Search Results (1,347)

This research contributes to advance the sustainable production of biofuels and provides insights into the energy and exergy assessment of bio-oil, which is essential for developing environmentally friendly energy production solutions. Energy and exergy analyses were performed to evaluate the pyrolysis of beech wood biomass at 500 °C in an Auger reactor. To improve the quality of the obtained bio-oil, its catalytic deoxygenation was performed within an in-line fluidized catalytic bed reactor using a catalyst based on HZSM5 zeolite modified with 5 wt.% Iron (5%FeHZSM-5). A thermodynamic analysis of the catalytic and non-catalytic pyrolysis system was carried out, as well as a comparative study of the calculation methods for the energy and exergy evaluation for bio-oil. The required heat for pyrolysis was found to be 1.2 MJ/kg_biomass in the case of non-catalytic treatment and 3.46 MJ/kg_biomass in the presence of the zeolite-based catalyst. The exergy efficiency in the Auger reactor was 90.3%. Using the catalytic system coupled to the Auger reactor, this efficiency increased to 91.6%, leading to less energy degradation. Calculating the total energy and total exergy of the bio-oil using two different methods showed a difference of 6%. In the first method, only the energy contributions of the model compounds, corresponding to the major compounds of each chemical family of bio-oil, were considered. In contrast, in the second method, all molecules identified in the bio-oil were considered for the calculation. The second method proved to be more suitable for thermodynamic analysis. The novelties of this work concern the thermodynamic analysis of a coupled system of an Auger biomass pyrolysis reactor and a fluidized bed catalytic deoxygenation reactor on the one hand, and the use of all the molecules identified in the oily phase for the evaluation of energy and exergy on the other hand. Full article

The utilisation of agrifood waste ashes has the potential to enhance the nutrient content of cereal crops, thereby optimising both yield and grain quality. This study investigated rye grain composition, the fermentation efficiency, and volatile compounds in mashes made from crops fertilised with agrifood waste ashes derived from the combustion of corn cob, wood chips, and biomass with defecation lime. The ashes were applied at 2, 4, and 8 t/ha, separately and as mixtures of corn cob (25%) with wood chips (75%) and corn cob (50%) with biomass and defecation lime (50%). Rye mashes were prepared using the pressureless starch liberation method. The starch content in the majority of the rye grains was comparable to the control sample (57.12 g/100 g). The range of ethanol concentrations observed in the fermented mashes was from 55.55 to 68.12 g/L, which corresponded to fermentation yields of 67.25–76.59% of theoretical. The lowest fermentation yield was exhibited by the mash derived from rye cultivated on soil fertilised with a 50:50 mixture of ashes from corn cob and biomass with defecation lime at 8 t/ha. This mash contained more than double the acetaldehyde concentration and total aldehyde content compared to the other samples. These findings demonstrate the potential of using waste biomass ash as a source of macro- and microelements for rye cultivation, enabling the production of agricultural distillates. To ensure high fermentation efficiency and low aldehyde levels, ash dosage and composition need to be established based on experimental optimisation. Full article

