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24 pages, 11697 KiB  
Article
Layered Production Allocation Method for Dual-Gas Co-Production Wells
by Guangai Wu, Zhun Li, Yanfeng Cao, Jifei Yu, Guoqing Han and Zhisheng Xing
Energies 2025, 18(15), 4039; https://doi.org/10.3390/en18154039 - 29 Jul 2025
Viewed by 185
Abstract
The synergistic development of low-permeability reservoirs such as deep coalbed methane (CBM) and tight gas has emerged as a key technology to reduce development costs, enhance single-well productivity, and improve gas recovery. However, due to fundamental differences between coal seams and tight sandstones [...] Read more.
The synergistic development of low-permeability reservoirs such as deep coalbed methane (CBM) and tight gas has emerged as a key technology to reduce development costs, enhance single-well productivity, and improve gas recovery. However, due to fundamental differences between coal seams and tight sandstones in their pore structure, permeability, water saturation, and pressure sensitivity, significant variations exist in their flow capacities and fluid production behaviors. To address the challenges of production allocation and main reservoir identification in the co-development of CBM and tight gas within deep gas-bearing basins, this study employs the transient multiphase flow simulation software OLGA to construct a representative dual-gas co-production well model. The regulatory mechanisms of the gas–liquid distribution, deliquification efficiency, and interlayer interference under two typical vertical stacking relationships—“coal over sand” and “sand over coal”—are systematically analyzed with respect to different tubing setting depths. A high-precision dynamic production allocation method is proposed, which couples the wellbore structure with real-time monitoring parameters. The results demonstrate that positioning the tubing near the bottom of both reservoirs significantly enhances the deliquification efficiency and bottomhole pressure differential, reduces the liquid holdup in the wellbore, and improves the synergistic productivity of the dual-reservoirs, achieving optimal drainage and production performance. Building upon this, a physically constrained model integrating real-time monitoring data—such as the gas and liquid production from tubing and casing, wellhead pressures, and other parameters—is established. Specifically, the model is built upon fundamental physical constraints, including mass conservation and the pressure equilibrium, to logically model the flow paths and phase distribution behaviors of the gas–liquid two-phase flow. This enables the accurate derivation of the respective contributions of each reservoir interval and dynamic production allocation without the need for downhole logging. Validation results show that the proposed method reliably reconstructs reservoir contribution rates under various operational conditions and wellbore configurations. Through a comparison of calculated and simulated results, the maximum relative error occurs during abrupt changes in the production capacity, approximately 6.37%, while for most time periods, the error remains within 1%, with an average error of 0.49% throughout the process. These results substantially improve the timeliness and accuracy of the reservoir identification. This study offers a novel approach for the co-optimization of complex multi-reservoir gas fields, enriching the theoretical framework of dual-gas co-production and providing technically adaptive solutions and engineering guidance for multilayer unconventional gas exploitation. Full article
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14 pages, 1959 KiB  
Article
Experimental Investigation of Environmental Factors Affecting Cable Bolt Corrosion in Simulated Underground Conditions
by Saisai Wu, Pengbo Cui, Chunshan Zheng, Krzysztof Skrzypkowski and Krzysztof Zagórski
Materials 2025, 18(15), 3460; https://doi.org/10.3390/ma18153460 - 23 Jul 2025
Viewed by 225
Abstract
Corrosion-related failures have emerged as a critical driver of premature support bolt failures in underground mines, emphasizing the urgency of understanding the phenomenon with respect to enhancing safety in underground environments. This study investigated key factors influencing bolt degradation through extensive experimental evaluation [...] Read more.
