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Magnetism, Volume 5, Issue 1 (March 2025) – 9 articles

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29 pages, 719 KiB  
Article
State Transitions and Hysteresis in a Transverse Magnetic Island Chain
by Gary M. Wysin
Magnetism 2025, 5(1), 9; https://doi.org/10.3390/magnetism5010009 - 12 Mar 2025
Viewed by 326
Abstract
A chain of dipole-coupled elongated magnetic islands whose long axes are oriented perpendicular to the chain is studied for its magnetization properties. With a magnetic field applied perpendicular to the chain, the competition between dipolar energy, shape anisotropy, and field energy leads to [...] Read more.
A chain of dipole-coupled elongated magnetic islands whose long axes are oriented perpendicular to the chain is studied for its magnetization properties. With a magnetic field applied perpendicular to the chain, the competition between dipolar energy, shape anisotropy, and field energy leads to three types of uniform states with distinct magnetizations: (1) oblique to the chain, (2) perpendicular to the chain, and (3) zero due to having alternating dipoles. The response of these states to a slowly varying field is analyzed, focusing on their stability limits and related oscillation modes, and the dependencies on the dipolar and anisotropy constants. Based on identifiable transitions among the three states and their instability points, the theoretically predicted zero-temperature magnetization curves show significant dependence on the anisotropy. The model suggests a path for designing advanced materials with desired magnetic properties. Different geometries and magnetic media for the islands are considered. Full article
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18 pages, 5243 KiB  
Article
Simultaneous Spin and Point-Group Adaptation in Exact Diagonalization of Spin Clusters
by Shadan Ghassemi Tabrizi and Thomas D. Kühne
Magnetism 2025, 5(1), 8; https://doi.org/10.3390/magnetism5010008 - 12 Mar 2025
Viewed by 438
Abstract
While either a spin or point-group adaptation is straightforward when considered independently, the standard technique for factoring isotropic spin Hamiltonians by the total spin S and the irreducible representation Γ of the point group is limited by the complexity of the transformations between [...] Read more.
While either a spin or point-group adaptation is straightforward when considered independently, the standard technique for factoring isotropic spin Hamiltonians by the total spin S and the irreducible representation Γ of the point group is limited by the complexity of the transformations between different coupling schemes that are related in terms of their site permutations. To overcome these challenges, we apply projection operators directly to uncoupled basis states, enabling the simultaneous treatment of spin and point-group symmetry without the need for recoupling transformations. This provides a simple and efficient approach for the exact diagonalization of isotropic spin models, which we illustrate, with applications in Heisenberg spin rings and polyhedra, including systems that are computationally inaccessible with conventional coupling techniques. Full article
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12 pages, 3181 KiB  
Article
Selection of a Suitable Conductor for Inductive Power Transfer
by Tanguy Phulpin, Rym Boulahbel, Hafaliana Randrianjanaka and Yann Leroy
Magnetism 2025, 5(1), 7; https://doi.org/10.3390/magnetism5010007 - 7 Mar 2025
Viewed by 434
Abstract
Inductive Power Transfer (IPT) is evolving fast in many domains, but its efficiency, its extensive resource requirements, and its cost remain crucial problems for its development. Although the inverter is mainly responsible for its cost and material consumption, a considerable quantity of conductors [...] Read more.
