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Hydrogen Production and Utilization: Challenges and Opportunities

A special issue of Energies (ISSN 1996-1073). This special issue belongs to the section "A5: Hydrogen Energy".

Deadline for manuscript submissions: 30 May 2025 | Viewed by 1653

Special Issue Editor


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Guest Editor
Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek 8, 30-239 Cracow, Poland
Interests: microcalorimetric research of heat evolution accompanying the sorption of gases on the supported noble metal catalysts; nonlinear dynamics of thermokinetic oscillations in the sorption of hydrogen in palladium; kinetic and thermochemistry of intercalation of hydrogen and the formation of hydrogen bronzes in the transition metal oxides

Special Issue Information

Dear Colleague,

Hydrogen is a surprising material. In its elemental state, it forms two-atomic molecules, H2, that are expectedly very stable, given their high bonding energy of 440 kJ/mol. Molecular hydrogen is indeed not very active, and for its numerous applications, the H2 molecules first need to be subjected to dissociation into atomic hydrogen. The single hydrogen atoms, in contrast, are considered to be extremely active and cannot be stored in a gaseous form, as they undergo immediate recombination. One solution to this predicament is to produce atomic hydrogen immediately before use, for which case the chemists of old have coined the term “in statu nascendi” hydrogen, meaning in Latin “at the moment of birth”. Another way is to fill voids in the crystal structure with guest hydrogen atoms in certain solid materials, applying them as the host lattice. Still, such intercalation must be preceded by an act of H2 dissociation, which usually occurs upon contact between gaseous hydrogen and certain metals, mostly the noble, Pt, Pd, or the semiprecious, including Ni and Cu. Here comes the surprising moment: in spite of its apparent stability, the dissociation of H2 proceeds rapidly at rather mild conditions and, moreover, turns out to be an exothermic process, despite the large barrier of its 440 kJ/mol bonding energy to be overcome. So, it is not always totally clear where the energy for splitting the H–H bond comes from during dissociation, since the atomic hydrogen species produced do not seem to form any strong bonds, or indeed any bonds at all, within the structure of their eventual host lattice. This seems to be a paradox, often ignored. Hydrogen is undoubtedly far too important an energy vector, and a material of too great industrial relevance for us, to let the progress of its technology to be slowed down by any scientific uncertainties. Only certain rare events, like exceptionally strong hydrogen explosions, or surprisingly anomalous scientific outcomes, like low-energy nuclear reaction (LENR) effects, still act as a reminder that we do not know everything about hydrogen yet. But if there is a hidden source of energy in hydrogen, how can it be harvested?

Hydrogen is not a natural resource; it does not appear in nature in its elemental form. It has to be produced from non-renewable resources like natural gas, and currently, the process of steam methane reforming (SMR) is the most widely used technology, covering around half of the global demand. The alternatives are legion. Various other hydrocarbons and alcohols may also be steam reformed. In particular, ethanol steam reforming (ESR), utilizing bioethanol as a renewable resource material, may be a way to limit the depletion of the finite resources. Other alternatives include the pyrolysis of hydrocarbons and the electrolysis of water. However, all of those methods consume high amounts of energy. Moreover, raw hydrogen contains impurities (like CO) and has to be carefully purified before it is usable for certain, more refined applications, like fuel cells, which consumes even more energy. Perhaps it is worthwhile to search for a way to apply the LENR effects, if still unconventional and indeed barely emerging from the scientific underground, in an effort to mitigate the high energy cost of hydrogen production.

This Special Issue welcomes contributions focused on hydrogen production and purification, as well as its energetic and environmentally friendly uses. Both conventional and less conventional aspects will be considered, but efforts to specifically gain insight into the energetic effects of investigated reactions will be appreciated. Manuscripts reporting any experimental or theoretical approaches will be considered.

