Search Results (18)

An advanced alkali-acid (NaOH-HCl) chemical method was used to deash aluminum-rich coals (ARCs) with a high ash content of 27.47 wt% to achieve a low ash content of 0.46 wt%. In the deashing process, aluminum in the coal ashes was dissolved in both alkali solutions and acid solutions. The deashing alkali solutions with dissolved coal ashes were regenerated by adding CaO, and the resulting precipitates were added with sodium bicarbonate for aluminum extraction. High temperatures increased aluminum extraction, and excessive sodium bicarbonate addition decreased aluminum extraction. The deashing acid solutions were concentrated by evaporation, and silica gels formed during the process. The obtained mixtures were calcinated at 350 °C for the decomposition of aluminum chlorides, and soaked with water at 60 °C to remove the soluble chlorides. For the insoluble oxides after soaking, diluted alkali solutions were used to extract the aluminum at 90 °C, and aluminum extraction failed due to the formation of albite in the presence of sodium, aluminum and silicon elements as proved by XRD and SEM/EDS. When silica gels were separated by pressure filtering, aluminum extraction greatly increased. Aluminum extractions were accordingly made in the form of sodium aluminate from the deashing solutions of coals, which could be advantageous for sandy alumina production. Full article

It is vital to stabilize pillar dams in underground reservoirs in coal mine goafs to protect groundwater resources and quarry safety, practice green mining, and protect the ecological environment. Considering the actual occurrence of coal pillar dams in underground reservoirs, acoustic emission (AE) mechanical tests were performed on dry, naturally absorbed, and soaked coal samples. According to the mechanical analysis, Quantitative analysis revealed that dry samples exhibited the highest mechanical parameters (peak strength: 12.3 ± 0.8 MPa; elastic modulus: 1.45 ± 0.12 GPa), followed by natural absorption (peak strength: 9.7 ± 0.6 MPa; elastic modulus: 1.02 ± 0.09 GPa), and soaked absorption showed the lowest values (peak strength: 7.2 ± 0.5 MPa; elastic modulus: 0.78 ± 0.07 GPa). The rate of mechanical deterioration increased by ~25% per 1% increase in moisture content. It was identified that the internal crack development presented a macrofracture surface initiating at the sample center and expanding radially outward, and gradually expanding to the edges by adopting AE seismic source localization and the K-means clustering algorithm. Soaked absorption was easier to produce shear cracks than natural absorption, and a higher water content increased the likelihood. The b-value of the AE damage evaluation index based on crack development was negatively correlated with the rock damage state, and the S-value was positively correlated, and both effectively characterized it. The research results can offer reference and guidance for the support design, monitoring, and warning of coal pillar dams in underground reservoirs. (The samples were tested under two moisture conditions: (1) ‘Soaked absorption’—samples fully saturated by immersion in water for 24 h, and (2) ‘Natural absorption’—samples equilibrated at 50% relative humidity and 25 °C for 7 days). Full article

In the past ten years, many coal mines have encountered the problem of a premature failure of anchor rod materials. Through field investigation and laboratory research, it was found that the premature failure of these bolt materials is mostly caused by mine water corrosion. In this paper, a Zn-Y₂O₃-Al₂O₃ composite coating was prepared by an electrodeposition method for the corrosion protection of underground anchors. Through the single-factor experiment method, the co-deposition process of Zn²⁺ nano-Y₂O₃ and nano-Al₂O₃ particles was studied. Microhardness was used as the index to determine the optimum preparation process for the composite coatings. Combined with FSEM and XRD tests, the results showed that the synergistic effect of nano-Y₂O₃ and nano-Al₂O₃ particles made the coating grain refined and reduced the coating defects. The hardness of the coating increased from 98.7 Hv to 347.9 Hv, and the hardness and wear resistance of the coating were improved. The hydrophobicity of the Zn-Y₂O₃-Al₂O₃ composite coating was improved, and its static contact angle was 93.28°. The corrosion resistance of the composite coating was studied through electrochemical impedance spectroscopy, the Tafel curve, corrosion morphology, and weight loss. Under the synergistic effect of nano-Y₂O₃ and nano-Al₂O₃ particles, the self-corrosion current density decreased from 4.21 × 10⁻⁴ A/cm² to 1.06 × 10⁻⁵ A/cm², which confirmed that the Zn-Y₂O₃-Al₂O₃ composite coating had better corrosion resistance and durability. After soaking in mine water for 63 days, the Zn-Y₂O₃-Al₂O₃ composite coating had no obvious shedding on the surface and was well preserved. The practical application results show that it has excellent corrosion resistance and durability. The Zn-Y₂O₃-Al₂O₃ nano-composite coating material has significant potential advantages in the field of corrosion resistance of underground anchor rods. Full article

