Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (71)

Search Parameters:
Keywords = AQM

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
20 pages, 472 KiB  
Review
Immersive, Secure, and Collaborative Air Quality Monitoring
by José Marinho and Nuno Cid Martins
Computers 2025, 14(6), 231; https://doi.org/10.3390/computers14060231 - 12 Jun 2025
Viewed by 633
Abstract
Air pollution poses a serious threat to both public health and the environment, contributing to millions of premature deaths worldwide each year. The integration of augmented reality (AR), blockchain, and the Internet of Things (IoT) technologies can provide a transformative approach to collaborative [...] Read more.
Air pollution poses a serious threat to both public health and the environment, contributing to millions of premature deaths worldwide each year. The integration of augmented reality (AR), blockchain, and the Internet of Things (IoT) technologies can provide a transformative approach to collaborative air quality monitoring (AQM), enabling real-time, transparent, and intuitive access to environmental data for community awareness, behavioural change, informed decision-making, and proactive responses to pollution challenges. This article presents a unified vision of the key elements and technologies to consider when designing such AQM systems, allowing dynamic and user-friendly immersive air quality data visualization interfaces, secure and trusted data storage, fine-grained data collection through crowdsourcing, and active community learning and participation. It serves as a conceptual basis for any design and implementation of such systems. Full article
Show Figures

Figure 1

10 pages, 593 KiB  
Brief Report
Locating Low-Cost Air Quality Monitoring Devices in Low-Resource Regions Is Not Enough to Acquire Robust Air Quality Data Usable for Policy Decisions
by Adaeze Emekwuru, Alexander Wokoma, Otonye Ojuka, Isaac Amadi, Miebaka Moslen, Chidinma Amuzie and Nwabueze Emekwuru
Environments 2025, 12(6), 189; https://doi.org/10.3390/environments12060189 - 4 Jun 2025
Viewed by 492
Abstract
Air quality monitoring (AQM) is key to maintaining healthy air in cities. This is crucial in low- and middle-income countries due to increasing evidence of poor air quality but lack of monitors to consistently collect evaluate air quality data and effect policy changes, [...] Read more.
Air quality monitoring (AQM) is key to maintaining healthy air in cities. This is crucial in low- and middle-income countries due to increasing evidence of poor air quality but lack of monitors to consistently collect evaluate air quality data and effect policy changes, mainly because of the costs of monitoring devices. In participating in a challenge for the development of low-cost AQM devices in low-resource regions, an Arduino-based device with sensors for particulate matter size, temperature, and humidity data acquisition was developed for deployment in Port Harcourt, a city in Nigeria’s Niger Delta region, exposed to poor air quality partly due to gas and oil production activities. During the project, challenges to AQM were encountered, including inadequate awareness of air quality issues, lack of necessary AQM device components, unavailability of trained manpower and partnerships, and lack of funding. However, lack of a means of calibrating the device was a major hindrance, as no reference AQM instrument was available, rendering the data acquired largely qualitative, educational, and useless for regulatory purposes. There is an urgent need for AQM in such cities. However, a robust AQM strategy must be designed and used to address these constraints, especially whilst using low-cost devices, for significant progress in acquiring robust air quality data in such low-resource regions to be made. Full article
Show Figures

