyzed in a scanning electron microscope equipped with a detector for electron backscatter diffraction. For identifying the correlation between magnetite, hematite and goethite lattice and topotaxity during transformation, multiple orientation relationships between the three phases were tested and verified using three-dimensional misorientation analysis. The results show that basal planes of goethite coincide with basal planes of hematite, which coincide with octahedral planes of magnetite. This indicates that transformation between the three minerals happens topotactically, and the oxygen lattice framework is preserved in all members of the reaction as a form of crystallographic memory. As a result of progressive and cyclical changes in oxidation/reduction conditions, an assemblage of high-order orientation relationships is observed and assigned to a complex process of transformation twinning in-between phase transformation of magnetite, hematite and goethite. In the N4WS iron ore deposit, iron oxides/hydroxides from martitized grains work as susceptible markers of environmental changes still in solid state during the diagenetic process. Full article

This review paper aims to integrate geological, tectonic and metallogenetic data, including new data, and propose a regional model for the gold (and base metal) mineralization in the south Amazonian Craton to support the mineral exploration concerning magmatic–hydrothermal deposits. The Proterozoic evolution of the Amazonian Craton comprises the accretion of terrains to the Archean Carajás Mineral Province. In the Tapajós and Juruena mineral provinces, located at the south part of the Amazonian craton, a long-lived ocean–continent subduction event produced ca. 2.0 to 1.77 Ga continental magmatic arcs. Extensive lava flows, volcaniclastic, sedimentary, and plutonic rocks were originated during at least four major orogenic magmatic events (ca. 2.1, 1.9, 1.88, and 1.80 Ga) and two post- to anorogenic events (ca. 1.87 and 1.77 Ga). Gold mineralization occurs in: (i) alluvial/colluvial occurrences, (ii) orogenic carbonate–sulfide-rich quartz veins in shear zones, (iii) stockworks, veins, and dissemination in granites, (iv) contact of basic dikes, (v) well-preserved high-, intermediate- and low-sulfidation epithermal mineralization, and (vi) porphyry-like and intrusion-related gold systems associated with late- to post-orogenic epizonal granites. The estimated historical gold production, mainly in secondary deposits, is over 27 Moz at the Tapajós and 6 Moz at the Juruena provinces. A total resource of over 5 Moz Au is currently defined in several small to large primary gold deposits. Andesite to rhyolite, volcaniclastic, and clastic sedimentary rocks (1.96–1.88 Ga) host epithermal (high-, intermediate-, and low-sulfidation) Au–(Ag–Pb–Zn) mineralization, whereas Au–Cu and Cu–Mo–Au mineralization is hosted in sub-volcanic tonalitic to granitic plutons. Advanced argillic alteration (alunite, pyrophyllite, enargite) associated with high-sulfidation mineralization occurs in ring volcanoes around nested volcanic calderas. This zone grades outward to propylitic or chlorite alteration, often covered by silica caps with vuggy silica. Lava flows and volcaniclastic rocks within faults or associated with volcanic edifices and rhyolitic domes host low- and intermediate-sulfidation mineralization. Low-sulfidation alteration zones typically have adularia and illite or sericite. Chalcopyrite, sphalerite, galena, pyrite, digenite, and manganiferous calcite are related to intermediate-sulfidation gold mineralization. Late- to post-orogenic evolved oxidized I-type granitoids host alkalic-type epithermal and porphyry-like gold mineralization. Porphyry-style hydrothermal alteration is analogous to those of modern systems, with inner sodic and potassic (potassic feldspar ± biotite or biotite) alterations grading to propylitic, muscovite-sericite, chlorite–sericite, and chlorite alterations. Potassic alteration zones are the locus of Cu–Mo mineralization, and gold-rich zones occur in muscovite/sericite–quartz–pyrite alteration. The Paleoproterozoic epithermal and porphyry-like mineralization in these large provinces defines a new frontier for the exploration of world-class gold deposits in the worldwide Proterozoic arc-related magmatic terrains. Full article

This study aims to handle an integrated evaluation of soil and stream sediment geochemical data to evaluate source apportionment and to establish geochemical threshold variations for Fe, Al, and 20 selected Potentially Toxic Elements (PTE) in the Parauapebas River Basin (PB), Eastern Amazon. The data set used in this study is from the Itacaiúnas Geochemical Mapping and Background Project (ItacGMBP), which collected 364 surface soil (0–10 cm) samples and 189 stream sediments samples in the entire PB. The <0.177 mm fraction of these samples were analyzed for 51 elements by ICP-MS and ICP-AES, following an aqua regia digestion. The geochemical maps of many elements revealed substantial differences between the north (NPB) and the south (SPB) of PB, mainly due to the geological setting. The new statistically derived threshold values of the NPB and SPB regions were compared to the threshold of the whole PB, reported in previous studies, and to quality guidelines proposed by Brazilian environmental agencies. The natural variation of geochemical background in soils and stream sediments of PB should be considered prior to defining new guideline values. At the regional scale, the local anomalies are mostly influenced by the predominant lithology rather than any anthropogenic impact. Full article

