Search Results (7,793)

Grain moisture content is a key variable for safe storage, drying control, and quality management. Microwave sensing is attractive because water strongly modulates the complex relative permittivity (ε* = ε′ – jε″) of granular agricultural products, thereby shaping broadband scattering-parameter spectra. This study presents a meter-referenced feasibility evaluation of an interpretable S-parameter–permittivity–moisture chain using a vector network analyzer over 2–18 GHz. Wheat, maize, and mung bean were prepared at six moisture levels, and the moisture values were referenced to two commercial grain moisture meters (MC_ref) to represent rapid on-site benchmarking rather than absolute gravimetric moisture determination. Therefore, the reported errors should be interpreted as commercial-meter-referenced calibration indicators rather than absolute gravimetric moisture prediction accuracy. Two free-space configurations were compared on the same platform: a two-horn transmission setup under controlled packing and a metal-backed double-pass reflection setup intended to represent single-sided access under loose bulk packing. After SOLT calibration and empty-holder background normalization, ε′ and ε″ were retrieved via complex-domain nonlinear least-squares fitting of physics-based slab models to measured S21 spectra. The results show that moisture-dependent dielectric responses were grain- and configuration-dependent. In particular, ε″ generally provided a more robust moisture-sensitive feature in the free-space transmission configuration, whereas the optimal single-parameter predictor in the metal-backed configuration differed among grains. A mid-band frequency window of approximately 8–16 GHz provided more stable inversion by avoiding low-frequency coupling artefacts and high-frequency signal-to-noise degradation. The metal-backed configuration preserved moisture trends but yielded lower effective ε′ values, likely due to increased air fraction under loose packing. These results indicate that packing state, grain type, and frequency-window selection are critical factors for transferring microwave moisture calibration from laboratory measurements to practical grain-handling scenarios. Full article

Serratia marcescens has emerged as an important opportunistic pathogen in intensive care units (ICUs), where critically ill patients, invasive devices, antimicrobial exposure, and complex environmental reservoirs create favorable conditions for colonization, infection, and recurrent outbreaks. This narrative review synthesizes evidence from the past decade regarding the clinical and molecular epidemiology, environmental persistence, device-associated transmission, biofilm-mediated resistance, and infection-control strategies of S. marcescens in ICU settings. The literature was reviewed using an integrative approach informed by Ferrari’s narrative review framework, with thematic synthesis across clinical, microbiological, environmental, and genomic domains. Recent evidence indicates that ICU-associated S. marcescens infections frequently involve respiratory tract colonization, ventilator-associated pneumonia, bloodstream infection, urinary tract infection, and device-related transmission. Hospital water systems, sink drains, wet surfaces, ventilator circuits, reusable equipment, and contaminated antiseptic or liquid products may serve as persistent reservoirs, particularly when biofilm formation supports long-term survival and recurrent dissemination. At the molecular level, S. marcescens demonstrates substantial genomic diversity, intrinsic and acquired antimicrobial resistance, inducible AmpC β-lactamase activity, efflux-mediated tolerance, and plasmid-associated resistance gene transfer. This review particularly emphasizes the molecular determinants that enable S. marcescens to persist in ICU ecosystems, including AmpC-mediated β-lactam resistance, efflux-associated tolerance, quorum-sensing-regulated biofilm formation, plasmid-mediated horizontal gene transfer, and WGS-defined clonal transmission. Whole-genome sequencing, rapid molecular diagnostics, active surveillance, environmental sampling, and integrated infection-control bundles have become increasingly important for distinguishing clonal outbreaks from endemic transmission and guiding timely interventions. Emerging perspectives emphasize the need to combine antimicrobial stewardship, environmental engineering, respiratory-care auditing, anti-biofilm strategies, and AI-assisted real-time surveillance into adaptive ICU infection-control frameworks. Overall, S. marcescens should be regarded not merely as an episodic outbreak organism, but as a highly adaptable ICU-associated pathogen requiring multidisciplinary prevention strategies. Full article

