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The Application of Polymers in Biomimetics

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: closed (31 December 2024) | Viewed by 4086

Special Issue Editor


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Guest Editor
1. Department of Chemical Engineering, Army Academy, Chung Li 32092, Taiwan
2. Center for General Education, Chung Yuan Christian University, Chung Li 32023, Taiwan
Interests: crystallization kinetics; polymer electrolytes; electrochemical sensing; biomimetic; antimicrobial coatings
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Special Issue Information

Dear Colleagues,

The advancement of polymer materials in the field of biomimetics is driving a wave of innovation in the scientific community. The development of these materials is deeply inspired by the structures and functions of biological entities found in nature. Self-healing materials, superhydrophobic surfaces, color-changing effects, and intelligent response characteristics are all products of mimicking the wondrous designs of the natural world, bringing new application possibilities to various industries. In the field of medicine, the application of polymer materials has already demonstrated their unique value. Polymer materials that mimic human tissue characteristics are being used in tissue engineering and drug delivery systems, offering more natural and effective treatment options. This is just one example among many fields, illustrating the broad application prospects of polymer materials. Therefore, we cordially invite experts and scholars with innovative technologies or unique insights in the fields of polymer materials and biomimetics to join our Special Issue, “The Application of Polymers in Biomimetics”, to share their research findings and perspectives. We eagerly await valuable submissions from your research team, such that we can jointly embark on a new chapter in the field of polymers in biomimetics.

Dr. Jiunn-Jer Hwang
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

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Keywords

  • self-healing materials
  • superhydrophobic and superhydrophilic surfaces
  • color-changing and optical properties
  • biomimetic adhesive
  • biomedical application
  • intelligent responsive materials
  • materials for biomimetic robotics

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Published Papers (3 papers)

