Search Results (280)

This study presents a comprehensive design, optimization, and intensification approach for enhancing the energy efficiency of electric grade isopropyl alcohol (IPA) production, a typical energy-intensive chemical process. The process entails preconcentration and dehydration steps, with the intensity of separation formulated from a multicomponent feed that consists of IPA and water, along with other impurities. Modeling and energy optimization were performed for a conventional distillation train as a base case by using the rigorous process simulator Aspen Plus V12.1. To improve energy efficiency, various options for intensifying distillation were examined. The side-stream preconcentration column was subsequently replaced by a dividing wall column (DWC) with two side streams, i.e., a Kaibel column, reducing the total energy consumption of corresponding distillation columns by 9.1% compared to the base case. Further strengthening was achieved by combining two columns in the preconcentration process into a single Kaibel column, resulting in a 22.8% reduction in reboiler duty compared to the base case. Optimization using the response surface methodology identified key operating parameters, such as side-draw positions and stage design, which significantly influence both energy efficiency and separation quality. The intensified Kaibel setup offers significant energy efficiencies and simplified column design, suggesting enormous potential for process intensification in energy-intensive distillation processes at the industrial level, including the IPA purification process. Full article

Fresh water is vital for human activities; however, an increase in the contamination of water bodies has been observed, so it is necessary to monitor the degree of contamination and take measures to preserve it. In Altamira, Tamaulipas, the Guayalejo-Tamesí River basin has three estuaries and seven lagoons, including Laguna El Conejo, of which the National Water Commission only monitors one. The objective of this research is to determine water quality on the basis of the parameters COD, BOD₅, T, pH, and sediment characteristics. The open reflux method was used according to NMX-AA-030-SCFI-2012 for COD, BOD Track II, HACH equipment for BOD₅, and the granulometric characterization recommended by the Unified Soil Classification System ASTM D-2487-17. The water was found to be uniformly contaminated throughout its length in the range of 117.3–200 mg/L COD, and BOD₅ ranged from 15.8–112.75 mg/L throughout the study period, with sediments dominated by poorly graded soil and fine clay. Comprehensive management is needed because the BOD₅/COD ratio varies between 0.11and 0.56, indicating that it contains recalcitrant organic matter, which is difficult to biodegrade. Full article

Rizhao Reservoir, Shandong Province, China, as a key regional water supply hub, provides water for domestic, industrial, and agricultural uses in and around Rizhao City by intercepting runoff, which plays a central role in guaranteeing water supply security and supporting regional development. This study systematically collected 66 surface water samples to elucidate the hydrochemical characteristics within the reservoir area, identify the principal influencing factors, and clarify the sources of dissolved ions, aiming to enhance the understanding of the prevailing water quality conditions. A systematic analysis of hydrochemical facies, solute provenance, and governing processes in the study area’s surface water was conducted, employing an integrated mathematical and statistical approach, comprising Piper trilinear diagrams, correlation analysis, and ionic ratios. Meanwhile, the entropy weight-based water quality index (EWQI) and irrigation water quality evaluation methods were employed to assess the surface water quality in the study area quantitatively. Analytical results demonstrate that the surface water system within the study area is classified as freshwater with circumneutral to slightly alkaline properties, predominantly characterized by Ca-HCO₃ and Ca-Mg-SO₄-Cl hydrochemical facies. The evolution of solute composition is principally governed by rock–water interactions, whereas anthropogenic influences and cation exchange processes exert comparatively minor control. Dissolved ions mostly originate from silicate rock weathering, carbonate rock dissolution, and sulfate mineral dissolution processes. Potability assessment via the entropy-weighted water quality index (EWQI) classifies surface waters in the study area as Grade I (Excellent), indicating compliance with drinking water criteria under defined boundary conditions. Irrigation suitability analysis confirms minimal secondary soil salinization risk during controlled agricultural application, with all samples meeting standards for direct irrigation use. Full article