Flow-cell ultrasonication of gelatinized rice flour slurries alters cultivar-dependent water solubility, viscosity, and retrogradation of pregelatinized rice flour, properties important for plant-based beverages and convenience foods. We tested whether cultivar-level composition descriptors, amylose, protein, and fiber, can represent cultivar-associated variation in ultrasonication responses while separating process-only prediction, within-domain cultivar representation, and unseen-cultivar transfer. Six rice cultivars were processed across nine amplitude-time combinations and two slurry concentrations. Water solubility index, apparent viscosity at a shear rate of 50 s⁻¹, and setback viscosity were modeled using ElasticNet, partial least squares regression, support vector regression, random forest, and extreme gradient boosting. Three input formulations were compared: process variables alone, process variables plus composition descriptors, and process variables plus cultivar identity. Repeated nested group cross-validation showed insufficient process-only prediction and substantial improvement from composition descriptors. Within-domain validation showed comparable composition-descriptor and cultivar-identity performance under nonlinear algorithms. However, because cultivar identity is undefined for absent cultivars, leave-one-cultivar-out transfer of the composition-descriptor model remained uncertain. Cross-fitted Shapley additive explanations showed predictions used process and composition variables. For the validated cultivar-process domain, this approach can screen cultivar-process combinations for beverage and convenience-food applications, but replacing categorical source identifiers with continuous descriptors requires explicit transfer validation. Full article

Sustainable water remediation requires catalytic strategies that remove contaminants efficiently while reducing chemical input, byproduct formation, and ecological disturbance. Conventional radical-dominated advanced oxidation processes can rapidly degrade pollutants, but their reliance on high oxidant dosages and freely diffusing reactive oxygen species often causes matrix quenching, non-selective oxidation, low oxidant utilization, and potential ecological risks. Mild interfacial catalysis provides a materials-chemistry strategy to regulate oxidative intensity and direct contaminant transformation under environmentally relevant conditions. In this review, mild catalysts are defined by pathway-selective, interfacially confined, and environmentally compatible oxidation rather than by low dosage alone. Representative non-radical or low-intensity pathways, including singlet oxygen generation, surface-mediated electron transfer, high-valent metal–oxo species, and direct oxidative transfer processes, are discussed in relation to active-site structure, oxidant utilization, matrix tolerance, and byproduct control. We further summarize how coordination environments, defect chemistry, heteroatom configurations, nanoconfinement, and immobilized interfaces regulate reactive-species formation and interfacial charge transfer. Key material platforms, including single-atom catalysts, heteroatom-doped carbons, defect-engineered oxides, catalytic membranes, hydrogels, and floating or immobilized composites, are evaluated from mechanistic and application-oriented perspectives. Finally, catalyst regeneration, cost, microbial community responses, algae–bacteria balance, ecotoxicity, and long-term safety are discussed to guide sustainable aquatic ecosystem restoration. Full article

Floodplain wetlands are globally important ecosystems, yet altered hydrological regimes increasingly disrupt the balance between woody and non-woody vegetation. In Australia’s regulated Murray–Darling Basin, it remains unclear whether woody plant encroachment represents a persistent shift toward terrestrialisation or a dynamic process that can be periodically reversed by flooding. This study quantified long-term patterns of woody-vegetation encroachment and retreat across 32,000 ha of mapped wetlands in the mid-Murrumbidgee River floodplain from 1988 to 2023, and assessed how hydrological variability and floodplain connectivity mediate these dynamics. Using open, analysis-ready Earth observation data from Digital Earth Australia (DEA) within the Open Data Cube (ODC) framework, we combined DEA Land Cover for transition mapping, Water Observations for hydrological masking, Landsat surface reflectance for Enhanced Vegetation Index (EVI)-based spectral plausibility testing, and the Wetlands Insight Tool for qualitative temporal context. Woody-vegetation dynamics were strongly non-linear and closely linked to alternating drought and flood phases. During the Millennium Drought (2001–2009), mapped woody-cover decline exceeded 50% of wetland area in some sub-regions, whereas the post-drought recovery interval (2008–2013) produced encroachment exceeding 40% in the most affected areas. Across the full 35-year record, mean encroachment rates ranged from 85 to 250 ha yr⁻¹ among sub-regions, summing to approximately 865 ha yr⁻¹ of woody expansion across the floodplain, while retreat rates were lower overall (approximately 634 ha yr⁻¹), resulting in a net expansion of woody cover. Local hydrological connectivity strongly mediated these responses: infrequently inundated wetlands showed persistent terrestrialisation, whereas more frequently inundated, better-connected wetlands experienced periodic flood-driven retreat. Landsat-derived EVI broadly supported the mapped transitions, indicating general consistency with canopy greening and canopy decline, supporting the ecological plausibility of the detected changes. This open DEA–ODC workflow provides a transparent, transferable framework for operational wetland monitoring and demonstrates that maintaining natural flood frequency, duration, and connectivity is essential for sustaining the resilience of regulated floodplain systems. Full article

