Search Results (925)

The induction quenching–tempering process typically enhances the surface strength and core toughness of alloy steels by utilizing the skin effect. However, the impact of parameters like quenching current and heating time on the microstructure and mechanical property of 34CrNiMo6 steel crankshafts remains unclear. In this work, the microstructure of 34CrNiMo6 steel after induction quenching exhibits three distinct zones: a martensite hardened layer; a transition zone of martensite and tempered sorbite; and a matrix of tempered sorbite. As the induction current (400, 500, and 600 mA) and heating time (3, 5, and 7 s) increase, the hardened layer thickness enhances (up to 3.21 mm). Under the 600 mA and 7 s, the hardened layer reaches peak hardness and residual stress values of 521.48 HV and −330.12 MPa, showing a decreasing trend from surface to core. After tempering at 330 °C for 2 h, the hardened layer mainly consists of tempered martensite, and the surface hardness and residual stress decrease to 417.94 HV and −12.33 MPa. The temperature gradient from quenching balances after tempering, with martensitic phase transformation and stress redistribution reducing hardness and residual stress. Furthermore, the induction quenching–tempering process enhances the toughness of 34CrNiMo6 steel when compared to the untreated specimen, boosting its tensile yield strength, elongation, and tensile strength by 15.3%, 14.9%, and 19.5%, respectively. This work deepens the understanding of induction quenching–tempering process and provides valuable insights for designing alloy steels with excellent mechanical properties. Full article

Cylindrical gears are used extensively due to their significant advantages including high efficiency, high load-bearing capacity, and long lifespan. However, the machining accuracy of cylindrical gears is significantly affected by motion errors and force-induced errors of machine tools. In this study, a motion error model of the machine tools was established based on multi-body system theory and homogeneous coordinate transformation method, quantifying the contributions and variation patterns of 12 key errors in the A and B-axes to workpiece geometric errors. Then, by using the stiffness analytical model and the spatial meshing theory, the influence of the force-induced elastic deformation of the shaft of rolling wheel and the springback of the workpiece tooth flank on the geometric error was revealed. Finally, taking the through rolling of a spur cylindrical gear with a module of 1.75 mm, a pressure angle of 20°, and 46 teeth as an example, the force-induced elastic deformation model of the shaft was verified by the rolling tests. Results show that for 40CrNiMo steel, the total profile deviation, total helix deviation, and single pitch deviation in the X-direction caused by rolling forces are 32.48 µm, 32.13 µm and 32.13 µm, respectively, with a maximum contact rebound is δ_c = 28.27. The relative error between theoretical and measured X-direction spindle deformation is 8.26%. This study provides theoretical foundation and experimental support for improving the precision of rolling process. Full article

The rapid dissipation of soft metal lubricants would deteriorate the self-lubricating properties of the coatings at elevated temperatures. In this study, the core-shell structured Mo@Ag@Ni particles were prepared via electroless plating to suppress the rapid dissipation of Ag and facilitate tribochemical reactions at high temperatures. The NiCrAlY-Mo@Ag@Ni composite coating was sprayed on the substrate of Inconel 718 alloy using atmospheric plasma spraying technology. The results of this study show that the structural design of Mo@Ag@Ni can enhance the bonding strength of the particle interface, resulting in a high microhardness of approximately 332.2 HV. During high-temperature friction tests, Mo@Ag@Ni can provide excellent tribological properties by promoting the silver molybdate formation on the worn surface. At 800 °C, the friction coefficient and wear rate are only about 0.32 and 1.58 × 10⁻⁵ mm³N⁻¹m⁻¹, respectively. Moreover, the Ni shell layer can inhibit the rapid diffusion of Ag and provide sufficient Ag₂O to maintain the continuity of Ag₂MoO₄ lubricating film, which endows the coating with a longer lubrication life. Over multi-thermal cycles, the friction coefficient and wear rate constantly maintain at about 0.3 and 2.5 × 10⁻⁵ mm³N⁻¹m⁻¹, respectively. Full article

To address the coarse and mixed grain phenomena in ultra-large martensitic stainless steel forgings, this study investigated the hot deformation behavior of 04Cr13Ni5Mo martensitic stainless steel under deformation conditions of 950–1200 °C and strain rates of 0.001–0.1 s⁻¹ using Gleeble-1500D thermomechanical simulation tests. Based on the experimental data, the flow stress curves of the steel were obtained, and a dynamic recrystallization (DRX) kinetic model was established. The model was then integrated into finite element software for simulation to verify its reliability, providing theoretical guidance for optimizing high-temperature forging processes. The results demonstrate that dynamic recrystallization in 04Cr13Ni5Mo steel occurs more readily at temperatures above 1050 °C and strain rates below 0.1 s⁻¹. Under the selected hot compression test condition (1100 °C/0.01 s⁻¹), the simulated grain size in the central deformation zone was 48.98 μm, closely matching the experimentally measured value of 48.18 μm. This agreement confirms the reliability of finite element-based prediction and control of grain size in martensitic stainless steel forgings. Full article