Corrosion-related failures have emerged as a critical driver of premature support bolt failures in underground mines, emphasizing the urgency of understanding the phenomenon with respect to enhancing safety in underground environments. This study investigated key factors influencing bolt degradation through extensive experimental evaluation of cable bolts in simulated underground bolt environments. Multi-stranded cable specimens were exposed to saturated clay, coal, mine water, and grout/cement environments. Water samples were collected weekly from critical packing sections and analyzed for pH, electrical conductivity, and dissolved oxygen. The mineralogy and atmospheric conditions were identified as principal corrosion factors, and clay-rich and coal matrices accelerated corrosion, linked to high ion mobility and oxygen diffusion. Secondary factors correlated context-dependently: pH was negatively associated with corrosion in mineral-packed environments, while conductivity was correlated with non-mineral matrices. Notably, multi-stranded cables exhibited higher localized galvanic corrosion in inter-strand zones, highlighting design vulnerabilities. This work provides pioneering evidence that geological conditions are primary drivers for corrosion-related failures, offering actionable guidance for corrosion mitigation strategies in mining infrastructure. Full article
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12 pages, 2262 KiB  
Article
Long-Term Creep Mechanical and Acoustic Emission Characteristics of Water-Immersed Coal Pillar Dam
by Ersheng Zha, Mingbo Chi, Zhiguo Cao, Baoyang Wu, Jianjun Hu and Yan Zhu
Appl. Sci. 2025, 15(14), 8012; https://doi.org/10.3390/app15148012 - 18 Jul 2025
Viewed by 192
Abstract
This study conducted uniaxial creep tests on coal samples under both natural and water-saturated conditions for durations of about 180 days per sample to study the stability of coal pillar dams of the Daliuta Coal Mine underground reservoir. Combined with synchronized acoustic emission [...] Read more.
This study conducted uniaxial creep tests on coal samples under both natural and water-saturated conditions for durations of about 180 days per sample to study the stability of coal pillar dams of the Daliuta Coal Mine underground reservoir. Combined with synchronized acoustic emission (AE) monitoring, the research systematically revealed the time-dependent deformation mechanisms and damage evolution laws of coal under prolonged water immersion and natural conditions. The results indicate that water-immersed coal exhibits a unique negative creep phenomenon at the initial stage, with the strain rate down to −0.00086%/d, attributed to non-uniform pore compaction and elastic rebound effects. During the steady-state creep phase, the creep rates under water-immersed and natural conditions were comparable. However, water immersion led to an 11.4% attenuation in elastic modulus, decreasing from 2300 MPa to 2037 MPa. Water immersion would also suppress AE activity, leading to the average daily AE events of 128, which is only 25% of that under natural conditions. In the accelerating creep stage, the AE event rate surged abruptly, validating its potential as an early warning indicator for coal pillar instability. Based on the identified long-term strength of the coal sample, it is recommended to maintain operational loads below the threshold of 9 MPa. This research provides crucial theoretical foundations and experimental data for optimizing the design and safety monitoring of coal pillar dams in CMURs. Full article
(This article belongs to the Section Civil Engineering)
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21 pages, 6724 KiB  
Article
Experimental Study on Damage Characteristics and Microcrack Development of Coal Samples with Different Water Erosion Under Uniaxial Compression
by Maoru Sun, Qiang Xu, Heng He, Jiqiang Shen, Xun Zhang, Yuanfeng Fan, Yukuan Fan and Jinrong Ma
Processes 2025, 13(7), 2196; https://doi.org/10.3390/pr13072196 - 9 Jul 2025
Viewed by 355
Abstract
It is vital to stabilize pillar dams in underground reservoirs in coal mine goafs to protect groundwater resources and quarry safety, practice green mining, and protect the ecological environment. Considering the actual occurrence of coal pillar dams in underground reservoirs, acoustic emission (AE) [...] Read more.