Figure 1

18 pages, 6278 KiB  
Article
Application of Deep Learning Techniques for Air Quality Prediction: A Case Study in Macau
by Thomas M. T. Lei, Jianxiu Cai, Wan-Hee Cheng, Tonni Agustiono Kurniawan, Altaf Hossain Molla, Mohd Shahrul Mohd Nadzir, Steven Soon-Kai Kong and L.-W. Antony Chen
Processes 2025, 13(5), 1507; https://doi.org/10.3390/pr13051507 - 14 May 2025
Viewed by 1151
Abstract
To better inform the public about ambient air quality and associated health risks and prevent cardiovascular and chronic respiratory diseases in Macau, the local government authorities apply the Air Quality Index (AQI) for air quality management within its jurisdiction. The application of AQI [...] Read more.
To better inform the public about ambient air quality and associated health risks and prevent cardiovascular and chronic respiratory diseases in Macau, the local government authorities apply the Air Quality Index (AQI) for air quality management within its jurisdiction. The application of AQI requires first determining the sub-indices for several pollutants, including respirable suspended particulates (PM10), fine suspended particulates (PM2.5), nitrogen dioxide (NO2), ozone (O3), sulfur dioxide (SO2), and carbon monoxide (CO). Accurate prediction of AQI is crucial in providing early warnings to the public before pollution episodes occur. To improve AQI prediction accuracy, deep learning methods such as artificial neural networks (ANNs) and long short-term memory (LSTM) models were applied to forecast the six pollutants commonly found in the AQI. The data for this study was accessed from the Macau High-Density Residential Air Quality Monitoring Station (AQMS), which is located in an area with high traffic and high population density near a 24 h land border-crossing facility connecting Zhuhai and Macau. The novelty of this work lies in its potential to enhance operational AQI forecasting for Macau. The ANN and LSTM models were run five times, with average pollutant forecasts obtained for each model. Results demonstrated that both models accurately predicted pollutant concentrations of the upcoming 24 h, with PM10 and CO showing the highest predictive accuracy, reflected in high Pearson Correlation Coefficient (PCC) between 0.84 and 0.87 and Kendall’s Tau Coefficient (KTC) between 0.66 and 0.70 values and low Mean Bias (MB) between 0.06 and 0.10, Mean Fractional Bias (MFB) between 0.09 and 0.11, Root Mean Square Error (RMSE) between 0.14 and 0.21, and Mean Absolute Error (MAE) between 0.11 and 0.17. Overall, the LSTM model consistently delivered the highest PCC (0.87) and KTC (0.70) values and the lowest MB (0.06), MFB (0.09), RMSE (0.14), and MAE (0.11) across all six pollutants, with the lowest SD (0.01), indicating greater precision and reliability. As a result, the study concludes that the LSTM model outperforms the ANN model in forecasting air pollutants in Macau, offering a more accurate and consistent prediction tool for local air quality management. Full article
Show Figures

Figure 1

39 pages, 7353 KiB  
Review
Innovations in Air Quality Monitoring: Sensors, IoT and Future Research
by Saim Shahid, David J. Brown, Philip Wright, Ahmad M. Khasawneh, Bryn Taylor and Omprakash Kaiwartya
Sensors 2025, 25(7), 2070; https://doi.org/10.3390/s25072070 - 26 Mar 2025
Cited by 1 | Viewed by 6197
Abstract
Recently, Air Quality Monitoring (AQM) has gained significant R&D attention from academia and industries, leading to advanced sensor-enabled IoT solutions. Literature highlights the use of nanomaterials in sensor design, emphasising miniaturisation, enhanced calibration, and low voltage, room-temperature operation. Significant efforts are aimed at [...] Read more.
Recently, Air Quality Monitoring (AQM) has gained significant R&D attention from academia and industries, leading to advanced sensor-enabled IoT solutions. Literature highlights the use of nanomaterials in sensor design, emphasising miniaturisation, enhanced calibration, and low voltage, room-temperature operation. Significant efforts are aimed at improving sensitivity, selectivity, and stability, while addressing challenges like high power consumption and drift. The integration of sensors with IoT technology is driving the development of accurate, scalable, and real-time AQM systems. This paper provides technical insights into recent AQM advancements, focusing on air pollutants, sensor technologies, IoT frameworks, performance evaluation, and future research directions. It presents a detailed analysis of air quality composition and potential air pollutants. Relevant sensors are examined in terms of design, materials and methodologies for pollutant monitoring. A critical review of IoT frameworks for AQM is conducted, highlighting their strengths and weaknesses. As a technical contribution, an experimental performance evaluation of three commercially available AQM systems in the UK is discussed, with a comparative and critical analysis of the results. Lastly, future research directions are also explored with a focus on AQM sensor design and IoT framework development. Full article
(This article belongs to the Section Environmental Sensing)
Show Figures