Despite being considering as having infinite fatigue life, failures of motor crankshafts forged from DIN 34CrNiMo6 steels have been reported in Brazilian power plants. As such, the present work aims to discuss the failure of a crankshaft within this context, with the purpose of verifying whether the stresses developed in critical locations of the component were in accordance with the steel’s fatigue limits, as well as if the material exhibits an adequate resistance to crack propagation. Taking into consideration a set of critical-plane stress-based multiaxial fatigue criteria, namely Findley, Matake, McDiarmid and Susmel and Lazzarin, the fatigue behaviour of the material is analysed and discussed. Furthermore, $da/dN$ versus $\mathsf{\Delta }K$ experiments were carried out with the purpose of determining the DIN 34CrNiMo6 steel’s crack growth threshold $\mathsf{\Delta }{K}_{th}$ and comparing it to the $\mathsf{\Delta }{K}_{th}$ of three other commercially available steels (DIN 42CrMo4, SAE 4140 and SAE 4340). The selected multiaxial fatigue criteria indicated that the stresses developed throughout the component were not sufficient to drive the crankshaft to failure, thus indicating safety. On the other hand, the DIN 34CrNiMo6 steel presented the lowest $\mathsf{\Delta }{K}_{th}$ ($6.6\mathrm{M}\mathrm{P}\mathrm{a}{\mathrm{m}}^{1/2}$) among all the considered steels ($10.86$, $12.38$ and $7.22\mathrm{M}\mathrm{P}\mathrm{a}{\mathrm{m}}^{1/2}$ for the DIN 42CrMo4, SAE 4140 and SAE 4340, respectively), therefore being susceptible to shorter fatigue lives in comparison to the other materials. Full article

The effects of intercritical quenching on the microstructure evolution and mechanical performance of Cr–Ni–Mo–V steel with a banded structure are studied. It is found that the intercritical quenching temperature has a significant effect on the morphology, distribution, and relative amount of ferrite/martensite, as well as the carbide precipitates upon tempering treatment. It is indicated that owing to the initial banded structure of Cr-Ni-Mo-V steel, the ferrite formation in intercritical heat treatment also exhibits a banded distribution. With the increase in quenching temperature, the proportion of ferrite in the Cr-Ni-Mo-V steel decreases from 30 ± 3.2 vol.% to 18 ± 2.8 vol.%. Tempering treatment has no significant effect on the distribution characteristics of ferrite, but it promotes the recovery of martensite laths and the precipitation of carbides. The mechanical properties of Cr-Ni-Mo-V steel are determined by both the changes in ferrite content induced by intercritical quenching and the evolution of carbide types during tempering. Delamination cracks are observed on the fracture surface, which is attributed to the lamellar microstructure, improving the plasticity of Cr-Ni-Mo-V steel through stress dispersion and a multi-stage energy absorption mechanism. Full article

An activation reaction sintering process was utilized to produce Cr-Cu-Mo-Ni porous alloys. Subsequently, weight loss measurements and electrochemical methods were applied to investigate the effect of Cr content ranging from 10wt% to 30wt% on the corrosive properties of Cr-Cu-Mo-Ni alloys in a 0.5 mol/L HF solution. Scanning electron microscopy (SEM) and X-ray diffraction analyses (XRD) were performed to assess the structural morphology and phase composition. As the results illustrated, Cr-Cu-Mo-Ni porous alloys possess good corrosion resistance, which is significantly higher than that of dense Ni and Cu alloys. The anti-corrosion performance of porous alloys is not proportional to the Cr content when the Cr concentration is gradually increased. When the chromium content is 20%, it exhibits the best corrosion resistance. Electrochemical measurements yielded similar results to weight loss measurements. With an increasing Cr content, double capacitive loops in electrochemical impedance spectroscopy (EIS) tests for Cr-Cu-Mo-Ni porous alloys first increased and then decreased, indicating that the corrosion process can be regulated by an electrochemical reaction. Meanwhile, after analysis, the results show that the corrosion products on the material surface adhere to the inner surface of the pores, thus improving the corrosion resistance. Full article