With the growing severity of environmental pollution, people are paying increasing attention to their health. However, naturally occurring wood with health benefits and applications in human healthcare is still scarce. Natural wood exhibits a limited negative oxygen ion release capacity, and this release has a short duration, failing to meet practical application requirements. This study innovatively developed a humidity-responsive, healthy wood material with a high negative oxygen ion release capacity based on fast-growing poplar. Through vacuum cyclic impregnation technology, hexagonal stone powder was infused into the pores of poplar wood, endowing it with the ability to continuously release negative oxygen ions. The healthy wood demonstrated a static average negative oxygen ion release rate of 537 ions/cm³ (peaking at 617 ions/cm³) and a dynamic average release rate of 3,170 ions/cm³ (peaking at 10,590 ions/cm³). The results showed that the particle size of hexagonal stone powder in suspension was influenced by the dispersants and dispersion processes. The composite dispersion process demonstrated optimal performance when using 0.5 wt% silane coupling agent γ-(methacryloxy)propyltrimethoxysilane (KH570), achieving the smallest particle size of 8.93 μm. The healthy wood demonstrated excellent impregnation performance, with a weight gain exceeding 14.61% and a liquid absorption rate surpassing 165.18%. The optimal impregnation cycle for vacuum circulation technology was determined to be six cycles, regardless of the type of dispersant. Compared with poplar wood, the hygroscopic swelling rate of healthy wood was lower, especially in PEG-treated samples, where the tangential, radial, longitudinal, and volumetric swelling rates decreased by 70.93%, 71.67%, 69.41%, and 71.35%, respectively. Combining hexagonal stone powder with fast-growing poplar wood can effectively enhance the release of negative oxygen ions. The static average release of negative oxygen ions from healthy wood is 1.44 times that of untreated hexagonal stone powder, and the dynamic release reaches 2 to 3 times the concentration of negative oxygen ions specified by national fresh air standards. The water-responsive mechanism revealed that negative oxygen ion release surged when ambient humidity exceeded 70%. This work proposes a sustainable and effective method to prepare healthy wood with permanent negative oxygen ion release capability. It demonstrates great potential for improving indoor air quality and enhancing human health. Full article

Spruce wood is a natural polymeric material, consisting of cellulose, lignin, hemicelluloses and other secondary components, which gives it a unique chemical footprint and architecture. Varnishes are used in musical instruments to protect the wood against humidity variations, wood being a hygroscopic material, but also to protect the wood from dirt. The varnishes used both to protect the wood from resonance and to ensure a special aesthetic appearance are either polymeric varnishes (nitrocellulose, oil-based) or volatile solvents (spirit). In this study, the color changes, the surface morphology and the chemical spectrum produced by three types of varnishes, applied in 5, 10 and 15 layers, on resonance spruce plates were analyzed. The results revealed significant changes in the color parameters: the lightness decreased by approximately 17% after the first layer, by 50% after 5 layers, by 65% after 10 layers and by 70% after 15 layers. The color parameters are most influenced by the anatomical quality of spruce wood (annual ring width and earlywood/latewood ratio) in the case of oil-based varnishes and least influenced in the case of nitrocellulose varnishes. The chemical fingerprint was determined by FTIR spectrum analysis, which revealed that the most pronounced absorptions were the double band 2926–2858 cm⁻¹, corresponding to aliphatic methylene and methyl groups (asymmetric and symmetrical C-H stretch), and the bands at 1724 cm⁻¹ (oil-based varnish), 1722 cm⁻¹ (nitrocellulose varnish) and 1708 cm⁻¹ (spirit varnish), all assigned to non-conjugated carbonyl groups in either carboxylic acids, esters aldehydes or ketones. The novelty of the study lies in the comparative analysis of three types of varnishes used in the musical instrument industry, applied to samples of spruce resonance wood with different macroscopic characteristics in three different layer thicknesses. Full article

Volatile organic compounds (VOCs) are highly volatile chemicals in natural and anthropogenic environments, significantly affecting indoor air quality. Major sources of indoor VOCs include emissions from building materials, furnishings, and consumer products. Natural wood products release VOCs, including terpenes and aldehydes, which exert diverse health effects ranging from mild respiratory irritation to severe outcomes, such as formaldehyde-induced carcinogenicity. The temporal dynamics of VOC emissions were investigated, and the toxicological and physiological effects of the VOCs emitted by two types of natural wood, Korean Red Pine (Pinus densiflora) and Japanese Cypress (Chamaecyparis obtusa), were evaluated. Using female C57BL/6 mice as an animal model, the exposure setups included phytoncides, formaldehyde, and intact wood samples over short- and long-term durations. The exposure effects were assessed using oxidative stress markers, antioxidant enzyme activity, hepatic and renal biomarkers, and inflammatory cytokine profiles. Long-term exposure to Korean Red Pine and Japanese Cypress wood VOCs did not induce significant pathological changes. Japanese Cypress exhibited more distinct benefits, including enhanced oxidative stress mitigation, reduced systemic toxicity, and lower pro-inflammatory cytokine levels compared to the negative control group, attributable to its more favorable VOC emission profile. These findings highlight the potential health and environmental benefits of natural wood VOCs and offer valuable insights for optimizing timber use, improving indoor air quality, and informing public health policies. Full article