Figure 1

46 pages, 8707 KiB  
Article
Design and Enhancement of a Fog-Enabled Air Quality Monitoring and Prediction System: An Optimized Lightweight Deep Learning Model for a Smart Fog Environmental Gateway
by Divya Bharathi Pazhanivel, Anantha Narayanan Velu and Bagavathi Sivakumar Palaniappan
Sensors 2024, 24(15), 5069; https://doi.org/10.3390/s24155069 - 5 Aug 2024
Cited by 5 | Viewed by 2616
Abstract
Effective air quality monitoring and forecasting are essential for safeguarding public health, protecting the environment, and promoting sustainable development in smart cities. Conventional systems are cloud-based, incur high costs, lack accurate Deep Learning (DL)models for multi-step forecasting, and fail to optimize DL models [...] Read more.
Effective air quality monitoring and forecasting are essential for safeguarding public health, protecting the environment, and promoting sustainable development in smart cities. Conventional systems are cloud-based, incur high costs, lack accurate Deep Learning (DL)models for multi-step forecasting, and fail to optimize DL models for fog nodes. To address these challenges, this paper proposes a Fog-enabled Air Quality Monitoring and Prediction (FAQMP) system by integrating the Internet of Things (IoT), Fog Computing (FC), Low-Power Wide-Area Networks (LPWANs), and Deep Learning (DL) for improved accuracy and efficiency in monitoring and forecasting air quality levels. The three-layered FAQMP system includes a low-cost Air Quality Monitoring (AQM) node transmitting data via LoRa to the Fog Computing layer and then the cloud layer for complex processing. The Smart Fog Environmental Gateway (SFEG) in the FC layer introduces efficient Fog Intelligence by employing an optimized lightweight DL-based Sequence-to-Sequence (Seq2Seq) Gated Recurrent Unit (GRU) attention model, enabling real-time processing, accurate forecasting, and timely warnings of dangerous AQI levels while optimizing fog resource usage. Initially, the Seq2Seq GRU Attention model, validated for multi-step forecasting, outperformed the state-of-the-art DL methods with an average RMSE of 5.5576, MAE of 3.4975, MAPE of 19.1991%, R2 of 0.6926, and Theil’s U1 of 0.1325. This model is then made lightweight and optimized using post-training quantization (PTQ), specifically dynamic range quantization, which reduced the model size to less than a quarter of the original, improved execution time by 81.53% while maintaining forecast accuracy. This optimization enables efficient deployment on resource-constrained fog nodes like SFEG by balancing performance and computational efficiency, thereby enhancing the effectiveness of the FAQMP system through efficient Fog Intelligence. The FAQMP system, supported by the EnviroWeb application, provides real-time AQI updates, forecasts, and alerts, aiding the government in proactively addressing pollution concerns, maintaining air quality standards, and fostering a healthier and more sustainable environment. Full article
(This article belongs to the Special Issue Artificial Intelligence Methods for Smart Cities—2nd Edition)
Show Figures