Eye shadows are cosmetic products widely used to enhance appearance. However, the use of raw materials contaminated with heavy metals poses potential health hazards. This study characterized 12 commercial eye shadow samples and quantified concentrations of Al, Ba, B, Cu, Cr, Fe, Mn, Ni, Pb, V, and Zn using inductively coupled plasma mass spectrometry (ICP-MS). Additional characterization using UV-vis, ATR-FTIR, and SEM-EDS techniques provided insights into the composition and potential sources of contamination. Multivariate analysis revealed differences in metal concentrations across brands. Health risk assessments, including margin of safety (MoS), hazard quotient (HQ), hazard index (HI), lifetime cancer risk (LCR), and lifetime cancer risk based on the long-term relevant daily systemic exposure dose (LCR′), indicated that one product may pose significant health risks. Specifically, sample M4 showed an HI of 2.67 × 10¹, exceeding acceptable limits. These findings highlight the need for stricter regulation and continuous monitoring of heavy metals in cosmetics to safeguard consumer health. Full article

Ship repair is hazardous, often presenting unsuitable working areas and risks due to the ship’s configuration. Welding tasks are particularly dangerous due to the high temperatures generated, high enough to melt the metal in structural elements, bulkheads, linings, and tanks. This study investigates the consequences of temperature distribution during the welding of naval plates and proposes some accident prevention measures. Industry working conditions were reproduced, including the materials, procedures, and tools used, as well as the certified personnel employed. DH 36-grade naval steel, with a composition of C max. 0.18%, Mn 0.90–1.60%, P 0.035%, S 0.04%, Si 0.10–0.50%, Ni max 0.4%, Cr max 0.25%, Mo 0.08%, Cu max 0.35%, Cb (Nb) 0.05%, and V 0.1%, was welded via FCAW-G (Gas-Shielded Flux-Cored Arc Welding), selected for this study because it is one of the most widely practiced in the naval industry. The main sensor used in the experiments was an FLIR model E50 thermographic camera, and thermal waxes were employed. The results for each thickness case are presented in both graphical and tabular form to provide accurate and actionable guidelines, prioritizing safety. After studying the butt jointing of naval plates of various thicknesses (8, 10, and 15 mm), safe distances to maintain were proposed to avoid risks in the most unfavorable cases: 350 mm from the welding seam to avoid burn injuries to unprotected areas of the body and 250 mm from the welding seam to avoid producing flammable gases. These numbers are less accurate but easier to remember, which prevents errors in the face of hazards throughout a long working day. Full article

The fracture toughness of nuclear reactor pressure vessel (RPV) steel is an important basis for the structural integrity evaluation of equipment. SA508 Gr.4N (Cr–Ni–Mo) low-alloy steel has attracted people’s attention because of its excellent strength and toughness, and it is considered as a candidate material for the next generation of RPV. The fracture toughness of SA508 Gr.4N alloy steel was analyzed from the perspective of macroscopic mechanical properties and microstructure, and compared with that of the SA508 Gr.3 (Mn–Ni–Mo) steel used in commercial PWR nuclear power plants. SA508 Gr.4N steel showed better toughness reserve than SA508 Gr.3 steel in terms of fracture toughness parameters such as the reference nil-ductility transition temperature RT_NDT, brittleness transition characteristic temperature T_41J, upper shelf energy and master curve reference temperature T₀. The reasons for the excellent fracture toughness of SA508 Gr.4N steel were analyzed from the aspects of microstructure, precipitation and grain boundary structure. Full article

In this study, we present a comprehensive theoretical analysis of modifications in the physical and chemical properties of MoSe₂ upon the introduction of substitutional transition metal impurities, specifically, Ti, V, Cr, Fe, Co, Ni, Cu, W, Pd, and Pt. Wet systematically calculated the adsorption enthalpies for various representative analytes, including O₂, H₂, CO, CO₂, H₂O, NO₂, formaldehyde, and ethanol, and further evaluated their free energies across a range of temperatures. By employing the formula for probabilities, we accounted for the competition among molecules for active adsorption sites during simultaneous adsorption events. Our findings underscore the importance of integrating temperature effects and competitive adsorption dynamics to predict the performance of highly selective sensors accurately. Additionally, we investigated the influence of temperature and analyte concentration on sensor performance by analyzing the saturation of active sites for specific scenarios using Langmuir sorption theory. Building on our calculated adsorption energies, we screened the catalytic potential of doped MoSe₂ for CO₂-to-methanol conversion reactions. This paper also examines the correlations between the electronic structure of active sites and their associated sensing and catalytic capabilities, offering insights that can inform the design of advanced materials for sensors and catalytic applications. Full article