This study explores the optimisation of nozzle design for external twin fluid, single-stage atomisation in handling high-viscosity, shear-thinning polydimethylsiloxane (PDMS). A single PDMS grade was employed and atomised using unheated sonic air and the viscosity was varied by the fluid temperature. A systematic experimental approach was used, varying nozzle geometry—specifically apex angle, gas nozzle diameter, and number of gas nozzles—to identify the optimal nozzle configuration (ONC). The spray qualities of the nozzle configurations were evaluated via high-speed imaging at 75,000 FPS. Shadowgraphy was employed for the optical characterisation of the spray, determining the optimal volumetric air-to-liquid ratio (ALR), a key parameter influencing energy efficiency and operational cost, and for assessing droplet size distributions under varying ALR and viscosity of PDMS. The ONC yielded a Sauter mean diameter $d_{32}$ of 570 × 10⁻⁶$\mathrm{m}$, at an ALR of 8532 and a zero-shear viscosity of 15.9 $\mathrm{Pa}$ $\mathrm{s}$. The results are relevant for researchers and engineers developing twin fluid atomisation systems for challenging industrial fluids with similar physical properties, such as those in wastewater treatment and coal–water slurry atomisation (CWS). This study provides design guidelines for external twin fluid atomisers to enhance atomisation efficiency under such conditions. Full article

The selection of process parameters for an ultra-high-pressure water jet directly affects the adhesion ability of the subsequent coating on the ship’s surface. This study investigates the effect of jet pressure, standoff distance, and nozzle traverse speed on the surface roughness of grade-A marine steel, aiming to optimize the process parameters and improve the quality of surface treatment. Based on single-factor experiments and orthogonal experiments, a three-factor, three-level experimental design was employed, considering jet pressure, standoff distance, and nozzle traverse speed. Scanning electron microscopy (SEM) and a confocal microscope were used to analyze the surface morphology and roughness of grade-A marine steel. The experimental results proved that surface roughness exhibited a nonlinear relationship with jet pressure, initially increasing and then decreasing as pressure rose. Conversely, surface roughness showed negative correlations with both standoff distance and nozzle traverse speed, progressively decreasing with increases in these parameters. Through hierarchical analysis, the effect hierarchy of the three factors on surface roughness was determined as follows: jet pressure > standoff distance > nozzle traverse speed. Parametric optimization revealed that a jet pressure of 150 MPa, a standoff distance of 25 mm, and a nozzle traverse speed of 180 mm/min collectively yielded a peak surface roughness of 62.549 μm. This value aligns with the pre-coating surface preparation standards for grade-A marine steel substrates, ensuring optimal adhesion for subsequent anti-corrosion treatments. Full article

Conducting ecological restoration has emerged as a critical governance strategy for enhancing ecosystem diversity, stability, and sustainability. The scientific identification of priority restoration areas is a prerequisite for effective ecological restoration projects. Current research on identifying priority restoration zones predominantly relies on administrative-scale frameworks, and the reliability and scientificity of the identified results are somewhat insufficient. To address this gap, this study selected Dali Prefecture in Yunnan Province, a region characterized by dense river networks, as the research area to identify the priority areas of ecological restoration. In view of the application of the InVest model in watershed-scale restoration, biodiversity assessment, and other fields, we utilize sub-watershed units and the InVEST model, and five key ecosystem services—water conservation, water purification (N/P), habitat quality, climate regulation, and soil retention—were quantified. Temporal changes in these services from 2015 to 2020 were analyzed alongside ecological risk assessments and restoration zoning. Priority areas were further identified through Ordered Weighted Averaging (OWA) operators under varying decision-making preferences. The optimal threshold for watershed delineation was determined as 11.04 km², resulting in 1513 refined sub-watershed units after correction, with 71.59% concentrated in the 10–50 km² range. A spatial analysis revealed an east-to-west gradient in ecosystem service distribution, where eastern regions consistently exhibited lower values compared to central and western areas. From 2015 to 2020, soil retention per unit area increased by 5.09%, while water purification for N and P showed marginal improvements of 0.97% and 0.39%, respectively. Conversely, water conservation declined significantly by 10.00%, with carbon sequestration and biodiversity protection experiencing slight reductions of 1.74% and 1.92%, all within a 2% variation margin. Ecological risk zoning identified low-risk areas (grades 1–3) predominantly in western and northeastern Dali, encompassing 1094 sub-watersheds (77.36% by count and 73.92% by area), while high-risk zones (grades 4–5) covered 386 units (26.08% by area). Integrating ecological quality and risk levels, the study area was classified into four functional zones: Zone I (high quality, high risk), Zone II (low quality, high risk), Zone III (low quality, low risk), and Zone IV (high quality, low risk). With increasing risk tolerance, the priority restoration areas expanded from eastward to central regions. Based on the scenario simulations under ecological priority, status quo, and development-oriented policies, the critical restoration areas include the Sangyuan River Basin, mid-reach of the Juli River, and upper Miyu River. This methodology provides a theoretical and technical foundation for ecosystem service enhancement and degraded ecosystem rehabilitation in Dali Prefecture and similar regions. Full article

