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Materials 2019, 12(1), 191; https://doi.org/10.3390/ma12010191

Perspective on Plasma Polymers for Applied Biomaterials Nanoengineering and the Recent Rise of Oxazolines

1
School of Engineering, University of South Australia, Adelaide, SA 5000, Australia
2
Future Industries Institute, University of South Australia, Adelaide, SA 5000, Australia
*
Author to whom correspondence should be addressed.
Received: 3 December 2018 / Revised: 21 December 2018 / Accepted: 2 January 2019 / Published: 8 January 2019
(This article belongs to the Special Issue Plasma Polymerized Materials)
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Abstract

Plasma polymers are unconventional organic thin films which only partially share the properties traditionally attributed to polymeric materials. For instance, they do not consist of repeating monomer units but rather present a highly crosslinked structure resembling the chemistry of the precursor used for deposition. Due to the complex nature of the deposition process, plasma polymers have historically been produced with little control over the chemistry of the plasma phase which is still poorly understood. Yet, plasma polymer research is thriving, in par with the commercialisation of innumerable products using this technology, in fields ranging from biomedical to green energy industries. Here, we briefly summarise the principles at the basis of plasma deposition and highlight recent progress made in understanding the unique chemistry and reactivity of these films. We then demonstrate how carefully designed plasma polymer films can serve the purpose of fundamental research and biomedical applications. We finish the review with a focus on a relatively new class of plasma polymers which are derived from oxazoline-based precursors. This type of coating has attracted significant attention recently due to its unique properties. View Full-Text
Keywords: plasma polymers; oxazoline; biomaterials; medical devices; implants; coatings plasma polymers; oxazoline; biomaterials; medical devices; implants; coatings
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Macgregor, M.; Vasilev, K. Perspective on Plasma Polymers for Applied Biomaterials Nanoengineering and the Recent Rise of Oxazolines. Materials 2019, 12, 191.

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