Inductive Power Transfer (IPT) is evolving fast in many domains, but its efficiency, its extensive resource requirements, and its cost remain crucial problems for its development. Although the inverter is mainly responsible for its cost and material consumption, a considerable quantity of conductors is required for the coupling realization. Therefore, A drastic cost reduction is possible when comparing the traditional most efficient copper Litz wire with aluminum conductors for a similar volume and a lighter embedded system. However, alternative ribbon wire solutions are also characterized and seem promising as substitutes for such applications. First, standard electrical efficiency is evaluated for all cases, before the price and weight. To complement the results and as the alternative couplers imply different materials and production processes, a Life Cycle Assessment is performed. A comparison is carried out on copper and aluminum litz wires and copper and aluminum ribbons. Results demonstrate the promising interest in industrial application of such study, furthermore for systems requiring many couplers as Dynamic IPT (DIPT). Full article
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15 pages, 1020 KiB  
Article
The Role of Blood Perfusion in the Thermal Interaction Between Magnetic Nanoparticles and Cancerous Tumors: A Computational Study
by Nikolaos Maniotis, Spyridon Mitropoulos, Nikolaos Vordos and Vassilios Tsiantos
Magnetism 2025, 5(1), 6; https://doi.org/10.3390/magnetism5010006 - 5 Mar 2025
Viewed by 559
Abstract
In this study, the role of blood perfusion in modulating the thermal response of tumors during magnetic nanoparticle hyperthermia was investigated through computational modeling. The thermal dissipation of 15 nm magnetite nanoparticles was estimated using micromagnetic simulations of their hysteresis loops under a [...] Read more.
In this study, the role of blood perfusion in modulating the thermal response of tumors during magnetic nanoparticle hyperthermia was investigated through computational modeling. The thermal dissipation of 15 nm magnetite nanoparticles was estimated using micromagnetic simulations of their hysteresis loops under a magnetic field of 20 mT and a frequency of 100 kHz. These calculations provided precise energy loss parameters, serving as inputs to simulate the temperature distribution in a tumor embedded within healthy tissue. Temperature-dependent blood perfusion rates, derived from experimental models, were integrated to differentiate the vascular dynamics in normal and cancerous tissues. The simulations were conducted using a bioheat transfer model on a 2D axisymmetric tumor geometry with magnetite nanoparticles dispersed uniformly in the tumor volume. Results showed that tumor tissues exhibit limited blood perfusion enhancement under hyperthermic conditions compared to healthy tissues, leading to localized heat retention favorable for therapeutic purposes. The computational framework validated these findings by achieving therapeutic tumor temperatures (41–45 °C) without significant overheating of surrounding healthy tissues, highlighting the critical interplay between perfusion and energy dissipation. These results demonstrate the efficacy of combining nanoparticle modeling with temperature-dependent perfusion for optimizing magnetic nanoparticle-based hyperthermia protocols. Full article
(This article belongs to the Special Issue Mathematical Modelling and Physical Applications of Magnetic Systems)
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15 pages, 2932 KiB  
Article
Microstructural and Magnetic Properties of Polyamide-Based Recycled Composites with Iron Oxide Nanoparticles
by Lucas G. Dos Santos, Daina D. A. Buelvas, Daniel F. Valezi, Bruno L. S. Vicentin, Christian M. M. Rocha, Eduardo Di Mauro and Felipe de A. La Porta
Magnetism 2025, 5(1), 5; https://doi.org/10.3390/magnetism5010005 - 25 Feb 2025
Viewed by 633
Abstract
This study explores a sustainable approach to developing magnetic nanocomposites by synthesizing a mixed-phase iron oxide (IO) and recycled polyamide (RPA) composite from textile waste. The RPA/IO nanocomposite’s microstructural and magnetic properties were characterized using X-ray diffraction (XRD) with Rietveld refinement, scanning, transmission [...] Read more.
This study explores a sustainable approach to developing magnetic nanocomposites by synthesizing a mixed-phase iron oxide (IO) and recycled polyamide (RPA) composite from textile waste. The RPA/IO nanocomposite’s microstructural and magnetic properties were characterized using X-ray diffraction (XRD) with Rietveld refinement, scanning, transmission electron microscopy (SEM, TEM), and vibrating sample magnetometry (VSM). The proportions of the Fe3O4 and γ-Fe2O3 phases were found to be 23.2 wt% and 76.8 wt%, respectively. SEM and TEM showed a porous, agglomerated IO surface morphology with an average particle size of 14 nm. Magnetic analysis revealed ferrimagnetic and superparamagnetic behavior, with VSM showing saturation magnetization values of 21.81 emu g−1 at 5 K and 18.84 emu g−1 at 300 K. Anisotropy constants were estimated at 4.28 × 105 and 1.53 × 105, respectively, for IO and the composite, with a blocking temperature of approximately 178 K at 300 K. These results contribute to understanding the magnetic behavior of IO and their nanocomposites, which is crucial for their potential applications in emerging technologies. Full article
(This article belongs to the Special Issue Magnetism and Correlations in Nanomaterials)
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26 pages, 3464 KiB  
Article
A Model-Based Method Applying Sliding Mode Methodology for SynRM Sensorless Control
by Vasilios C. Ilioudis
Magnetism 2025, 5(1), 4; https://doi.org/10.3390/magnetism5010004 - 4 Feb 2025
Cited by 1 | Viewed by 632
Abstract
In this paper, a new sensorless approach is proposed to address the speed and position estimation of the Synchronous Reluctance Machine (SynRM). The design of the sensorless control algorithm is developed on the basis of the modified SynRM mathematical model employing a simple [...] Read more.
