Thermo, Volume 5, Issue 2 (June 2025) – 8 articles

Based on the First and the Second laws of Thermodynamics the energy dissipated in engineering materials and structures is calculated in a multidimensional mechanics framework. The existing practice of computing the dissipated energy by the area of the stress-strain (or force-displacement) curve is objected to. The conditions under which the area of a stress-strain diagram correctly measures the dissipated energy are derived and clearly presented. A general mathematical form for the dissipated energy when those conditions are not satisfied is provided. An internal variables formulation is employed in this work. Erroneous results from the literature calculating the dissipated energy are given. Erroneous calculations are abundant in publications, Theses and Dissertations, books, and even engineering codes. The terms hysteresis and hysteretic loss are technically explained and their wrong use in cases other than in viscoelasticity is explicated. Full article

This study investigates the effects of varying hydrogen percentages in fuel blends on combustion dynamics, engine performance, and emissions. Experimental data and analytical equations were used to evaluate combustion parameters such as equivalent lambda, in-cylinder pressure, heat release rate, and ignition timing. The findings demonstrate that hydrogen blending enhances combustion stability, shortens ignition delay, and shifts peak heat release to be closer to the top dead center (TDC). These changes improve thermal efficiency and reduce cycle-to-cycle variation. Hydrogen blending also significantly lowers carbon dioxide (CO₂) and hydrocarbon (HC) emissions, particularly at higher blend levels (H0–H5), while lower blends increase nitrogen oxides (NO_x) emissions and risk pre-ignition due to advanced start of combustion (SOC). Engine performance improved with an average hydrogen energy contribution of 12% under a constant load. However, the optimal hydrogen blending range is crucial to balancing efficiency gains and emission reductions. These results underline the potential of hydrogen as a cleaner additive fuel and the importance of optimizing blend ratios to harness its benefits effectively. Full article

A crucial stage in the post-harvest processing of cocoa beans, drying, has a direct effect on the finished product’s quality and market value. This study investigates the efficiency, quality outcomes, and environmental implications of a mixed forced convection solar dryer designed for drying cocoa beans in Ntui, Cameroon, compared to traditional open-air drying methods. The solar dryer’s design, incorporating a solar collector, forced ventilation, and thermal storage, leverages local materials and renewable energy, offering an environmentally sustainable alternative by reducing fossil fuel reliance and post-harvest losses. Experimental trials were conducted to assess key drying parameters, including the temperature, relative humidity, water removal rate, pH, and free fatty acid (FFA) content, under the equatorial climate conditions of high solar irradiation and humidity. Results demonstrate that the solar dryer significantly reduces drying time from an average of 4.83 days in open-air drying to 2.5 days, a 50% improvement, while maintaining optimal conditions for bean quality preservation. The solar-dried beans exhibited a stable pH (5.7–5.9), a low FFA content (0.282% oleic acid equivalent, well below the EU standard of 1.75%), and superior uniformity in texture and color, meeting international quality standards. In contrast, open-air drying showed greater variability in quality due to weather dependencies and contamination risks. The study highlights the dryer’s adaptability to equatorial climates and its potential to enhance cocoa yields and quality for small-scale producers. These findings underscore the viability of solar drying as a high-performance, eco-friendly solution, paving the way for its optimization and broader adoption in cocoa-producing regions. This research contributes to the growing body of knowledge on sustainable drying technologies, addressing both economic and environmental challenges in tropical agriculture. Full article

In the age of widespread renewable energy integration, coal-fired power plants are transitioning from a primary baseload role to a more flexible peak-shaving capacity. Under frequent load changes, the thermal efficiency will significantly decrease. In order to achieve efficient dynamic operation, this study proposes a comprehensive mechanical model of a 300 MW drum-type boiler. Based on the Modelica/DYMOLA platform, the multi-domain equations describing energy and mass balance are programmed and solved. A comprehensive evaluation of the energy transformation within the boiler’s heat exchange components was performed. Utilizing the principles of exergy analysis, this study investigates how fluctuating operational conditions impact the energy dynamics and exergy losses in the drum and heating surfaces. Steady-state simulation reveals that the evaporator and superheater units account for 81.3% of total exergy destruction. Dynamic process analysis shows that the thermal inertia induced by the drum wall results in a significant delay in heat transfer quantity, with a dynamic period of up to 5000 s. The water wall exhibits the highest total dynamic exergy destruction at 9.5 GJ, with a destruction rate of 7.9–8.5 times higher than other components. Full article

Thermal modelling of additive manufacturing is a key method for furthering the quality of the components produced, as it allows for analysis that is not possible via experimental methods due to the difficulties involved with in situ monitoring. The thermal gradients present during the additive manufacturing process have a large impact on the formation of defects, such as porosity, residual stress, and cracking. The thermal gradients also have a large impact on material properties by controlling the microstructure formed. Thermal modelling methods are often based on numerical solutions of the heat conduction equation. Whilst numerical methods can be more accurate, they are often very slow because of the fine mesh requirements to capture high thermal gradients and iterative solvers to approximate the real-world solution to the required thermal field equations. An analytical model was developed to provide a fast solution to the problem. The analytical model used in this research was based on the Rosenthal equation and was analysed under a range of process parameters. A temperature-dependent Rosenthal model was also created with the aim of improving the results. The analytical model was then compared with a finite element numerical model to act as verification for the results. The analytical model accurately predicted the meltpool width over a range of process conditions. The analytical model underestimated the meltpool length compared to the numerical model, especially at high velocities. When using the standard Rosenthal model, the use of room-temperature or high-temperature thermal conductivities underestimated or overestimated the cooling rates from the meltpool, respectively. A temperature-dependent Rosenthal model was shown to produce more accurate cooling rates compared to the original Rosenthal equation. Full article

