Research Progress on Thermoelectric Materials

A special issue of Crystals (ISSN 2073-4352).

Deadline for manuscript submissions: 20 December 2025 | Viewed by 764

Special Issue Editors


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Guest Editor
School of Materials Science and Engineering, University of Jinan, Jinan 250022, China
Interests: thermoelectric materials; new quantum materials

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Guest Editor
Physics Department, Northern Illinois University, DeKalb, IL 60115, USA
Interests: condensed matter physics; materials science; neutron and X-ray scattering; functional materials; bulk materials; thin films; superconductivity; magnetism; multiferroics; thermoelectrics

Special Issue Information

Dear Colleagues,

Thermoelectric materials and devices enable direct conversion between thermal and electrical energy, offering unparalleled advantages in waste heat recovery, energy conservation, and small- to medium-scale refrigeration. The design of thermoelectric materials and devices is a critical focus in thermoelectric research, as improving their design can significantly enhance service performance and operational stability. To this end, researchers are actively exploring novel high-performance material systems, developing innovative strategies (band engineering, defect chemistry, carrier optimization, etc.) to improve thermoelectric properties, and advancing cutting-edge fabrication techniques (e.g., spark plasma sintering, MBE, sol–gel) to engineer high-performance thermoelectric materials and device integration with excellent operational performance (e.g., module design, interfacial engineering). These breakthroughs hold great promise for driving technological advancements in microelectronics, information technology, healthcare, clean energy, and other related industries.

This Special Issue, titled “Research Progress on Thermoelectric Materials”, highlights recent advancements in thermoelectric materials, focusing on material design, synthesis, characterization, and performance optimization for energy conversion applications. The material systems include traditional thermoelectric materials (Bi2Te3, PbTe, SiGe, Skutterudites), emergent materials (oxide thermoelectrics, organic/hybrid materials, chalcogenides (e.g., SnSe), and half-Heusler alloys), and low-dimensional and nanostructured materials (quantum dots, superlattices, nanocomposites). By bringing together diverse perspectives (reviews, original research, and perspectives), this Special Issue can serve as a reference for future research directions while accelerating the transition of lab-scale innovations to practical applications.

Dr. Changcun Li
Prof. Dr. Omar Chmaissem
Guest Editors

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Keywords

  • thermoelectric material 
  • thermoelectric efficiency
  • X-ray diffraction
  • electrical conductivity 
  • Seebeck coefficient 
  • thermal conductivity 
  • ZT value
  • band gap
  • phonon engineering
  • microstructure 
  • sustainable materials 
  • energy harvesting

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Published Papers (1 paper)

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17 pages, 2210 KB  
Article
The Preparation and Properties of Polycrystalline Bi2O2Se—Pitfalls in Reproducibility and Charge-Transport Limiting Factors
by Jan Zich, Tomáš Plecháček, Antonín Sojka, Petr Levinský, Jiří Navrátil, Pavlína Ruleová, Stanislav Šlang, Karel Knížek, Jiří Hejtmánek, Vojtěch Nečina and Čestmír Drašar
Crystals 2025, 15(11), 951; https://doi.org/10.3390/cryst15110951 - 3 Nov 2025
Viewed by 426
Abstract
Thermoelectric materials enable the direct conversion of heat into electricity, but progress is often limited by challenges in reproducibility and stability. Bi2O2Se has recently attracted attention as a promising candidate; however, reported transport properties of undoped polycrystalline samples vary [...] Read more.
Thermoelectric materials enable the direct conversion of heat into electricity, but progress is often limited by challenges in reproducibility and stability. Bi2O2Se has recently attracted attention as a promising candidate; however, reported transport properties of undoped polycrystalline samples vary by several orders of magnitude, complicating its use as a baseline for doping studies. In this work, we investigate the sources of variability and identify key factors including precursor contamination, reactions with quartz ampoules and graphite dies, grain size effects, and surface oxidation. To mitigate these issues, we employed calcination of Bi2O3 precursors, synthesis with controlled temperature gradients, coarse-fraction powders, and hot pressing in Si3N4 dies. The resulting polycrystalline Bi2O2Se exhibits improved reproducibility, reduced sensitivity to thermal cycling, and characteristic transport values around σRT ≈ 500 S·m−1 and S ≈ −300 μV·K−1 at room temperature. This is a good starting point for further doping studies and a prerequisite of thermoelectric efficiency studies in the future, which can reveal the true thermoelectric potential of this material. Full article
(This article belongs to the Special Issue Research Progress on Thermoelectric Materials)
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