Coal seam water injection technology enables seam permeability enhancement and facilitates outburst risk reduction. This study investigated the microscale effects of water infiltration on coal and the evolution mechanisms of its mechanical properties. To this end, we systematically analyzed dynamic changes (such as mineral composition, pore structure, and mechanical performance) in coal soaked for various durations using X-ray diffraction, low-field nuclear magnetic resonance (NMR), and uniaxial compression testing. The results indicate: (1) the coal NMR T₂ spectrum displays three characteristic peaks, corresponding to rapid water absorption, uniform transition, and stabilization stages of soaking traditionally divided according to peak area variation trends. (2) The coal strength decreases with progressive soaking, influenced by water content, pore volume, mineral composition, etc. Its compressive strength and elastic modulus drop by 22.4% and 19.5%, respectively, compared to the initial values. (3) The expansion of clay minerals during immersion reduces average pore size. In contrast, quartz particle displacement, pore water movement, and soluble mineral dissolution increase pore volume, reducing the overall structure strength. (4) The dominant factors driving the degradation of mechanical properties vary across immersion stages, including water content and specific mineral concentration. This work offers new insights into how hydraulic technology alters coal seams, providing theoretical support for optimizing water injection strategies in the seam. Full article

This paper demonstrates that ash composites, comprising fly ash and polyurethane, can be used to develop value-added products that exhibit an effective decrease in the leaching of coal ash inorganics to less than one-third of the Environmental Protection Agency (EPA)’s maximum contaminant level (MCL) when soaked in a water circulation system for 14 months. Furthermore, the composite blocks remain safe even with ruptured surfaces. The concept of encapsulating fly ash within ash composites by using a polar polymer to bind the fine inorganic particles, mimicking how nature does it in the original unburned coal, ensures the safety of the composite. The ash composites can be formulated to have designed mechanical, fire, and electrical properties by controlling the formulation and the density. The properties of typical density composites were produced, measured, and compared with commercial materials. This paper also demonstrates that ash composite technology can be extended to coal ash stored in ponds. Finally, a typical electric utility box cover was designed, fabricated, and test validated. The box cover has less than one-half the weight of the original box cover for the same design limits. Finally, the benefits of this ash-composite technology for product manufacturers, society, and ash producers are summarized. Full article

The instability and failure of coal pillars is one of the important factors leading to the catastrophic consequences of coal mine goaf collapse. Coal mine water has the characteristics of high salinity. Long-term mine water erosion can easily deform the coal pillar structure, eventually leading to instability and damage. This study carried out tests on coal samples soaked in salt solutions with different concentrations, and the nuclear magnetic resonance (NMR) method was used to obtain the dynamic evolution of the pore-fracture structure of coal. On the basis of fractal theory, the changes in fractal dimension of pore structure during the soaking process were discussed. The damage variable based on the pore fractal dimension was defined and the evolution relationship between the damage variable and immersion time was characterized. The findings demonstrated that the porosity change rate has an exponentially increasing relationship with the immersion time, and with the increasement of concentration of salt solution, the porosity change rate also shows increasing trends. The number of seepage pores and total pores increased with the immersion time. While, with the extension of soaking time, the number of adsorption pores first increased and then decreased. The connectivity between pores was enhanced. The relationship between the fractal dimension and the immersion time is linearly decreasing. The damage variable showed an increasing trend with the immersion time. As the concentration of salt solution increased, the damage of coal increased. The research results are of great significance for rationally evaluating the stability of coal pillars and ensuring the safe operation of underground engineering. Full article

