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Search Results (2,769)

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Keywords = waste reuse

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28 pages, 3181 KB  
Article
Freeze–Thaw Damage of Coal Gangue–Iron Tailings Sintered Porous Bricks in Cold Region Environments
by Jing Li, Su Lu, Jiaxin Liu, Shuaihong Fan, Jianqing Tang, Shasha Li, Zhongying Li, Shunshun Ren and Zilong Liu
Materials 2026, 19(9), 1779; https://doi.org/10.3390/ma19091779 (registering DOI) - 27 Apr 2026
Abstract
Coal gangue (CG) and iron tailings (ITs) are major industrial solid wastes, and their high-value reuse is crucial for sustainable construction materials. This study explores the feasibility of fabricating sintered porous bricks using CG and ITs as primary constituents, with shale as an [...] Read more.
Coal gangue (CG) and iron tailings (ITs) are major industrial solid wastes, and their high-value reuse is crucial for sustainable construction materials. This study explores the feasibility of fabricating sintered porous bricks using CG and ITs as primary constituents, with shale as an auxiliary component. To evaluate durability in cold regions, laboratory freeze–thaw (F-T) cycling experiments were conducted. A degradation assessment framework based on the Wiener stochastic process was developed to predict frost-resistance service life by integrating experimental data with regional climatic conditions. Results show that the fabricated bricks exhibit satisfactory initial properties, with a compressive strength of 10.6 MPa and water absorption of 13.3%. With increasing F-T cycles, compressive strength decreases significantly, accompanied by increased mass loss and water absorption. Stress–strain analysis reveals progressive stiffness reduction and a transition from brittle to ductile failure. Microstructural observations confirm degradation of the glassy phase, pore expansion, and enhanced interconnectivity. The Wiener process-based model effectively describes the stochastic accumulation of F-T damage. By establishing equivalence between laboratory and natural F-T cycles, the long-term service life of coal gangue–iron tailing sintered porous bricks (CG-IT SPBs) in cold regions is theoretically evaluated. This work provides an integrated understanding of F-T damage behavior and establishes a scientific foundation for durability-oriented design and application of such bricks in extremely cold environments. Full article
(This article belongs to the Section Construction and Building Materials)
13 pages, 2921 KB  
Article
Investigation of Shredded Glass Fiber Composites from Post-Industrial and Post-Consumer Waste from Wind Turbine Blades for Reuse in Structural Epoxy Resin Plates
by Bianca Purgleitner, Barbara Liedl and Christoph Burstaller
Fibers 2026, 14(5), 47; https://doi.org/10.3390/fib14050047 (registering DOI) - 24 Apr 2026
Viewed by 94
Abstract
The global expansion of wind energy increases the need for sustainable recycling strategies for glass fiber-reinforced plastic (GFRP) from end-of-life wind turbine blades (WTB). Mechanical recycling is currently the most economically and ecologically viable technology. This study compares post-industrial (PI) waste from laminate [...] Read more.
The global expansion of wind energy increases the need for sustainable recycling strategies for glass fiber-reinforced plastic (GFRP) from end-of-life wind turbine blades (WTB). Mechanical recycling is currently the most economically and ecologically viable technology. This study compares post-industrial (PI) waste from laminate cutoffs and post-consumer (PC) GFRP waste from end-of-life WTBs to investigate the influence of waste origin, pretreatment of shredded GFRP, different particle sizes and various matrix formulations on the tensile modulus and tensile strength of pressed bulk molding compounds produced with virgin epoxy resin. Thermogravimetric analysis showed a fiber content of up to 70 wt.%, but the resin residues on the embedded glass fibers dimmish a sufficient bonding of the new matrix system. Finer GFRP fractions consistently yielded higher tensile modulus and strength, with PI and pretreated PC materials performing best. The findings of this study demonstrate that controlled particle size distribution, impurity removal and optimized resin viscosity are key factors to achieve reliable mechanical performance and enable high-value recycling routes for glass fiber composite waste. Full article
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32 pages, 963 KB  
Review
Low-Cost, Sustainable Materials and 3D-Printed Systems for Wastewater Treatment and Reuse in Rural Communities: A Critical Review
by Wathsala Benthota Pathiranage, Hunain Alkhateb and Matteo D’Alessio
Water 2026, 18(9), 1002; https://doi.org/10.3390/w18091002 - 23 Apr 2026
Viewed by 258
Abstract
Global water scarcity has intensified over recent decades, with projections suggesting that nearly six billion people may face limited access to clean water by 2050. Water reuse has emerged as a viable strategy to alleviate pressure on freshwater resources, particularly for non-potable applications. [...] Read more.