Figure 1

37 pages, 18482 KiB  
Article
Active Queue Management in L4S with Asynchronous Advantage Actor-Critic: A FreeBSD Networking Stack Perspective
by Deol Satish, Jonathan Kua and Shiva Raj Pokhrel
Future Internet 2024, 16(8), 265; https://doi.org/10.3390/fi16080265 - 25 Jul 2024
Cited by 2 | Viewed by 2322
Abstract
Bufferbloat is one of the leading causes of high data transmission latency and jitter on the Internet, which severely impacts the performance of low-latency interactive applications such as online streaming, cloud-based gaming/applications, Internet of Things (IoT) applications, voice over IP (VoIP), real-time video [...] Read more.
Bufferbloat is one of the leading causes of high data transmission latency and jitter on the Internet, which severely impacts the performance of low-latency interactive applications such as online streaming, cloud-based gaming/applications, Internet of Things (IoT) applications, voice over IP (VoIP), real-time video conferencing, and so forth. There is currently a pressing need for developing Transmission Control Protocol (TCP) congestion control algorithms and bottleneck queue management schemes that can collaboratively control/reduce end-to-end latency, thus ensuring optimal quality of service (QoS) and quality of experience (QoE) for users. This paper introduces a novel solution by experimentally integrate the low latency, low loss, and scalable throughput (L4S) architecture (specified by the IETF in RFC 9330) in FreeBSD framework with the asynchronous advantage actor-critic (A3C) reinforcement learning algorithm. The first phase involves incorporating a modified dual-queue coupled active queue management (AQM) system for L4S into the FreeBSD networking stack, enhancing queue management and mitigating latency and packet loss. The second phase employs A3C to adjust and fine-tune the system performance dynamically. Finally, we evaluate the proposed solution’s effectiveness through comprehensive experiments, comparing it with traditional AQM-based systems. This paper contributes to the advancement of machine learning (ML) for transport protocol research in the field. The experimental implementation and results presented in this paper are made available through our GitHub repositories. Full article
Show Figures

Figure 1

38 pages, 14898 KiB  
Article
Audio Steganalysis Estimation with the Goertzel Algorithm
by Blanca E. Carvajal-Gámez, Miguel A. Castillo-Martínez, Luis A. Castañeda-Briones, Francisco J. Gallegos-Funes and Manuel A. Díaz-Casco
Appl. Sci. 2024, 14(14), 6000; https://doi.org/10.3390/app14146000 - 10 Jul 2024
Cited by 2 | Viewed by 1441
Abstract
Audio steganalysis has been little explored due to its complexity and randomness, which complicate the analysis. Audio files generate marks in the frequency domain; these marks are known as fingerprints and make the files unique. This allows us to differentiate between audio vectors. [...] Read more.
Audio steganalysis has been little explored due to its complexity and randomness, which complicate the analysis. Audio files generate marks in the frequency domain; these marks are known as fingerprints and make the files unique. This allows us to differentiate between audio vectors. In this work, the use of the Goertzel algorithm as a steganalyzer in the frequency domain is combined with the proposed sliding window adaptation to allow the analyzed audio vectors to be compared, enabling the differences between the vectors to be identified. We then apply linear prediction to the vectors to detect any modifications in the acoustic signatures. The implemented Goertzel algorithm is computationally less complex than other proposed stegoanalyzers based on convolutional neural networks or other types of classifiers of lower complexity, such as support vector machines (SVD). These methods previously required an extensive audio database to train the network, and thus detect possible stegoaudio through the matches they find. Unlike the proposed Goertzel algorithm, which works individually with the audio vector in question, it locates the difference in tone and generates an alert for the possible stegoaudio. In this work, we apply the classic Goertzel algorithm to detect frequencies that have possibly been modified by insertions or alterations of the audio vectors. The final vectors are plotted to visualize the alteration zones. The obtained results are evaluated qualitatively and quantitatively. To perform a double check of the fingerprint of the audio vectors, we obtain a linear prediction error to establish the percentage of statistical dependence between the processed audio signals. To validate the proposed method, we evaluate the audio quality metrics (AQMs) of the obtained result. Finally, we implement the stegoanalyzer oriented to AQMs to corroborate the obtained results. From the results obtained for the performance of the proposed stegoanalyzer, we demonstrate that we have a success rate of 100%. Full article
(This article belongs to the Special Issue Advances in Security, Trust and Privacy in Internet of Things)
Show Figures