Urban heat stress is intensifying under climate change, particularly in outdoor public spaces where conventional mechanical cooling is impractical. This study develops a climate-driven, system-level numerical framework to evaluate the pre-deployment feasibility of modular, solar-powered spray cooling canopies across 110 cities in Türkiye. Hourly Typical Meteorological Year (TMYx) weather files, representing a single typical year constructed from 2009 to 2023 source data, are used to estimate photovoltaic (PV) energy yield, electrical load, feasible misting duration, water demand, and PV-to-load autonomy under summer daytime conditions. The misting operation is governed by a rule-based adaptive control strategy based on air temperature, relative humidity, and plane-of-array irradiance. To support transferable comparison, the cities are classified into six summer climate-archetype zones using k-means clustering of standardized climate variables, including temperature, humidity, irradiance, wind speed, and summer precipitation. Results show that evaporative cooling feasibility is governed primarily by humidity rather than temperature alone. Hot–Dry Inland cities exhibit the longest mean misting duration (501.90 h) and highest water demand (30,152 L per module), but the lowest PV-to-load autonomy ratio (1.55) because of high pump-driven electrical demand. In contrast, Humid Black Sea cities show minimal misting duration (11.43 h) and water use (465 L per module), but the highest autonomy ratio (39.68) due to very limited system activation. Thus, high autonomy does not necessarily indicate high cooling usefulness. The proposed framework provides a reproducible screening tool for identifying where PV-powered spray cooling canopies are climatically suitable, where water and PV sizing become limiting, and where alternative outdoor heat-mitigation strategies may be more appropriate. Full article

Public concrete datasets often contain duplicate records, coupled variables, and cross-source distribution shifts, which may lead to overly optimistic model evaluation. Based on a deduplicated UCI high-performance concrete dataset (1005 samples), this study develops a leakage-controlled data-driven workflow with applicability-domain assessment. TabPFN, SHAP, and NSGA-II are used for compressive strength prediction, model-response attribution, and scenario-based candidate mix screening, respectively. Model evaluation follows a unified data split, inner training-set cross-validation, and an independent test-set protocol. In addition, 502 non-overlapping records from the Mendeley PCC dataset are used as an external benchmark to examine cross-source transferability and sensitivity to distribution shift. The results show that TabPFN achieves the highest R² and the lowest RMSE, MAE, and MAPE on the internal UCI test set, with values of 0.953, 3.744 MPa, 2.265 MPa, and 7.580%, respectively; however, its advantage over strong baselines such as CatBoost is limited. On the external Mendeley PCC dataset, TabPFN remains competitive, with R², RMSE, and MAE values of 0.490, 15.175 MPa, and 11.457 MPa, respectively, but its performance is close to that of random forest, XGBoost, and CatBoost. The 5NN applicability-domain stratification shows that external samples located within the 95% 5NN applicability domain achieve improved performance (R² = 0.634 and RMSE = 12.367 MPa), suggesting that external prediction errors are associated with the distance from the source-domain distribution. SHAP results indicate that cement, ground granulated blast-furnace slag, curing age, and water are the main attribution variables in the model output; their response directions should be interpreted as statistical attributions rather than material causal mechanisms. The Pareto candidate mixes generated by NSGA-II satisfy basic engineering constraints. Nevertheless, because the external benchmark reveals sensitivity to cross-source distribution shift, the resulting mix proportions should be treated as pre-experimental screening candidates rather than engineering-validated low-GWP concrete mix proportions. Full article

