Nanoscale Transport Phenomena at Interfaces

The free-piston Stirling engine is a closed-cycle regenerative heat engine that converts heat energy into mechanical work, and requires a spring element for vibratory operations of the displacer and power pistons. In this study, the geometry of the flexural spring design was optimized through structural finite element analyses and fatigue test evaluations. First, we constructed a target design space considering the required natural frequency of the displacer spring assembly under the geometric constraints of total mass and module height. The design of experiments was employed to construct simulation cases for design factors such as the outer diameter, thickness, and number of spirals in the spring sheet. As a result, the optimized design values were obtained to satisfy the design requirements. We also fabricated a test spring specimen and conducted fatigue tests using a linear actuator system developed to have the same motion as the engine. The test results indicated that the optimized spiral spring had no fracture under operating conditions with the design piston amplitude, revealing the effectiveness of the design method. Full article

Superhydrophobic surfaces have been extensively studied for their unique interfacial interaction between water and the surface, and they can be used for self-cleaning, drag reduction, anti-icing, and other applications. To make the superhydrophobic surfaces, nano/microscale structures and a low surface energy should be realized. The development of a durable superhydrophobic surface was hindered by the vulnerability of the surface to mechanical contact. To improve the robustness of the superhydrophobic surface toward mechanical damage, the hydrophobic polypropylene (PP) surface was coated with a thick layer of hydrophobic silica nanoparticles (SNPs) using a simple compression molding process. The thick layer consists of SNPs and PP, and the roles of SNPs and PP are nano/microscale structures with a low surface energy and binder for nanoparticles, respectively. This revealed improvement in the superhydrophobic tendency, with an apparent contact angle of about 170° and a sliding angle of less than 5°. The morphology and the corresponding elemental analysis of the PP/SNPs coated films were investigated using field emission scanning electron microscopy and energy-dispersive spectrometry. The mechanical durability of the superhydrophobic surface was evaluated by the scotch tape test and scratch test with sandpaper. The coated films with SNPs showed the superhydrophobic behavior after 25 tape tests. In addition, the coated films with SNPs showed a contact angle greater than 150° and a sliding angle less than 10° after a 100-cm scratch test with 1000 grit sandpaper, under a weight of 500 g, on an area of 40 × 40 mm². The chemical stability of PP/SNPs coated films was also investigated in acidic, neutral, and alkaline medium solutions. The films showed good stability under the acidic and neutral medium solutions even after 24 h, but an alkaline medium could damage the surface. The obtained results demonstrated the robustness of the superhydrophobic coating with SNPs. Full article