Figure 1

15 pages, 3209 KiB  
Article
Robust H Static Output Feedback Control for TCP/AQM Routers Based on LMI Optimization
by Changhyun Kim
Electronics 2024, 13(11), 2165; https://doi.org/10.3390/electronics13112165 - 2 Jun 2024
Cited by 3 | Viewed by 677
Abstract
This paper proposes a new H static output feedback control method to address the congestion control problem in transmission control protocol networks using active queue management routers. Based on linear matrix inequality optimization, this method determines a static output feedback control law [...] Read more.
This paper proposes a new H static output feedback control method to address the congestion control problem in transmission control protocol networks using active queue management routers. Based on linear matrix inequality optimization, this method determines a static output feedback control law to minimize the H norm of the transfer function between the controlled queue length of the buffer and the exogenous disturbance affecting the available link bandwidth. A linear matrix inequality formulation is presented as a sufficient condition to guarantee the closed-loop system’s asymptotic stability while maintaining disturbance rejection within a specified level, regardless of round-trip time delays. The proposed robust static output feedback control eliminates the need to measure or estimate all system states, thus simplifying practical implementation. The effectiveness of the proposed design method is demonstrated by applying it in a practical process, as illustrated through a numerical example. Full article
(This article belongs to the Special Issue Transmission Control Protocols (TCPs) in Wireless and Wired Networks)
Show Figures

Figure 1

12 pages, 4232 KiB  
Article
Spatiotemporal Exposure Assessment of PM2.5 Concentration Using a Sensor-Based Air Monitoring System
by Jihun Shin, Jaemin Woo, Youngtae Choe, Gihong Min, Dongjun Kim, Daehwan Kim, Sanghoon Lee and Wonho Yang
Atmosphere 2024, 15(6), 664; https://doi.org/10.3390/atmos15060664 - 31 May 2024
Viewed by 1331
Abstract
Sensor-based air monitoring instruments (SAMIs) can provide high-resolution air quality data by offering a detailed mapping of areas that air quality monitoring stations (AQMSs) cannot reach. This enhances the precision of estimating PM2.5 concentration levels for areas that have not been directly [...] Read more.
Sensor-based air monitoring instruments (SAMIs) can provide high-resolution air quality data by offering a detailed mapping of areas that air quality monitoring stations (AQMSs) cannot reach. This enhances the precision of estimating PM2.5 concentration levels for areas that have not been directly measured, thereby enabling an accurate assessment of exposure. The study period was from 30 September to 2 October 2019 in the Guro-gu district, Seoul, Republic of Korea. Four models were applied to assess the suitability of the SAMIs and visualize the temporal and spatial distribution of PM2.5. Assuming that the PM2.5 concentrations measured at a SAMI located in the center of the Guro-gu district represent the true values, the PM2.5 concentrations estimated using QGIS spatial interpolation techniques were compared. The SAMIs were used at seven points (S1–S7) according to the distance. Models 3 and 4 accurately estimated the unmeasured points with higher coefficients of determination (R2) than the other models. As the distance from the AQMS increased from S1 to S7, the R2 between the observed and estimated values decreased from 0.89 to 0.29, respectively. The auxiliary installation of SAMIs could resolve regional concentration imbalances, allowing for the accurate estimation of pollutant concentrations and improved risk assessment for the population. Full article
(This article belongs to the Special Issue Air Pollution Exposure and Health Impact Assessment (2nd Edition))
Show Figures

