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Inorganics, Volume 4, Issue 3

2016 September - 8 articles

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Articles (8)

  • Article
  • Open Access
20 Citations
7,635 Views
17 Pages

Optical Properties of Heavily Fluorinated Lanthanide Tris β-Diketonate Phosphine Oxide Adducts

  • Adam N. Swinburne,
  • Madeleine H. Langford Paden,
  • Tsz Ling Chan,
  • Simon Randall,
  • Fabrizio Ortu,
  • Alan M. Kenwright and
  • Louise S. Natrajan

20 September 2016

The construction of lanthanide(III) chelates that exhibit superior photophysical properties holds great importance in biological and materials science. One strategy to increase the luminescence properties of lanthanide(III) chelates is to hinder comp...

  • Communication
  • Open Access
9 Citations
4,874 Views
7 Pages

Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine

  • Christine A. Bange,
  • Neil T. Mucha,
  • Morgan E. Cousins,
  • Abigail C. Gehsmann,
  • Anna Singer,
  • Taylor Truax,
  • Lee J. Higham and
  • Rory Waterman

Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine 8-[(4-phosphino)phenyl]-4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene furnishes fluorescent phosphine pro...

  • Article
  • Open Access
8 Citations
6,530 Views
14 Pages

The Trans Influence in Unsymmetrical Pincer Palladacycles: An Experimental and Computational Study

  • Sarote Boonseng,
  • Gavin W. Roffe,
  • Rhiannon N. Jones,
  • Graham J. Tizzard,
  • Simon J. Coles,
  • John Spencer and
  • Hazel Cox

A library of unsymmetrical SCN pincer palladacycles, [ClPd{2-pyr-6-(RSCH2)C6H3}], R = Et, Pr, Ph, p-MePh, and p-MeOPh, pyr = pyridine, has been synthesized via C–H bond activation, and used, along with PCN and N’CN unsymmetrical pincer palladacycles...

  • Article
  • Open Access
9 Citations
6,081 Views
10 Pages

Composite materials, which can optimally use the advantages of different materials, have been studied extensively. Herein, hybrid tungsten nitride and oxide (WN/WO3) composites were prepared through a simple aqueous solution route followed by nitridi...

  • Article
  • Open Access
4 Citations
5,267 Views
9 Pages

Nanocomposites of ordered mesoporous carbon associated with chromium nitride (CrN) or vanadium nitride (VN) nanoparticles were obtained by a simple one-pot synthesis based on the solvent evaporation induced self-assembly (EISA) process using Pluronic...

  • Article
  • Open Access
14 Citations
6,279 Views
9 Pages

Recently, homogeneous cobalt systems were reported to catalyze the reductive silylation of dinitrogen. In this study the investigations on the silylation of dinitrogen catalyzed by CoH(PPh3)3N2 are presented. We show that in the presence of the title...

  • Communication
  • Open Access
8 Citations
6,026 Views
9 Pages

We have here synthesized new chiral Schiff base Ni(II), Cu(II), Zn(II) complexes (Ni, Cu, Zn) and hybrid materials with azobenzene (AZ) in polymethyl methacrylate (PMMA). Linearly polarized UV light irradiation of these hybrid materials slightly incr...

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Inorganics - ISSN 2304-6740