Search Results (318)

A novel self-healing brass powder/waterborne acrylic decorative coating for wooden substrates was developed, in which γ-methacryloxypropyltrimethoxysilane (KH570)-modified brass powder (with a coupling agent concentration of 6% and reaction solution pH of 5) was employed as the filler, and melamine-formaldehyde (MF) resin-encapsulated water-based paint microcapsules were utilized as the healing agent. The brass powder content and the core–wall ratio of the topcoat microcapsules were identified as the predominant factors affecting both the optical and mechanical properties of the self-healing brass powder/waterborne acrylic coating on Basswood surfaces. Therefore, the brass powder content was selected as the primary influencing factor. With concentration gradients of 0.5%, 1%, 3%, 5%, 7%, 9%, and 10%, and under constant conditions of 3% microcapsule content and room temperature curing, the effect of brass powder content on the properties of self-healing microcapsule coatings with different core–wall ratios was investigated. The waterborne acrylic wood coating containing 3% brass powder and 3% microcapsules with a core–wall ratio of 0.58:1 exhibited superior overall performance. This optimized formulation not only maintained excellent optical properties but also significantly enhanced mechanical performance, while preserving outstanding aging resistance, liquid resistance, and self-healing capability. The coating demonstrated the following comprehensive performance metrics: a glossiness of 24.0 GU, color difference (ΔE) of 2.13, chromatic aberration (ΔE*) of 13.68, visible light reflectance of 0.5879, dominant wavelength of 587.47 nm, visible light transmittance of 74.33%, pencil hardness of H grade, impact resistance of 2 kg·cm, adhesion rating of class 2, surface roughness of 2.600 μm, along with excellent aging resistance and liquid resistance properties, while achieving a self-healing efficiency of 19.62%. The coating also exhibited a smooth and uniform microscopic morphology, with the chemical bonds of both the modified brass powder and microcapsules remaining intact within the coating matrix. Full article

The surface of the Great Wall harbors a large number of non-vascular plants dominated by cyanobacteria, lichens and mosses as well as microorganisms, and form biocrusts by cementing with the soils and greatly alters the pore structure of the soil and the ecohydrological processes associated with the soil pore space, and thus influences the soil resistance to erosion. However, the microscopic role of the biocrusts in influencing the pore structure of the surface of the Great Wall is not clear. This study chose the Warring States Qin Great Wall in Weiyuan, Gansu Province, China, as research site to quantify thepore structure characteristics of the three-dimensional of bare soil, cyanobacterial-lichen crusts, and moss crusts at the depth of 0–50 mm, by using optical microscopy, scanning electron microscopy, and X-ray computed tomography and image analysis, and the precipitation infiltration process. The results showed that the moss crust layer was dominated by large pores with long extension and good connectivity, which provided preferential seepage channels for precipitation infiltration, while the connectivity between the cyanobacterial-lichen crust voids was poor; The porosity of the cyanobacterial-lichen crust and the moss crust was 500% and 903.27% higher than that of the bare soil, respectively. The porosity of the subsurface layer of cyanobacterial-lichen crust and moss crust was significantly lower than that of the biocrusts layer by 92.54% and 97.96%, respectively, and the porosity of the moss crust was significantly higher than that of the cyanobacterial-lichen crust in the same layer; Cyanobacterial-lichen crusts increased the degree of anisotropy, mean tortuosity, moss crust reduced the degree of anisotropy, mean tortuosity. Biocrusts increased the fractal dimension and Euler number of pores. Compared with bare soil, moss crust and cyanobacterial-lichen crust increased the isolated porosity by 2555% and 4085%, respectively; Biocrusts increased the complexity of the pore network models; The initial infiltration rate, stable infiltration rate, average infiltration rate, and the total amount of infiltration of moss crusted soil was 2.26 and 3.12 times, 1.07 and 1.63 times, respectively, higher than that of the cyanobacterial-lichen crusts and the bare soil, by 1.53 and 2.33 times, and 1.13 and 2.08 times, respectively; CT porosity and clay content are significantly positively correlated with initial soil infiltration rate (|r| ≥ 0.85), while soil type and organic matter content are negatively correlated with initial soil infiltration rate. The soil type and bulk density are directly positively and negatively correlated with CT porosity, respectively (|r| ≥ 0.52). There is a significant negative correlation between soil clay content and porosity (|r| = 0.15, p < 0.001). Biocrusts alter the erosion resistance of rammed earth walls by affecting the soil microstructure of the earth’s great wall, altering precipitation infiltration, and promoting vascular plant colonisation, which in turn alters the erosion resistance of the wall. The research results have important reference for the development of disposal plans for biocrusts on the surface of archaeological sites. Full article