Figure 1

20 pages, 963 KiB  
Article
Evaluation of Ergonomic Risks for Construction Workers Based on Multicriteria Decision Framework with the Integration of Spherical Fuzzy Set and Alternative Queuing Method
by Yu Tao, Hao Hu, Jie Xue, Zhipeng Zhang and Feng Xu
Sustainability 2024, 16(10), 3950; https://doi.org/10.3390/su16103950 - 8 May 2024
Cited by 4 | Viewed by 4064
Abstract
Ergonomic risks critically impact workers’ occupational health, safety, and productivity, and thereby the sustainability of a workforce. In the construction industry, the physical demands and dynamic environment exposes workers to various ergonomic hazards. While previous research has mainly focused on postural risks, there [...] Read more.
Ergonomic risks critically impact workers’ occupational health, safety, and productivity, and thereby the sustainability of a workforce. In the construction industry, the physical demands and dynamic environment exposes workers to various ergonomic hazards. While previous research has mainly focused on postural risks, there is a need to broaden the scope to include more relevant factors and assess them systematically. This study introduces a multi-criteria decision framework integrating the Spherical Fuzzy Sets (SFSs) and Alternative Queuing Method (AQM) to evaluate and prioritize ergonomic hazards. First, SFSs are employed to quantify the linguistic expressions of experts, addressing the inherent vagueness and uncertainty. Then, an entropy-based objective weighting method is adopted to determine the criteria weights. Finally, AQM is utilized to generate the risk priority. The proposed method has been implemented in a real-life construction project, where “overexertion due to unreasonable task organization”, “hypertension and heart diseases”, and “existing WMSD record” are identified as the top three ergonomic hazards. Then, a thorough discussion of intervention strategies regarding different risk categories is presented to facilitate ergonomic interventions. This proposed decision support system can promote effective ergonomic risk management, benefiting workers’ health and well-being and contributing to the sustainable workforce development of the construction industry. Full article
(This article belongs to the Section Health, Well-Being and Sustainability)
Show Figures

Figure 1

16 pages, 4392 KiB  
Article
The Impact of Vertical Eddy Diffusivity Changes in the CMAQ Model on PM2.5 Concentration Variations in Northeast Asia: Focusing on the Seoul Metropolitan Area
by Dong-Ju Kim, Tae-Hee Kim, Jin-Young Choi, Jae-bum Lee, Rhok-Ho Kim, Jung-Seok Son and Daegyun Lee
Atmosphere 2024, 15(3), 376; https://doi.org/10.3390/atmos15030376 - 19 Mar 2024
Cited by 2 | Viewed by 1800
Abstract
The vertical eddy diffusion process plays a crucial role in PM2.5 prediction, yet accurately predicting it remains challenging. In the three-dimensional atmospheric chemistry transport model (3-D AQM) CMAQ, a parameter, Kz, is utilized, and it is known that PM2.5 prediction tendencies [...] Read more.
The vertical eddy diffusion process plays a crucial role in PM2.5 prediction, yet accurately predicting it remains challenging. In the three-dimensional atmospheric chemistry transport model (3-D AQM) CMAQ, a parameter, Kz, is utilized, and it is known that PM2.5 prediction tendencies vary according to the floor value of this parameter (Kzmin). This study aims to examine prediction characteristics according to Kzmin values, targeting days exceeding the Korean air quality standards, and to derive appropriate Kzmin values for predicting PM2.5 concentrations in the DJFM Seoul Metropolitan Area (SMA). Kzmin values of 0.01, 0.5, 1.0, and 2.0, based on the model version and land cover, were applied as single values. Initially focusing on December 4th to 12th, 2020, the prediction characteristics were examined during periods of local and inflow influence. Results showed that in both periods, as Kzmin increased, surface concentrations over land decreased while those in the upper atmosphere increased, whereas over the sea, concentrations increased in both layers due to the influence of advection and diffusion without emissions. During the inflow period, the increase in vertically diffused pollutants led to increased inflow concentrations and affected contribution assessments. Long-term evaluations from December 2020 to March 2021 indicated that the prediction performance was superior when Kzmin was set to 0.01, but it was not significant for the upwind region (China). To improve trans-boundary effects, optimal values were applied differentially by region (0.01 for Korea, 1.0 for China, and 0.01 for other regions), resulting in significantly improved prediction performance with an R of 0.78, IOA of 0.88, and NMB of 0.7%. These findings highlight the significant influence of Kzmin values on winter season PM2.5 prediction tendencies in the SMA and underscore the need for considering differential application of optimal values by region when interpreting research and making policy decisions. Full article
(This article belongs to the Special Issue Novel Insights into Air Pollution over East Asia)
Show Figures