The complex system of high-entropy materials makes it challenging to reveal the specific function of each site for oxygen evolution reaction (OER). Here, with nickel foam (NF) as the substrate, FeCoNiCrMo/NF is designed to be prepared by metal–organic frameworks (MOF) as a precursor under an argon atmosphere. XRD analysis confirms that it retains a partial MOF crystal structure (characteristic peak at 2θ = 11.8°) with amorphous carbon (peaks at 22° and 48°). SEM-EDS mapping and XPS demonstrate uniform distribution of Fe, Co, Ni, Cr, and Mo with a molar ratio of 27:24:30:11:9. Electrochemical test results show that FeCoNiCrMo/NF has excellent OER characteristics compared with other reference prepared samples. FeCoNiCrMo/NF has an overpotential of 285 mV at 100 mA cm⁻² and performs continuously for 100 h without significant decline. The OER mechanism of FeCoNiCrMo/NF further reveal that Co and Ni are true active sites, and the dissolution of Cr and Mo promote the conversion of active sites into MOOH following the lattice oxygen mechanism (LOM). The precipitation–dissolution equilibrium of Fe also plays an important role in the OER process. The study of different reaction sites in complex systems points the way to designing efficient and robust catalysts. Full article

This article provides a comprehensive overview of recent studies concerning laser heat treatment (LHT) of structural and tool steels, with particular attention to the 21NiCrMo2 steel used for carburized gear wheels. Analysis includes the influence of critical laser processing conditions—including power output, motion speed, spot size, and focusing distance—on surface microhardness, hardening depth, and microstructure development. The findings indicate that the energy density is the dominant factor that affects the outcomes of LHT. Optimal results, in the form of a high surface microhardness and a sufficient depth of hardening, were achieved within the energy density range of 80–130 J/mm², allowing for martensitic transformation while avoiding defects such as melting or cracking. At densities below 50 J/mm², incomplete hardening occurred with minimal microhardness improvement. On the contrary, densities exceeding 150–180 J/mm² caused surface overheating and degradation. For carburized 21NiCrMo2 steel, the most effective parameters included 450–1050 W laser power, 1.7–2.5 mm/s scanning speed, and 2.0–2.3 mm beam diameter. The review confirms that process control through energy-based parameters allows for reliable prediction and optimization of LHT for industrial applications, particularly in components exposed to cyclic loads. Full article

A novel stainless steel with high Mn and Mo content (much higher than traditional stainless steel), designated CH241SS, was developed as a potential replacement for Cr-Mo-V alloy steel in the cold forging applications of precision industry. Through carbon reduction in an environmentally friendly manner and a two-stage heat treatment process, the hardness of as-cast CH241 was tailored from HRC 37 to HRC 29, thereby meeting the industrial specifications of cold-forged steel (≤HRC 30). X-ray diffraction analysis of the as-cast microstructure revealed the presence of a small amount of ferrite, martensite, austenite, and alloy carbides. After heat treatment, CH241 exhibited a dual-phase microstructure consisting of ferrite and martensite with dispersed Cr(Ni-Mo) alloy carbides. The CH241 alloy demonstrated excellent high-temperature stability. No noticeable softening occurred after 72 h for the second-stage heat treatment. Based on the mechanical and room-temperature tensile fatigue properties of CH241-F (forging material) and CH241-ST (soft-tough heat treatment), it was demonstrated that the CH241 stainless steel was superior to the traditional stainless steel 4xx in terms of strength and fatigue life. Therefore, CH241 stainless steel can be introduced into cold forging and can be used in precision fatigue application. The relevant data include composition design and heat treatment properties. This study is an important milestone in assisting the upgrading of the vehicle and aerospace industries. Full article

The microstructure and mechanical properties of welded joints of API 5L X-52 steel plates cladded with AISI 316L-Si austenitic stainless steel were evaluated. The gas metal arc welding process with pulsed arc (GMAW-P) and controlled arc oscillation were used to join the bimetallic plates. After the root welding pass, buttering with an ERNiCrMo-3 filler wire was performed and multi-pass welding followed using an ER70S-6 electrode. The results obtained by optical and scanning electron microscopy indicated that the shielding atmosphere, welding parameters, and electric arc oscillation enabled good arc stability and proper molten metal transfer from the filler wire to the sidewalls of the joint during welding. Vickers microhardness (HV) and tensile tests were performed for correlating microstructural and mechanical properties. The mixture of ERNiCrMo-3 and ER70S-6 filler materials presented fine interlocked grains with a honeycomb network shape of the Ni–Fe mixture with Ni-rich grain boundaries and a cellular-dendritic and equiaxed solidification. Variation of microhardness at the weld metal (WM) in the middle zone of the bimetallic welded joints (BWJ) is associated with the manipulation of the welding parameters, promoting precipitation of carbides in the austenitic matrix and formation of martensite during solidification of the weld pool and cooling of the WM. The BWJ exhibited a mechanical strength of 380 and 520 MPa for the yield stress and ultimate tensile strength, respectively. These values are close to those of the as-received API 5L X-52 steel. Full article