This study develops a value-added processing technique for grade-out cape gooseberry (Physalis peruviana Linn.) by applying mild hydrostatic osmotic pretreatment combined with rotary tray drying. Fruits classified as grade-out, often discarded due to aesthetic flaws, were subjected to osmotic treatment at 0.5 bar for 12 h using a sucrose solution enhanced with citric acid and glycerin. Pretreatment significantly elevated water loss (52.61%) and solid gain (18.12%), reducing moisture content prior to drying. Rotary tray drying was conducted at temperatures of 50, 60, and 70 °C. Drying at 60 °C achieved the ideal balance between efficiency and product quality. Samples pretreated and dried at 60 °C exhibited a 35% reduction in drying time while preserving superior color (ΔE = 13.54 ± 1.81), vitamin C (71.76 ± 2.57 mg/100 g dry matter, DM), total phenolic content (202.9 ± 10.91 mg GAE/100 g DM), and antioxidant activity (ABTS = 95.87 ± 3.41 µmol TE/g DM; DPPH = 89.97 ± 1.27 µmol TE/g DM). A production trial was conducted using 1500 kg of raw material from the Mae Hae Royal Project Development Center in Chiang Mai, Thailand. This process yielded 220 kg of high-quality dried fruit at an overall cost of USD 6.93 per kg. Local farmers successfully applied this technique, demonstrating its potential to enhance livelihoods, avoid postharvest losses, and valorize low-quality produce in line with Sustainable Development Goal 12. This supports the Royal Project Foundation’s vision for sustainable agriculture. Full article

Microbial detection in milk is crucial for food safety and quality, as beneficial and harmful microorganisms can affect consumer health and dairy product integrity. Identifying and quantifying these microorganisms helps prevent contamination and spoilage. The study employs advanced molecular techniques to detect and quantify the genomic DNA for the target hydrolytic enzyme coding genes lipA and aprX based on the multi-align sequence conserved region, specific primer pair, and hydrolysis probes designed using the singleplex qPCR and multiplex qPCR. Cultured isolates and artificially contaminated sterilized ultra-high-temperature (UHT) milk were analyzed for their specificity, cross-reactivity, and sensitivity. The finding indicated that strains with lipA and aprX genes were amplified while the other strains were not amplified. This indicated that the designed primer pairs/probes were very specific to the target gene of interest. The specificity of each design primer pair was checked using SYBR Green qPCR using 16 different isolate strains from the milk sample. The quantification specificity of each strain target gene was deemed to be with a mean Ct value for positive pseudomonas strain > 16.98 ± 1.76 (p < 0.0001), non-pseudomonas positive strain ≥ 27.47 ± 1.25 (p < 0.0001), no Ct for the negative control and molecular grade water. The sensitivity limit of detection (LOD) analyzed based on culture broth and milk sample was >10⁵ and >10⁴ in PCR amplification while it was >10⁴ and >10³ in real-time qPCR, respectively. At the same time, the correlation regression coefficient of the standard curve based on the pure culture cell DNA as the DNA concentration serially diluted (20 ng/µL to 0.0002 ng/µL) was obtained in multiplex without interference and cross-reactivity, yielding R² ≥ 0.9908 slope (−3.2591) and intercepting with a value of 37, where the efficiency reached the level of 95–102% sensitivity reached up to 0.0002 ng/µL concentration of DNA, and sensitivity of microbial load was up to 1.2 × 10² CFU/mL. Therefore, multiplex TaqMan qPCR simultaneous amplification was considered the best method developed for the detection of the lipA and aprX genes in a single tube. This will result in developing future simultaneous (three- to four-gene) detection of spoilage psychrotrophic bacteria in raw milk. Full article