The Vale do Curaçá and Riacho do Pontal copper districts are located within the northern part of the Archaean São Francisco Craton and represent two pulses of mineralization. The copper districts have been identified as Iron-Oxide-Copper-Gold (IOCG) classes of deposits. An older metallogenic event associated with the Caraíba copper deposit, which is located in the Vale do Curaçá district, is related to Palaeoproterozoic (ca. 2 to 2.2 Ga) hydrothermal processes. A younger Neoproterozoic (ca. 750 to 570 Ma) episode of volcanism and associated plutonism is represented by the Riacho do Pontal mineral district. Seismic tomography data from across east-central Brazil show that the multiage Carajás province and Vale do Curaçá and Riacho do Pontal copper districts sit along either side of a prominent NW-trending upper lithospheric high-velocity zone. The edges of the high-velocity zone point to long-lived subparallel transcrustal structures that have been the focus of multiple reactivations and copper mineralization events. Regional gravity and magnetic maps show that the Vale do Curaçá copper district extends over an area greater than 110 km by 22 km. The magnetic and gravity values show significant variations correlated with this area. The district includes high gravity values associated with the Caraíba copper mine (>−35 mGal), which has a greater density (3.13 g/cm³) than the nonmineralized host rock density (2.98 g/cm³). The gravity anomaly signature over the Riacho do Pontal copper district is characterized by a 40-km long NW–SE trending Bouguer gravity low. The Ria4 occurrences of the Riacho do Pontal copper district are situated in these regional low-gravity domains. Data from regional airborne magnetic and ground gravity surveys were inverted to obtain a 3D magnetic susceptibility and density model, respectively, for the known districts. The results show that the Caraíba deposit is characterized by a both dense and magnetic source showing structural control by thrust shear zones. The 2D and 3D geological models show two main NNW prospective trends. Trends I and II have a sigmoidal shear shape and are positioned in the contact zone between domains with high magnetic susceptibility (SI > 0.005) and density > 0 g/cm³). Trend I is 40 km × 10 km in size and hosts the Caraíba, Surubim, and Vermelho copper mines and other minor deposits. The results obtained from the 3D magnetic inversion model for the region of the Riacho do Pontal district show weak magnetic anomaly highs extending along a NW–SE magnetic gradient trend. The gradient is related to mapped shear zones that overprint older and deeper NE–SW features of the São Francisco cratonic root. The area includes high gravity values associated with the Caraíba copper deposit, which has a greater density (3.13 g/cm³) than the nonmineralized host rock density (2.4 g/cm³). Full article

The southeastern Amazon region has been intensively occupied by human settlements over the past three decades. To evaluate the effects of human settlements on land-cover and land-use (LCLU) changes over time in the study site, we evaluated multitemporal Landsat images from the years 1984, 1994, 2004, 2013 and Sentinel to the year 2017. Then, we defined the LCLU classes, and a detailed “from-to” change detection approach based on a geographic object-based image analysis (GEOBIA) was employed to determine the trajectories of the LCLU changes. Three land-cover (forest, montane savanna and water bodies) and three land-use types (pasturelands, mining and urban areas) were mapped. The overall accuracies and kappa values of the classification were higher than 0.91 for each of the classified images. Throughout the change detection period, ~47% (19,320 km²) of the forest was preserved mainly within protected areas, while almost 42% (17,398 km²) of the area was converted from forests to pasturelands. An intrinsic connection between the increase in mining activity and the expansion of urban areas also exists. The direct impacts of mining activities were more significant throughout the montane savanna areas. We concluded that the GEOBIA approach adopted in this study combines the advantages of quality human interpretation and the capacities of quantitative computing. Full article

This work presents an investigation to determine ground deformation based on an integration of DInSAR Time-Series (DTS) and Persistent Scatterer Interferometry (PSI) techniques aiming at detecting high rates of linear and non-linear ground movement. The combined techniques were applied in an open pit iron mine located in Carajás Mineral Province (Brazilian Amazon region), using a set of 33 TerraSAR-X-1 images acquired from March 2012 to April 2013 when, due to a different deformation behavior during the dry and wet seasons in the Amazon region, a non-linear deformation was detected. The DTS analysis was performed on a stack of multi-look unwrapped interferograms using an extension of the SVD (Singular Value Decomposition), where a set of additional weighted constraints on the acceleration of the displacement was incorporated to control the smoothness of the time-series solutions, whose objective was to correct the atmospheric phase artifacts. The height errors and the deformation history provided by the DTS technique were used as previous information to perform the PSI analysis. This procedure improved the capability of the PSI technique to detect non-linear movement as well as to increase the numbers of point density of the final results. The results of the combined techniques are presented and compared with total station/prisms and ground-based radar (GBR) measurements. Full article