Search Results (1,884)

To address the central cracking problem in continuous casting slabs of 38CrMoAl steel, high-temperature tensile tests were performed using a Gleeble-3800 thermal simulator to characterize the hot ductility of the steel within the temperature range of 600–1200 °C. The phase transformation behavior was computationally analyzed via the Thermo-Calc software, while the microstructure, fracture morphology, and precipitate characteristics were systematically investigated using a metallographic microscope (MM), a field-emission scanning electron microscope (FE-SEM), and transmission electron microscopy (TEM). Additionally, the effects of different holding times and cooling rates on the microstructure and precipitates of 38CrMoAl steel were also studied. The results show that the third brittle temperature region of 38CrMoAl steel is 645–1009 °C, and the fracture mechanisms can be classified into three types: (I) in the α single-phase region, the thickness of intergranular proeutectoid ferrite increases with rising temperature, leading to reduced hot ductility; (II) in the γ single-phase region, the average size of precipitates increases while the number density decreases with increasing temperature, thereby improving hot ductility; and (III) in the α + γ two-phase region, the precipitation of proeutectoid ferrite promotes crack propagation and the dense distribution of precipitates at grain boundaries causes stress concentration, further deteriorating hot ductility. Heat treatment experiments indicate that the microstructures of the specimen transformed under water cooling, air cooling, and furnace cooling conditions as follows: martensite + proeutectoid ferrite → bainite + ferrite → ferrite. The average size of precipitates first decreased, then increased, and finally decreased again with increasing holding time, while the number density exhibited the opposite trend. Therefore, when the holding time was the same, reducing the cooling rate could increase the average size of the precipitates and decrease their number density, thereby improving the hot ductility of 38CrMoAl steel. Full article

In light of the environmental impact of disposable products made from petroleum-based plastics, this study focused on developing biodegradable foam trays made from a starch (PS) derived from potato waste and beer malt flour (BMBF). The objective of this study was to evaluate the effect of the concentration of BMBF on the physical and mechanical properties of potato starch-based foam trays prepared by the thermoforming process at temperatures of 150 °C (upper plate) and 145 °C (lower plate) for 5 min and 40 s. The results showed that increasing the BMBF concentration from 0 to 40% reduced the moisture content from 4.68% to 3.42%, increased the thickness from 2.63 cm to 4.77 cm, and decreased the density from 0.28 g.cm⁻³ to 0.15 g.cm⁻³. Meanwhile, the water absorption capacity increased from 38.7% to 69.7%. In terms of mechanical properties, increasing the BMBF concentration in the PS foam tray resulted in a decrease in hardness from 5.61 N to 2.87 N, a decrease in tensile strength from 2.92 MPa to 0.85 MPa, and a decrease in elongation from 1.42% to 0.59%. Meanwhile, fracturability increased from 2.04 mm to 3.68 mm. FTIR analysis revealed interactions between BMBF and PS in the composite foam tray. Thermogravimetric analysis (TGA) showed two thermal events: one between 20.96 °C and 172.89 °C, and another between 189.14 °C and 517.69 °C, with weight losses of 5.53% and 74.23%, leaving an ash residue of 20.24%. Differential calorimetry analysis (DSC) showed a glass transition at 152.88 °C and a melting at 185.94 °C, with an enthalpy of fusion of 74.11 J.g⁻¹. Higher concentrations of BMBF (>10%) decreased the water resistance, mechanical strength, and flexibility of the PS foam trays. Therefore, a formulation of 90% PS and 10% BMBF was better for producing a foam tray with improved mechanical properties and water resistance, which could be used as a sustainable alternative to conventional single-use plastic. Full article

Natural hydrogen is generated by fairly deep processes and/or in low-permeability rocks. In such contexts, fluids circulate mainly through the network of faults and fractures. However, hydrogen flows from these hydrogen-generating layers can reach sedimentary rocks with more typical permeability and porosity, allowing H₂ flows to spread out rather than be concentrated in fractures. In that case, three different H₂ transport modes exist: advection (displacement of water carrying dissolved gas), diffusion, and free gas Darcy flow. Numerical models have been run to compare the efficiency of these different modes and the pathway they imply for the H₂ in a sedimentary basin with active aquifers. The results show the key roles of these aquifers but also the competition between free gas flow and the dissolved gas displacement which can go in opposite directions. Even with a conservative hypothesis on the H₂ charge, a gaseous phase exists at few kilometers deep as well as free gas accumulation. Gaseous phase displacement could be the faster and diffusion is neglectable. The modeling also allows us to predict where H₂ is expected in the soil: in fault zones, eventually above accumulations, and, more likely, due to exsolution, above shallow aquifers. Full article

