Recent Advances in Coordination Chemistry of Metal Organic Polygons and Polyhedra (MOPs)

A special issue of Inorganics (ISSN 2304-6740). This special issue belongs to the section "Coordination Chemistry".

Deadline for manuscript submissions: closed (30 November 2022) | Viewed by 4675

Special Issue Editor


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Guest Editor
School of Chemistry, University of Bristol, Cantock’s Close BS8 1TS, UK
Interests: coordination chemistry; molecular machine; host–guest chemistry; drug delivery; supramolecular chemistry

Special Issue Information

Dear Colleagues,

The field of coordination chemistry is undergoing rapid transformation from synthesizing monometallic complexes to multimetallic complexes.  Multimetallic complexes with well-defined cavity popularly known as metal organic polygons and polyhedra (MOPs) have been an active field of research. Understanding coordination chemistry of monometallic complexes can lead to a structurally diverse class of MOPs. By virtue of the inner space available within MOPs, they become a very useful tool for carrying out precious jobs that are otherwise not achievable. The host–guest chemistry allows sequestering chemicals for better protection and transportation. Chemical transformations within a confined cavity follow a different pathway than the bulk environment, benefitting the field of catalysis. More recently, MOPs have found applications in biomedical applications for delivery and bio-imaging due to their structural tunability. Given the scope and possibility of metal coordination chemistry, the field of MOPs occupies the central theme of modern chemistry from the prospect of pure and applied chemistry.

The purpose of this issue is to bring critical insight into how a detailed understanding of coordination chemistry can have a tremendous impact on the emerging field of metal organic polygons and polyhedra. In this Special Issue, we intend to cover the most recent advances in designing and synthesizing various classes of MOPs. We wish to invite papers exploring the potential of MOPs toward various applications such as host–guest chemistry, separation, catalysis, sensing, storage, transport, delivery, and biomedical applications in the form of original research articles and comprehensive reviews.

Dr. Soumen K. Samanta
Guest Editor

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Keywords

  • coordination chemistry
  • metal organic polygons and polyhedra
  • designing and synthesizing
  • host–guest chemistry
  • catalysis
  • sensors
  • storage and transport
  • biomedical applications

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Published Papers (1 paper)

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Review

65 pages, 17382 KiB  
Review
Metal Organic Polygons and Polyhedra: Instabilities and Remedies
by Soumen K. Samanta
Inorganics 2023, 11(1), 36; https://doi.org/10.3390/inorganics11010036 - 9 Jan 2023
Cited by 3 | Viewed by 3751
Abstract
The field of coordination chemistry has undergone rapid transformation from preparation of monometallic complexes to multimetallic complexes. So far numerous multimetallic coordination complexes have been synthesized. Multimetallic coordination complexes with well-defined architectures are often called as metal organic polygons and polyhedra (MOPs). In [...] Read more.
The field of coordination chemistry has undergone rapid transformation from preparation of monometallic complexes to multimetallic complexes. So far numerous multimetallic coordination complexes have been synthesized. Multimetallic coordination complexes with well-defined architectures are often called as metal organic polygons and polyhedra (MOPs). In recent past, MOPs have received tremendous attention due to their potential applicability in various emerging fields. However, the field of coordination chemistry of MOPs often suffer set back due to the instability of coordination complexes particularly in aqueous environment-mostly by aqueous solvent and atmospheric moisture. Accordingly, the fate of the field does not rely only on the water solubilities of newly synthesized MOPs but very much dependent on their stabilities both in solution and solid state. The present review discusses several methodologies to prepare MOPs and investigates their stabilities under various circumstances. Considering the potential applicability of MOPs in sustainable way, several methodologies (remedies) to enhance the stabilities of MOPs are discussed here. Full article
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