Oxygen (O₂) leakage in macrophyte rhizospheres is an adaptive strategy for hypoxic environments, which is important in lake ecological restoration. In this investigation, the fluorescent planar optode (PO) technique is used for two-dimensional (2D) distribution of dissolved O₂ at a submillimeter scale in the rhizosphere of Vallisneria spiralis under various environmental conditions. The spatial heterogeneity in the distribution of oxic microniches is frequently verified in the rhizosphere. The radial oxygen loss (ROL) rate for root systems is characterized by the following sequence: basal root (20.6 ± 5.1–49.6 ± 9.5 nmol m⁻² s⁻¹, n = 7) > lateral root (14.1 ± 4.1–36.6 ± 8.3 nmol m⁻² s⁻¹, n = 7) > root tip (13.1 ± 4.6–28.8 ± 6.4 nmol m⁻² s⁻¹, n = 7). The O₂ maximum value on lines transecting each kind of root also obeys the sequence mentioned above. For one typical root, (1) O₂ decreases from 131.2 ± 2.4–147.4 ± 3.7 μmol L⁻¹ at the root center to 47.2 ± 1.4–75.9 ± 2.2 μmol L⁻¹ in the rhizosphere fringe due to O₂ supply from the root surface and O₂ consumption in rhizosphere sediment, and (2) the furthest distance from the aboveground part to the root tip leads to the lowest O₂ concentration at the root apex of that root. The light/dark transition and O₂ level in overlying water modulate the photosynthetic activity of leaves and the transfer of oxygen in the water column through aerenchyma tissue to the roots. The sequence of the oxygenated area (%), ROL rate, and O₂ concentration in rhizosphere sediment under various conditions is demonstrated as: high illumination/high O₂ > darkness/high O₂ > high illumination/low O₂ > darkness/low O₂. The effect of O₂ in water on the ROL of Vallisneria spiralis is more distinct than illumination. Oxygen storage in roots, and especially O₂ diffusion from overlying water, can supplement O₂ deficiency in the rhizosphere during the cessation of photosynthesis under darkness. This research advances the understanding of complex interrelationships among O₂ dynamics in different root parts, photosynthesis, O₂ in overlying water and O₂ transfer through plant aerenchyma to the rhizosphere. Full article

Accurate real-time soil moisture monitoring is critical for optimizing water use and ensuring crop health and food security. This study aims to calibrate and integrate low-cost capacitive soil moisture sensors into a solar-powered sensor node for real-time soil moisture monitoring in a loamy sand soil. Three capacitive soil moisture sensors were calibrated in the laboratory under controlled volumetric water content conditions (0–40%) using a constrained linear regression approach. The system was tested in a limited pilot-scale in a drip-irrigated onion field at the IWAD farm, Yagaba (North-East Region, Ghana). The results showed good agreement of the sensor readings with the soil moisture obtained using the gravimetric method (R² of 0.92–0.94, RMSE of 0.40–0.52%, and MAE of 0.35–0.39%) demonstrating the successful transfer of the calibration functions to field conditions. Soil moisture data was successfully monitored and transmitted from the nodes to a LoRa gateway via LoRaWAN (433 MHz) and from the gateway to a Raspberry Pi edge server via Wi-Fi. Data was stored both locally in SQLite on the Raspberry Pi and on the InfluxDB cloud. These results suggest that the developed system, when extensively validated under field conditions, can be used to support decision-making for data-driven IoT-based irrigation scheduling. Full article