The emission and presence of volatile organic compounds (VOCs) in the indoor air of houses and factories has been a growing topic of debate in the industry and related research fields. Given the extended times people in modern society spend indoors, monitoring VOCs is crucial due to the associated potential health hazards, with formaldehyde being particularly noteworthy. Wood and wood-based panels (WBPs) (the latter constituting a significant segment of the wood-transforming industry, being widely used in furniture, construction, and other applications) are known sources for the emission of VOCs to indoor air. In the case of the WBPs, the emission of VOCs depends on the type and species of wood, together with industrial processing and addition of additives. This review integrates perspectives on the production processes associated with WBPs, together with the evolving global regulations, and thoroughly examines VOC sources associated with WBPs, health risks from exposure, and current analytical methods utilized for VOC detection. It comprises an overview of the WBP industry, providing relevant definitions, descriptions of manufacturing processes and adhesive use, analysis of legal constraints, and explanations of VOC source identification and describing analysis techniques utilized for VOCs in WBPs. Full article

Wood, as a natural material that stores carbon, is gaining increasing attention and has potential for use in interior architectural applications. Given the long indoor stay time characteristic of modern society, it is important to scientifically understand the effects of indoor wood application on the occupants. In this study, three residential buildings with an identical area and structure were constructed with different degrees of wood coverage (0%, 45%, 90%) using Larix kaempferi. Subsequently, indoor air quality (IAQ) evaluations and relative humidity measurements were conducted to assess the physical and chemical changes in each environment. The IAQ in wooden and non-wooden environments met the recommended IAQ standards established in South Korea. The results of the 8-month observation showed that, the higher the wood coverage ratio, the more the indoor humidity fluctuations were alleviated, and, in the case of the 90% wood coverage ratio condition, the humidity was maintained 5.2% lower in the summer and 10.9% higher in the winter compared to the 0% condition. To further assess the physiological responses induced by the wooden environment, the heart rate variability (HRV) was measured and compared for 26 participants exposed to each environment for two hours. In environments with a 0% and 90% degree of wood coverage, no statistically significant differences were found in the participants’ HRV indicators. But, in the group exposed to the 45% wooden environment, the results showed an increase in HRV indicators, natural logarithm of high frequency power (lnHF): 4.87 → 5.40 (p < 0.05), and standard deviation of normal-to-normal intervals (SDNN): 30.57 → 38.48 (p < 0.05), which are known indicators of parasympathetic nervous system activation. Full article

In the era of climate change, the strategic importance of forestry products for sustainable development is increasingly recognized. Amid a global resurgence of industrial policy aimed at addressing environmental challenges, this study investigates the impact of China’s central and provincial green industrial policies on the export competitiveness of wood-processing enterprises. Utilizing firm-level data from the China Industrial Enterprise Database and China Customs Export Database (2000–2013), we apply a double machine learning (DML) approach and construct a heterogeneous competitiveness model to evaluate policy effects along two dimensions: export quantity (volume and intensity) and export quality (product complexity and consumer-perceived quality). Our findings reveal a clear dichotomy in policy outcomes. While industrial policies have significantly improved export product complexity—reflecting China’s comparative advantage in labor-intensive production—they have had limited or even negative effects on export volume, intensity, and product quality. This suggests that current policy frameworks disproportionately reward horizontal innovation (product diversification) while neglecting vertical upgrading (quality enhancement), thereby hindering comprehensive export performance gains. Those results highlight the need for more balanced and targeted policy design. By aligning industrial policy instruments with both complexity and quality objectives, policymakers can better support the sustainable transformation of China’s forestry sector and enhance its competitiveness in global value chains. Full article

