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Open AccessArticle

Selective Hydrogenation of m-Dinitrobenzene to m-Nitroaniline over Ru-SnOx/Al2O3 Catalyst

1
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
2
Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
*
Author to whom correspondence should be addressed.
Catalysts 2014, 4(3), 276-288; https://doi.org/10.3390/catal4030276
Received: 19 May 2014 / Revised: 23 June 2014 / Accepted: 25 June 2014 / Published: 14 July 2014
(This article belongs to the Special Issue Metal Catalysts Recycling and Heterogeneous/Homogeneous Catalysis)
Series catalysts of Ru-SnOx/Al2O3 with varying SnOx loading of 0–3 wt% were prepared, and their catalytic activity and selectivity have been discussed and compared for the selective hydrogenation of m-dinitrobenzene (m-DNB) to m-nitroaniline (m-NAN). The Ru-SnOx/Al2O3 catalysts were characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM) and hydrogen temperature-programmed reduction (H2-TPR) and desorption (H2-TPD). Under the modification of SnOx, the reaction activity increased obviously, and the best selectivity to m-NAN reached above 97% at the complete conversion of m-DNB. With the increasing of the SnOx loading, the amount of active hydrogen adsorption on the surface of the catalyst increased according to the H2-TPD analysis, and the electron transferred from Ru to SnOx species, as determined by XPS, inducing an electron-deficient Ru, which is a benefit for the absorption of the nitro group. Therefore, the reaction rate and product selectivity were greatly enhanced. Moreover, the Ru-SnOx/Al2O3 catalyst presented high stability: it could be recycled four times without any loss in activity and selectivity. View Full-Text
Keywords: Ru catalyst; SnOx doping; hydrogenation; m-dinitrobenzene; m-nitroaniline; catalyst recycling Ru catalyst; SnOx doping; hydrogenation; m-dinitrobenzene; m-nitroaniline; catalyst recycling
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MDPI and ACS Style

Cheng, H.; Lin, W.; Li, X.; Zhang, C.; Zhao, F. Selective Hydrogenation of m-Dinitrobenzene to m-Nitroaniline over Ru-SnOx/Al2O3 Catalyst. Catalysts 2014, 4, 276-288. https://doi.org/10.3390/catal4030276

AMA Style

Cheng H, Lin W, Li X, Zhang C, Zhao F. Selective Hydrogenation of m-Dinitrobenzene to m-Nitroaniline over Ru-SnOx/Al2O3 Catalyst. Catalysts. 2014; 4(3):276-288. https://doi.org/10.3390/catal4030276

Chicago/Turabian Style

Cheng, Haiyang; Lin, Weiwei; Li, Xiaoru; Zhang, Chao; Zhao, Fengyu. 2014. "Selective Hydrogenation of m-Dinitrobenzene to m-Nitroaniline over Ru-SnOx/Al2O3 Catalyst" Catalysts 4, no. 3: 276-288. https://doi.org/10.3390/catal4030276

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