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Crystals 2018, 8(2), 50; https://doi.org/10.3390/cryst8020050

Super-Lattice Structure and Phase Evolution of Pb(Lu0.5Nb0.5)O3-PbTiO3 Single Crystal with Low PbTiO3

Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
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Received: 29 November 2017 / Revised: 19 January 2018 / Accepted: 20 January 2018 / Published: 23 January 2018
(This article belongs to the Special Issue Crystal Growth for Optoelectronic and Piezoelectric Applications)
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Abstract

The phase diagram of the Pb(Lu0.5Nb0.5)O3-PbTiO3 (PLN-PT) binary system was previously reported based on XRD and dielectric measurements results. Unusually, the Curie temperature of PLN-PT with low PT obtained from the phase diagram is much lower than that of PLN and PT end members, which is different from others, such as PZT. Therefore, the complex structure of PLN-PT with low PT is desired to be studied. In this work, PLN-PT single crystals with low PT were grown for the study of their super-lattice structure and phase evolution. The super-lattice reflections were identified by X-ray diffraction. Domains and their evolution by heating from room temperature to 150 °C were observed under a polarized light microscope. The phase transition from the ferroelectric phase to the paraelectric phase was determined by dielectric spectra and polarized light microscopy. A precursor/intermediate phase exhibiting pinched hysteresis loops was displayed above the Curie temperature, which originates from some polar region embedded in the non-polar matrix. The coexistence of the ferroelectric and antiferroelectric domains leads to peculiarities of the phase transitions, such as a lower Curie temperature compared with PLN and PT. The studies of the phase evolution of PLN-PT with low PT single crystal is a supplementary amendment of the PLN-PT phase diagram as previously reported. View Full-Text
Keywords: antiferroelectric; super-lattice; phase diagram; single crystals antiferroelectric; super-lattice; phase diagram; single crystals
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Liu, Y.; Yang, X.; He, C.; Li, X.; Wang, Z.; Long, X. Super-Lattice Structure and Phase Evolution of Pb(Lu0.5Nb0.5)O3-PbTiO3 Single Crystal with Low PbTiO3. Crystals 2018, 8, 50.

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