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13 pages, 500 KB  
Systematic Review
Listericidal Novel Processing Technological Approaches for the Safety of Milk and Dairy Products: A Systematic Review
by Diana Víquez-Barrantes, Jessie Usaga, Rosa María García-Gimeno and Guiomar Denisse Posada-Izquierdo
Encyclopedia 2025, 5(3), 143; https://doi.org/10.3390/encyclopedia5030143 - 9 Sep 2025
Viewed by 745
Abstract
Listeria monocytogenes is a major public health concern in milk and ready-to-eat dairy products. To meet consumer demand for fresher, minimally processed foods with high nutritional and sensory quality, several non-thermal technologies are being explored as alternatives to conventional heat treatments. This systematic [...] Read more.
Listeria monocytogenes is a major public health concern in milk and ready-to-eat dairy products. To meet consumer demand for fresher, minimally processed foods with high nutritional and sensory quality, several non-thermal technologies are being explored as alternatives to conventional heat treatments. This systematic review (2020–2025), following PRISMA guidelines, examines recent applications of selected non-thermal technologies to control Listeria in milk and dairy matrices. Peer-reviewed studies available in full-text, in English or Spanish, focusing on applications at laboratory or pilot plant scales, with milk or dairy produced onsite or purchased, containing Listeria sp., were included. Studies with applications to plant-based or non-dairy products or those not inoculated with Listeria, were excluded. Conference abstracts, corrections, editorials, letters, news, and scientific opinions were excluded as well. The databases searched were Web of Science, Scopus, and ProQuest, which were last consulted in April 2025. Given the naturality of the review, the risk of bias was assessed through independent screening by two of the researchers, focusing on clear objectives, analytical validity, statistical analysis, and methodology. The results are presented in tabulated format. Of the 157 records identified, 22 were included in this review. Seven of the records reported hurdle technologies, while fifteen reported single technology applications, with high-pressure processing being the most frequent. Limitations observed are primarily the use of unreported strains, a lack of information regarding the initial load of inoculum, and expected log reductions. The equipment used is mostly at the laboratory scale, except for HPP. Non-thermal technologies present a promising option for the control of Listeria in dairy products. The basic principles of GMP, HACCP, and cold-chain control in dairy processing are of special importance in safety assurance. This research was funded by Vicerrectoría de Investigación, Universidad de Costa Rica, grant number 735-C3-460. Full article
(This article belongs to the Section Chemistry)
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18 pages, 309 KB  
Review
Geographical Indication Labels for Food Products: A Literature Review
by Bella Crespo-Moncada, Guiomar Denisse Posada-Izquierdo, Jorge Velásquez-Rivera, John Molina-Villamar and Rosa María García-Gimeno
Encyclopedia 2025, 5(3), 115; https://doi.org/10.3390/encyclopedia5030115 - 5 Aug 2025
Viewed by 1431
Abstract
Geographical Indication labels are an increasingly popular alternative among producers and governments seeking to protect the products and producers of their countries. This trend has grown due to the opening of markets and consumers’ increasing desire to know the origin of the products [...] Read more.
Geographical Indication labels are an increasingly popular alternative among producers and governments seeking to protect the products and producers of their countries. This trend has grown due to the opening of markets and consumers’ increasing desire to know the origin of the products they purchase. A bibliographic review was conducted, including studies on the feasibility of applying quality labels, the associated challenges, and examples. This review identifies the processes involved in obtaining Designation of Origin and presents a positive perspective on their application. It was concluded that obtaining a differentiated quality label can improve production and quality of life, provided that it is the result of an evaluation of the area’s context and the main actors in production chains. Full article
(This article belongs to the Section Chemistry)
17 pages, 284 KB  
Entry
The Health Impact of Fast Fashion: Exploring Toxic Chemicals in Clothing and Textiles
by Vivian Christine Dourado Pinto and Meital Peleg Mizrachi
Encyclopedia 2025, 5(2), 84; https://doi.org/10.3390/encyclopedia5020084 - 18 Jun 2025
Viewed by 14122
Definition
The fashion industry is widely recognized for its environmental challenges, but the health impacts related to textile toxicity remain significantly underexplored. Beyond the well-known issues of pollution and resource depletion, modern clothing often harbors a hidden threat: hazardous chemicals embedded within fabrics. These [...] Read more.