It is vital to stabilize pillar dams in underground reservoirs in coal mine goafs to protect groundwater resources and quarry safety, practice green mining, and protect the ecological environment. Considering the actual occurrence of coal pillar dams in underground reservoirs, acoustic emission (AE) mechanical tests were performed on dry, naturally absorbed, and soaked coal samples. According to the mechanical analysis, Quantitative analysis revealed that dry samples exhibited the highest mechanical parameters (peak strength: 12.3 ± 0.8 MPa; elastic modulus: 1.45 ± 0.12 GPa), followed by natural absorption (peak strength: 9.7 ± 0.6 MPa; elastic modulus: 1.02 ± 0.09 GPa), and soaked absorption showed the lowest values (peak strength: 7.2 ± 0.5 MPa; elastic modulus: 0.78 ± 0.07 GPa). The rate of mechanical deterioration increased by ~25% per 1% increase in moisture content. It was identified that the internal crack development presented a macrofracture surface initiating at the sample center and expanding radially outward, and gradually expanding to the edges by adopting AE seismic source localization and the K-means clustering algorithm. Soaked absorption was easier to produce shear cracks than natural absorption, and a higher water content increased the likelihood. The b-value of the AE damage evaluation index based on crack development was negatively correlated with the rock damage state, and the S-value was positively correlated, and both effectively characterized it. The research results can offer reference and guidance for the support design, monitoring, and warning of coal pillar dams in underground reservoirs. (The samples were tested under two moisture conditions: (1) ‘Soaked absorption’—samples fully saturated by immersion in water for 24 h, and (2) ‘Natural absorption’—samples equilibrated at 50% relative humidity and 25 °C for 7 days). Full article
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18 pages, 8224 KiB  
Article
Cascaded Absorption Heat Pump Integration in Biomass CHP Systems: Multi-Source Waste Heat Recovery for Low-Carbon District Heating
by Pengying Wang and Hangyu Zhou
Sustainability 2025, 17(13), 5870; https://doi.org/10.3390/su17135870 - 26 Jun 2025
Viewed by 271
Abstract
District heating systems in northern China predominantly rely on coal-fired heat sources, necessitating sustainable alternatives to reduce carbon emissions. This study investigates a biomass combined heat and power (CHP) system integrated with cascaded absorption heat pump (AHP) technology to recover waste heat from [...] Read more.
District heating systems in northern China predominantly rely on coal-fired heat sources, necessitating sustainable alternatives to reduce carbon emissions. This study investigates a biomass combined heat and power (CHP) system integrated with cascaded absorption heat pump (AHP) technology to recover waste heat from semi-dry flue gas desulfurization exhaust and turbine condenser cooling water. A multi-source operational framework is developed, coordinating biomass CHP units with coal-fired boilers for peak-load regulation. The proposed system employs a two-stage heat recovery methodology: preliminary sensible heat extraction from non-saturated flue gas (elevating primary heating loop (PHL) return water from 50 °C to 55 °C), followed by serial AHPs utilizing turbine extraction steam to upgrade waste heat from circulating cooling water (further heating PHL water to 85 °C). Parametric analyses demonstrate that the cascaded AHP system reduces turbine steam extraction by 4.4 to 8.8 t/h compared to conventional steam-driven heating, enabling 3235 MWh of annual additional power generation. Environmental benefits include an annual CO2 reduction of 1821 tonnes, calculated using regional grid emission factors. The integration of waste heat recovery and multi-source coordination achieves synergistic improvements in energy efficiency and operational flexibility, advancing low-carbon transitions in district heating systems. Full article
(This article belongs to the Section Energy Sustainability)
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20 pages, 6844 KiB  
Article
Influence of Water Immersion on Coal Rocks and Failure Patterns of Underground Coal Pillars Considering Strength Reduction
by Haihua Zhu, Peitao Wang, Kewei Zhang, Yijun Gao, Zhenwu Qi and Meifeng Cai
Appl. Sci. 2025, 15(12), 6700; https://doi.org/10.3390/app15126700 - 14 Jun 2025
Viewed by 356
Abstract
The long-term immersion of coal rock may affect its mechanical properties and failure modes, potentially impacting the stability of coal pillars. This work aims to investigate the influence of the immersion duration on the mechanical properties and fracture evolution processes of coal, employing [...] Read more.
