C- versus O-Arylation of an Enol-Lactone Using Potassium tert-butoxide
1
INRS-Institut Armand-Frappier, 531 Boul. des Prairies, Laval, Québec, Canada
2
Laboratoire de Chimie Organique Hétérocyclique, Faculté des Sciences, Université Mohamed V, Rabat, Marocco
*
Author to whom correspondence should be addressed.
Int. J. Mol. Sci. 2003, 4(6), 371-378; https://doi.org/10.3390/i4060371
Received: 31 October 2002 / Accepted: 6 March 2003 / Published: 31 May 2003
The use of potassium tert-butoxide as the base in arylation reactions of an enollactone with a series of benzyl halides was explored. Our work demonstrates that the ratio of C-arylation to O-arylation varies with the substitution pattern of the aryl halide.
Keywords:
Arylation; Enol-lactone; Potassium tert-butoxide
This is an open access article distributed under the Creative Commons Attribution License
MDPI and ACS Style
Ibrahimi, S.; Sauvé, G.; Essassi, E.M. C- versus O-Arylation of an Enol-Lactone Using Potassium tert-butoxide. Int. J. Mol. Sci. 2003, 4, 371-378. https://doi.org/10.3390/i4060371
AMA Style
Ibrahimi S, Sauvé G, Essassi EM. C- versus O-Arylation of an Enol-Lactone Using Potassium tert-butoxide. International Journal of Molecular Sciences. 2003; 4(6):371-378. https://doi.org/10.3390/i4060371
Chicago/Turabian StyleIbrahimi, Sanae; Sauvé, Gilles; Essassi, El M. 2003. "C- versus O-Arylation of an Enol-Lactone Using Potassium tert-butoxide" Int. J. Mol. Sci. 4, no. 6: 371-378. https://doi.org/10.3390/i4060371
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