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Application and Degradation of Polymeric Materials in Agriculture

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: 10 May 2026 | Viewed by 365

Special Issue Editors

National Engineering Research Center of Engineering Plastics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Interests: biodegradable plastics; degradation mechanism; microplastics; intermediates; environmental behavior

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Guest Editor
College of Mechanical and Electronic Engineering, Northwest A&F University, Yangling, Xianyang 712100, China
Interests: biomass energy chemistry; lignin; high-value utilization of biomass-based resources
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Special Issue Information

Dear Colleagues,

With their excellent physical and chemical properties, polymer materials have become a crucial support for the development of modern agriculture. However, the extensive use of traditional non-degradable polymer materials (such as polyethylene and polypropylene) has given rise to a severe "white pollution" problem. These materials are difficult to degrade in the natural environment; their long-term presence in soil damages the soil structure, hinders the development of crop root systems, and poses a threat to the ecosystem and human health through the food chain.

Currently, the approaches to addressing this issue mainly fall into two categories. First, the development of biodegradable polymer materials, such as PBAT, PCL, PLA, and starch-based composite materials, has been a significant advancement. These materials can be decomposed into carbon dioxide and water under the action of microorganisms, enabling an environmentally friendly cycle. Second, optimizing degradation control technologies. Through blending modification, the addition of photo/biodegradants, and other methods, the degradation rate of traditional materials is enhanced while maintaining their performance in use.

In the future, the development of polymer materials in the agricultural sector needs to strike a balance between functionality and environmental compatibility. On the one hand, it is necessary to enhance the performance optimization and cost control of new biodegradable materials to promote their widespread application. On the other hand, a comprehensive system for evaluating material recycling and degradation should be established. Combined with precision agriculture technologies, this will realize the efficient and sustainable utilization of polymer materials, providing technical support for the green development of agriculture.

This issue invites contributions on key topics, including: molecular design for controlled degradation; applications in packaging, agriculture, biomedicine, and so on; degradation kinetics and mechanisms in various environments; and advanced in situ and ex situ techniques to monitor degradation, identify degradation products such as microplastics and intermediates, and assess ecotoxicity. We welcome original research and reviews that consolidate recent advances in the field. The goal is to foster a cradle-to-grave understanding and support the development of safer, high-performance polymeric materials, contributing to a circular economy.

Dr. Dan Huang
Dr. Mingqiang Zhu
Dr. Yanyan Dong
Guest Editors

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • biodegradable polymer materials
  • plastics
  • degradation mechanism
  • process monitoring
  • microplastics
  • intermediates
  • analytical methods
  • characterization
  • environmental behavior

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Published Papers (1 paper)

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Research

23 pages, 2948 KB  
Article
The Use of Natural Rubber as an Initiator of LDPE Biodegradation in Soil
by Ivetta Varyan, Polina Tyubaeva, Matheus Poletto, Egor S. Morokov, Anastasia V. Bolshakova, Svetlana G. Karpova, Evgeny A. Kolesnikov and Anatoly Popov
Polymers 2025, 17(21), 2885; https://doi.org/10.3390/polym17212885 - 29 Oct 2025
Viewed by 288
Abstract
The control of the quantities of multi-tonnage polymers, in particular, making them biodegradable, is an urgent task. This study suggests a new approach in the application of natural rubber (NR) as an initiator of biodegradation of low-density polyethylene (LDPE) in soil. The study [...] Read more.
The control of the quantities of multi-tonnage polymers, in particular, making them biodegradable, is an urgent task. This study suggests a new approach in the application of natural rubber (NR) as an initiator of biodegradation of low-density polyethylene (LDPE) in soil. The study examines the structure, properties and rates of biodegradation of thin LDPE films with different content of NR. Such methods as fourier transform infrared spectroscopy (FTIR), electron paramagnetic resonance (EPR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscope (SEM), atomic force microscopy (AFM), gel-permeation chromatography (GPC), and acoustic microscopy were used for the most complete characterization of NR/LDPE composite systems. It was shown for the first time that at concentrations above 30%, NR is able to form an interpenetrating structure with the LDPE matrix, which has a decisive effect on the initiation of biodegradation during exposure in soil. Thus, the composition with 50% natural rubber exhibits the highest mass loss. The sample with 50% natural rubber content lost 70% of its mass, while the one with 40% NR content lost 38%. Furthermore, after soil burial, a significant decrease in crystallinity was observed: from 39.5% to 31.5% for the 90/10 composition and from 39.1% to 24.2% for the 50/50 composition. The results obtained are confirmed by a noticeable decrease in the molecular weight characteristics of LDPE. Full article
(This article belongs to the Special Issue Application and Degradation of Polymeric Materials in Agriculture)
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