This study aims to reveal the impact of immersion duration on the internal structural damage and mechanical property degradation of coal rocks. Coal rocks from the post-mining area of Liangshuijing Coal Mine were selected as the research subject. Physical and mechanical tests were carried out on these with different immersion durations (0 d, 15 d, 30 d, 60 d, 120 d, and 240 d) using scanning electron microscopy (SEM), nuclear magnetic resonance (NMR), acoustic emission (AE), digital image correlation (DIC), and compression testing, further elucidating the damage degradation mechanisms of water-immersed coal rocks. The research demonstrates that changes in the pore structure of coal rocks can be divided into two stages as the soaking time varies: the stage of water swelling (saturation process) and the stage of soaking damage (long-term immersion process). The water swelling stage of coal rock extends from surface drying and contraction to water swelling, and the soaking damage stage of coal rock extends from expansion to soaking damage. During the stage of soaking damage, the water showed dynamic changes from macropores to mesopores to micropores, with a gradual increase in the number of micropores. The AE count and cumulative count of coal rock decrease first and then increase, and the four stages’ acoustic characteristics and macroscopic characterization phenomena appear. The mechanical properties declined. After 240 d of immersion, the uniaxial compressive strength and elastic modulus decreased by 48.93% and 29.53%, respectively, and the plastic characteristics were enhanced. These research results provide a beneficial reference for understanding and predicting the instability and destruction of water-immersed coal rocks. Full article

The Cretaceous Zhidan group (K1zh) pore fissure-confined water aquifer in Yingpanhao Coal Mine, Ordos City, China, has loose stratum structure, high porosity, strong permeability and water conductivity. In order to explore the fluid–solid coupling similar material and its constitutive model suitable for the aquifer, a kind of fluid–solid coupling similar material with low strength, strong permeability and no disintegration in water was developed by using 5~20 mm stone as aggregate and P.O32.5 Portland cement as binder. The controllable range of uniaxial compressive strength is 0.394~0.528 MPa, and the controllable range of elastic modulus is 342.22~400.24 MPa. The stress–strain curve and elastic modulus of similar materials are analyzed. It is found that the elastic modulus of similar materials with different water–cement ratios conforms to the linear law, the elastic modulus of similar materials with the same water–cement ratio after soaking treatment and without soaking treatment also conforms to the linear law. Based on the material failure obeying the maximum principal stress criterion and Weibull distribution, combined with the elastic modulus fitting formula, a constitutive model suitable for the fluid–solid coupling similar material was established, and the parameters of the constitutive model were determined by differential method. By comparing the theoretical stress–strain curve with the experimental curve, it is found that the constitutive model can better describe and characterize the fluid–solid coupling similar materials with different water–cement ratios and before and after soaking. Full article

Water–gas displacement occurring during the drainage of water-soaked goafs facilitates the oxidation of water-soaked coal. The characteristics of oxygen migration and the oxidation and spontaneous combustion (SC) of soaked residual coal during goaf drainage were explored through laboratory research, water drainage simulation and on-site measurement. The results reveal that compared with raw coal samples, the amount and rate of gas products of water-soaked coal samples are higher in the heating oxidation process, demonstrating a strengthened spontaneous combustion (SC) propensity. Its cross-point temperature falls and the apparent activation energy decreases by 1.43–8.75%, that is, the soaked coal sample is easier to spontaneously combust during the drainage of water-soaked goafs. Through simulation, it is found that after water is drained, air leakage in the goaf is significantly intensified, and the pressure difference inside and outside the goaf reaches 498 Pa. By taking the air inlet roadway as the air leakage point for fitting, it is found that the oxygen concentration in the air leakage range increases to 18% during water drainage. The simulation results are basically consistent with the on-site measurement. The on-site monitoring result shows that during water drainage of 7₂25 goaf in Qinan Coal Mine, water-immersed coal is more prone to spontaneous combustion, and air leakage leads to low-temperature oxidation of water-immersed coal, which increases the on-site temperature rapidly and increases the risk of spontaneous combustion in the goaf. With respect to water drainage in the goaf, an optimization measure of fixed-point and quantitative nitrogen injection during water drainage was put forward on site. Full article