The long-term immersion of coal rock may affect its mechanical properties and failure modes, potentially impacting the stability of coal pillars. This work aims to investigate the influence of the immersion duration on the mechanical properties and fracture evolution processes of coal, employing acoustic emission detection and the digital image correlation (DIC) method. The work focuses on the weakening law of the coal pillar dam in contact with water and obtains a model of the strength deterioration after different periods of water immersion. The stress–strain curves of coal specimens with varying immersion durations are obtained. The results show that the peak absorption rate of coal samples immersed in water transpires within 24 h, with fundamental saturation being achieved at between 25 and 30 days at saturation moisture content of 1.97%. The specimen’s compressive stress after being immersed in water for 7 days is 3.34 MPa, with strain of 0.18%. The cracking stress is 15.60 MPa, with strain of 0.54%. The peak stress is recorded at 27.65 MPa, with strain of 0.92%. The complete rupture stress measures 23.37 MPa, with the maximum strain at 0.95%. During the yielding stage, the specimen has the highest strain increment of 0.38%. Short-term immersion brings about an increase in the coal sample’s plasticity, exhibiting a relatively minor softening impact of water, resulting in comparatively intact fragmentation and modest breakage. A negative exponential function relationship is observed between the compressive strength of coal and the immersion duration. The mechanical reduction relationship is utilized to analyze the failure patterns of coal pillars in underground reservoirs. With prolonged water immersion, the damage area expands to include the coal pillars and the surrounding rock of the excavation area. Full article
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13 pages, 2357 KiB  
Article
Effect of Coal Gangue Powder Addition on Hydraulic Properties of Aeolian Sandy Soil and Plant Growth
by Xiaoyun Ding, Ruimin He, Zhenguo Xing, Haoyan Wei, Jiping Niu, Shi Chen and Min Li
Horticulturae 2025, 11(6), 634; https://doi.org/10.3390/horticulturae11060634 - 5 Jun 2025
Viewed by 449
Abstract
Coal gangue is a fine-grained mineral with nutrient content, which can be used as a potential soil amendment. Nevertheless, current research on using coal gangue to improve soil water and support plant growth is still insufficient. In this study, coal gangue powder (CGP) [...] Read more.
Coal gangue is a fine-grained mineral with nutrient content, which can be used as a potential soil amendment. Nevertheless, current research on using coal gangue to improve soil water and support plant growth is still insufficient. In this study, coal gangue powder (CGP) was added to aeolian sandy soil. We compared the soil hydraulic properties and plant growth of original aeolian sandy soil (CK) and different CGP application rates (10% and 20%). The results indicated that the application of CGP transformed the soil texture from sandy to loamy, significantly reduced soil bulk density and saturated hydraulic conductivity (Ks) values, altered the soil water characteristic curve, enhanced soil water-holding capacity, and increased plant-available water. Compared with the CK group, the emergence rate of alfalfa seeds increased from approximately 50% to over 70% after CGP application. During the growth process, CGP application significantly elevated the net photosynthetic rate, transpiration rate, and stomatal conductance of alfalfa leaves. Rapid fluorescence kinetics monitoring of leaves demonstrated that alfalfa treated with CGP had a higher efficiency in light energy utilization. However, the photosynthetic capacity of leaves did not improve as the CGP application rate increased from 10% to 20%, suggesting that excessive CGP addition did not continuously benefit plant gas exchange. In conclusion, CGP application can improve the soil hydraulic properties of aeolian sandy soil and support plant growth and development, which is conducive to reducing the accumulated amount of coal gangue, alleviating plant water stress, and promoting ecological restoration in arid mining areas. We recommend a 10% addition of coal gangue powder as the optimal amount for similar soils. Full article
(This article belongs to the Section Plant Nutrition)
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16 pages, 5360 KiB  
Article
Petrophysics Parameter Inversion and Its Application Based on the Transient Electromagnetic Method
by Xiaozhen Teng, Jianhua Yue, Kailiang Lu, Danyang Xi, Herui Zhang and Kua Wang
Appl. Sci. 2025, 15(11), 6256; https://doi.org/10.3390/app15116256 - 2 Jun 2025
Viewed by 430
Abstract
The transient electromagnetic (TEM) method is a widely used geophysical technique for detecting subsurface electrical structures. However, its inversion results are typically limited to resistivity parameters, making it challenging to directly infer key petrophysical properties, such as water saturation and porosity. This study [...] Read more.