The fashion industry is widely recognized for its environmental challenges, but the health impacts related to textile toxicity remain significantly underexplored. Beyond the well-known issues of pollution and resource depletion, modern clothing often harbors a hidden threat: hazardous chemicals embedded within fabrics. These include dyes containing heavy metals, antimicrobial agents that foster bacterial resistance, and synthetic fibers that release microplastics. Unlike environmental discussions, the dialogue around the direct and long-term health effects of these substances is still limited. This entry addresses critical yet often-overlooked concerns, such as how chemicals in textiles contribute to chronic skin conditions, hormonal disruptions, and even carcinogenic risks. It also examines the proliferation of bacteria in synthetic garments, leading to dermatological infections and rapid fabric degradation. Furthermore, the globalized nature of production masks the contamination risks transferred from producer to consumer countries. Through an interdisciplinary approach, this entry highlights the urgent need for integrating scientific innovation, stringent regulation, and consumer awareness to mitigate health hazards in fashion. It calls for the adoption of safer textile technologies, sustainable materials, and transparent production practices, paving the way for a fashion future that prioritizes human health as much as environmental sustainability. Full article
(This article belongs to the Section Chemistry)
12 pages, 466 KB  
Entry
Matrix Certified Reference Materials
by Tadeusz Gorewoda, Justyna Kostrzewa, Marta Wolska, Ewa Jamroz and Jacek Anyszkiewicz
Encyclopedia 2025, 5(2), 76; https://doi.org/10.3390/encyclopedia5020076 - 3 Jun 2025
Viewed by 1718
Definition
Matrix certified reference materials (mCRMs) are materials characterized by suitable homogeneity, stability, and traceability, with certified values, including uncertainties, and a specific matrix. mCRMs constitute a reference for instrumental analytical methods and ensure their metrological consistency. Matrix certified reference materials (mCRMs) are essential [...] Read more.
Matrix certified reference materials (mCRMs) are materials characterized by suitable homogeneity, stability, and traceability, with certified values, including uncertainties, and a specific matrix. mCRMs constitute a reference for instrumental analytical methods and ensure their metrological consistency. Matrix certified reference materials (mCRMs) are essential tools for ensuring the accuracy and traceability of analytical measurements, particularly for samples with complex matrices. These mCRMs are carefully manufactured materials that closely mimic the composition and properties of real samples, allowing laboratories to validate their analytical methods, calibrate analytical instruments, or check the classical methods. This article highlights the challenges associated with the production and characterization of these complex mCRMs, including obtaining homogeneous materials, establishing accurate target values, and ensuring stability for different types of materials, such as gases, liquids, and metal alloys. Additionally, the process of statistical evaluation through the use of advanced statistical methods is discussed, as is the systems approach associated with the implementation of the ISO 17034 standard, which specifies the requirements for manufacturers of reference materials. This paper also includes a summary of the current status in trends of normalization as well as mCRM production. Full article
(This article belongs to the Section Chemistry)
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15 pages, 308 KB  
Entry
Quantifying Methane Emission Rates Using Downwind Measurements
by Stuart N. Riddick
Encyclopedia 2025, 5(2), 57; https://doi.org/10.3390/encyclopedia5020057 - 30 Apr 2025
Viewed by 1118
Definition
This entry describes the methods used to quantify methane emissions from either point or area sources using downwind methods. The methods described could be used as a practical guide to quantify emissions of any trace gas type from either a point or area [...] Read more.
