New Frontiers in Organometallic Catalysis

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalysis in Organic and Polymer Chemistry".

Deadline for manuscript submissions: closed (31 October 2022) | Viewed by 6151

Special Issue Editor


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Guest Editor
Inst Super Tecn, Ctr Quim Estrutural, Univ Lisbon, Av Rovisco Pais, P-1049001 Lisbon, Portugal
Interests: catalysis; organometallic chemistry; organic chemistry; sustainable chemistry
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Special Issue Information

Dear Colleagues,

Nowadays, the demand for cost-effective and sustainable methodologies for the activation or synthesis of new molecules, valorization of biomass resources and waste, environmental remediation and energy conversion is continuously growing as a result of industrial and environmental requirements. Catalysts can play a fundamental role when it comes to this subject. This Special Issue embraces original research articles or relevant critical reviews on the recent achievements, current challenges and future opportunities in the field of new frontiers in organometallic catalysis. Submissions are welcome especially (but not exclusively) in the following topics:

  • Molecule activation
  • Development of cost-efficient catalytic methodologies
  • Synthesis of value-added compounds
  • Applications in organic synthesis and pharmaceutical industry
  • Sustainable chemical catalysis
  • Environmental catalysis
  • Valorization of biomass resources and plastic waste
  • Energy conversion
  • Catalytic materials
  • Applications in asymmetric synthesis

Dr. Ana Cristina Fernandes
Guest Editor

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Keywords

  • Molecule activation
  • Development of cost-efficient catalytic methodologies
  • Synthesis of value-added compounds
  • Applications in organic synthesis and pharmaceutical industry
  • Sustainable chemical catalysis
  • Environmental catalysis
  • Valorization of biomass resources and plastic waste
  • Energy conversion
  • Catalytic materials
  • Applications in asymmetric synthesis

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Published Papers (2 papers)

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Research

10 pages, 1573 KiB  
Article
Substrate-Dependent Selectivity in Sc(OTf)3-Catalyzed Cyclization of Alkenoic Acids and N-Protected Alkenamides
by Hailong Zhang, Romain Carlino, Régis Guillot, Richard Gil, Sophie Bezzenine and Jérôme Hannedouche
Catalysts 2022, 12(11), 1481; https://doi.org/10.3390/catal12111481 - 20 Nov 2022
Cited by 2 | Viewed by 2654
Abstract
Five- and six-membered ring lactones and lactams are ubiquitous frameworks in various natural and synthetic molecules and are key building blocks in organic synthesis. Catalytic addition of an O-H or N-H bond across an unactivated C–C double bond is an appealing approach to [...] Read more.
Five- and six-membered ring lactones and lactams are ubiquitous frameworks in various natural and synthetic molecules and are key building blocks in organic synthesis. Catalytic addition of an O-H or N-H bond across an unactivated C–C double bond is an appealing approach to rapidly access such highly valuable N- and O-containing skeletons in a waste-free and 100% atom efficient process. Herein, we report, for the first time, the efficient and high-yield cyclization of δ/ε-alkenoic acids and N-protected δ-alkenamides catalyzedby practical and easily accessible Lewis acid scandium(III) triflate under thermal and microwave conditions. The selectivity outcome of the reaction of δ/ε-alkenoic acids was dependent on the substitution patterns of the backbone chain and alkene moiety, leading to the exclusive formation of either the corresponding γ/δ-lactones via an O-selective cyclization or the Friedel–Crafts-type product by C-selective cyclization. An uncommon and rarely disclosed O-selective cyclization occurred preferentially or exclusively when N-protected δ-alkenamides were engaged in the reaction. The atom selectivity of the cyclization was unambiguously confirmed by single crystal X-ray crystallography. Full article
(This article belongs to the Special Issue New Frontiers in Organometallic Catalysis)
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9 pages, 1993 KiB  
Article
Depolymerization of P4HB and PBS Waste and Synthesis of the Anticancer Drug Busulfan from Plastic Waste
by Daniel L. Lourenço and Ana C. Fernandes
Catalysts 2022, 12(4), 381; https://doi.org/10.3390/catal12040381 - 29 Mar 2022
Cited by 7 | Viewed by 2733
Abstract
Sustainable synthesis of pharmaceuticals is one of the main challenges for the pharmaceutical industry. Production of these compounds from plastic waste can provide an innovative and ecological approach to their sustainable synthesis. In this context, plastic waste can be regarded as a potential [...] Read more.
Sustainable synthesis of pharmaceuticals is one of the main challenges for the pharmaceutical industry. Production of these compounds from plastic waste can provide an innovative and ecological approach to their sustainable synthesis. In this context, plastic waste can be regarded as a potential cheap resource for the production of compounds of interest to the pharmaceutical industry. In this work, the first methodologies for the reductive depolymerization of poly(4-hydroxybutyrate) (P4HB) and polybutylene succinate (PBS) plastic waste are reported using the catalyst systems MoO2Cl2(H2O)2/silane, MoO2Cl2(H2O)2/borane and KOH/PhSiH3 with moderate to excellent yields. We also developed the first synthetic strategy for the synthesis of a drug, the anticancer busulfan, from P4HB and PBS plastic waste with moderate overall yields. Full article
(This article belongs to the Special Issue New Frontiers in Organometallic Catalysis)
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