Climate change and soil degradation pose a challenge to grape quality, motivating the development of integrated monitoring approaches combining soil analysis with remote sensing techniques. However, harmonized information addressing this multidisciplinary challenge remains scarce. Therefore, this systematic review synthesizes the scientific literature published since 2020 with the aim of (i) identifying key soil properties and techniques applied, (ii) evaluating remote sensing approaches and their integration with soil data, and (iii) highlighting knowledge gaps and challenges for sustainable precision viticulture. A search in Scopus yielded 197 full-text articles classified into three thematic groups and analyzed using a standardized extraction protocol. Our synthesis reveals that pH, electrical conductivity, soil organic matter, and cation exchange capacity are the most consistently reported physicochemical parameters across the reviewed studies, while next-generation sequencing and multi-omics approaches are increasingly adopted in microbiological research to characterize rhizosphere communities and their links to terroir expression. In remote sensing, multispectral UAV platforms and satellite missions (Sentinel-2, Landsat) combined with vegetation indices, principally NDVI, dominate the toolset for monitoring vine vigor and water status. Nevertheless, genuine integration of remote-sensing outputs with root-zone soil measurements remains uncommon, with most studies treating both data streams independently. The principal knowledge gaps identified concern the absence of standardized sustainability assessment frameworks, limited cross-terroir transferability of predictive models, and insufficient long-term multi-site datasets to underpin climate change adaptation in vineyard management. Full article

The transition to renewable energy requires scalable and sustainable hydrogen production technologies. Dark fermentation (DF) can generate biohydrogen from diverse biomass feedstock, but its efficiency remains limited. Immobilising anaerobic consortia offers a route to improve performance. This study reports on the immobilisation of whole cells in hybrid biochar–alginate beads (BAB) compared with control alginate beads (CAB) during DF. Biochar from oakwood and water hyacinth, pyrolysed at 450 and 600/650 °C, were incorporated into BAB. BAB increased biohydrogen production rates by 1.4–2.6-fold relative to CAB, driven by enhanced microbial attachment, synergistic interactions, and improved mass transfer. High-temperature biochar generated the strongest effects, raising hydrogen yield by up to 23% and shortening the lag phase by 94%. Biochar properties, including porosity, surface area, inorganic content, electrical conductivity and buffering capacity, likely support these effects. These results establish hybrid biochar-alginate support as a promising platform to accelerate DF and advance biohydrogen as a sustainable biofuel. Full article

Sediment deposition in water diversion channels threatens the operational safety and water supply reliability of large-scale inter-basin water transfer projects. This study investigates the deposition patterns and sediment reduction strategies for the diversion channel of the Shigu Water Source Project, a key intake hub of the Central Yunnan Water Diversion Project on the Jinsha River. A one-dimensional total-load sediment mathematical model (HELIU-2) was used to simulate deposition volume, particle size distribution, and sediment concentration at the pumping station intake under eight design scenarios spanning high-, medium-, and low-sediment years. Results show that over 95% of the deposited sediment in front of the pumping station is finer than 0.05 mm. Dredging reduces the deposition thickness at the pump intake by 13–25% in high-sediment years, significantly enhancing sediment trapping efficiency and reducing both average and maximum sediment concentrations. Longer diversion channels increase total deposition by 9–13% but reduce intake sediment concentration by 2–5% and decrease local deposition thickness by 27–42%, especially in high-sediment years. These findings provide quantitative support for optimizing desilting basin layout, channel length design, and dredging schedules. The proposed modeling framework and mitigation strategies may provide a reference for other large-scale water diversion systems facing similar sedimentation challenges. Full article