As a carbon-rich material with sufficient inorganic nutrients, biochar is potentially an inexpensive and suitable additive to improve the quality of soil and achieve sustainable agriculture. However, the addition of biochar generally increases pesticide adsorption in soil because of the well-maintained porous structure, and the specific effects of the properties of biochar, soil, and pesticides on the adsorption capacity of pesticides remain unknown. In this study, a meta-analysis was conducted to investigate the effects of biochar addition on pesticide adsorption in soils, focusing on characteristics such as the biochar addition dosage, biochar properties (pH, specific surface area (SSA), pore diameter, (O+N)/C, H/C), and soil properties (texture, initial pH, cation exchange capacity). Overall, wood-derived biochar that was treated at ≥700 °C for 2–4 h, with a pH of 9–10 and a 2–4% addition rate led to the greatest enhancement in the pesticide adsorption capacity of soil. Additionally, the pyrolysis temperature of the biochar, the biochar’s pore diameter, and the soil’s pH significantly influenced the adsorption capacity. Based on this meta-analysis, we conclude that the (O+N)/C ratio of biochar is the most influential predictor of soil’s pesticide adsorption capacity. Full article

The development of sustainable and functional nanocomposites has attracted considerable attention in recent years due to their broad spectrum of potential applications, including wood preservation. Also, a global goal is to reuse the large volumes of waste for environmental issues. In this context, the aim of the study was to obtain soda lignin particles, to graft ZnO nanoparticles onto their surface and to apply these hybrids, embedded into a biodegradable polymer matrix, as protection/preservation coating for oak wood. The organic–inorganic hybrids were characterized in terms of compositional, structural, thermal, and morphological properties that confirm the efficacy of soda lignin extraction and ZnO grafting by physical adsorption onto the decorating support and by weak interactions and coordination bonding between the components. The developed solution based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and lignin-ZnO was applied to oak wood specimens by brushing, and the improvement in hydrophobicity (evaluated by water absorption that decreased by 48.8% more than wood, humidity tests where the treated sample had a humidity of 4.734% in comparison with 34.911% for control, and contact angle of 97.8° vs. 80.5° for untreated wood) and UV and fungal attack protection, while maintaining the color and aspect of specimens, was sustained. L.ZnO are well dispersed into the polymer matrix, ensuring a smooth and less porous wood surface. According to the results, the obtained wood coating using both a biodegradable polymeric matrix and a waste-based preservative can be applied for protection against weathering degradation factors, with limited water uptake and swelling of the wood, UV shielding, reduced wood discoloration and photo-degradation, effective protection against fungi, and esthetic quality. Full article

This study proposes a novel LK-BP-AFPSO model for the nondestructive evaluation of wood mechanical properties, combining a backpropagation neural network (BP) with adaptive fractional-order particle swarm optimization (AFPSO) and Liang–Kleeman (LK) information flow theory. The model accurately predicts four key mechanical properties—longitudinal tensile strength (SPG), modulus of elasticity (MOE), bending strength (MOR), and longitudinal compressive strength (CSP)—using only nondestructive physical features. Tested across diverse wood types (fast-growing YKS, red-heart CSH/XXH, and iron-heart XXT), the framework demonstrates strong generalizability, achieving an average prediction accuracy (R²) of 0.986 and reducing mean absolute error (MAE) by 23.7% compared to conventional methods. A critical innovation is the integration of LK causal analysis, which quantifies feature–target relationships via information flow metrics, effectively eliminating 29.5% of spurious correlations inherent in traditional feature selection (e.g., PCA). Experimental results confirm the model’s robustness, particularly for heartwood variants, while its adaptive fractional-order optimization accelerates convergence by 2.1× relative to standard PSO. This work provides a reliable, interpretable tool for wood quality assessment, with direct implications for grading systems and processing optimization in the forestry industry. Full article