Deep coalbed methane (CBM) reservoirs are characterized by high hydrocarbon content and are considered an important strategic resource. Due to their inherently low permeability and porosity, horizontal well drilling is commonly employed to enhance production, with the length of the horizontal section playing a critical role in determining CBM output. However, during extended horizontal drilling, wellbore instability frequently occurs as a result of drilling fluid invasion into the coal formation, posing significant safety challenges. This instability is primarily caused by the physical intrusion of drilling fluids and their interactions with the coal seam, which alter the mechanical integrity of the formation. To address these challenges, interpenetrating and semi-interpenetrating network (IPN/s-IPN) hydrogels have gained attention due to their superior physicochemical properties. This material offers enhanced sealing and support performance across fracture widths ranging from micrometers to millimeters, making it especially suited for plugging applications in deep CBM reservoirs. A self-degradable interpenetrating double-network hydrogel particle plugging agent (SSG) was developed in this study, using polyacrylamide (PAM) as the primary network and an ionic polymer as the secondary network. The SSG demonstrated excellent thermal stability, remaining intact for at least 40 h in simulated formation water at 120 °C with a degradation rate as high as 90.8%, thereby minimizing potential damage to the reservoir. After thermal aging at 120 °C, the SSG maintained strong plugging performance and favorable viscoelastic properties. A drilling fluid containing 2% SSG achieved an invasion depth of only 2.85 cm in an 80–100 mesh sand bed. The linear viscoelastic region (LVR) ranged from 0.1% to 0.98%, and the elastic modulus reached 2100 Pa, indicating robust mechanical support and deformation resistance. Full article

Traditional hydrogel preparation methods typically require multiple steps and certain external stimuli. In this study, rapid and stable gelation of polyvinyl alcohol (PVA)-tannic acid (TA)-based hydrogels was achieved through the regulation of hydrogen bonds. The cross-linking between PVA and TA is triggered by the evaporation of ethanol. Rheological testing and analysis of the liquid-solid transformation process of the hydrogel were performed. The gelation onset time (GOT) could be tuned from 10 s to over 100 s by adjusting the ethanol content and temperature. The addition of polyhydroxyl components (e.g., glycerol) significantly enhances the hydrogel’s water retention capacity (by 858%) and tensile strain rate (by 723%), while concurrently increasing the gelation time. Further studies have shown that the addition of alkaline substances (such as sodium hydroxide) promotes the entanglement of PVA molecular chains, increasing the tensile strength by 23% and the fracture strain by 41.8%. The experimental results indicate that the optimized PVA-TA hydrogels exhibit a high tensile strength (>2 MPa) and excellent tensile properties (~600%). Moreover, the addition of an excess of weakly alkaline substances (such as sodium acetate) reduces the degree of hydrolysis of PVA, enabling the system to form a hydrogel with extrudable characteristics before the ethanol has completely evaporated. This property allows for patterned printing and thus demonstrates the potential of the hydrogel in 3D printing. Overall, this study provides new insights for the application of PVA-TA based hydrogels in the fields of rapid prototyping and strength optimization. Full article

After the 2011 earthquake, lake water depletion has become a widespread issue in Sikkim, especially in regions classified as high to very high seismic zones, where many lakes have turned into seasonal water bodies. This study investigates Chochen Lake in the Barapathing area of Sikkim’s Pakyong district, which is facing severe water seepage and instability. The problem, intensified by the 2011 seismic event and ongoing local construction, is examined through subsurface fracture mapping using Vertical Electrical Sounding (VES) and profiling techniques. A statistical factor method, applied to interpret VES data, helped identify fracture patterns beneath the lake. Results from two sites (VES-1 and VES-2) reveal significant variations in weathered and semi-weathered soil layers, indicating fractures at depths of 17–50 m (VES-1) and 20–55 m (VES-2). Higher fracture density near VES-1 suggests increased settlement risk and ground displacement compared to VES-2. Contrasting resistivity values emphasize the greater instability in this zone and the need for cautious construction practices. The findings highlight the role of seismic-induced fractures in ongoing water depletion and underscore the importance of continuous dewatering to stabilize the swampy terrain. Full article

