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7 November 2020

Research on the Influence of Carbonation on the Content and State of Chloride Ions and the Following Corrosion Resistance of Steel Bars in Cement Paste

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1
School of Civil and Environmental Engineering, Ningbo University, Ningbo 315000, China
2
School of Civil Engineering, Sichuan College of Architectural Technology, Deyang 618000, China
3
School of Construction Engineering, Qingdao Agricultural University, Qingdao 266000, China
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This article belongs to the Special Issue Interface and Surface Modification for Durable Concretes

Abstract

In this paper, the changes of free chloride ion concentration and bound chloride concentration in cement paste with different total and proportion of mineral admixtures under carbonation were studied. Moreover, the following corrosion resistance of steel bars buried in cement paste under carbonation was researched by testing the electrical resistance and alternating current (AC) impedance spectroscopy of reinforced cement paste. Results indicated that fly ash and granulated blast furnace slag powder with the content less than 20% by mass ratio of total binder hindered the solidification of chloride ions in cement-based materials, and blast furnace slag powder with the content higher than 20% promoted the solidification of chloride ions in cement paste. The carbonation effect was able to decrease the amount of solidified chloride ion and increase the amount of free chloride ions leading to accelerating the corrosion of reinforcement. Meanwhile, the blast furnace slag powder with the content higher than 20% could effectively promote the corrosion resistance of steel bars.

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