Figure 1

18 pages, 4512 KiB  
Article
Output Stream from the AQM Queue with BMAP Arrivals
by Andrzej Chydzinski
J. Sens. Actuator Netw. 2024, 13(1), 4; https://doi.org/10.3390/jsan13010004 - 2 Jan 2024
Viewed by 2032
Abstract
We analyse the output stream from a packet buffer governed by the policy that incoming packets are dropped with a probability related to the buffer occupancy. The results include formulas for the number of packets departing the buffer in a specific time, for [...] Read more.
We analyse the output stream from a packet buffer governed by the policy that incoming packets are dropped with a probability related to the buffer occupancy. The results include formulas for the number of packets departing the buffer in a specific time, for the time-dependent output rate and for the steady-state output rate. The latter is the key performance measure of the buffering mechanism, as it reflects its ability to process a specific number of packets in a time unit. To ensure broad applicability of the results in various networks and traffic types, a powerful and versatile model of the input stream is used, i.e., a BMAP. Numeric examples are provided, with several parameterisations of the BMAP, dropping probabilities and loads of the system. Full article
(This article belongs to the Section Communications and Networking)
Show Figures

Figure 1

14 pages, 2028 KiB  
Article
New Quinoid Bio-Inspired Materials Using Para-Azaquinodimethane Moiety
by Walaa Zwaihed, François Maurel, Marwan Kobeissi and Bruno Schmaltz
Molecules 2024, 29(1), 186; https://doi.org/10.3390/molecules29010186 - 28 Dec 2023
Cited by 5 | Viewed by 3132
Abstract
Quinoid single molecules are regarded as promising materials for electronic applications due to their tunable chemical structure-driven properties. A series of three single bio-inspired quinoid materials containing para-azaquinodimethane (p-AQM) moiety were designed, synthesized and characterized. AQM1, AQM2 and AQM3, prepared using aldehydes [...] Read more.
Quinoid single molecules are regarded as promising materials for electronic applications due to their tunable chemical structure-driven properties. A series of three single bio-inspired quinoid materials containing para-azaquinodimethane (p-AQM) moiety were designed, synthesized and characterized. AQM1, AQM2 and AQM3, prepared using aldehydes derived from almonds, corncobs and cinnamon, respectively, were studied as promising quinoid materials for optoelectronic applications. The significance of facile synthetic procedures is highlighted through a straightforward two-step synthesis, using Knoevenagel condensation. The synthesized molecules showed molar extinction coefficients of 22,000, 32,000 and 61,000 L mol−1 cm−1, respectively, for AQM1, AQM2 and AQM3. The HOMO-LUMO energy gaps were calculated experimentally, theoretically showing the same trends: AQM3 < AQM2 < AQM1. The role of the aryl substituent was studied and showed an impact on the electronic properties. DFT calculations show planar structures with quinoidal bond length alternation, in agreement with the experimental results. Finally, these bio-based materials showed high thermal stabilities between 290 °C and 340 °C and a glassy behavior after the first heating–cooling scan. These results highlight these bio-based single molecules as potential candidates for electronic or biomedical applications. Full article
(This article belongs to the Special Issue Novel Functional Materials: Design, Modeling and Characterization)
Show Figures

