Advances in Structure and Topochemistry of Nitro and Nitroso Compounds
A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Organic Chemistry".
Deadline for manuscript submissions: closed (1 August 2022) | Viewed by 168
Special Issue Editor
Interests: solid-state reactions; reactive intermediates; topochemistry; mechanochemistry; solid-state kinetics; matastable phases
Special Issues, Collections and Topics in MDPI journals
Special Issue Information
Dear Colleagues,
Nitro and nitroso compounds afford special and interesting behavior in the solid polycrystalline phases. They, especially nitroso compounds, undergo chemical transformation that could be induced either photochemically or thermally. The investigation of these solid-state processes has provided us with deeper insight into the coupling between chemical reactions and phase transformations. The role of the molecular and crystal structure, as well as the topotactic effect on these processes is of high interest for the development of physical organic chemistry of solid-state reaction mechanisms. Rearrangements of nitro- and nitroso molecules in crystal phases by transformations of covalent bonds triggered by UV or VIS irradiation and the possibility of the formation of (semi)conducting organic polymers are interesting properties for the design of new materials with applications in molecular electronics.
Prof. Dr. Hrvoj Vančík
Guest Editor
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Keywords
- nitroso compounds
- nitro compounds
- azodioxides
- topochemistry
- solid-state reaction mechanisms
- intermolecular interactions
- crystal structures
- organic semiconductors
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