The transient electromagnetic (TEM) method is a widely used geophysical technique for detecting subsurface electrical structures. However, its inversion results are typically limited to resistivity parameters, making it challenging to directly infer key petrophysical properties, such as water saturation and porosity. This study proposes a petrophysics parameter inversion approach based on TEM data. By constructing multiple geoelectric models with varying porosities and water saturation values for numerical simulations, the results demonstrated that both the forward and inversion responses of the TEM field maintained errors within 5%. The inversion procedure begins with the reconstruction of the subsurface resistivity distribution, which reliably reflects the true geoelectric model. Based on the inverted resistivity, the water saturation and porosity parameters are subsequently estimated. The inversion results closely match the overall trend of the actual model and exhibit a clear response at the target layer. Finally, the proposed method is applied to a field test at the Tongxin Coal Mine. By integrating subsurface electrical responses with geological data, the spatial distributions of water saturation and porosity within the coal-bearing strata were delineated. This provides a scientific basis for the detailed characterization of the physical properties of coal and surrounding rock, as well as for understanding the development of pores and fractures in underground strata. Full article
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21 pages, 4797 KiB  
Article
Multifractal Characterization of Pore Heterogeneity and Water Distribution in Medium- and High-Rank Coals via Nuclear Magnetic Resonance
by Huan Liu, Shasha Zhang, Yu Qiao, Danfeng Xie and Long Chang
Fractal Fract. 2025, 9(5), 290; https://doi.org/10.3390/fractalfract9050290 - 28 Apr 2025
Viewed by 373
Abstract
Comprehensive assessment of pore structure and multiphase water distribution is critical to the flow and transport process in coalbed methane (CBM) reservoirs. In this study, nuclear magnetic resonance (NMR) and multifractal analysis were integrated to quantify the multiscale heterogeneity of nine medium- and [...] Read more.
Comprehensive assessment of pore structure and multiphase water distribution is critical to the flow and transport process in coalbed methane (CBM) reservoirs. In this study, nuclear magnetic resonance (NMR) and multifractal analysis were integrated to quantify the multiscale heterogeneity of nine medium- and high-rank coals under water-saturated and dry conditions. By applying the box-counting method to transverse relaxation time (T2) spectra, multifractal parameters were derived to characterize pore heterogeneity and residual water distribution. The influencing factors of pore heterogeneity were also discussed. The results show that pore structures in high-rank coals (HCs) exhibit a broader multifractal spectrum and stronger rightward spectrum than those of medium-rank coals, reflecting micropore-dominated heterogeneity and the complexity induced by aromatization in HCs. The vitrinite content enhances micropore development, increasing the heterogeneity and complexity of pore structure and residual water distribution. Inertinite content shows opposite trends compared to vitrinite content for the effect on pore structure and water distribution. Volatile yield reflects coal metamorphism and thermal maturity, which inversely correlates with pore heterogeneity and complexity. Residual water mainly distributes to adsorption pores and pore throats, shortening T2 relaxation (bound water effect) and reducing spectral asymmetry. The equivalence of the multifractal dimension and singularity spectrum validates their joint utility in characterizing pore structure. Minerals enhance pore connectivity but suppress complexity, while moisture and ash contents show negligible impacts. These findings provide a theoretical reference for CBM exploration, especially in optimizing fluid transportation and CBM production strategies and identifying CBM sweet spots. Full article
(This article belongs to the Special Issue Multiscale Fractal Analysis in Unconventional Reservoirs)
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14 pages, 5227 KiB  
Article
Study on Wellbore Instability Mechanism and High-Performance Water-Based Drilling Fluid for Deep Coal Reservoir
by Jinliang Han, Jie Xu, Jinsheng Sun, Kaihe Lv, Kang Ren, Jiafeng Jin, Hailong Li, Yifu Long and Yang Wu
Processes 2025, 13(5), 1262; https://doi.org/10.3390/pr13051262 - 22 Apr 2025
Cited by 2 | Viewed by 507
Abstract
Deep coalbed methane (CBM) reservoirs have the characteristics of low permeability, low porosity, and low water saturation, which easily experience wellbore instability due to drilling fluid, severely affecting drilling safety. Based on the physical property analysis of coal samples, the wellbore instability mechanism [...] Read more.