Graphical abstract

6 pages, 1214 KiB  
Proceeding Paper
Changes in Air Quality Health Index in a Coastal City of the Southeastern Aegean Sea between a Summer and Winter Period of 2022
by Ioannis Logothetis, Christina Antonopoulou, Georgios Zisopoulos, Adamantios Mitsotakis and Panagiotis Grammelis
Environ. Sci. Proc. 2023, 27(1), 13; https://doi.org/10.3390/ecas2023-15128 - 14 Oct 2023
Cited by 1 | Viewed by 634
Abstract
The increased concentration of pollutants is a challenge to the health of the population. This work aims to investigate the health risk that is related to the pollutants’ level in the center of Rhodes city. Rhodes Island is a desirable tourist destination with [...] Read more.
The increased concentration of pollutants is a challenge to the health of the population. This work aims to investigate the health risk that is related to the pollutants’ level in the center of Rhodes city. Rhodes Island is a desirable tourist destination with important economic activity over the southeastern Aegean Sea. This analysis covers the (summer) July–August months and the (winter) December month of 2022. Hourly recordings of the concentrations of PM2.5, NO2 and O3 from a mobile air quality monitoring system (AQMS) are analyzed. In order to investigate the effects of pollution level on people’s health, the Air Quality Health Index (AQHI) is calculated. Results show that summer shows an increased health danger compared to winter period, possibly due to increased traffic emissions, tourist density and the different meteorological conditions. In the summer period, the AQHI is classified between the middle and upper-medium health risk class. During the winter month, AQHI is mainly classified in the low-medium health risk class. The summer shows increased health risk despite the AQHI diurnal variability being lower when compared to December. Additionally, the diurnal differences between the two periods show an increased health risk in the summer period for the majority of the hours. Finally, this analysis shows that traffic activities possibly affect the health risk and also highlights that the authorities should adopt green policies to protect human health and the environment. Full article
(This article belongs to the Proceedings of The 6th International Electronic Conference on Atmospheric Sciences)
Show Figures

Figure 1

21 pages, 6720 KiB  
Article
Fuzzy-Based Active Queue Management Using Precise Fuzzy Modeling and Genetic Algorithm
by Ahmad Adel Abu-Shareha, Adeeb Alsaaidah, Ali Alshahrani and Basil Al-Kasasbeh
Symmetry 2023, 15(9), 1733; https://doi.org/10.3390/sym15091733 - 10 Sep 2023
Cited by 2 | Viewed by 1393
Abstract
Active Queue Management (AQM) methods significantly impact the network performance, as they manage the router queue and facilitate the traffic flow through the network. This paper presents a novel fuzzy-based AQM method developed with a computationally efficient precise fuzzy modeling optimized using the [...] Read more.
Active Queue Management (AQM) methods significantly impact the network performance, as they manage the router queue and facilitate the traffic flow through the network. This paper presents a novel fuzzy-based AQM method developed with a computationally efficient precise fuzzy modeling optimized using the Genetic Algorithm. The proposed method focuses on the concept of symmetry as a means to achieve a more balanced and equitable distribution of the resources and avoid bandwidth wasting resulting from unnecessary packet dropping. The proposed method calculates the dropping probability of each packet using a precise fuzzy model that was created and tuned in advance and based on the previous dropping probability value and the queue length. The tuning process is implemented as an optimization problem formulated for the b0, b1, and b2 variables of the precise rules with an objective function that maximizes the performance results in terms of loss, dropping, and delay. To prove the efficiency of the developed method, the simulation was not limited to the common Bernoulli process simulation; instead, the Markov-modulated Bernoulli process was used to mimic the burstiness nature of the traffic. The simulation is conducted on a machine operated with 64-bit Windows 10 with an Intel Core i7 2.0 GHz processor and 16 GB of RAM. The simulation used Java programming language in Apache NetBeans Integrated Development Environment (IDE) 11.2. The results showed that the proposed method outperformed the existing methods in terms of computational complexity, packet loss, dropping, and delay. As such, in low congested networks, the proposed method maintained no packet loss and dropped 22% of the packets with an average delay of 7.57, compared to the best method, LRED, which dropped 21% of the packets with a delay of 10.74, and FCRED, which dropped 21% of the packets with a delay of 16.54. In highly congested networks, the proposed method also maintained no packet loss and dropped 48% of the packets, with an average delay of 16.23, compared to the best method LRED, which dropped 47% of the packets with a delay of 28.04, and FCRED, which dropped 46% of the packets with a delay of 40.23. Full article
(This article belongs to the Topic Complex Systems and Network Science)
Show Figures

Figure 1

Back to TopTop