Energy-efficient and cost-effective water desalination systems can significantly replenish freshwater reserves without further stressing limited energy resources. Currently, the majority of the desalination systems are operated by non-renewable energy sources such as fossil fuel power plants. The viability of any desalination process depends primarily on the type and amount of energy it utilizes and on the product recovery. In recent years, membrane distillation (MD) and forward osmosis (FO) have drawn the attention of the scientific community because of FO’s low energy demand and the potential of MD operation with low-grade heat or a renewable source like geothermal, wind, or solar energy. Despite the numerous potential advantages of MD and FO, there are still some limitations that negatively affect their performance associated with the water–energy nexus. This critical review focuses on the hybrid forward osmosis–membrane distillation (FO-MD) processes, emphasizing energy demand and product quality. It starts with exploring the limitations of MD and FO as standalone processes and their performance. Based on this, the importance of combining these technologies into an FO-MD hybrid process and the resulting strengths of it will be demonstrated. The promising applications of this hybrid process and their advantages will be also explored. Furthermore, the performance of FO-MD processes will be compared with other hybrid processes like FO–nanofiltration (FO-NF) and FO–reverse osmosis (FO-RO). It will be outlined how the FO-MD hybrid process could outperform other hybrid processes when utilizing a low-grade heat source. In conclusion, it will be shown that the FO-MD hybrid process can offer a sustainable solution to address water scarcity and efficiently manage the water–energy nexus. Full article

Experiences in the production, transportation and preparation of crude oil for transportation have shown that specific problems arise related to their mixing, including water contamination. In recent years, interest in studying these problems has significantly increased, mainly due to the development of extraction technologies for heavy oil samples and bitumen. Along with various difficulties encountered during the pipeline transportation of complex rheological crude oil blended with each other and with light oil, including condensate (such as sedimentation, etc.), imbalances are also observed during storage, as well as in the processes of delivery and reception. During the dehydration of oil mixtures, a synergistic effect is observed in the consumption of demulsifier. The article investigates, in accordance with international standards and based on laboratory tests, how the physico-chemical properties (density, viscosity, freezing point, saturated vapor pressure, chemical composition) of mixtures formed by blending various grades and compositions of Azerbaijani oil examples with each other and with condensate change and how the efficiency of dehydration of oil mixtures is affected by the mixing ratio of the oil involved. It was found that the quality indicators (physico-chemical parameters) of oil mixtures differ non-additively from the initial parameters of the blended products and in some cases, this difference is even observed with anomalies. Moreover, depending on the mixing ratio of the oil, variations in the consumption of demulsifier were also identified. Full article