Global water scarcity has intensified over recent decades, with projections suggesting that nearly six billion people may face limited access to clean water by 2050. Water reuse has emerged as a viable strategy to alleviate pressure on freshwater resources, particularly for non-potable applications. However, safe implementation requires wastewater to be treated to meet fit-for-purpose quality standards established through regional and national regulatory frameworks. Despite high levels of basic sanitation coverage in high-income countries such as the United States, persistent gaps remain in affordable and equitable wastewater management, particularly in small and underserved communities. This review focused on current knowledge of sustainable low-cost materials, including plant-based, clay, and clay-based ceramics; animal-derived products; and industrial by-products, used to remove a broad range of contaminants, including heavy metals, dyes, nutrients, emerging contaminants, and pathogens, from wastewater. The mechanisms governing their performance, such as adsorption, coagulation–flocculation, and filtration, were examined alongside contaminant-specific performance. The review further highlights the emerging role of 3D printing in developing customizable, efficient, and scalable treatment units using low-cost or waste-derived materials. Life cycle assessment (LCA) studies were evaluated to highlight their role as a flexible framework for assessing environmental impacts across life-cycle stages and for guiding the selection of sustainable materials and treatment systems. Together, these perspectives provide a comprehensive foundation for developing decentralized, community-oriented wastewater treatment solutions that support safe and effective water reuse, especially in rural and small communities. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
43 pages, 8252 KB  
Systematic Review
Sustainable Recycling and Reuse of Marble Waste in the Construction Industry: A Systematic Review Towards a Circular Economy
by Salmabanu Luhar and Ismail Luhar
J. Compos. Sci. 2026, 10(5), 221; https://doi.org/10.3390/jcs10050221 - 22 Apr 2026
Viewed by 253
Abstract
The global construction sector, a major consumer of virgin raw materials, is under increasing pressure to transition from a linear to a circular economy model. Marble waste, generated in large quantities during quarrying, cutting, and polishing operations, represents a promising secondary resource for [...] Read more.
The global construction sector, a major consumer of virgin raw materials, is under increasing pressure to transition from a linear to a circular economy model. Marble waste, generated in large quantities during quarrying, cutting, and polishing operations, represents a promising secondary resource for sustainable construction applications. This systematic review was conducted in accordance with the PRISMA 2020 reporting guidelines to critically evaluate the utilization of marble waste in concrete and other building materials. A comprehensive literature search was performed using major scientific databases, and relevant studies published between 2000 and 2025 were analyzed. The findings consistently indicate that marble waste performs most effectively as a fine aggregate replacement at 10–20%, resulting in improved compressive strength, pore refinement, and durability. As a cement substitute, the optimum replacement level is generally 5–10%, beyond which dilution effects may adversely affect strength development. The performance is primarily attributed to improved particle packing and microstructural refinement. This review further highlights future pathways for industrial-scale implementation, mix optimization, standardisation, and policy integration to accelerate circular construction practices. These findings support the potential of marble waste as a sustainable material in advancing circular economy principles in the construction industry. Full article
(This article belongs to the Special Issue Sustainable Composite Construction Materials, 3rd Edition)
36 pages, 8045 KB  
Article
Operationalizing Social–Ecological Systems Dynamics Through Spatial Metrics for Urban Waste Space Transformation in İzmir, Türkiye
by Gurkan Guney
Urban Sci. 2026, 10(5), 221; https://doi.org/10.3390/urbansci10050221 - 22 Apr 2026
Viewed by 283
Abstract
Unused, underutilized, abandoned, and residual urban spaces are increasingly recognized as potential resources for adaptive reuse, ecological improvement, and urban resilience. In this study, such areas are approached through the overarching concept of waste space, a term that captures both their underutilized condition [...] Read more.