As a pivotal clean energy source with considerable reserves, geothermal water plays an indispensable role in diminishing reliance on fossil fuels and accomplishing carbon neutrality. This study employed conventional electrical prospecting and radon gas surveys in the Lantian area of Ningdu, aimed at curtailing geothermal development costs by precise targeting of resource locations. The investigations successfully delineated fracture structures within the Lantian region. Distinct anomalies were identified in the electrical profiling along Survey Lines 1, 2, and 4, with the most pronounced features observed on Line 4. Accordingly, characteristic peak anomalies were exhibited by the radon gas measurement profiles S1, S2, and S4 corresponding to Lines 1, 2, and 4, respectively. The synergistic interpretation of resistivity and radon survey data recognized two primary fracture zones: the NE-trending zone F1 and the NEE-trending zone F2. This integrated approach not only ascertained the efficacy of the radon gas measurement, but also lays a robust basis for future geothermal water exploration targeting. Full article

Three-dimensional printing is commonly used to fabricate provisional dental restorations. Studies have reported that changes in printing orientation affect the physical and mechanical properties of 3D-printed polymeric provisional restorations; however the findings have been inconsistent. Therefore, this systematic review and meta-analysis aims to analyze the articles evaluating the influence of printing orientation on the physical and mechanical properties of 3D-printed polymeric provisional dental restorations. Recommendations provided by the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines were followed to structure and compose the review. The PICO (Participant, Intervention, Comparison, Outcome) question ordered was: ‘Do 3D-printed provisional dental restorations (P) printed at various orientations (except 0°) (I) exhibit similar physical and mechanical properties (O) when compared to those printed at a 0° orientation (C)?’. An electronic search was conducted on 28 and 29 April 2025, by two independent researchers across four databases (MEDLINE/PubMed, Scopus, Cochrane Library, and Web of Science) to systematically collect relevant articles published up to March 2025. After removing duplicate articles and applying predefined inclusion and exclusion criteria, twenty-one articles were incorporated into this review. Self-designed Performa’s were used to tabulate all relevant information. For the quality analysis, the modified CONSORT scale was utilized. The quantitative analysis was performed on only fifteen out of twenty-one articles. It can be concluded that the printing orientation affects some of the tested properties, which include fracture strength (significantly higher for specimens printed at 0° when compared to 90°), wear resistance (significantly higher for specimens printed at 90° when compared to 0°), microhardness (significantly higher for specimens printed at 90°and 45° when compared to 0°), color stability (high at 0°), and surface roughness (significantly higher for specimens printed at 45° and 90° when compared to 0°). There were varied outcomes in terms of flexural strength and elastic modulus. Full article

To study hydrogeological characteristics after the occurrence of abnormal water bursts from the weak water-rich (permeable) aquifer of the Changxing Formation limestone overlying deep working faces during production in Guizhou karst landform mining areas, hydrogeological data covering the exploration and production periods of the Xinhua mining region in Jinsha County, Guizhou Province, were collected. On the basis of surface and underground drilling, geophysical exploration techniques, empirical equations, and indoor material simulation methods, the hydrogeological evolution characteristics of the Changxing Formation limestone in the mining region after mining damage to coalbed 9 were studied. The research results indicated that the ratio of the height of the roof failure fracture zone (as obtained via numerical simulation and ground borehole detection) to the mining height exceeded 25.78, which is far greater than the empirical model calculation values (from 13.0 to 15.8). After mining the underlying coalbed 9, an abnormal water-rich area developed in the Changxing Formation limestone, and mining damage fractures led to the connection of the original dissolution fissures and karst caves within the limestone, resulting in the weak water-rich (permeable) aquifer of the Changxing Formation limestone becoming a strong water-rich (permeable) aquifer, which served as the water source for mine water bursts. Over time, after mining damage occurrence, the voids in the Changxing Formation limestone were gradually filled with various substances, yielding water storage space and connectivity decreases. The specific yield decreased with an increasing water burst time and interval after the cessation of mining in the supply area, and the correlation coefficient R was 0.964, indicating a high degree of correlation between the two parameters. Full article

Roadway deformation failure is often related to the presence of weak structural planes (WSPs) in the surrounding rock mass. Especially in coastal mining environments, WSP-induced deformation can create pathways that connect faults with seawater, accelerating groundwater seepage and inrush hazards. This study employs an optimized Finite–Discrete Element Method (Y-Mat) to simulate WSP-driven fracture evolution, introducing an elastoplastic failure criterion and enhanced contact force calculations. The results show that the farther the WSP is from the roadway, the lower its influence; its existence alters the shape of the plastic zone by lengthening the failure zone along the fault direction, while its angle changes the shape and location of the failure zone and deflects fracture directions, with the surrounding rock between the roadway and WSP suffering the most severe failure. The deformation failure of roadway surrounding rock is influenced by WSPs. Excavation unloading reduces the normal stress and shear strength in the weak structural plane of surrounding rock, resulting in slip and deformation. Additionally, WSP-induced fractures act as groundwater influx conduits, especially in fault-proximal roadways or where crack angles align with hydraulic gradients, so mitigation in water-rich mining environments should prioritize sealing these pathways. The results provide a theoretical basis for roadway excavation and support engineering under the influence of WSPs. Full article