Habitat suitability assessment for forest and grassland ecosystems is a critical component of ecological restoration and land use planning in the Loess Plateau, aiming to advance soil and water conservation and foster sustainable ecological environment development. Despite progress in vegetation restoration, systematic evaluations of habitat suitability in complex geomorphic regions like the Loess Plateau remain scarce, particularly in balancing hydrological and ecological trade-offs. The Yanhe River Basin (7725 km²), a sediment-prone tributary of the Yellow River, exemplifies the challenges of soil erosion and semi-arid climatic constraints, making it a critical case for evaluating restoration strategies. This study employed a comprehensive approach utilizing Analytic Hierarchy Process (AHP), Geographic Detector, mathematical statistics, and other methods. An evaluation indicator system and methodology were established to assess the suitability of forest and grassland habitats in the Yanhe River Basin, evaluating the suitability and quality improvement potential under the current land use conditions. The results indicate: (1) The dominant factors influencing the suitable distribution of forests include photosynthetically active radiation (PAR), soil total phosphorus content, annual precipitation, and elevation. For grasslands, the dominant factors include photosynthetically active radiation, annual average temperature, elevation, and annual precipitation. (2) In the watershed, forestland and grassland areas classified as moderately suitable or higher cover 1064.9 km² and 4196.9 km², accounting for 91.9% and 94.7% of their total respective areas, indicating a generally rational spatial allocation of forest and grassland ecosystems. (3) The improvable area for forests measures 366 km² (34.4% of moderately or higher suitability zones), with most already meeting coverage thresholds. In contrast, grasslands have an improvable area of 2491.6 km² (59.4% of moderately or higher suitability zones), where over half of the area remains below coverage thresholds corresponding to their habitat conditions. (4) Forests can adopt natural restoration-focused low-intensity interventions through strengthened closure management, while grasslands require spatially tailored measures—such as precipitation interception and enhanced stewardship—targeting suitability-based potential grades, collectively achieving overall improvement in grassland vegetation coverage. This study represents the first systematic evaluation of forest–grassland habitat suitability in the Yanhe River Basin, elucidating its spatial distribution patterns and providing critical insights for watershed-scale ecological restoration. Full article

This study investigated the beneficial effects of individual and co-inoculation with Lactobacillus delbrueckii subsp. lactis N102 and Lactobacillus sakei H1-5 on improving safety parameters, sensory characteristics, and non-volatile metabolite profiles in dry-fermented sausages. Comprehensive analyses were conducted throughout the 20-day maturation period (0, 6, 13, 16, and 20 days), including physicochemical monitoring (moisture content, malondialdehyde (MDA) levels, biogenic amine concentrations, and sodium nitrite residues); sensory evaluation (color parameters and textural properties); and ¹H NMR-based metabolomic profiling. Key findings revealed strain-specific advantages: the N102 inoculation significantly delayed lipid oxidation, achieving the lowest final MDA concentration (4.5 mg/kg) among all groups. Meanwhile, H1-5 supplementation notably improved color attributes (a*/b* ratio = 1.34). The co-inoculation strategy demonstrated synergistic effects through (1) accelerated acidification (pH 5.3 by day 6); (2) enhanced textural properties (significantly increased hardness and elasticity vs. control); (3) optimized water distribution (free water reduced to 0.56% with 64.73% immobilized water); and (4) a significant reduction in sodium nitrite residues (70% decrease) and complete elimination of phenylethylamine (total biogenic amines: 702.94 mg/kg). ¹H NMR metabolomics identified 30 non-volatile metabolites, and the co-inoculation significantly increased the amount of essential amino acids (leucine, isoleucine), flavor-related compounds (glutamic acid, succinic acid), and bioactive substances (gooseberry, creatine). These metabolites enhanced antioxidant capacity, freshness, and nutritional value. Our findings demonstrate that strategic co-cultivation of food-grade lactobacilli can synergistically enhance both the techno-functional properties and biochemical composition of fermented meat products, providing a viable approach for quality optimization in industrial applications. Full article

Maintaining or improving habitat quality is essential for conserving biodiversity and ensuring the long-term survival of species. Nevertheless, increasing global warming and intensifying human activities have led to varying degrees of habitat degradation and biodiversity loss, especially in semi-arid regions. Focusing on China’s West Songnen Plain—the nation’s largest saline-alkali region confronting acute environmental challenges—this study introduced the soil salinization level and mean NDVI of farmland during the growing season as dynamic threat factors and systematically explored the spatiotemporal dynamic characteristics of habitat quality in the semiarid area of the West Songnen Plain from 1990 to 2020. The results showed the following: (1) Habitat quality exhibited a continuous decline during the study period, following a “degradation–recovery” trajectory with deterioration peaking in 2010; the low- and poor-quality habitats predominantly distributed in the central areas characterized by severe salinization, interspersed with patches of good-quality habitat. (2) The degradation of habitat quality was mainly concentrated in natural land cover types, whereas improvements were observed locally in farmland and bare land. However, slight opposite trends were detected between the mean habitat quality values and the habitat change areas in forests, waters, and bare land. As the elevation continuously increased, the habitat quality grade shifted towards better conditions. (3) A spatial autocorrelation analysis revealed a significant clustering of habitat quality, but the extent of hot spots and cold spots gradually shrank as grassland degradation and saline land management progressed. By incorporating dynamic threat factors and integrating multi-source data, this study improved the habitat quality assessment framework for semi-arid regions and provided scientific support for spatially stratified conservation strategies. Full article