Deep coalbed methane (CBM) reservoirs have the characteristics of low permeability, low porosity, and low water saturation, which easily experience wellbore instability due to drilling fluid, severely affecting drilling safety. Based on the physical property analysis of coal samples, the wellbore instability mechanism of the deep CBM reservoir was investigated by multiple methods. It was found that the wellbore instability is mainly caused by drilling fluid intrusion and the interaction between drilling fluid and coal formation; the fracture pressure of coal after immersion decreased from 27.4 MPa to 25.0 MPa because of the imbibition of drilling fluid. A novel nano-plugging agent with a size of 460 nm was prepared that can cement coal particles to form disc-shaped briquettes with a tensile strength of 2.27 MPa. Based on that, an effective anti-collapse drilling fluid for deep coal rock reservoirs was constructed, the invasion depth of the optimized drilling fluid was only 6 mm. The CT result shows that the number of fractures and pores in coal rock significantly reduced after treatment with the wellbore-stabilizing drilling fluid; nano-plugging anti-collapse agent in drilling fluid can form a dense layer on the coal surface, and then the hydration swelling of clay in the wellbore region can be effectively suppressed. Finally, the drilling fluid in this work can achieve the purpose of sealing and wettability alternation to prevent the collapse of the wellbore in the deep coal reservoir. Full article
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27 pages, 6070 KiB  
Article
The Effects of Water Immersion-Induced Softening and Anisotropy of Mechanical Properties on Gas Depletion in Underground Coal Mines
by Yuling Tan, Hanlei Zhang, Xiuling Chen, Qinghe Niu and Guanglei Cui
Energies 2025, 18(8), 2033; https://doi.org/10.3390/en18082033 - 16 Apr 2025
Viewed by 292
Abstract
Coalbed methane (CBM), a highly efficient and clean energy source with substantial reserves, holds significant development potential. Permeability is a crucial factor in CBM recovery in underground coal mines. Hydraulic fracturing technology causes water to enter the coal reservoir, which will change mechanical [...] Read more.
Coalbed methane (CBM), a highly efficient and clean energy source with substantial reserves, holds significant development potential. Permeability is a crucial factor in CBM recovery in underground coal mines. Hydraulic fracturing technology causes water to enter the coal reservoir, which will change mechanical properties, affecting permeability changes and gas depletion trends. This study combines theoretical analysis with numerical simulation techniques to create a coupling model for fluid flow and reservoir deformation. The numerical model is established by referring to the geological conditions of the Wangpo coal mine, Shanxi province. Specifically, the impact of water immersion-induced softening and changes in the anisotropic mechanical properties on the directional permeability and gas flow rate is examined through parametric analysis. The dominant role in controlling the evolution of permeability varies depending on the orientation. Horizontal deformation primarily affects vertical permeability, which is subsequently influenced by the gas adsorption effect. In contrast, horizontal permeability is mainly determined by vertical deformation. Water immersion-induced softening significantly reduces the permeability and gas flow rate. Young’s modulus, which is dependent on water saturation, alters the permeability trend under water-rich conditions. Vertical permeability evolution is more sensitive to water-induced softening and changes in the anisotropic mechanical properties. When Sw0 is 0.7, the vertical permeability decreases by 60%, while the horizontal permeability decreases by 43%. Ultimately, the vertical permeability ratio stabilizes between 0.9 and 1.0, while the horizontal permeability ratio stabilizes in the range of 0.6 to 0.7. The influence of permeability on gas production characteristics is dependent on the water saturation conditions. In water-scarce conditions, variations in the fracture permeability greatly influence production flow rates. Conversely, in water-rich conditions, a higher permeability facilitates a quicker return to original levels and also enhances gas production flow rates. The research findings from this study provide important insights for fully understanding the mechanical properties of coal and ensuring the sustainable production of CBM. Full article
(This article belongs to the Special Issue Advanced Clean Coal Technology)
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16 pages, 5538 KiB  
Article
Magnetic Coal Gasification Slag/Graphite Phase Carbon Nitride Composites for Photocatalytic Degradation of Tetracycline
by Yue Yin, Tingan Yao, Guohui Dong and Chuanyi Wang
Processes 2025, 13(3), 770; https://doi.org/10.3390/pr13030770 - 7 Mar 2025
Viewed by 675
Abstract
Graphite-phase carbon nitride (CN) has the advantages of high stability, non-toxicity, and harmlessness in degrading antibiotic pollutants in water. How to achieve the reduction of its electron-hole complexation efficiency as well as the improvement of its recyclability, while at the same time ensuring [...] Read more.