Unused, underutilized, abandoned, and residual urban spaces are increasingly recognized as potential resources for adaptive reuse, ecological improvement, and urban resilience. In this study, such areas are approached through the overarching concept of waste space, a term that captures both their underutilized condition and their transformation potential. While existing research has largely focused on the definition, classification, and emergence of such spaces, their potential for transformation across varying spatial and institutional contexts has received comparatively limited attention. Addressing this gap, this study operationalizes selected social–ecological system (SES) dynamics through spatial analysis in the metropolitan area of İzmir, Türkiye, offering a proxy-based assessment of transformation capacity rather than a direct transformation. Using district-level analysis across ten metropolitan districts, this research combines typological and morphological classification of waste spaces with four spatial indicators: the Density Index, Location Quotient, Shannon Diversity Index, and Typology Dominance Index. The results show that waste spaces are unevenly distributed across İzmir and form distinct district-level configurations shaped by infrastructure expansion, post-industrial transformation, speculative vacancy, and fragmented urban growth. This study concludes that waste spaces cannot be addressed through a uniform regeneration logic. By linking SES dynamics with measurable spatial indicators, the proposed framework offers a context-sensitive, proxy-based basis for indicating transformation capacity of waste spaces and supporting district-specific planning and policy decisions. Full article
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21 pages, 6202 KB  
Article
Adsorption of Pb(II) by Manganese Sand-Modified Drinking Water Treatment Plant Residual Particles
by Xiaoli Du, Shiyi Chen, Huihui Sheng, Xinhong Yu and Yuhao Sun
Sustainability 2026, 18(8), 4130; https://doi.org/10.3390/su18084130 - 21 Apr 2026
Viewed by 119
Abstract
Urban stormwater runoff often contains toxic metals that threaten aquatic environments. Meanwhile, the large quantities of drinking water treatment residuals (DWTRs) generated worldwide offer opportunities for sustainable reuse as pollutant removal materials. In this study, a manganese sand-modified drinking water treatment residual particle [...] Read more.
Urban stormwater runoff often contains toxic metals that threaten aquatic environments. Meanwhile, the large quantities of drinking water treatment residuals (DWTRs) generated worldwide offer opportunities for sustainable reuse as pollutant removal materials. In this study, a manganese sand-modified drinking water treatment residual particle (RDP-M) was prepared from DWTRs and manganese sand for Pb(II) removal from water. Characterization by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS) showed that RDP-M had a rough surface morphology and abundant oxygen-containing functional groups, which provided adsorption sites. Batch experiments showed that the maximum Pb(II) adsorption capacity of RDP-M reached 2.79 mg g−1 at 298 K and pH 7.0, which was about 48% higher than that of the unmodified particles (RDP). The adsorption process followed the pseudo-second-order kinetic model and the Langmuir isotherm model, indicating a chemisorption-dominated process. Thermodynamic analysis further showed that the process was spontaneous and exothermic. RDP-M maintained stable Pb(II) removal over a wide pH range, showed low sensitivity to coexisting ions, and retained high efficiency during repeated use. These results demonstrate that RDP-M has potential as a sustainable granular material for stormwater treatment and waste resource valorization. Full article
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68 pages, 7328 KB  
Review
Sustainable Valorization of Spent Coffee Grounds Within the Circular Economy: Innovative Applications in Food, Agriculture, Environmental, and Industrial Sectors
by Nicoleta Ungureanu and Nicolae-Valentin Vlăduț
Sustainability 2026, 18(8), 4127; https://doi.org/10.3390/su18084127 - 21 Apr 2026
Viewed by 179
Abstract
Spent coffee grounds (SCGs) are one of the most abundant agro-industrial by-products worldwide, with 650 kg generated per ton of green coffee processed, corresponding to an estimated global production of 6.7 million tons in 2022/2023. Improper disposal of SCG raises environmental concerns, while [...] Read more.