This entry describes the methods used to quantify methane emissions from either point or area sources using downwind methods. The methods described could be used as a practical guide to quantify emissions of any trace gas type from either a point or area emission source. Methane is a relatively strong greenhouse gas, its GWP is 25 times larger than CO2 over a 100-year period, and an increase in methane anthropogenic emissions has been correlated to a changing global climate. Emission estimates that are calculated and used for national inventories are usually derived from bottom-up approaches, however there is now an increasing pressure for these to be validated by direct measurement. Calculating emission rates from downwind measurements has proven to be a versatile and relatively simple approach for direct measurement. Downwind measurement method descriptions are presented here as a practicable guide to quantifying point and area source emissions. Emission quantification is a two-stage process where methane concentration and meteorological data must be measured downwind of a source and then converted to emissions using an atmospheric dispersion model. Only four technology types currently measure in the range typical of downwind methane concentrations: metal oxide sensors, non-dispersive infrared sensors, tunable diode laser absorption spectrometers and optical cavity instruments. The choice of methane measurement is typically determined by the size of the emission source, location and the budget of the project. Meteorological data are essential to quantifying emissions, especially regarding wind speed and direction. In most cases, simple atmospheric dispersion approaches can be used to quantify both area and point emissions using these downwind measurements. Emissions can be generated using limited data (only methane concentration, wind speed, wind direction, and locations are necessary), but quantification uncertainty can be reduced using more input data. Site selection and location of instrument deployment are essential because quantification approaches assume a flat fetch (no aerodynamic obstructions) and constant wind fields. When modeling assumptions are violated, quantification uncertainty can range between +250% and −100% of the actual emission rate. At present there, is no happy medium between modeling complexity and computational time, and this remains the biggest challenge for downwind emission quantification. Full article
(This article belongs to the Section Chemistry)
17 pages, 3401 KB  
Review
Fermentative Butanol Production—Perspectives and Scale-Up Challenges
by Seedhabadee Ganeshan and Mehmet Çağlar Tülbek
Encyclopedia 2025, 5(2), 50; https://doi.org/10.3390/encyclopedia5020050 - 9 Apr 2025
Viewed by 3711
Abstract
Sustainable solutions to the use of petrochemical products have been increasingly sought after in recent years. While alternatives such as biofuels have been extensively explored and commercialized, major challenges remain in using heterogeneous feedstocks and scaling-up processes. Among biofuels, higher alcohols have recently [...] Read more.
Sustainable solutions to the use of petrochemical products have been increasingly sought after in recent years. While alternatives such as biofuels have been extensively explored and commercialized, major challenges remain in using heterogeneous feedstocks and scaling-up processes. Among biofuels, higher alcohols have recently gained renewed interest, especially in the context of upcycling agri-food residues and other industrial organic wastes. One of the higher alcohols produced via fermentation is butanol, which was developed over a century ago. However, the commercial production of butanol is still not widespread, although diverse feedstocks are readily available. Hydrolysis of the feedstocks and scale-up challenges in the fermentation and purification of butanol are recurring bottlenecks. This review addresses the current state of fermentative butanol production and opportunities to address scale-up challenges, including purification. With the significant interest and promise of precision fermentation, this review also addresses some of the recent advances and potential for enhanced fermentative butanol production. Full article
(This article belongs to the Section Chemistry)
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16 pages, 986 KB  
Review
Influence of Starch on the Rheological, Textural, and Microstructural Properties of Processed and Analogue Cheeses
by FNU Akshit, Vaishali Poswal, Rakesh Kaushik, Gaurav Kr Deshwal and Thom Huppertz
Encyclopedia 2025, 5(2), 41; https://doi.org/10.3390/encyclopedia5020041 - 26 Mar 2025
Viewed by 2592
Abstract
Processed cheese (PC) is a widely consumed dairy product and has undergone significant evolution over time, leading to various formulations aimed at enhancing texture and functionality. This review addresses the role of starch addition on PC, focusing on starch interactions with milk proteins [...] Read more.