Graphite-phase carbon nitride (CN) has the advantages of high stability, non-toxicity, and harmlessness in degrading antibiotic pollutants in water. How to achieve the reduction of its electron-hole complexation efficiency as well as the improvement of its recyclability, while at the same time ensuring these advantages, is the focus of this paper. In this study, modified magnetic particles selected from coal gasification slag were used as carriers, which were compounded with CN and then subjected to a simple roasting process to obtain composite magnetic photocatalysts (MCN) with different ratios. The introduction of porous magnetic carriers increased the specific surface area of MCN, provided more active sites, and effectively improved the migration ability and redox capacity of CN carriers. Among them, 50% MCN showed excellent photodegradation performance, and the removal rate of tetracycline reached 82% within 60 min, which was much higher than that of CN. 50% MCN has a saturated magnetisation intensity of 1.55 emu·g−1, which can be regenerated after recycling using a magnetic field, and the degradation efficiency of tetracycline is still more than 70% after five cycles, indicating that 50% MCN has good stability. This work demonstrates that magnetic gasification slag as a modified carrier can effectively promote the separation of photogenerated electron-hole pairs of graphite-phase carbon nitride, which provides a reference for the resourceful utilisation of coal gasification slag, as well as for the construction of g-C3N4-based photocatalysts with highly efficient and stable photodegradation activity. This work exemplifies how waste-derived materials can advance photocatalyst design, addressing both efficiency and sustainability challenges in water treatment. Full article
(This article belongs to the Section Environmental and Green Processes)
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20 pages, 10795 KiB  
Article
Study on Damage Rupture and Crack Evolution Law of Coal Samples Under the Influence of Water Immersion Pressure
by Jianhua Shangguan, Haotian Guo, Shenggen Cao and Jialong Sun
Water 2025, 17(2), 263; https://doi.org/10.3390/w17020263 - 18 Jan 2025
Viewed by 775
Abstract
Underground reservoir technology in coal mines enables the effective storage and utilization of water resources disturbed by mining activities. Owing to the effects of mining operations and water extraction/injection activities, the water head in underground reservoirs fluctuates dynamically. The total bearing capacity of [...] Read more.
Underground reservoir technology in coal mines enables the effective storage and utilization of water resources disturbed by mining activities. Owing to the effects of mining operations and water extraction/injection activities, the water head in underground reservoirs fluctuates dynamically. The total bearing capacity of a coal pillar dam is significantly reduced due to the combined effects of overlying rock stress, dynamic and static water pressures, and mining-induced stresses, which are critical for ensuring the safe operation of underground reservoirs. Based on the correlation between different water head heights and the corresponding water pressures on the coal pillar dam, a custom-made coal rock pressure water immersion test device was used to saturate the coal samples under various water pressure conditions. The mechanical deformation and failure characteristics of the samples and fracture propagation patterns under different water pressure conditions were studied using uniaxial compression, acoustic emission (AE), and three-dimensional X-ray microimaging. The results indicated that, compared with the dry state, the peak strain of the water-immersed coal samples increased to varying degrees with increasing water pressure. Additionally, the average porosity and the number of pores with diameters in the range of 0 to 150 μm significantly increased in water-immersed coal samples. Under the combined influence of water immersion pressure and uniaxial stress, loading the water-saturated coal samples to the fracture damage threshold significantly intensified deformation, failure, and fracture propagation within the samples, and the failure mode changed from tension to a composite tensile–shear failure. Full article
(This article belongs to the Special Issue Mine Water Safety and Environment, 2nd Edition)
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19 pages, 4327 KiB  
Study Protocol
Improving Saline–Alkaline Soil and Ryegrass Growth with Coal Gangue Treatments
by Siqi Li, Xingqiang Li, Xiaolin Qiang, Zhao Yu, Hongyuan Li, Zhaojun Sun, Qian Li, Jun He, Lei Han and Ningxin Zhao
Plants 2024, 13(23), 3419; https://doi.org/10.3390/plants13233419 - 5 Dec 2024
Cited by 4 | Viewed by 1455
Abstract
Soil covering is a soil management technique used to address issues such as high alkalinity, nutrient deficiency, and a low soil and water-holding capacity in saline–alkali lands. Coal gangue, a solid waste generated from coal mining, contains nutrients and trace elements comparable to [...] Read more.