Spent coffee grounds (SCGs) are one of the most abundant agro-industrial by-products worldwide, with 650 kg generated per ton of green coffee processed, corresponding to an estimated global production of 6.7 million tons in 2022/2023. Improper disposal of SCG raises environmental concerns, while their reuse offers opportunities for sustainable resource management and circular economy strategies. This review examines SCG valorization by addressing their chemical composition, functional properties, and key applications in sectors such as food, agriculture, environmental remediation, bioenergy, and selected industrial fields, including pharmaceuticals, cosmetics, construction materials, and functional devices. In this context, it discusses technological approaches, performance outcomes, and implementation considerations, emphasizing the multifunctional potential of SCGs as a renewable feedstock capable of reducing waste, improving resource efficiency, and generating economic value. By consolidating the current state of knowledge and exploring diverse valorization pathways, this work frames SCG utilization within a circular bioeconomy framework and highlights how innovative applications can transform this widely available waste into sustainable and economically valuable products. Full article
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20 pages, 7389 KB  
Article
Proposal for a Protocol and a Handmade Arduino-Based and Open Source Device for Measuring the Residual Charge of Alkaline Batteries in View of an Attempt to Recharge Them
by Giovanni Visco, Maria Pia Sammartino, Angela Marchetti, Mauro Castrucci and Mauro Tomassetti
Methods Protoc. 2026, 9(2), 66; https://doi.org/10.3390/mps9020066 - 19 Apr 2026
Viewed by 244
Abstract
Portable devices are powered in direct current (DC) or by batteries (primary battery), accumulators (secondary battery), and now supercapacitors, which can also be used for energy storage. The European Portable Battery Association states that approximately 239,000 tons of batteries were placed on the [...] Read more.
Portable devices are powered in direct current (DC) or by batteries (primary battery), accumulators (secondary battery), and now supercapacitors, which can also be used for energy storage. The European Portable Battery Association states that approximately 239,000 tons of batteries were placed on the market in the European Economic Area (EEA) plus Switzerland in 2022. Even if they were all disposed of correctly respecting the 3R paradigm (Reduce, Reuse and Recycle), non-rechargeable batteries create an environmental problem because they do not discharge completely with an obvious waste of energy. Secondary batteries and supercapacitors can be recharged because they use reversible chemical/physical processes while primary batteries cannot be recharged because they are based on irreversible redox reactions; nevertheless, it is possible to try to recover their residual charge if this is higher than a threshold beyond which the reactions can be reversible. The most used batteries are alkaline zinc/manganese dioxide and they are non-rechargeable; an inappropriate recharge attempt can lead to serious harm to the operator and the environment. This paper describes a simple Arduino-based circuit and the protocol to measure and graph the residual charge of an alkaline battery in order to establish if it can be recharged. The circuit, design, the Arduino Uno R3 sketch (i.e., microprocessor software) and the full protocol are here presented under the open source license (Copyright Creative Commons Public license, CC BY-NC-ND 4.0 EN) so that they could become a pilot system and then a commercial product. The residual charge of 158 batteries, obtained after discharging those that, by eye, appeared damaged, was measured. Results evidenced that 49% of batteries had a residual voltage, under low load, between 1.2 and 1.6 V, making them good candidates for a recharge attempt. Full article
(This article belongs to the Section Biochemical and Chemical Analysis & Synthesis)
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18 pages, 6791 KB  
Article
Recycling of End-of-Life AlNiCo-5 into Polyamide 12-Bonded Magnets by Material Extrusion (MEX) Additive Manufacturing: Effects of Filler Loading on Printability and Properties
by Hossein Naderi, Ioannis Xanthis, Theofilos Giannopoulos, Efstratios Kroustis and Elias P. Koumoulos
Processes 2026, 14(8), 1290; https://doi.org/10.3390/pr14081290 - 17 Apr 2026
Viewed by 282
Abstract
This work explores a sustainable route for producing recycled AlNiCo-based magnetic composites by incorporating end-of-life AlNiCo-5 particles into a polyamide 12 (PA12) matrix, thereby eliminating conventional debinding requirements. The study emphasizes material circularity through the reuse of mechanically recovered magnetic waste and polymeric [...] Read more.
This work explores a sustainable route for producing recycled AlNiCo-based magnetic composites by incorporating end-of-life AlNiCo-5 particles into a polyamide 12 (PA12) matrix, thereby eliminating conventional debinding requirements. The study emphasizes material circularity through the reuse of mechanically recovered magnetic waste and polymeric residues. Virgin PA12 powder was used as the matrix material for high magnetic filler loadings of 40, 60, and 70 wt.% AlNiCo-5, while stearic acid was introduced to enhance interfacial compatibility and overall processability. The resulting composites were shaped into filaments and processed via material extrusion additive manufacturing, demonstrating that commercially available fused filament fabrication systems can successfully handle highly filled metal-polymer blends when supported by appropriate formulation and process parameter optimization. The findings confirm the feasibility of manufacturing flexible, functional, and resource-efficient magnetic components using widely accessible equipment, highlighting a promising pathway toward the cost-effective recycling and reuse of AlNiCo magnetic materials. Full article
(This article belongs to the Special Issue Polymer Nanocomposites for Smart Applications)
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29 pages, 1570 KB  
Article
ESG and Circular Business Models: Towards a Sector-Specific Circular–ESG Integration Framework
by Arnesh Telukdarie and Musawenkosi Hope Lotriet Nyathi
Sustainability 2026, 18(8), 4006; https://doi.org/10.3390/su18084006 - 17 Apr 2026
Viewed by 269
Abstract
Across the globe, companies are facing significant pressure to reduce waste, improve resource efficiency, and report their sustainability efforts transparently. ESG frameworks have become essential tools for sustainability transformation. However, traditional business models, based on a linear “take–make–dispose” approach, continue to dominate industries, [...] Read more.