In this paper, a new sensorless approach is proposed to address the speed and position estimation of the Synchronous Reluctance Machine (SynRM). The design of the sensorless control algorithm is developed on the basis of the modified SynRM mathematical model employing a simple sliding mode observer (SMO) and a modified EMF observer that are connected in series. All variables of the modified SynRM model are expressed in the arbitrary rotating frame, which is the so-called estimated γδ reference frame. The derived modified rotor flux terms contain angle error information in the form of trigonometric functions. Initially, the modified rotor flux is expressed as a function of saliency and the stator current id, including the angular deviation between the dq and γδ reference frames, which are rotating at synchronous and estimated speeds, respectively. A suitably designed SMO is utilized to estimate the modified stator flux components in the γδ reference frame. Once the SMO operates in sliding mode, the derived equivalent control inputs of the flux/current observer are used to obtain the required angular position and speed information of rotor by means of the modified EMF and Speed/Position observer. Only measures of stator voltages and currents are required for the speed and position estimation. In addition, Lyapunov Candidate Functions (LCFs) have been applied to determine the sliding mode existence conditions and the gains of the modified EMF observer. The SynRM observer–controller system is tested and evaluated in a wide speed range, even at very low speeds, in the presence of torque load disturbances. Simulation results demonstrate the overall efficacy and robustness of the proposed sensorless approach. Moreover, simulation tests verify the fast convergence and high performance of the modified EMF/speed/angle observer. Full article
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16 pages, 5848 KiB  
Article
Recovery of Neodymium from Spent Hard Disk Drivers by Microwave Treatment and Magnesium Liquid Extraction
by Sabina Andreea Fironda, Ioana Cristina Badea, Marian Burada, Radu-Robert Piticescu and Lidia Licu
Magnetism 2025, 5(1), 3; https://doi.org/10.3390/magnetism5010003 - 30 Jan 2025
Viewed by 895
Abstract
Rare earth elements (REEs) possess unique physical and chemical properties that render them indispensable in various industries, including electronics, energy production and storage, hybrid and electric vehicles, metallurgy, and petro-chemical processing. The criticality of REE underscores the need to enhance the efficiency of [...] Read more.