Soil covering is a soil management technique used to address issues such as high alkalinity, nutrient deficiency, and a low soil and water-holding capacity in saline–alkali lands. Coal gangue, a solid waste generated from coal mining, contains nutrients and trace elements comparable to those in soil, making it a promising covering material. This study investigates the effects and mechanisms of coal gangue coverage on the physicochemical properties of soil, enzyme activity, and the growth of ryegrass. The experimental treatments comprised (1) three coal gangue particle sizes (0–0.5 cm, 0.5–1 cm, and 1–2 cm) and (2) three coverage thicknesses (4 cm, 8 cm, and 12 cm). The results show that with particle sizes of 0–1 cm and cover thicknesses of 8–12 cm, the saturated water content of the soil increased by 11.1% to 17.23%, the content of organic matter rose by 4.99 to 13.64 mg/kg, the total nitrogen increased by 0.07 to 0.12 mg/kg, and the urease activity increased by 0.56 to 0.64 μg/(d·g). Our analyses indicated that an improvement in soil porosity, a reduction in pH, and an increase in urease, organic matter, and total nitrogen collectively promoted ryegrass growth, with similar impacts. Among the treatments, coverage with 12 cm of coal gangue with a size of 0.5–1 cm produced the best results, increasing the ryegrass height by 16.24 cm, primarily due to a high level of soil porosity and elevated urease activity. In conclusion, coal gangue coverage significantly improves the properties of soil, enhances enzyme activity, and promotes ryegrass growth. Full article
(This article belongs to the Section Plant Response to Abiotic Stress and Climate Change)
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16 pages, 13187 KiB  
Article
NMR-Based Investigation of Pore–Fracture Structure Heterogeneity in Deep Coals of Different Macrolithotypes in the Daning-Jixian Block, Ordos Basin
by Wei Zhang, Zheng Zhang, Liheng Bian, Rui Shi, Hewei Zhang and Jian Shen
Energies 2024, 17(23), 6081; https://doi.org/10.3390/en17236081 - 3 Dec 2024
Viewed by 756
Abstract
Deep coalbed methane (CBM) demonstrates significant production potential, and a fervent exploration and development boom is currently underway in China. The permeability of coal reservoirs is heavily influenced by pore–fracture structure heterogeneity. Some researches have been conducted on deep coals’ pore–fracture structure; however, [...] Read more.
Deep coalbed methane (CBM) demonstrates significant production potential, and a fervent exploration and development boom is currently underway in China. The permeability of coal reservoirs is heavily influenced by pore–fracture structure heterogeneity. Some researches have been conducted on deep coals’ pore–fracture structure; however, these studies mostly consider coal as a homogeneous material, neglecting the heterogeneity of the macrolithotypes within the coal. In this study, 33 deep coals with burial depths of more than 2000 m were obtained from the Daning-Jixian block of the Ordos Basin, covering all macrolithotypes: bright coal (BC), semi-bright coal (SBC), semi-dull coal (SDC), and dull coal (DC). These samples were subjected to three sets of NMR tests in dry, fully saturated, and irreducible water conditions, with the pore–fracture structure characteristics being analyzed. The results demonstrate that the sampled deep coals’ pore–fracture structure is highly heterogeneous, with transitional pores being dominant, followed by mesopores, “macropores and fractures”, and micropores. The NMR T2C ranges from 0.61 to 2.44 ms, with an average of 1.19 ms; a higher T2C value indicates more developed micropores. The ranges for producible water porosity (φpr) and producible water saturation (Spr) are 0.31–7.24% (avg. 2.42%) and 6.97–71.47% (avg. 31.06%), respectively. Both of them exhibit a high positive correlation with the total volumes of “macropores and fractures” and mesopores. Compared to SDC and DC, the BC and SBC, especially the former, overall contain more “macropores and fractures” and mesopores, fewer transitional pores and micropores, and higher φpr and Spr. These findings suggest that regions with abundant BC and SBC should be prioritized during deep CBM exploration and production due to the inherently superior permeability and gas extraction potential of BC and SBC, and these coals are likely to require less intensive stimulation to achieve higher recovery rates and could provide more sustainable gas production over time. Full article
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