Across the globe, companies are facing significant pressure to reduce waste, improve resource efficiency, and report their sustainability efforts transparently. ESG frameworks have become essential tools for sustainability transformation. However, traditional business models, based on a linear “take–make–dispose” approach, continue to dominate industries, limiting the impact of ESG efforts. The circular economy offers a compelling alternative: it encourages designing products for reuse, recycling, and regeneration, thus aligning closely with ESG principles. When businesses transition to circular models, they reduce their environmental footprint, create new green jobs and social inclusion opportunities, and strengthen accountability across business value chains. This study explores how selected firms in the mining, energy, consumer cyclical, technology, and healthcare sectors are aligning circular principles with ESG practices. Using a longitudinal, multi-sector comparative analysis of ESG indicators spanning 2014–2024, the research examines sector-level ESG evolution, firm-level ESG leadership, and the alignment of ESG performance with circular business model pathways. Rather than directly measuring circular transformation, ESG indicators are interpreted as signals of emerging circular business model pathways. This study identifies ESG-based ways and enabling conditions through which circularity may be increasingly embedded across different sectors. Full article
(This article belongs to the Special Issue Enterprise Operation and Innovation Management Sustainability)
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27 pages, 949 KB  
Systematic Review
Material Reuse in the European Union Construction Sector: A Review
by Inês Silva, Graça Martinho and Mário Ramos
Recycling 2026, 11(4), 79; https://doi.org/10.3390/recycling11040079 - 16 Apr 2026
Viewed by 444
Abstract
The progression towards a circular economy in the construction sector has gained attention as a response to rising resource consumption and construction and demolition waste generation, with material reuse playing a central role. In this context, this study analyses the literature on reuse [...] Read more.
The progression towards a circular economy in the construction sector has gained attention as a response to rising resource consumption and construction and demolition waste generation, with material reuse playing a central role. In this context, this study analyses the literature on reuse in the construction sector, examining its investigation over time and its relation to European regulatory frameworks and policy strategies. A systematic literature review was conducted using a structured search across the B-on, Scopus, and Web of Science databases. The search targeted peer-reviewed journal articles in English, published between 2008 and 2023, focusing on titles, abstracts, and keywords with predefined terms. A total of 78 articles met the inclusion criteria and were analysed. Research activity has increased in recent years, reflecting growing European policy attention, particularly the Waste Framework Directive, its 2018 amendment, and the Circular Economy Action Plan. Most studies address strategies to promote the circular economy, waste management practices, life cycle assessments, and the identification of barriers and opportunities to reuse. Despite the expanding literature, reuse remains insufficiently addressed. These findings underline the need for more targeted research and stronger integration between policy and practice to support effective reuse in the construction sector. Full article
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42 pages, 1762 KB  
Article
A Behavior-Based 3R Measurement Model for Assessing Sustainability in Residential Interior Spaces: Evidence from Jordan
by Rammah Mahmoud Almaqbool and Kamil Guley
Sustainability 2026, 18(8), 3969; https://doi.org/10.3390/su18083969 - 16 Apr 2026
Viewed by 911
Abstract
Residential interior spaces significantly contribute to material consumption, renovation waste, and indoor environmental exposure, yet sustainability at the interior scale is still commonly assessed through prescriptive design guidelines, rather than measurable performance. The existing literature lacks an empirically validated framework that operationalizes circular [...] Read more.