Channeling in cementing causes interlayer interference, severely restricting oilfield recovery. Existing channeling plugging agents, such as cement and gels, often lead to reservoir damage or insufficient strength. Oil-soluble resin (OSR) particles show great potential in selective plugging of channeling fractures due to their excellent oil solubility, temperature/salt resistance, and high strength. However, their application is limited by the efficient filling and retention in deep fractures. This study innovatively combines the OSR particle plugging system with the mature rapid filtration loss plugging mechanism in drilling, systematically exploring the influence of particle size and sorting on their filtration, packing behavior, and plugging performance in channeling fractures. Through API filtration tests, visual fracture models, and high-temperature/high-pressure (100 °C, salinity 3.0 × 10⁵ mg/L) core flow experiments, it was found that well-sorted large particles preferentially bridge in fractures to form a high-porosity filter cake, enabling rapid water filtration from the resin plugging agent. This promotes efficient accumulation of OSR particles to form a long filter cake slug with a water content <20% while minimizing the invasion of fine particles into matrix pores. The slug thermally coalesces and solidifies into an integral body at reservoir temperature, achieving a plugging strength of 5–6 MPa for fractures. In contrast, poorly sorted particles or undersized particles form filter cakes with low porosity, resulting in slow water filtration, high water content (>50%) in the filter cake, insufficient fracture filling, and significantly reduced plugging strength (<1 MPa). Finally, a double-slug strategy is adopted: small-sized OSR for temporary plugging of the oil layer injection face combined with well-sorted large-sized OSR for main plugging of channeling fractures. This strategy achieves fluid diversion under low injection pressure (0.9 MPa), effectively protects reservoir permeability (recovery rate > 95% after backflow), and establishes high-strength selective plugging. This study clarifies the core role of particle size and sorting in regulating the OSR plugging effect based on rapid filtration loss, providing key insights for developing low-damage, high-performance channeling plugging agents and scientific gradation of particle-based plugging agents. Full article

In petroleum exploration and production, lost circulation not only significantly increases exploration and development costs and operational cycles but may also lead to major incidents such as wellbore instability or even project abandonment. This paper constructs a polymer gel plugging system by optimizing high-molecular-weight polymers, crosslinker systems, and resin hardeners. The optimized system composition was determined as 1% polymer J-1, 0.3% catechol, 0.6% hexamethylenetetramine (HMTA), and 15% urea–formaldehyde resin. Experimental studies demonstrated that during the initial stage (0–3 days) at 120 °C, the optimized gel system maintained a storage modulus (G′) of 17.5 Pa and a loss modulus (G″) of 4.3 Pa. When the aging period was extended to 9 days, G′ and G″ decreased to 16 Pa and 4 Pa, respectively. The insignificant reduction in gel strength indicates excellent thermal stability of the gel system. The gel exhibited superior self-filling capacity during migration, enabling complete filling of fractures of varying sizes. After aging for 1 day at 120 °C, the plugging capacity of the gel system under water flooding and gas flooding conditions was 166 kPa/m and 122 kPa/m, respectively. Furthermore, a complete gel barrier layer formed within a 6 mm wide vertical fracture, demonstrating a pressure-bearing capacity of 105.6 kPa. This system shows good effectiveness for wellbore isolation and fracture plugging. The polymer gel plugging system studied in this paper can simplify lost circulation treatment procedures while enhancing plugging strength, providing theoretical support and technical solutions for addressing lost circulation challenges. Full article

