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4 December 2025

Non-Invasive Analysis of Bulk and Surface Remodeling of Non-Woven PLLA and Fiber-Sponge PLLA/Chitosan Scaffolds in Cell Culture Environment

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1
Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334 Moscow, Russia
2
National Research Center “Kurchatov Institute”, Department of Nanobiomaterials and Structures, 123182 Moscow, Russia
3
Moscow Center of Advanced Studies, 123592 Moscow, Russia
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Author to whom correspondence should be addressed.
This article belongs to the Special Issue Physicochemical Research on Material Surfaces, 2nd Edition

Abstract

The expanding application of three-dimensional matrices with complex surface topographies in regenerative medicine requires new methods to visualize and analyze the evolving elastic properties of tissue-engineered constructs (TECs) during maturation. In this study, scanning impulse acoustic microscopy (SIAM) was employed for the non-invasive investigation of non-woven matrices based on PLLA and its composites with chitosan. This technique was used to determine the speed of sound, integral attenuation, and spectral characteristics within the samples. The data obtained through acoustic microscopy were compared with the results from tensile testing, gel permeation chromatography, differential scanning calorimetry, scanning electron microscopy, and CCK-8 assays. The findings demonstrate that SIAM exhibits high sensitivity to alterations in the TEC’s composition, including the presence of functionalizing additives, embedded cells, and the subsequent processes of cell proliferation and extracellular matrix synthesis, as well as to changes in its geometric structure. Consequently, this methodology can be recommended as a powerful and non-destructive tool for the comprehensive monitoring of TECs throughout their in vitro maturation period.

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