Residential interior spaces significantly contribute to material consumption, renovation waste, and indoor environmental exposure, yet sustainability at the interior scale is still commonly assessed through prescriptive design guidelines, rather than measurable performance. The existing literature lacks an empirically validated framework that operationalizes circular economy practices within residential interiors and links them to consumption-related behavior. To address this gap, this study develops and validates a multidimensional measurement model based on the 3R framework (Reduce, Reuse, Recycle) to evaluate interior sustainability through environmental, economic, and social indicators and examine its relationship with perceptions of overconsumption and continuous interior change. The model was empirically tested in Jerash, Jordan, using a structured survey of adult homeowners (N = 304). Reliability and construct validity were confirmed through exploratory and confirmatory analyses, followed by regression modeling. The results demonstrate that interior sustainability can be reliably quantified using coherent 3R-based constructs, with environmental, economic, and social indicators strongly associated with the three dimensions (r > 0.8). Engagement in reduce and Recycle practices showed significant associations, with more critical attitudes toward trend-driven renovation and excessive consumption, whereas reuse did not demonstrate a statistically significant effect. The model explained 43% of the variance in these perceptions (R2 = 0.432, p < 0.001). The findings advance interior sustainability from prescriptive guidance toward analytical, behavior-based measurement and provide a transferable framework for assessing circular material practices in residential interiors. Full article
(This article belongs to the Section Green Building)
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29 pages, 754 KB  
Review
Sustainability: A Comprehensive Overview of Palm Oil Waste Upcycling in Civil Engineering Applications
by Nura Shehu Aliyu Yaro, Jacob Adedayo Adedeji, Zesizwe Ngubane and Jacob Olumuyiwa Ikotun
Constr. Mater. 2026, 6(2), 23; https://doi.org/10.3390/constrmater6020023 - 15 Apr 2026
Viewed by 178
Abstract
Palm oil waste (POW) is generated during the production of palm oil, and a large quantity of this waste often travels to landfills for disposal. This review aims to provide a comprehensive understanding of the circular economy approach to sustainable engineering and environmental [...] Read more.
Palm oil waste (POW) is generated during the production of palm oil, and a large quantity of this waste often travels to landfills for disposal. This review aims to provide a comprehensive understanding of the circular economy approach to sustainable engineering and environmental applications of POW, including its generation, disposal concerns, challenges, and prospects. This review provides an overview of the features, composition, and prospective applications of several POWs, including palm oil clinkers (POCs), palm oil fuel ashes (POFAs), palm oil kernel shells (POKSs), and palm oil fibres (POFs). Furthermore, this overview describes the different applications that POW has found, such as sustainable construction materials, renewable energy production, and environmental remediation. Moreover, this review discusses the leaching and risk assessment of POW. The overview also discusses the circular economy implications of using POW. The results showed that while some wastes are reused and recycled, a good quantity are still discarded in environmentally harmful ways. With this overview of a wide circular economy approach to the sustainable use of POW, there will be a rallying call to experts and researchers to identify research gaps that could contribute to the sustainable use of POW. The results of this overview of the sustainable engineering and environmental applications of POW with a circular economy approach indicate that cleaner production technologies and better environmental sustainability of the palm oil industry are feasible through proper waste management, renewable energy generation, resulting in minimal environmental impacts. Furthermore, this analysis will be very useful in providing tools to engineers, environmentalists, and other relevant stakeholders to enable the efficient and sustainable use of POW in the global circular economy. Full article
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20 pages, 1886 KB  
Article
Development of an Electrochemical System for Cleaning Oil Refinery Waste from Sulfides and Organic Pollutants
by Antonina Andreevna Filimonova, Hristo Ivanov Beloev, Artur Maratovich Khairutdinov, Andrey Alexandrovich Chichirov, Egor Sergeevich Mayorov, Alena Yurevna Vlasova, Ruzina Farsilovna Kamalieva, Andrey Artemovich Filimonov, Iliya Krastev Iliev and Ivan Hristov Beloev
Energies 2026, 19(8), 1904; https://doi.org/10.3390/en19081904 - 14 Apr 2026
Viewed by 252
Abstract
Sulfide-alkaline wastewater (SAW) from petrochemical plants, particularly from pyrolysis and hydrotreating units, presents a significant environmental challenge due to its high toxicity, extreme alkalinity (pH > 12), and high concentrations of sulfides and organic pollutants. Traditional treatment methods like acid neutralization or air [...] Read more.