Processed cheese (PC) is a widely consumed dairy product and has undergone significant evolution over time, leading to various formulations aimed at enhancing texture and functionality. This review addresses the role of starch addition on PC, focusing on starch interactions with milk proteins and understanding its influence on the rheological properties, microstructure, and overall quality of PC. Our key findings indicate that starch serves as a cost-effective ingredient that can replace or supplement dairy components, improving texture and water-binding capacity while reducing formulation costs. Generally, starches containing a higher amylose content are associated with the increased hardness and decreased meltability of PC. The insights provided in this review underscore the importance of understanding starch–milk component interactions to optimize PC formulations, paving the way for future research and innovation. Full article
(This article belongs to the Section Chemistry)
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19 pages, 1160 KB  
Entry
Fundamentals of Water Radiolysis
by Jean-Paul Jay-Gerin
Encyclopedia 2025, 5(1), 38; https://doi.org/10.3390/encyclopedia5010038 - 7 Mar 2025
Cited by 9 | Viewed by 9057
Definition
Radiolysis of water and aqueous solutions refers to the decomposition of water and its solutions under exposure to ionizing radiation, such as γ-rays, X-rays, accelerated particles, or fast neutrons. This exposure leads to the formation of highly reactive species, including free radicals like [...] Read more.
Radiolysis of water and aqueous solutions refers to the decomposition of water and its solutions under exposure to ionizing radiation, such as γ-rays, X-rays, accelerated particles, or fast neutrons. This exposure leads to the formation of highly reactive species, including free radicals like hydroxyl radicals (OH), hydrated electrons (eaq), and hydrogen atoms (H), as well as molecular products like molecular hydrogen (H2) and hydrogen peroxide (H2O2). These species may further react with each other or with solutes in the solution. The yield and behavior of these radiolytic products depend on various factors, including pH, radiation type and energy, dose rate, and the presence of dissolved solutes such as oxygen or ferrous ions, as in the case of the ferrous sulfate (Fricke) dosimeter. Aqueous radiation chemistry has been pivotal for over a century, driving advancements in diverse fields, including nuclear science and technology—particularly in water-cooled reactors—radiobiology, bioradical chemistry, radiotherapy, food preservation, wastewater treatment, and the long-term management of nuclear waste. This field is also vital for understanding radiation effects in space. Full article
(This article belongs to the Section Chemistry)
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21 pages, 7595 KB  
Review
Importance of High-Concentration Electrolytes for Lithium-Based Batteries
by Susanna Krämer, Dominik Weintz, Martin Winter, Isidora Cekic-Laskovic and Mariano Grünebaum
Encyclopedia 2025, 5(1), 20; https://doi.org/10.3390/encyclopedia5010020 - 5 Feb 2025
Cited by 2 | Viewed by 5327
Abstract
Each battery cell consists of three main components: the anode, the cathode, and the separator soaked with liquid electrolyte, the medium in the battery that allows charged ions to move between the two electrodes. Besides a wide electrochemical stability window and good compatibility [...] Read more.
Each battery cell consists of three main components: the anode, the cathode, and the separator soaked with liquid electrolyte, the medium in the battery that allows charged ions to move between the two electrodes. Besides a wide electrochemical stability window and good compatibility with both electrodes, the electrolyte should also be safe, thermally stable and environmentally benign, showing a high ionic conductivity of the charge-carrying Li ions and finally a low price. This unique combination of properties is impossible to achieve with a simple salt–solvent mixture and usually requires a combination of different electrolyte components, i.e., several liquid solvents and additives and one or more conducting salt(s). For lithium-based batteries, which are the most common electrochemical energy storage devices today, a solution based on lithium hexafluorophosphate (LiPF6) in a mixture of organic carbonates as the solvent is used. Usually, the conducting salt concentrations used for lithium-based electrolytes are in the range of ≈1 to 1.2 M, but recently, electrolytes with much higher conducting salt concentrations of 5 M and even over 10 M have been investigated as they offer several benefits ranging from increased safety to a broadened electrochemical stability window, thus enabling cheap and safe solvents, even water. Full article
(This article belongs to the Section Chemistry)
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15 pages, 1645 KB  
Review
Distribution of Salts in Milk and Cheese: Critical Methodological Aspects
by Gaurav Kr Deshwal, Liesbeth van der Meulen and Thom Huppertz
Encyclopedia 2024, 4(4), 1629-1643; https://doi.org/10.3390/encyclopedia4040107 - 30 Oct 2024
Viewed by 2826
Abstract
The salt fractions of milk consist of cations (e.g., Ca, Mg, and Na) and anions (e.g., phosphate, citrate, and chloride). These salts are present as free ions or in complexes with other ions or proteins, primarily the caseins. Furthermore, significant levels of Ca [...] Read more.