Passive solar desalination with no discharge promises great potential for sustainable desalination. Herein, we provide a comprehensive modelling scheme for the investigation of coupled heat and mass transport in passive desalination devices. Our modelling approach integrates mass, momentum, species, and energy transport models to study the coupled phenomena of wicking, solar-driven evaporation, and salt precipitation. Our numerical model can predict the impact of spatiotemporal variation in temperature, salt concentration, and wicking velocity on the evaporation flux and thermal efficiency of solar evaporators. The impact of the evaporator’s shape, solar flux, salt concentration, and light reflection by salt crystals has been studied on the evaporator’s performance. We observed a two-fold increase in evaporation flux when solar irradiance increases from 1000 W/m² to 2500 W/m². A reduction in the thermal efficiency of the evaporators is predicted at higher solar fluxes. The modelled evaporator can achieve an evaporation flux of over 0.5 kg/m²h under 1000 W/m² for 3.5 wt.% saline water. The salt concentration along the z-position of the evaporator exhibited a double arch-shaped profile, which influences its evaporation performance. These findings provide vital guidelines for the design of high-throughput solar desalination systems. Full article

Energy transition is a challenge for remote northern communities mainly relying on diesel for electricity generation and space heating. Solar-assisted ground-coupled heat pump (SAGCHP) systems represent an alternative that was investigated in this study for the Kuujjuaq Forum, a multi-activity facility in Nunavik, Canada. The energy requirements of community buildings facing a subarctic climate are poorly known. Based on energy bills, technical documents, and site visits, this study provided an opportunity to better document the energy consumption of such building, especially considering the recent solar photovoltaic (PV) system installed on part of the roof. A comprehensive model was developed to analyze the building’s heating demand and simulate the performance of a ground-source heat pump (GSHP) coupled with PV panels. The air preheating load, accounting for 268,200 kWh and 47% of the total heating demand, was identified as an interesting and realistic load that could be met by SAGCHP. The GSHP system would require a total length of at least 8000 m, with boreholes at depths between 170 and 200 m to meet this demand. Additional PV panels covering the entire roof could supply 30% of the heat pump’s annual energy demand on average, with seasonal variations from 22% in winter to 53% in spring. Economic and environmental analysis suggest potential annual savings of CAD 164,960 and 176.7 tCO₂eq emissions reduction, including benefits from exporting solar energy surplus to the local grid. This study provides valuable insights on non-residential building energy consumption in subarctic conditions and demonstrates the technical viability of SAGCHP systems for large-scale applications in remote communities. Full article

In this study, a thin film of silicon carbide (SiC) was deposited on a porous silicon (P-Si) substrate using pulsed laser deposition (PLD). The photo–electrochemical etching method with an Nd: YAG laser at 1064 nm wavelength and 900 mJ pulse energy and at a vacuum of 10⁻² mbar P-Si was utilized to create a sufficiently high amount of surface area for SiC film deposition to achieve efficient SiC film growth on the P-Si substrate. X-ray diffraction (XRD) analysis was performed on the crystalline structure of SiC and showed high-intensity peaks at the (111) and (220) planes, indicating that the substrate–film interaction is substantial. Surface roughness particle topography was examined via atomic force microscopy (AFM), and a mean diameter equal to 72.83 nm was found. Field emission scanning electron microscopy (FESEM) was used to analyze surface morphology, and the pictures show spherical nanoparticles and a mud-sponge-like shape demonstrating significant nanoscale features. Photoluminescence and UV-Vis spectroscopy were utilized to investigate the optical properties, and two emission peaks were observed for the SiC and P-Si substrates, at 590 nm and 780 nm. The SiC/P-Si heterojunction photodetector exhibited rectification behavior in its dark I–V characteristics, indicating high junction quality. The spectral responsivity of the SiC/P-Si observed a peak responsivity of 0.0096 A/W at 365 nm with detectivity of 24.5 A/W Jones, and external quantum efficiency reached 340%. The response time indicates a rise time of 0.48 s and a fall time of 0.26 s. Repeatability was assured by the tight clustering of the data points, indicating the good reproducibility and stability of the SiC/P-Si deposition process. Linearity at low light levels verifies efficient photocarrier generation and separation, whereas a reverse saturation current at high intensities points to the maximum carrier generation capability of the device. Moreover, Raman spectroscopy and energy dispersive spectroscopy (EDS) analysis confirmed the structural quality and elemental composition of the SiC/P-Si film, further attesting to the uniformity and quality of the material produced. This hybrid material’s improved optoelectronic properties, achieved by combining the stability of SiC with the quantum confinement effects of P-Si, make it useful in advanced optoelectronic applications such as UV-Vis photodetectors. Full article