Large-scale goafs are left after coal seam mining. Due to the low-lying terrain, the goaf will be filled and soaked by groundwater, which may lead to instability of the remaining coal pillars in the goaf and cause uneven settlement of the overlying rock. Consequently, there may be overlying rock movement and surface subsidence, which endangers the safety of the building (structure) above the goaf. Considering the strip goaf of Dai Zhuang coal pillar as an example, this study investigated the evolution of instability and deformation of surrounding rocks affected by water immersion using the similar material simulation test method. The results of the study reveal that under the effect of prolonged water immersion in the goaf, the damage to the coal pillar in the strip underwent a stagewise evolution process of several instances of creep damage at the edge of coal pillar followed by overall destabilization damage, and the overburden movement revealed stage characteristics of small step subsidence several times followed by sudden large subsidence. Furthermore, based on Wilson’s coal pillar instability theory, the instability mechanism of the strip coal pillar under the action of water immersion was found to be triggered by the reduced strength of the coal pillar from the effect of water immersion, the continuous creep damage to the strip coal pillar from outside to inside, and the continuous shortening of the elastic zone of the coal pillar until its bearing capacity was lower than the load it was carrying. The research results are expected to serve as theoretical guidance for the study of coal pillar stability and the development and utilization of surface construction above goafs. Full article

The coal mine underground reservoir is an effective facility for mine groundwater utilization in water-deficient and ecologically fragile areas. Usually, the artificial reserved coal pillar is used as the dam of underground reservoir, and little research has been done on its tightness performance. Comsol software is used to simulate the leakage of underground reservoirs in Shendong area, in the western part of China, and the long-term tightness of coal pillar dam under different operation conditions is evaluated. The results show that: (1) When the underground reservoir is not connected with the upper water system, the coal pillar dam has good tightness performance. When they are connected, the leakage of reservoir increased due to the raised water level, and the deeper the burial depth, the greater the leakage amount. (2) When reservoir is pumping and storing water, the leakage is only half of that under constant water pressure storage, indicating that this operation mode is beneficial to the long-term tightness of a coal pillar dam. (3) With the increase of the permeability of a coal pillar dam, the leakage will be aggravated. It is suggested that the permeability of a coal pillar dam should not exceed 1 × 10⁻¹⁵ m². (4) The tightness of the coal pillar dam damaged by brine immersion is greatly reduced. With only 3 m of soaking damage distance, the total leakage is twice that of the undamaged one. For a coal pillar dam with poor tightness, some protection countermeasures are proposed to reduce the reservoir water level or improve the anti-seepage performance of a coal pillar dam, so as to ensure the long-term tightness of the dam. This research can provide theoretical support and technical guidance for evaluating the seepage stability of a coal pillar dam in an underground reservoir and strengthening its seepage control. Full article

Many underground reservoirs for storing water have been constructed in China’s western coal mines to protect water resources. Coal pillars which work as dams are subjected to a long-term soaking environment of concentrated salty water. Deterioration of the coal dam under the attack of the salty solution poses challenges for the long-term stability and serviceability of underground reservoirs. The evolution of the physical and mechanical properties of coal subjected to salty solutions are investigated in this paper. Coal from a western China mine is made to standard cylinder samples. The salty solution is prepared according to chemical tests of water in the mine. The coal samples soaked in the salty solution for different periods are tested by scanning electron microscope, nuclear magnetic resonance, and ultrasonic detector techniques. Further, uniaxial compression tests are carried out on the coal specimens. The evolutions of porosity, mass, microstructures of coal, solution pH values, and stress–strain curves are obtained for different soaking times. Moreover, a damage constitutive model for the coal samples is developed by introducing a chemical-stress coupling damage variable. The result shows that the corrosion effect of salty solution on coal samples becomes stronger with increasing immersion time. The degree of deterioration of the longitudinal wave velocity (v_p) is positively correlated with the immersion time. With the increase in soaking times, the porosity of coal gradually increases. The relative mass firstly displays an increasing trend and then decreases with time. The peak strength and elastic modulus of coal decreases exponentially with soaking times. The developed damage constitutive model can well describe the stress–strain behavior of coal subjected to salty solution under the uniaxial compression. Full article