Underground pumped storage hydropower stations (UPSH) are of great significance for energy structure adjustment, and coal mine underground reservoirs are an integral part of UPSH. This study investigates the fracture mechanics behavior of coal in mine water immersion environments with varying loading rates and layer direction. Three types of samples were analyzed: Crack-arrester, Crack-splitter, and Crack-divider types. The immersion duration extended up to 120 days. The results indicate that, after immersion in mine water for 120 days, the fracture toughness (K_IC), fracture modulus (E_S), and absorbed energy (U_T) of coal decreased by 60.87%, 53.38%, and 63.21%, respectively, compared to the unsaturated coal samples. An immersion period of 30 days significantly weakens the mechanical properties of coal fractures. The K_IC, E_S, and U_T of coal demonstrate a positive correlation with loading rate, primarily influenced by the duration of coal damage. At the same loading rate, the order of fracture toughness among the three coal types is as follows: Crack-divider > Crack-arrester > Crack-splitter. This hierarchy is determined by the properties of the coal matrix and bedding planes, as well as the mechanical structures composed of them. This study holds significant implications for the safe construction and operational design of underground water reservoirs in coal mines. Full article

Water source identification and dynamic assessment are critical for mining safety, particularly in mines governed by complex geological structures. The hydrochemical mixing model demonstrates a natural advantage for early warning of water intrusion compared to geophysical monitoring techniques. This study discusses core issues related to the mixing model, including the conceptual framework, selection of end-members, and choice of tracers, and formulates principles for general applicability. In this study, three sources were identified using the conceptual model and hydrochemical analysis: water in F7 (main fault), shallow fracture water, and river water. A correlation analysis and variability analysis were applied to determine the tracers, and the ¹⁸O, D, Cl, B, and Li were determined. The end-members of the three sources are time-dependent in July and September, especially the shallow fracture water’s end-members. The dynamics of the mixing ratios of the three sources suggest that river water contributes only to the inrush (1–4%), with this being especially low in September, as the increasing hydraulic gradient from south to north prevents recharge. The water in F7 accounts for at least 70% of the inrush water. Shallow fracture water accounts for the rest and increases slightly in September as the precipitation increases in mining-disturbed areas. Finally, this work makes the later water control work more targeted. Full article

Against the backdrop of global energy transition and strict environmental regulations, supercritical carbon dioxide (scCO₂) fracturing and oil displacement technologies have emerged as pivotal green approaches in shale gas exploitation, offering the dual advantages of zero water consumption and carbon sequestration. However, the inherent low viscosity of scCO₂ severely restricts its sand-carrying capacity, fracture propagation efficiency, and oil recovery rate, necessitating the urgent development of high-performance thickeners. The current research on scCO₂ thickeners faces a critical trade-off: traditional fluorinated polymers exhibit excellent philicity CO₂, but suffer from high costs and environmental hazards, while non-fluorinated systems often struggle to balance solubility and thickening performance. The development of new thickeners primarily involves two directions. On one hand, efforts focus on modifying non-fluorinated polymers, driven by environmental protection needs—traditional fluorinated thickeners may cause environmental pollution, and improving non-fluorinated polymers can maintain good thickening performance while reducing environmental impacts. On the other hand, there is a commitment to developing non-noble metal-catalyzed siloxane modification and synthesis processes, aiming to enhance the technical and economic feasibility of scCO₂ thickeners. Compared with noble metal catalysts like platinum, non-noble metal catalysts can reduce production costs, making the synthesis process more economically viable for large-scale industrial applications. These studies are crucial for promoting the practical application of scCO₂ technology in unconventional oil and gas development, including improving fracturing efficiency and oil displacement efficiency, and providing new technical support for the sustainable development of the energy industry. This study innovatively designed an amphiphilic modified amino silicone oil polymer (MA-co-MPEGA-AS) by combining maleic anhydride (MA), methoxy polyethylene glycol acrylate (MPEGA), and amino silicone oil (AS) through a molecular bridge strategy. The synthesis process involved three key steps: radical polymerization of MA and MPEGA, amidation with AS, and in situ network formation. Fourier transform infrared spectroscopy (FT-IR) confirmed the successful introduction of ether-based CO₂-philic groups. Rheological tests conducted under scCO₂ conditions demonstrated a 114-fold increase in viscosity for MA-co-MPEGA-AS. Mechanistic studies revealed that the ether oxygen atoms (Lewis base) in MPEGA formed dipole–quadrupole interactions with CO₂ (Lewis acid), enhancing solubility by 47%. Simultaneously, the self-assembly of siloxane chains into a three-dimensional network suppressed interlayer sliding in scCO₂ and maintained over 90% viscosity retention at 80 °C. This fluorine-free design eliminates the need for platinum-based catalysts and reduces production costs compared to fluorinated polymers. The hierarchical interactions (coordination bonds and hydrogen bonds) within the system provide a novel synthetic paradigm for scCO₂ thickeners. This research lays the foundation for green CO₂-based energy extraction technologies. Full article