Green Technologies of Hydrogen and Ammonia Production as Energy Vectors

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Chemical Processes and Systems".

Deadline for manuscript submissions: closed (10 October 2023) | Viewed by 1501

Special Issue Editors


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Guest Editor
Chemical and Materials Engineering Department, Faculty of Engineering, King Abdulaziz University, Jeddah 21589, Saudi Arabia
Interests: NH3 decomposition; H2 production; CO2 utilization; syngas chemistry

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Guest Editor
Chemical Engineering Department, BUET, Dhaka 1000, Bangladesh
Interests: energy modeling; process control; process monitoring; fault detection; GHG modeling

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Guest Editor
Department of Chemical Engineering, Jashore University of Science and Technology, Jashore 7408, Bangladesh
Interests: energy, environment and sustainability; functional materials, catalysis and mathematical modeling

Special Issue Information

Dear Colleagues,

In comparison to present fossil fuel-based technologies, researchers are focusing on hydrogen and ammonia as the next generation energy vectors that will be able to supply efficient and environmentally friendly energy. Although hydrogen is the best option for a carbon-free energy source, it has the drawback of having a low volumetric energy density in the gas phase, necessitating a cryogenic storage system with low temperatures (−252.8 oC) and high pressures (700 bar). To overcome this disadvantage, researchers are looking for suitable hydrogen storage materials, which must meet and surplus the hydrogen storage criteria set by DOE and ease of hydrogen extraction from the material for feasible commercial application. Ammonia is one of the most potential hydrogen storge materials which fulfills the DOE criteria, and its storage condition is also much safe compared to hydrogen. Furthermore, ammonia production is a mature technology and been used for more than 100 years using the Haber–Bosch process, a route to produce N2-based fertilizer. Ammonia must undergo catalytic decomposition in order to produce hydrogen, which may then be fed into a fuel cell to produce electricity. One thing to keep in mind is that using fossil fuels to make hydrogen or ammonia is the cheapest option, but doing so results in carbon emissions into the atmosphere. Therefore, the greatest need is for a green way to produce ammonia and hydrogen.

High-caliber papers focusing on the most recent novel developments in theoretical and experimental hydrogen and ammonia decomposition technologies are sought for this Special Issue on "Green Technologies of Hydrogen and Ammonia Production as Energy Vectors". The subject may, but is not restricted to:

  • Hydrogen production from fossil fuels or other hydrogen storage materials.
  • Green Hydrogen production via water splitting via electrocatalysis and photocatalysis.
  • Green ammonia production.
  • Ammonia decomposition and Kinetics of ammonia decomposition.
  • Reactor design for ammonia decomposition and feasibility analysis.

Prof. Dr. Sharif Fakhruz Zaman
Prof. Dr. Mohammad Ali A. Shoukat Choudhury
Dr. Md. Wasikur Rahman
Guest Editors

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Keywords

  • water splitting
  • photocatalysis
  • electrocatalysis
  • NH3 decomposition
  • NH3 decomposition reactor design
  • NH3 decomposition kinetics

Published Papers (1 paper)

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Research

13 pages, 2855 KiB  
Article
Ammonia Decomposition over Alkali Metal (Li, K, Cs)-Promoted Bulk Mo2N Catalyst
by Hisham S. Bamufleh and Sharif F. Zaman
Processes 2023, 11(8), 2287; https://doi.org/10.3390/pr11082287 - 30 Jul 2023
Cited by 1 | Viewed by 1003
Abstract
Ammonia (NH3), which has a 17.7 wt% gravimetric hydrogen density, has been considered as a potential hydrogen storage material. This study looked at the thermocatalytic decomposition of NH3 using a bulk Mo2N catalyst that was boosted by alkali [...] Read more.
Ammonia (NH3), which has a 17.7 wt% gravimetric hydrogen density, has been considered as a potential hydrogen storage material. This study looked at the thermocatalytic decomposition of NH3 using a bulk Mo2N catalyst that was boosted by alkali metals (AM: 5 wt% Li, K, Cs). The K-Mo2N catalyst outperformed all other catalysts in this experiment in terms of catalytic performance. At 6000 h−1 GHSV, 100% conversion of NH3 was accomplished using the K-Mo2N, Cs-Mo2N, and Mo2N catalysts. However, when compared to other catalysts, K-Mo2N had the highest activity, or 80% NH3 conversion, at a lower temperature, or 550 °C. The catalytic activity exhibited the following trend for the rate of hydrogen production per unit surface area: K-Mo2N > Cs-Mo2N > Li-Mo2N > Mo2N. Up to 20 h of testing the K-Mo2N catalyst at 600 °C revealed no considerable deactivation. Full article
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