This study evaluated birch and oak ash extracts as alternative extractants for isolating humic substances (HSs) from peat and lignite. The effects of ultrasound intensity, extraction time, and temperature were optimized using a Box–Behnken design and validated statistically. The highest HSs yields were obtained from peat with oak ash extract (pH 13.18), compared to birch ash extract (pH 12.09). Optimal process parameters varied by variant, falling within 309–391 mW∙cm⁻², 116–142 min, and 67–79 °C. HSs extracted under optimal conditions were fractionated into humic acids (HAs) and fulvic acids (FAs), and then analyzed by elemental analysis, Fourier Transform Infrared Spectroscopy (FTIR), and Cross-Polarization Magic Angle Spinning Carbon-13 Nuclear Magnetic Resonance Spectroscopy (CP/MAS ¹³C NMR). The main differences in HSs quality were influenced by raw material and fraction type. However, the use of birch ash extract consistently resulted in a higher proportion of carboxylic structures across all fractions. Overall, wood ash extract, especially from oak, offers a sustainable and effective alternative to conventional extractants, particularly for HSs isolation from lignite. Notably, HSs yield from lignite with oak ash extract (29.13%) was only slightly lower than that achieved with 0.5 M NaOH (31.02%), highlighting its practical potential in environmentally friendly extraction technologies. Full article

Background: Catalpa bungei ‘Jinsi’ has excellent wood properties and golden texture, which is widely used in producing furniture and crafts. The lignin content and structural composition often determine the use and value of wood. Hence, investigating the characteristics of the annual dynamics of lignin anabolic metabolites in C. bungei ‘Jinsi’ and analyzing their synthesis pathways are particularly important. Methods: We carried out targeted metabolomics analysis of lignin synthesis metabolites using ultra-performance liquid chromatography–tandem mass spectrometry (UPLC-MS/MS) on the xylem samples of C. bungei ‘Jinsi’ in February, April, July, October 2022, and January 2023. Results: A total of 10 lignin synthesis–related metabolites were detected: L-phenylalanine, cinnamic acid, p-coumaraldehyde, sinapic acid, p-coumaric acid, coniferaldehyde, ferulic acid, sinapaldehyde, caffeic acid, and sinapyl alcohol (annual total content from high to low). These metabolites were mainly annotated to the synthesis of secondary metabolites and phenylpropane biosynthesis. The annual total content of the 10 metabolites showed the tendency of “decreasing, then increasing, and then decreasing”. Conclusions: C. bungei ‘Jinsi’ is a typical G/S-lignin tree species, and the synthesis of G-lignin occurs earlier than that of S-lignin. The total metabolite content decreased rapidly, and the lignin anabolism process was active from April to July; the metabolites were accumulated, and the lignin anabolism process slowed down from July to October; the total metabolite content remained basically unchanged, and lignin synthesis slowed down or stagnated from October to January of the following year. This reveals the annual dynamic pattern of lignin biosynthesis, which contributes to improving the wood quality and yield of C. bungei ‘Jinsi’ and provides a theoretical basis for its targeted breeding. Full article

Next to solid wood, laminated particleboard is the most widely used wood-based material in the furniture industry. Ensuring the high quality of the laminate surface after machining is of critical importance for furniture manufacturers, particularly prior to the edge banding process, as this process significantly influences the final aesthetic and functional quality of panel elements. The objective of this review article is to gather and evaluate the current state of knowledge regarding the influence of machining process parameters and the physical and mechanical properties of laminated particleboard on machining quality. Particular emphasis is placed on the occurrence of laminate damage, commonly referred to as delamination, a prevalent defect in the furniture manufacturing sector. Both categories of influencing factors—process-related and material-related—are analyzed within the context of the three primary technological processes employed in the woodworking industry, namely drilling, cutting, and milling. The analysis revealed that a persistent research gap concerns the relationship between machining quality and material parameters, particularly in the case of milling—a process of critical importance in the furniture industry. Full article

This study aimed to enhance sustainable innovations in intelligent wood pellets by integrating smart customized furniture design with Total Quality Management (TQM) principles. Through qualitative interviews with manufacturers and the application of lean production frameworks, the research explored how sustainability-driven customization can lead to optimized resource usage, reduced environmental impact, and increased market competitiveness. While the study was exploratory and limited in sample size, it provided practical insights for green manufacturing strategies and product differentiation in circular economies. Full article