The intensification and continuous evolution of dairy sheep and goat farming have played an essential role in the development and implementation of milking equipment. The increasing demand for time-efficient milking procedures, reduced labour costs, sustained milk production, and optimal mammary health have driven the widespread adoption and optimisation of machine milking technologies. The objectives of this article are (i) the review of milking systems and relevant technological developments in milking equipment and (ii) the evaluation and description of their impact on udder health, as applied on dairy small ruminant farms. Milking systems used on farms depend on the available space and number of animals on the farms. Appropriate settings in milking systems are important for ensuring good milk quality; among them, vacuum level, pulsation rate and ratio are important characteristics that must be monitored regularly. Further, use of appropriate teatcups specific to the animal species to be milked is significant. An important aspect of proper maintenance of the milking system is the cleaning procedure after completion of milking. Points for consideration are quality and temperature of the water used for cleaning, use of detergents and disinfectants, and maintenance schedule and teatcup replacement. Some technological features that are part of milking systems include automatic vacuum shut off, electronic milk recording, electronic identification of animals, automatic flushing of milking clusters and automatic pre-stimulators. Farms will benefit from applying precision technologies, which will use data from tools related to animal genetic background, animal behavioural indicators, environmental conditions and disease-related functions for more holistic and cost-effective farm management. In this context, integration of sensor-based technologies in milking systems will be able to provide real-time information regarding quality of milk produced at individual and farm levels. Moreover, the introduction of automatic system flushing in-between animals during the milking procedure can contribute to breaking chains of potential bacterial transfer and reducing animal infections during milking. Overall, although machine milking has certainly contributed to improved efficiency, milk quality and labour conditions, flaws in system function may adversely affect mammary health. Full article

Industrial waste heat recovery is an important approach for improving energy utilization efficiency and reducing environmental impacts. Thermoelectric devices can directly convert waste heat into electricity, but their practical application is limited by relatively low output power. Active water cooling can enhance the power generation performance of thermoelectric devices, but the pumping power may reduce the net output power. In this study, a water-cooling thermoelectric device is investigated under constant heat input conditions using three-dimensional numerical simulations and a semi-analytical prediction model. The effects of cooling water inlet temperature and flow rate on the thermal response, electrical output, heat transfer behavior, and net output power are systematically analyzed. The results show that increasing the cooling water flow rate increases the gross electrical power but also increases pumping power, resulting in an optimal flow rate of approximately 3 m/s to maximize the net output power. At inlet temperatures of 24 °C, 28 °C, and 32 °C, the maximum net output powers are 51.46 W, 49.89 W, and 48.68 W, respectively. A prediction model for cooling water input conditions is further developed based on energy balance and convective heat transfer correlations, and the predicted velocities agree with the numerical results with relative errors below 2%. Full article

Earth-based materials are promising candidates for balancing thermal performance, hygrothermal regulation, and environmental sustainability. The objective of this study is to evaluate and compare the hygrothermal behavior of two earthen materials, structural cob and lightweight insulating earth, against conventional reference concrete, taking into account not only their insulating properties but also their ability to regulate coupled heat and moisture transfers. Experimental tests show a significantly higher hygroscopic buffering capacity for earth-based materials, with an MBV of 2.23 g/(m²∙%RH) for the structural material and 1.21 g/(m²∙%RH) for the insulation material, compared to less than 0.5 g/(m²∙%RH) for concrete. The sorption isotherms confirm distinct water storage behaviors, with an average sensitivity to relative humidity of 10.47% for the insulation material, compared to 3.8% for concrete and 2.25% for the structural material, in addition to an average reduction of 26% in the adsorption capacity between 23 °C and 45 °C for both earthen materials. Coupled heat–moisture simulations in COMSOL quantitatively demonstrate the hygrothermal superiority of bio-based materials over conventional concrete, as concrete promotes interstitial moisture accumulation due to its low vapor permeability. The parametric sensitivity analysis highlights the effect of hygrothermal properties, where diffusivity controls transport kinetics and sorption governs water storage, while thermal conductivity modulates the spatial redistribution of thermo-hygric fields. The next and final step made it possible to link the phenomena observed at the material scale to the actual energy performance of the building, confirming the potential of the double-wall cob + lightweight earth system to reduce heating and cooling requirements and maintain stable indoor comfort, where the annual heating demand is reduced by approximately 24% compared to the conventional prototype. Full article