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Preparation and Application of Cellulose-Based and Chitosan-Based Materials

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Biobased and Biodegradable Polymers".

Deadline for manuscript submissions: 31 July 2025 | Viewed by 2902

Special Issue Editors


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State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China
Interests: biomass-based materials; polymer composites; pretreatment of biomass; valorization of low-cost waste
Special Issues, Collections and Topics in MDPI journals
State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China
Interests: biomass-based composites; carbon-based nanomaterials; electrocatalysis; electrochemical energy storage and conversion; environmental remediation
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

To prevent catastrophic global climate change, carbon peak and carbon neutrality targets have been put forward worldwide. In this context, as renewable and biodegradable biomass resources, the most common natural polymers, such as cellulose, lignin, chitin, collagen, and so on, have dramatically attracted significant attention in recent decades. Moreover, a large number of biomass-based materials have been developed from these natural polymers, which have a wide range of applications in various fields, such as the packaging, energy, and biomedical fields.

To promote the development of biomass-based materials and expand their application, this Special Issue is focused on the preparation and application of cellulose-based and chitosan-based materials.

Dr. Guangmei Xia
Dr. Peng Jia
Guest Editors

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Keywords

  • biomass-based materials
  • preparation
  • application
  • renewable
  • biodegradable
  • cellulose
  • chitosan

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Published Papers (3 papers)

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Research

17 pages, 2894 KiB  
Article
Preparation of Chitooligosaccharides with Specific Sequence Arrangement and Their Effect on Inducing Salt Resistance in Wheat Seedlings
by Jingwen Li, Anbang Li, Yupeng Li, Siqi Zhu, Lin Song, Song Liu, Ronge Xing and Kecheng Li
Polymers 2025, 17(9), 1194; https://doi.org/10.3390/polym17091194 - 27 Apr 2025
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Abstract
Chitooligosaccharides (COS) exhibits good activity of inducing plant resistance, but the structure–activity relationship is still unclear. In this study, chitin oligosaccharides (CHOS) with a degree of polymerization (DP) of 2~6 were used as raw materials. Three deacetylases (NodB, VcCOD, and ArCE4A) [...] Read more.
Chitooligosaccharides (COS) exhibits good activity of inducing plant resistance, but the structure–activity relationship is still unclear. In this study, chitin oligosaccharides (CHOS) with a degree of polymerization (DP) of 2~6 were used as raw materials. Three deacetylases (NodB, VcCOD, and ArCE4A) were employed to prepare three different sequence-arranged COSs, namely N-COS, C-COS, and A-COS, and their structures were characterized by infrared spectroscopy, high-performance liquid chromatography, and mass spectrometry. Further studies were conducted on inducing the plant salt resistance of the three different sequence-arranged COSs on wheat seedlings. The results showed a sequence-dependent effect of COS inducing plant salt resistance. Among them, A-COS exhibited the best activity. When sprayed at a concentration of 10 mg/L on wheat seedlings under salt stress for 3 days, the leaf length of the wheat seedlings sprayed with A-COS was recovered, and the wet mass and dry mass were recovered by 20.40% and 6.64%, respectively. Following the enhancement of proline accumulation, the malondialdehyde content decreased by 34.75%, and the Na+/K+ ratio also exhibited a significant reduction, thereby alleviating salt stress-induced damage. This study was the first to demonstrate the effect of COS with specific sequences on inducing plant salt resistance, providing a theoretical basis for the development of a new generation of efficient COS plant biostimulator. Full article
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17 pages, 1890 KiB  
Article
Development of Curcumin-Loaded TiO2-Reinforced Chitosan Monofilaments for Biocompatible Surgical Sutures
by Fatma Demirci
Polymers 2025, 17(4), 484; https://doi.org/10.3390/polym17040484 - 12 Feb 2025
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Abstract
Sutures provide mechanical support for wound closure after various traumas and surgical operations. Absorbable sutures are increasingly favored as they eliminate the need for secondary procedures and minimize additional damage to the wound site. In this study, chitosan sutures were produced using the [...] Read more.
Sutures provide mechanical support for wound closure after various traumas and surgical operations. Absorbable sutures are increasingly favored as they eliminate the need for secondary procedures and minimize additional damage to the wound site. In this study, chitosan sutures were produced using the dry jet–wet spinning method, achieving number 7-0 sutures (approximately 76 μm diameter) with a homogeneous surface. FTIR analysis demonstrated molecular interactions between chitosan and TiO2 or curcumin, confirming successful incorporation. The addition of 3% TiO2 increased the tensile strength of chitosan sutures by 12.32%, reaching 189.41 MPa. Morphological analysis revealed smooth surfaces free of pores and bubbles, confirming the production of high-quality sutures. Radical scavenging activity analysis showed that curcumin-loaded sutures exhibited 43% scavenging ability after 125 h, which was significantly higher compared to pure chitosan sutures. In vitro antibacterial tests demonstrated that curcumin-loaded sutures provided 98.87% bacterial inactivation against S. aureus within 24 h. Additionally, curcumin release analysis showed a cumulative release of 77% over 25 h. The bioactivity of the sutures was verified by hydroxyapatite layer formation after incubation in simulated body fluid, supporting their potential for tissue regeneration. These findings demonstrate that TiO2 reinforcement and curcumin loading significantly enhance the functional properties of chitosan sutures, making them strong candidates for biocompatible and absorbable surgical applications. Full article
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11 pages, 5365 KiB  
Article
Evaluation of Mechanical Properties of Composite Material with a Thermoplastic Matrix Reinforced with Cellulose Acetate Microfibers
by Pedro Rodríguez Sandoval, Andres Felipe Rubiano-Navarrete, Edwin Yesid Gómez-Pachón and Ricardo Vera-Graziano
Polymers 2024, 16(18), 2557; https://doi.org/10.3390/polym16182557 - 10 Sep 2024
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Abstract
Low-density polyethylene (LDPE) has been widely used in various applications due to its flexibility, lightness, and low production cost. However, its massive use in disposable products has raised environmental concerns, prompting the search for more sustainable alternatives. This study aims to investigate the [...] Read more.
Low-density polyethylene (LDPE) has been widely used in various applications due to its flexibility, lightness, and low production cost. However, its massive use in disposable products has raised environmental concerns, prompting the search for more sustainable alternatives. This study aims to investigate the mechanical properties achievable in a composite material utilizing low-density polyethylene (LDPE), potato starch (PS), and cellulose microfibrils (MFCA) at loadings of 0.05%, 0.15%, and 0.30%. Initially, the cellulose acetate microfibrils (MFCA) were produced via an electrospinning process. Subsequently, a dispersive mixture of the aforementioned materials was created through the extrusion and pelletizing process to form pellets. These pellets were then molded by injection molding to produce test specimens in accordance with ASTM D 638, the standard for tensile strength testing. The evaluation of the properties was conducted through mechanical tensile tests (ASTM D638), hardness tests (ASTM D 2240), melt flow index (ASTM D1238), and scanning electron microscopy (SEM). This study determined the influence of cellulose acetate microfibril loadings below 0.3% as reinforcement within a thermoplastic LDPE matrix. It was demonstrated that these microfibrils, due to their length-to-diameter ratio, contribute to an enhancement in the mechanical properties. Full article
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