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Nanostructured Oxides Synthesised via scCO2-Assisted Sol-Gel Methods and Their Application in Catalysis

Chemical Engineering Group, Engineering and Technology Institute Groningen (ENTEG), University of Groningen, Nijenborgh 4, Groningen 9747, The Netherlands
Author to whom correspondence should be addressed.
Catalysts 2018, 8(5), 212;
Received: 2 April 2018 / Revised: 3 May 2018 / Accepted: 9 May 2018 / Published: 17 May 2018
(This article belongs to the Special Issue Sol–Gel Chemistry: A Toolbox for Catalyst Preparation)
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Nanostructured metal oxides and silicates are increasingly applied in catalysis, either as supports or as active species in heterogeneous catalysts, owing to the physicochemical properties that typically distinguish them from bulk oxides, such as higher surface area and a larger fraction of coordinatively unsaturated sites at their surface. Among the different synthetic routes for preparing these oxides, sol-gel is a relatively facile and efficient method. The use of supercritical CO2 (scCO2) in the sol-gel process can be functional to the formation of nanostructured materials. The physical properties of the scCO2 medium can be controlled by adjusting the processing temperature and the pressure of CO2, thus enabling the synthesis conditions to be tuned. This paper provides a review of the studies on the synthesis of oxide nanomaterials via scCO2-assisted sol-gel methods and their catalytic applications. The advantages brought about by scCO2 in the synthesis of oxides are described, and the performance of oxide-based catalysts prepared by scCO2 routes is compared to their counterparts prepared via non-scCO2-assisted methods. View Full-Text
Keywords: nanostructured oxides; supercritical CO2; sol-gel; catalysis nanostructured oxides; supercritical CO2; sol-gel; catalysis

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Tao, Y.; Pescarmona, P.P. Nanostructured Oxides Synthesised via scCO2-Assisted Sol-Gel Methods and Their Application in Catalysis. Catalysts 2018, 8, 212.

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