The salt fractions of milk consist of cations (e.g., Ca, Mg, and Na) and anions (e.g., phosphate, citrate, and chloride). These salts are present as free ions or in complexes with other ions or proteins, primarily the caseins. Furthermore, significant levels of Ca and phosphate are also found in insoluble form, inside the casein micelles. The distribution of salts between this micellar phase and the soluble phase is important for the stability and properties of milk and dairy products. Various processes, such as (ultra-)centrifugation, (ultra-)filtration, dialysis, and selective precipitation have been used to separate the micellar and soluble phases in milk and dairy products to allow for studying the salts’ distribution between these phases. These different methods can lead to different levels of soluble salts because the salts in the supernatant from centrifugation, the permeate from ultrafiltration, and the diffusate from dialysis can differ notably. Hence, understanding which components are fractionated with these techniques and how this affects the levels of the soluble salts determined is critical for milk and dairy products. Applying the aforementioned methods to cheese products is further challenging because these methods are primarily developed for fractionating the soluble and micellar phases of milk. Instead, methods that analyze salts in water-soluble extracts, or soluble phases expressed from cheese by pressing or centrifugation are typically used. This review focuses on the significance of salt distribution and variations in salt fractions obtained using different methodologies for both milk and cheese. Full article
(This article belongs to the Section Chemistry)
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12 pages, 809 KB  
Entry
The 1H HR-NMR Methods for the Evaluation of the Stability, Quality, Authenticity, and Shelf Life of Foods
by Gianfranco Picone
Encyclopedia 2024, 4(4), 1617-1628; https://doi.org/10.3390/encyclopedia4040106 - 29 Oct 2024
Cited by 4 | Viewed by 3647
Definition
1H High-Resolution Nuclear Magnetic Resonance (1H HR-NMR) spectroscopy is a powerful analytical methodology used in various fields, including food science. In the food science field, NMR combined with the principles of metabolomics can provide detailed information about a food’s molecular [...] Read more.
1H High-Resolution Nuclear Magnetic Resonance (1H HR-NMR) spectroscopy is a powerful analytical methodology used in various fields, including food science. In the food science field, NMR combined with the principles of metabolomics can provide detailed information about a food’s molecular composition, structure, dynamics, and interactions within food matrices, making it invaluable for assessing changes during storage, processing, and shelf life. This entry aims to list the main applications of one-dimensional 1H HR-NMR methods in the field of food science, such as their use in the assessment of the stability, quality, authenticity, and shelf life of food samples. Several kinds of foods are taken into consideration to give a huge overview of the potentiality of the methods. Full article
(This article belongs to the Section Chemistry)
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13 pages, 272 KB  
Review
Nuclear Magnetic Resonance and Artificial Intelligence
by Stefan Kuhn, Rômulo Pereira de Jesus and Ricardo Moreira Borges
Encyclopedia 2024, 4(4), 1568-1580; https://doi.org/10.3390/encyclopedia4040102 - 18 Oct 2024
Cited by 6 | Viewed by 5829
Abstract
This review explores the current applications of artificial intelligence (AI) in nuclear magnetic resonance (NMR) spectroscopy, with a particular emphasis on small molecule chemistry. Applications of AI techniques, especially machine learning (ML) and deep learning (DL) in the areas of shift prediction, spectral [...] Read more.
This review explores the current applications of artificial intelligence (AI) in nuclear magnetic resonance (NMR) spectroscopy, with a particular emphasis on small molecule chemistry. Applications of AI techniques, especially machine learning (ML) and deep learning (DL) in the areas of shift prediction, spectral simulations, spectral processing, structure elucidation, mixture analysis, and metabolomics, are demonstrated. The review also shows where progress is limited. Full article
(This article belongs to the Collection Nuclear Magnetic Resonance Techniques)
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13 pages, 4180 KB  
Entry
Perovskite-Type Oxides as Exsolution Catalysts in CO2 Utilization
by Thomas Ruh, Florian Schrenk, Tobias Berger and Christoph Rameshan
Encyclopedia 2023, 3(4), 1461-1473; https://doi.org/10.3390/encyclopedia3040104 - 23 Nov 2023
Cited by 1 | Viewed by 3305
Definition
Perovskite-type oxides (ABO3) are a highly versatile class of materials. They are compositionally flexible, as their constituents can be chosen from a wide range of elements across the periodic table with a vast number of possible combinations. This flexibility enables the [...] Read more.