In citriculture, inputs like water and fertilizer are applied through traditional basin methods, thereby incurring reduced use-efficiency. The response of conventional crop coefficient-based fertigation scheduling continues to be inconsistent and complex in its field implementation, thereby necessitating the intervention of sensor-based (Internet of Things; IoT) technology for fertigation scheduling on a real-time basis. The study aimed to investigate fertigation scheduling involving four levels of irrigation, viz., I₁ (100% evapotranspiration (ET) as the conventional practice), I₂ (15% volumetric moisture content (VMC)), I₃ (20% VMC), and I₄ (25% VMC), as the main treatments and three levels of recommended doses of fertigation, achieved by reappropriating different nutrients across phenologically defined critical growth stages, viz., F₁, F₂, and F₃ (conventional fertilization practice), as sub-treatments, which were evaluated through a split-plot design over two harvesting seasons in 2021–2023. Nagpur mandarin (Citrus reticulata Blanco) was used as the test crop, which was raised on Indian Vertisol facing multiple nutrient constraints. Maximum values for physiological growth parameters (plant height, canopy area, canopy volume, and relative leaf water content (RLWC)) and fruit yield (characterized by 9% and 5%, respectively, higher A-grade-sized fruits with the I₄ and F₁ treatments over corresponding conventional practices, viz., I₁ and F₃) were observed with the I₄ irrigation treatment in combination with the F₁ fertilizer treatment (I₄F₁). Likewise, fruit quality parameters, viz., juice content, TSS, TSS: acid ratio, and fruit diameter, registered significantly higher with the I₄F₁ treatment, featuring the application of B at the new-leaf initiation stage (NLI) and Zn across the crop development (CD), color break (CB), and crop harvesting (CH) growth stages, which resulted in a higher leaf nutrient composition. Treatment I₄F₁ conserved 20–30% more water and 65–87% more nutrients than the I₁F₃ treatment (conventional practice) by reducing the rate of evaporation loss of water, thereby elevating the plant’s available nutrient supply within the root zone. Our study suggests that I₄F₁ is the best combination of sensor-based (IoT) irrigation and fertilization for optimizing the quality production of Nagpur mandarin, ensuring higher water productivity (WP) and nutrient-use-efficiency (NUE) coupled with the improved nutritional quality of the fruit. Full article

Over the past years, we experienced more extreme weather conditions during the growing season, April till October, with prolonged droughts. Rain-fed production of high-quality forest trees was possible, but recent droughts proved to have an economic impact on the plant quality. Therefore, the hardy nursery sector demands irrigation thresholds and suitable tools including soil and plant sensors to schedule irrigation based on crop water demand. Two trials were conducted with Acer pseudoplatanus liners (1 + 0) grown in a sandy soil in 2022 and 2023 at Viaverda (Destelbergen, Belgium). A rain-fed treatment was compared with a sprinkler irrigation treatment in both trials. Irrigation doses were evaluated with a soil water balance model, which is based on reference crop evapotranspiration (ET₀), rainfall, and soil hydraulic properties. The soil water balance model was calibrated based on the measurements of soil sensors and soil samples. Simultaneously, stem water potential at solar noon, tree length, and growth were measured. The irrigation treatment had a positive effect on the stem water potential of Acer in both trials with a less negative value, ±0.7 MPa, compared to the rain-fed treatment. Irrigation increased growth with 28.4% in 2022 and 5.8% in 2023 compared to the rain-fed treatment, resulting in trees of higher commercial quality that could even be classified into a superior grading range in 2022. Full article