Mechanochemistry and Mechanocatalysis

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalysis in Organic and Polymer Chemistry".

Deadline for manuscript submissions: closed (31 March 2025) | Viewed by 1076

Special Issue Editors


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Guest Editor
Centro de Química Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal
Interests: catalyst design; C-scorpionate; single-site heterogeneous catalysis; C-H activation; CO2 fixation; biomass conversion
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Centro de Química Estrutural, Institute of Molecular Sciences, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal
Interests: mechanochemistry; antibiotic coordination frameworks; crystal engineering; supramolecular chemistry
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Centro de Química Estrutural—Institute of Molecular Sciences, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal
Interests: mechanochemistry; heterogeneous catalysis; CO2 fixation and conversion; biomass valorization
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

As Guest Editors, we are pleased to announce this Special Issue, entitled "Mechanochemistry and Mechanocatalysis". We aim to shed light on the transformative role of mechanical forces in driving chemical reactions and catalytic processes. This Special Issue aims to feature groundbreaking research that demonstrates how mechanical energy can replace conventional methods to induce chemical transformations. By bringing together innovative studies on the synthesis of novel materials, the elucidation of reaction mechanisms, and the development of efficient mechanocatalytic systems, we aim to provide a comprehensive understanding of mechanochemistry and mechanocatalysis, fostering progress in this exciting field. A wide range of applications—from sustainable synthesis to advanced materials science—are expected to be covered by this Special Issue, which will certainly highlight how mechanochemical methods can enhance reaction efficiency, selectivity, and environmental sustainability. Hopefully, this Special Issue will be a valuable resource for researchers exploring the potential of mechanical forces in chemical innovation.

If you would like to submit papers for publication in this Special Issue or have any questions, please contact the in-house Editor, Mr. Ives Liu (ives.liu@mdpi.com).

Prof. Dr. Luísa Margarida Martins
Dr. Vânia André
Dr. Ana Paula Da Costa Ribeiro
Guest Editors

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Keywords

  • mechanochemistry
  • liquid-assisted grinding
  • medicinal mechanochemistry
  • flow mechanochemistry
  • reactive milling
  • mechanochemical activation
  • solid-state reactions
  • green chemistry

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Published Papers (1 paper)

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Research

15 pages, 1367 KiB  
Article
Green Chemistry’s Contribution to the Kamal Qureshi Protocol: Comparing Various Activating Modes, the Use of Bentonitic Clay as the Catalyst, and the Use of a Green Solvent
by Amira Jalil Fragoso-Medina, Jesús A. Hernández-Fernández, María Inés Nicolás-Vázquez, Joel Martínez, Adriana Lizbeth Rivera Espejel, María Z. Saavedra-Leos, Francisco Javier Pérez Flores and René Miranda Ruvalcaba
Catalysts 2025, 15(3), 238; https://doi.org/10.3390/catal15030238 - 1 Mar 2025
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Abstract
After attending both the “Decade to Educate in the Sustainable Development and the Agenda 30 of the UNESCO” and the “ACS GCI Pharmaceutical Roundtable”, which focused on sustainable chemistry, in this article, a green chemistry contribution to the Kamal Qureshi protocol is offered; [...] Read more.
After attending both the “Decade to Educate in the Sustainable Development and the Agenda 30 of the UNESCO” and the “ACS GCI Pharmaceutical Roundtable”, which focused on sustainable chemistry, in this article, a green chemistry contribution to the Kamal Qureshi protocol is offered; thus, DIM® and several of its analogs (3,3′-diindolylmethanes) were suitably produced under the green chemistry protocol. In the first stage, the substrate indol-3-yl carbinol was evaluated using mechanochemistry (the best mode) in comparison to other activating methods (near-infrared and microwave electromagnetic irradiation and ultrasound), wishing to highlight the employment of both TAFF®, an excellent and well-characterized natural catalyst (bentonitic clay), and acetone, a green solvent, in addition to the analysis of the procedures in real-time. In the second stage, the mechanochemical methodology was extended to produce a set of fifteen DIMs, in the last stage, the use of a green metric exhibited the greenness of the approach, with it being important to highlight that, to our knowledge, after a search in the literature, this is the first time that the process has been evaluated to demonstrate its greenness. Full article
(This article belongs to the Special Issue Mechanochemistry and Mechanocatalysis)
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