Rare earth elements (REEs) possess unique physical and chemical properties that render them indispensable in various industries, including electronics, energy production and storage, hybrid and electric vehicles, metallurgy, and petro-chemical processing. The criticality of REE underscores the need to enhance the efficiency of primary resource extraction and promote circularity through increased recycling from secondary sources. This paper provides a brief overview of REE recovery from secondary sources, particularly waste from electronic and electric equipment (WEEE). The discussion encompasses direct reuse of magnets, short-loop recycling (direct recycling), hydro- and pyrometallurgical processes, highlighting microwave (MW) technology. Original results are presented, focusing on the recovery of neodymium (Nd) from permanent magnet scraps from hard disk drives (HDD-PC) using microwave-assisted liquid metal extraction (LME) with magnesium (Mg) as the extractant. The subsequent separation of Nd from the Mg-Nd alloy via vacuum Mg distillation that is reused in the process is described. The experimental study demonstrates that the LME process, conducted in a microwave furnace, is a viable method for recovering Nd from permanent magnet scraps, which are essential for reducing the environmental impact of REE extraction and promoting a circular economy. By separating Nd from the alloy through vacuum distillation (450–550 mmHg), at temperatures of 850–900 °C for 8 h, a Nd sponge with a content of 95–98 wt.% Nd was obtained. The extracted content of Nd in the Mg alloy increases with increasing temperature and holding time. It was found that ≈ 97% of the Nd in the scrap was extracted from 2 to 5 mm crushed scrap at 800 °C for 8 h, using a LiF-LiCl-MgF2 protecting flux in a furnace Ar atmosphere. Full article
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17 pages, 7389 KiB  
Article
Quadruple-Q Skyrmion Crystal in Centrosymmetric Body-Centered Tetragonal Magnets
by Satoru Hayami
Magnetism 2025, 5(1), 2; https://doi.org/10.3390/magnetism5010002 - 17 Jan 2025
Viewed by 862
Abstract
We conduct a numerical investigation into the stability of a quadruple-Q skyrmion crystal, a structure generated by the superposition of four spin density waves traveling in distinct directions within three-dimensional space, hosted on a centrosymmetric body-centered tetragonal lattice. Using simulated annealing applied [...] Read more.
We conduct a numerical investigation into the stability of a quadruple-Q skyrmion crystal, a structure generated by the superposition of four spin density waves traveling in distinct directions within three-dimensional space, hosted on a centrosymmetric body-centered tetragonal lattice. Using simulated annealing applied to an effective spin model that includes momentum-resolved bilinear and biquadratic interactions, we construct a magnetic phase diagram spanning a broad range of model parameters. Our study finds that a quadruple-Q skyrmion crystal does not emerge within the phase diagram when varying the biquadratic interaction and external magnetic field. Instead, three distinct quadruple-Q states with topologically trivial spin textures are stabilized. However, we demonstrate that the quadruple-Q skyrmion crystal can become the ground state when an additional high-harmonic wave–vector interaction is considered. Depending on the magnitude of this interaction, we obtain two types of quadruple-Q skyrmion crystals exhibiting the skyrmion numbers of one and two. These findings highlight the emergence of diverse three-dimensional multiple-Q spin states in centrosymmetric body-centered tetragonal magnets. Full article
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13 pages, 3902 KiB  
Article
A Study on the Effect of Plastic Strain on Magnetic Phenomenology and Microstructure
by Mehrija Hasičić, Spyridon Angelopoulos, Aphrodite Ktena and Evangelos Hristoforou
Magnetism 2025, 5(1), 1; https://doi.org/10.3390/magnetism5010001 - 14 Jan 2025
Viewed by 659
Abstract
The present work aspires to contribute to the discussion on the relationship between macroscopic measurements and microstructure, helping establish a methodology that will allow the quantitative assessment of the effect of strain on magnetic properties in the plastic deformation regime. In particular, we [...] Read more.
The present work aspires to contribute to the discussion on the relationship between macroscopic measurements and microstructure, helping establish a methodology that will allow the quantitative assessment of the effect of strain on magnetic properties in the plastic deformation regime. In particular, we study the effect of strain on the magnetization process as a result of varying the anisotropy profile at the grain level. Results on micromagnetic calculations of hysteresis loops for various configurations of magnetic anisotropy are shown and discussed against the interplay between the energy terms involved in the calculations, namely anisotropy, demagnetizing, and exchange. The results are in line with previously obtained results using vector Preisach modeling with the Stoner–Wohlfarth model acting both as a switching and rotation mechanism. The hysteresis loop phenomenology is consistent with the emergence of a hard phase in the form of a boundary around soft grains which is assumed to be the result of the onset of compressive stresses in the plastic region. Future research will be oriented toward the study of the effect of the secondary peak in differential permeability, which is observed experimentally in the plastic deformation region, and its dependence on the angle of misalignment between the hard boundary and the soft grain. Full article
(This article belongs to the Special Issue Mathematical Modelling and Physical Applications of Magnetic Systems)
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