Research on the effective use of secondary products is gaining more and more importance in Poland due to the intensively implementing idea of the circular economy. The solution used in this work are one of many tests useful in construction. The subject of this work was therefore the formation and testing of a new ecological construction binder, in particular for mortars or prefabricated elements working in the environment with high humidity. The binder was made of alkaline activated ground granular blast furnace slag (AAS), fly ash from biomass combustion (BFA) and furnace slag from brown coal combustion (LFS). The mixture was modified by introducing the zeolite to check the degree of metals immobilization contained in the ingredients of the mixture. A series of three mixtures were prepared: without and with zeolite soaked in distilled water or calcium nitrate. The strength of binders in time in dry and wet curing were tested and compared with the microstructure. The maximum compressive strength values at the eighth week were about 30 MPa. The strength values after 4 weeks of dry and wet curing were also compared. It was shown that 28-day wet curing increased the bending strength of the beams more than twice, but slightly decreased the compressive strength. The microstructure of the mixture with the highest values of compressive strength was the densest and the one with the lowest values of compressive strength, the most loosened with the most differentiated topographically fracture. The impregnation of zeolite with calcium nitrate decreased the compressive strength of the binder significantly. The bending strength of samples curing in dry conditions decreased during hardening. The results of the metals leaching test showed that the mixtures were safe for the environment, and due to the impregnation of zeolite with calcium nitrate, the binding effect of copper and zinc in the first weeks was greater than in the other mixtures. Full article

It is imperative to have an in-depth understanding of the effect of extraneous moisture on the spontaneous combustion of coal not only for the control and prevention of coal spontaneous combustion in the coal mining industry, but also for the optimization design and application of the technological process. In this study, the type of moisture in a coal body has been redefined for the first time from the perspective of disaster prevention and control, i.e., original occurrence of moisture in the coal matrix and the extraneous moisture from the technological process. A suit of coal bodies with different extraneous moisture was prepared by soaking long-flame coal with a low water content. Using a temperature-programmed oxidation test, the effects of extraneous moisture on the temperature increase rate of coal bodies and the emission characteristics of gaseous products during coal spontaneous combustion were studied. Moreover, combined with the characterization of thermal analysis and of pore structure test, the action the mechanism of extraneous moisture on the coal spontaneous combustion process was also explored. The experimental results indicated that the effect of the extraneous moisture content varied with the development of coal spontaneous combustion. In the slow oxidation stage, extraneous moisture played a physical inhibition role in the coal oxidation. In the accelerated oxidation stage, extraneous moisture exhibited a catalytic effect on the coal–oxygen reaction or directly participated in the reaction. After entering the rapid oxidation stage, a delayed effect appeared. When the coal temperature exceeded 180 °C, the spontaneous combustion characteristics of coals with different initial moisture contents gradually tended to achieved balance. Full article

The stability of water-preventing coal pillar plays an important role in preventing gob water inrush. The gob side of the water-preventing coal pillar is soaked in a certain height of mine water. Different soaking heights may affect the stability of coal pillars. Few studies have been conducted on the properties of coals with different water-soaking heights. We carried out uniaxial compressive tests on coal specimens with different water-soaking heights to gain a better understanding of different water-soaking-height-induced weakening characteristics of coal. Results show that: (1) The water content of coal specimens increases with the soaking height. Water significantly weakens the strength of coal specimens. However, the extent of strength weakening of the coal specimen does not increase with the increase of the soaked height. The strength of the fully soaked coal specimen is lowest among all groups of coal specimens. The strength of the three groups of partially soaked coal specimens is between the fully soaked coal specimens and the coal specimens without being soaked in the water. In the three groups of partially soaked coal specimens, the strength of the coal specimens increases with the increase of the soaking height. (2) The acoustic emission activities of complete water soaking and nonsoaking coal specimens are relatively concentrated, occurring mainly in unstable fracture expansion stage and post-peak destruction stage, and acoustic emission exhibits main-shock mode. Partially soaking coal specimens, especially the 25% water-soaking height and 50% water-soaking height coal specimens, produces obvious acoustic emission activities during the fracture expansion stabilization phase, and then generates more acoustic emission activities during the unstable expansion stage and the post-peak stage. The acoustic emission presents foreshock—main shock mode. (3) The softening effect of the water soaking on the coal specimens is obvious. It was further found that the deformation of coal specimens with partial water soaking is not synchronized in different layers, the nonuniform deformations of partially soaked coal specimens aggravate its damage. Full article