Perovskite-type oxides (ABO3) are a highly versatile class of materials. They are compositionally flexible, as their constituents can be chosen from a wide range of elements across the periodic table with a vast number of possible combinations. This flexibility enables the tuning of the materials’ properties by doping the A- and/or B-sites of the base structure, facilitating the application-oriented design of materials. The ability to undergo exsolution under reductive conditions makes perovskite-type oxides particularly well-suited for catalytic applications. Exsolution is a process during which B-site elements migrate to the surface of the material where they form anchored and finely dispersed nanoparticles that are crucially important for obtaining a good catalytic performance, while the perovskite base provides a stable support. Recently, exsolution catalysts have been investigated as possible materials for CO2 utilization reactions like reverse water–gas shift reactions or methane dry reforming. Full article
(This article belongs to the Section Chemistry)
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22 pages, 765 KB  
Entry
Physical-Chemical Properties of Nano-Sized Phyllosilicates: Recent Environmental and Industrial Advancements
by Chiara Elmi
Encyclopedia 2023, 3(4), 1439-1460; https://doi.org/10.3390/encyclopedia3040103 - 17 Nov 2023
Cited by 11 | Viewed by 4706
Definition
Phyllosilicates are common minerals that include the most widely known micas and clay minerals. These minerals are found in several natural environments and have unique physical-chemical features, such as cation exchange capacity (CEC) and surface charge properties. When phyllosilicates are nano-sized, their physical-chemical [...] Read more.
Phyllosilicates are common minerals that include the most widely known micas and clay minerals. These minerals are found in several natural environments and have unique physical-chemical features, such as cation exchange capacity (CEC) and surface charge properties. When phyllosilicates are nano-sized, their physical-chemical properties are enhanced from those of the micro-sized counterpart. Because of their unique crystal chemical and physical-chemical features, kinetics, and particle size, nano-sized clay minerals (i.e., kaolinite, montmorillonite/illite) and micas (i.e., muscovite) are of great interest in several fields spanning from environmental applications to engineered materials. This paper aims to overview the recent developments of environmental protection and technological applications employing nano-sized natural micas and clay minerals. Emphasis is given to the role that the unique physical-chemical properties of montmorillonite, vermiculite, kaolinite, and muscovite play in nanoparticle formulations, manufacture, and technical performance. Full article
(This article belongs to the Section Chemistry)
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12 pages, 1346 KB  
Entry
Scanning Electrochemical Microscopy for Electrochemical Energy Conversion and Storage
by Matthias Steimecke
Encyclopedia 2023, 3(4), 1320-1331; https://doi.org/10.3390/encyclopedia3040094 - 20 Oct 2023
Cited by 3 | Viewed by 2541
Definition
Scanning electrochemical microscopy (SECM) is a type of scanning probe microscopy (SPM) where an electrochemical reaction at a microelectrode is used to generate information about an electrochemically (in)active surface in its immediate vicinity. Careful preparation and knowledge of the microelectrode response as well [...] Read more.
Scanning electrochemical microscopy (SECM) is a type of scanning probe microscopy (SPM) where an electrochemical reaction at a microelectrode is used to generate information about an electrochemically (in)active surface in its immediate vicinity. Careful preparation and knowledge of the microelectrode response as well as the application of a suitable method enable the study of spatially resolved electrochemical kinetics or the electrocatalytic activity of any structure or material. In addition to a wide range of other applications, the method has become particularly well established in the research field of electrochemical energy storage and conversion. Full article
(This article belongs to the Collection Encyclopedia of Electrochemical Energy Storage and Conversion)
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