Dr. Erwin Lalik
Guest Editor

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Keywords

  • catalytic stem reforming of methane (MSR) and other hydrocarbons
  • catalytic stem reforming of alcohols, including bio-alcohols
  • hydrogen purification methods and processes
  • catalytic hydrogenation reactions
  • catalytic hydrogen-assisted processes
  • electrochemical systems, such as fuel cells or electrolytic hydrogen evolution processes
  • catalytic oxidation of hydrogen
  • low-energy nuclear reactions (LENR)
  • hydrogen evolution reactions
  • pseudocapacitive materials
  • electrochemical energy storage systems
  • application of hydrogen as fuel

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Published Papers (2 papers)

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Research

13 pages, 3227 KiB  
Article
Development of a Multi-Bed Catalytic Heat Generator Utilizing a Palladium-Based Hydrogen Combustion System
by Grzegorz Mordarski, Konrad Skowron, Dorota Duraczyńska, Anna Drabczyk and Robert P. Socha
Energies 2025, 18(6), 1348; https://doi.org/10.3390/en18061348 - 10 Mar 2025
Viewed by 579
Abstract
The growing demand for sustainable energy solutions requires the development of safe and efficient systems for hydrogen utilization. Hydrogen, with its high energy density and clean combustion characteristics, has become a promising alternative for heating applications. However, conventional combustion technologies often suffer from [...] Read more.
The growing demand for sustainable energy solutions requires the development of safe and efficient systems for hydrogen utilization. Hydrogen, with its high energy density and clean combustion characteristics, has become a promising alternative for heating applications. However, conventional combustion technologies often suffer from inefficiencies and safety concerns, such as NOx emissions and explosion risks. To address these challenges, this study aimed to design and evaluate a catalytic heat generator utilizing hydrogen–air mixtures under controlled conditions to eliminate the need for pure oxygen and mitigate associated risks. A single-bed catalytic system was developed using palladium-based catalysts supported on ceramic fibers, followed by its heating, activation, and further characterization using the SEM-EDS technique. A multi-bed generator was later constructed to enhance scalability and performance. Thermal imaging and temperature monitoring were employed to optimize activation processes and assess system performance under varying hydrogen flow rates. The experimental results demonstrated efficient heat transfer and operational stability. Full article
(This article belongs to the Special Issue Hydrogen Production and Utilization: Challenges and Opportunities)
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19 pages, 2299 KiB  
Article
Microbial Fuel Cells as CO2 Source in the Autotrophic Cultivation of the Green Microalgae Tetraselmis subcordiformis: Impact on Biomass Growth, Nutrient Removal, and Hydrogen Production
by Marcin Zieliński, Łukasz Barczak, Paulina Rusanowska, Anna Nowicka and Marcin Dębowski
Energies 2025, 18(4), 874; https://doi.org/10.3390/en18040874 - 12 Feb 2025
Viewed by 614
Abstract
Carbon dioxide (CO2) is often a limiting factor for the growth of microalgal biomass. Consequently, the search for new CO2 sources that do not contain components inhibitory to microalgal metabolism remains a priority. An alternative to the solutions tested thus [...] Read more.
Carbon dioxide (CO2) is often a limiting factor for the growth of microalgal biomass. Consequently, the search for new CO2 sources that do not contain components inhibitory to microalgal metabolism remains a priority. An alternative to the solutions tested thus far may involve the use of CO2-rich gas derived from microbial fuel cells (MFCs). This concept served as the basis for the original experimental work described in this study. The objective of the research was to evaluate the effect of using gases from the anode chamber of an MFC as a CO2 source in the autotrophic cultivation of Tetraselmis subcordiformis. The highest biomass growth efficiency was observed when the CO2 concentration in the culture medium was maintained at 220.0 ± 8.0 mg/L. Under these conditions, the microalga proliferation rate reached 0.52 ± 0.03 g VS/(L∙day) and 11.54 ± 0.42 mg chl-a/(L∙day), with a final biomass concentration of 2.68 ± 0.10 g VS/L and 63.53 ± 2.44 mg chl-a/L at the end of the cultivation cycle. Moreover, the highest total hydrogen (H2) production of 312 ± 38 mL was achieved in the same experimental variant, corresponding to an H2 production rate of 62.4 ± 6.1 mL/day. The removal efficiency of ammonium nitrogen (N-NH4) was notably high in experimental variants using MFC-derived biogas, ranging from 97.0 ± 2.2% to 98.2 ± 1.8%. Additionally, the growing microalgal biomass effectively utilized phosphate phosphorus (P-PO4) and iron, further highlighting its potential for nutrient recovery. Full article
(This article belongs to the Special Issue Hydrogen Production and Utilization: Challenges and Opportunities)
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