Sulfide-alkaline wastewater (SAW) from petrochemical plants, particularly from pyrolysis and hydrotreating units, presents a significant environmental challenge due to its high toxicity, extreme alkalinity (pH > 12), and high concentrations of sulfides and organic pollutants. Traditional treatment methods like acid neutralization or air oxidation are often inefficient, generate secondary waste, or fail to recover valuable components. This study investigates the effectiveness of a novel electrochemical system for the simultaneous treatment of SAW and recovery of valuable products. A lab-scale four-chamber electrodialyzer, equipped with cation-exchange membranes and nickel bipolar electrodes, was designed and tested using real industrial wastewater. The wastewater was characterized by a pH of 13.06, chemical oxygen demand of 12,600 mg/L, and a sulfide content of approximately 5000 mg/L. The process leverages anodic oxidation to convert sulfide ions into elemental sulfur, while sodium cations migrate through cation-exchange membranes to the cathodic compartments. There, water reduction generates high-purity hydrogen (≥99.9%) and a concentrated, purified sodium hydroxide solution. The results demonstrate the ineffectiveness of electrodialysis with anion-exchange membranes due to rapid membrane degradation. In contrast, the proposed electrodialyzer with bipolar electrodes achieved excellent performance: a caustic soda solution with a concentration of 2.3–2.5% was recovered with a current efficiency of 83–85%, containing only trace amounts of sulfides (0.0052%) and organic impurities (0.053%). The process completely removed the original sulfide alkalinity. The study confirms the chemical and mechanical stability of the cation-exchange membranes under harsh SAW conditions. The proposed technology offers a path towards a closed-loop system in refineries by enabling the reuse of recovered caustic, utilization of hydrogen, and potential recovery of sulfur, aligning with the principles of green chemistry and circular economy. Full article
(This article belongs to the Section B: Energy and Environment)
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19 pages, 1205 KB  
Article
Recycled Denim and Polyurethane Foam for Building Insulation and Resource Conservation
by Neelima Madasu, Farnaz Saadat, Nadia Laredj, Mustapha Maliki, Anthony Lamanna, Hamed Khodadadi Tirkolaei and Elham H. Fini
Sustainability 2026, 18(8), 3847; https://doi.org/10.3390/su18083847 - 13 Apr 2026
Viewed by 507
Abstract
Construction industry remains a major driver of global resource use and waste generation, therefore, identifying sustainable material alternatives is increasingly important. Recycled-textile-based insulation presents a promising pathway to support circular economy principles by diverting post-consumer waste from landfills and reducing reliance on virgin [...] Read more.
Construction industry remains a major driver of global resource use and waste generation, therefore, identifying sustainable material alternatives is increasingly important. Recycled-textile-based insulation presents a promising pathway to support circular economy principles by diverting post-consumer waste from landfills and reducing reliance on virgin petrochemical materials. This study conducts a cradle-to-gate life cycle assessment (LCA) using SimaPro to compare polyurethane (PU) foam and recycled denim (cotton fiber) insulation. The system boundary includes raw material extraction, transportation, and manufacturing. A functional unit of 1 m2 of installed insulation with a thermal resistance of RSI = 1 m2·K/W at the factory gate ensures comparability, with mass-based results reported as secondary metrics. The results indicate that recycled denim exhibits higher embodied carbon per unit mass, despite lower production energy and lower cradle-to-gate impacts per installed area, reinforcing the need for a declared-unit-based comparison tied to thermal performance. Air leakage is evaluated separately as a complementary performance indicator influencing in-service energy behavior showing significantly lower air leakage for PU; but is not included in the cradle-to-gate normalization. However, it could be argued that materials with improved airtightness may enable the use of reduced insulation thickness while still achieving equivalent performance, thereby potentially lowering overall material demand. Nevertheless, recycled denim offers environmental advantages by reducing landfill waste and promoting resource conservation through material reuse. A transient coupled heat–moisture model in COMSOL Multiphysics, using climate data from Arizona and Florida, further reveals that denim absorbs more moisture than polyurethane. This leads to larger heat flux fluctuations, highlighting a trade-off between denim’s sustainability advantages and its reduced hygrothermal durability. Overall, these findings demonstrate the limitations of single-metric comparisons and emphasize the need for performance-based, multi-criteria assessments that integrate functional efficiency with circularity. Future research should incorporate occupant health and comfort to enable a more comprehensive evaluation of insulation sustainability. Full article
(This article belongs to the Section Energy Sustainability)
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