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Research

11 pages, 4078 KiB  
Article
Biomimetic Silicone Surfaces for Antibacterial Applications
by Marie Barshutina, Dmitry Yakubovsky, Aleksey Arsenin, Valentyn Volkov, Sergey Barshutin, Anastasiya Vladimirova and Andrei Baymiev
Polymers 2025, 17(2), 213; https://doi.org/10.3390/polym17020213 - 16 Jan 2025
Cited by 1 | Viewed by 829
Abstract
Biomimetic patterning emerges as a promising antibiotic-free approach to protect medical devices from bacterial adhesion and biofilm formation. The main advantage of this approach lies in its simplicity and scalability for industrial applications. In this study, we employ it to produce antibacterial coatings [...] Read more.
Biomimetic patterning emerges as a promising antibiotic-free approach to protect medical devices from bacterial adhesion and biofilm formation. The main advantage of this approach lies in its simplicity and scalability for industrial applications. In this study, we employ it to produce antibacterial coatings based on silicone materials, widely used in the healthcare industry. In doing so, we patterned silicone substrates with a topography of various flower petals (rose, chamomile, pansy, and magnolia) and studied the relationship between the antibacterial properties of the obtained biomimetic substrates and their surface topography. To study the surface topography of biomimetic surfaces, we used the fractal analysis of their SEM images. In particular, as a measure of surface complexity and heterogeneity, we used the values of the developed interfacial area ratio (Sdr) and lacunarity coefficient (β). In the result, we found that the bacterial area coverage of biomimetic substrates decreased exponentially with the increase in their surface complexity and heterogeneity, and prominent antibacterial properties were observed at β > 1.6 and Sdr > 50. The results of this study can be used to identify biomimetic materials with superior antibacterial properties and produce efficient antibacterial silicone coatings for biomedical and healthcare applications. Full article
(This article belongs to the Special Issue The Application of Polymers in Biomimetics)
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12 pages, 3132 KiB  
Article
Entrapment of Cyanase from Thermomyces lanuginosus Using Biomimetic Silica and Its Application for Cyanate Bioremediation
by Su-Chun How, Chia-Jung Hsieh and Chi-Yang Yu
Polymers 2024, 16(18), 2594; https://doi.org/10.3390/polym16182594 - 13 Sep 2024
Viewed by 835
Abstract
Cyanate, a toxic product from the chemical oxidation treatment of highly toxic cyanide, can be converted to harmless ammonia and carbon dioxide by cyanase (EC 4.2.1.104). Cyanase from Thermomyces lanuginosus was entrapped in biomimetic silica to improve stability and reusability. After entrapment, the [...] Read more.
Cyanate, a toxic product from the chemical oxidation treatment of highly toxic cyanide, can be converted to harmless ammonia and carbon dioxide by cyanase (EC 4.2.1.104). Cyanase from Thermomyces lanuginosus was entrapped in biomimetic silica to improve stability and reusability. After entrapment, the enzyme’s activity increased by two-fold, and the residual activity after 30-min of incubation at 60 °C also increased by two-fold, compared to the free enzyme. After being stored at room temperature for 28 days, the entrapped cyanase retained 79% of the initial activity, while the free form retained 61%. The immobilized cyanase was successfully applied to cyanate detoxification; the co-entrapment of carbonic anhydrase from Sulfurihydrogenibium azorense decreased the amount of bicarbonate necessary for cyanate detoxification by 50%. The cyanate degradation retained 53% of the initial value after the co-entrapped cyanate and carbonic anhydrase were reused five times. Full article
(This article belongs to the Special Issue The Application of Polymers in Biomimetics)
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21 pages, 26879 KiB  
Article
Leaf on a Film: Mesoporous Silica-Based Epoxy Composites with Superhydrophobic Biomimetic Surface Structure as Anti-Corrosion and Anti-Biofilm Coatings
by Jiunn-Jer Hwang, Pei-Yu Chen, Kun-Hao Luo, Yung-Chin Wang, Ting-Ying Lai, Jolleen Natalie I. Balitaan, Shu-Rung Lin and Jui-Ming Yeh
Polymers 2024, 16(12), 1673; https://doi.org/10.3390/polym16121673 - 12 Jun 2024
Cited by 1 | Viewed by 1672
Abstract
In this study, a series of amine-modified mesoporous silica (AMS)-based epoxy composites with superhydrophobic biomimetic structure surface of Xanthosoma sagittifolium leaves (XSLs) were prepared and applied as anti-corrosion and anti-biofilm coatings. Initially, the AMS was synthesized by the base-catalyzed sol–gel reaction of tetraethoxysilane [...] Read more.
In this study, a series of amine-modified mesoporous silica (AMS)-based epoxy composites with superhydrophobic biomimetic structure surface of Xanthosoma sagittifolium leaves (XSLs) were prepared and applied as anti-corrosion and anti-biofilm coatings. Initially, the AMS was synthesized by the base-catalyzed sol–gel reaction of tetraethoxysilane (TEOS) and triethoxysilane (APTES) through a non-surfactant templating route. Subsequently, a series of AMS-based epoxy composites were prepared by performing the ring-opening polymerization of DGEBA with T-403 in the presence of AMS spheres, followed by characterization through FTIR, TEM, and CA. Furthermore, a nano-casting technique with polydimethylsiloxane (PDMS) as the soft template was utilized to transfer the surface pattern of natural XSLs to AMS-based epoxy composites, leading to the formation of AMS-based epoxy composites with biomimetic structure. From a hydrophilic CA of 69°, the surface of non-biomimetic epoxy significantly increased to 152° upon introducing XSL surface structure to the AMS-based epoxy composites. Based on the standard electrochemical anti-corrosion and anti-biofilm measurements, the superhydrophobic BEAMS3 composite was found to exhibit a remarkable anti-corrosion efficiency of ~99% and antimicrobial efficacy of 82% as compared to that of hydrophilic epoxy coatings. Full article
(This article belongs to the Special Issue The Application of Polymers in Biomimetics)
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