Biomass Catalytic Conversion to Value-Added Chemicals

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Biomass Catalysis".

Deadline for manuscript submissions: 31 July 2025 | Viewed by 462

Special Issue Editor


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Guest Editor
Key Laboratory of Marine Chemistry Theory and Technology of Ministry of Education, Ocean University of China, Qingdao 266100, China
Interests: biomass; catalysts; graphene; metal-organic frameworks (MOFs); energy
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Special Issue Information

Dear Colleagues,

The catalytic conversion of biomass is a sustainable and environmentally friendly strategy that transforms biomass resources (such as agricultural and forestry waste, organic waste, etc.) into value-added chemicals and fuels, offering a promising solution to global energy and environmental challenges.

This Special Issue focuses on the latest advancements and trends in the field of biomass catalytic conversion, including but not limited to catalytic decomposition, hydrogenation, oxidation, alkylation, and deoxygenation processes. Original research articles related to catalyst design, synthesis, and characterization for biomass conversion are particularly welcome. In addition, submissions related to industrial applications, economic analyses, and net-zero-carbon aspects of biomass catalytic conversion are also encouraged.

If you would like to submit papers for publication in this Special Issue or have any questions, please contact the in-house Editor, Mr. Ives Liu (ives.liu@mdpi.com).

Prof. Dr. Junjie Bian
Guest Editor

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Keywords

  • biomass
  • catalytic conversion
  • value-added chemicals
  • catalysts
  • sustainability

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Published Papers (2 papers)

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Research

12 pages, 2819 KiB  
Article
Hydrogenation of Dodecanoic Acid over Iridium-Based Catalysts
by Heny Puspita Dewi and Shun Nishimura
Catalysts 2025, 15(4), 404; https://doi.org/10.3390/catal15040404 - 21 Apr 2025
Viewed by 196
Abstract
This study develops iridium (Ir)-based catalysts for the hydrogenation of dodecanoic acid, a medium-chain fatty acid abundant in palm kernel and coconut oils, for producing fatty alcohols and alkanes. Among various supports such as AlOOH, SiO2, TiO2, Nb2 [...] Read more.
This study develops iridium (Ir)-based catalysts for the hydrogenation of dodecanoic acid, a medium-chain fatty acid abundant in palm kernel and coconut oils, for producing fatty alcohols and alkanes. Among various supports such as AlOOH, SiO2, TiO2, Nb2O5, MoO3, Ta2O5, ZrO2, and WO3 for 7.5 wt% Ir loading, an Ir-impregnated Nb2O5 (Ir/Nb2O5) catalyst demonstrated remarkable performance with 100% conversion and a high dodecanol yield (89.1%) under mild conditions (170 °C, 4.0 MPa H2), while at higher temperatures and pressures (200 °C, 8.0 MPa H2), Ir-impregnated MoO3 (Ir/MoO3) produced dodecane as the main product with a yield of 90.7%. These findings can tailor product selectivity toward desired bio-based chemicals and fuels, offering sustainable pathways for fatty acid hydrogenation by optimizing catalyst supports and reaction conditions in the Ir-based catalyst. Full article
(This article belongs to the Special Issue Biomass Catalytic Conversion to Value-Added Chemicals)
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16 pages, 6203 KiB  
Article
Application of Clay-Based Catalysts in Co-Conversion and Co-Pyrolysis of Chlorella and Oil Shale
by Xianglong Meng, Ranran Song and Junjie Bian
Catalysts 2025, 15(4), 322; https://doi.org/10.3390/catal15040322 - 27 Mar 2025
Viewed by 268
Abstract
In this study, natural clay-like silicate minerals were used as precursors to prepare highly acid-catalytic hydrophobic catalysts. A series of sulfonic acid-functionalized attapulgite catalysts, SO3H-APG, were fabricated by the ball-milling–oxidation method. The catalytic performance in the co-liquefaction and co-pyrolysis of Chlorella [...] Read more.
In this study, natural clay-like silicate minerals were used as precursors to prepare highly acid-catalytic hydrophobic catalysts. A series of sulfonic acid-functionalized attapulgite catalysts, SO3H-APG, were fabricated by the ball-milling–oxidation method. The catalytic performance in the co-liquefaction and co-pyrolysis of Chlorella and oil shale was investigated. The catalysts were analyzed using hydrophobicity evaluation, TEM, BET, FTIR, and other characterization methods. The SO3H-APG catalysts exhibited good hydrophobicity and dispensability. Sulfonation grafting improved their excellent hydrocarbon conversion activity. According to the GC–MS results, the addition of the SO3H-APG catalysts shifted the co-liquefaction products of microalgae and oil shale towards lower carbon numbers, with the majority of the products concentrated between C5 and C12, and a content of 84.9% in the range of C5–C11, while the content of products in the range of C12–C20 was only 15.1%. In the co-pyrolysis experiments, the addition of the catalysts promoted the thermal decomposition reaction. The synergistic effect between oil shale and microalgae facilitated the production of more hydrocarbon compounds with a higher H/C atomic ratio. The development of this type of catalyst provides an economically favorable approach for the co-conversion of algae and oil shale. The oil shale pyrolysis kinetic diagram shows that adding the APG clay-based catalyst significantly reduces the time for achieving the same conversion rate, especially below 300 °C, where the in situ catalytic effect is most pronounced. Full article
(This article belongs to the Special Issue Biomass Catalytic Conversion to Value-Added Chemicals)
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