During the operation of structures, the components and materials from which they are made are exposed to various environmental, technological, and operational impacts. In this context, the use of a modified water-dispersion composition containing finely dispersed fillers with enhanced protective and performance characteristics proves to be effective. This article examines the development of a paint-and-coating composition using hollow glass microspheres and modified diatomite as finely dispersed fillers. The influence of technological factors on the properties of coating materials based on a synthesized acrylic dispersion and fillers—such as modified diatomite and hollow glass microspheres ranging from 20 to 100 μm in size with a bulk density of 0.107–0.252 g/cm³—is analyzed. The optimal formulation of the coating materials was determined to ensure the required coating quality. Experimental results demonstrate the improved strength and hardness of the coating due to the use of acrylic dispersion obtained through an emulsifier-free method and modifiers in the form of finely dispersed fillers. It has been established that the resulting samples also exhibit high adhesion to mineral and metallic substrates, along with excellent corrosion resistance. Moreover, the incorporation of acrylic dispersion contributes to increased elasticity of the coating, resulting in improved resistance to washing and abrasion. The developed protective material can be applied to a variety of surfaces, including walls, ceilings, and roofs of buildings and structures, pipelines, and many other applications. Thus, modified water-dispersion compositions based on synthesized acrylic dispersion showed the following results: resistance to sticking—5, which is the best; chemical resistance and gloss level with standard single-phase acrylic dispersion—no destruction or change in gloss. The adhesion of coatings cured under natural conditions and under the influence of UV radiation was 1 point. The developed formulations for obtaining water-dispersion paint and varnish compositions based on synthesized polymer dispersions, activated diatomite, and hollow glass microspheres, meet all the regulatory requirements for paint and varnish materials in terms of performance, and in terms of economic indicators, the cost of 1 kg of paint is 30% lower than the standard. Full article

This review synthesizes the corpus of archaeometric and analytical investigations focused on mortar-based materials, including wall paintings, plasters, and concrete, in the Roman Regio X and neighboring territories of northeastern Italy from the mid-1970s to the present. Organized into three principal categories—wall paintings and pigments, structural and foundational mortars, and flooring preparations—the analysis highlights the main methodological advances and progress in petrographic microscopy, mineralogical analysis, and mechanical testing of ancient mortars. Despite extensive case studies, the review identifies a critical need for systematic, statistically robust, and chronologically anchored datasets to fully reconstruct socio-economic and technological landscapes of this provincial region. This work offers a programmatic research agenda aimed at bridging current gaps and fostering integrated understandings of ancient construction technologies in northern Italy. The full forms of the abbreviations used throughout the text to describe the analytical equipment are provided at the end of the document in the “Abbreviations” section. Full article

This article traces the historical evolution of mural painting as a medium of cultural expression from prehistoric cave art to contemporary street interventions. Adopting a diachronic and interdisciplinary approach, it investigates how muralism has developed across civilizations in relation to techniques, symbolic systems, social function, and its embeddedness in architectural and urban contexts. The analysis is structured around key historical periods using emblematic case studies to examine the interplay between materiality, iconography, and socio-political meaning. From sacred enclosures and civic monuments to post-industrial walls and digital projections, murals reflect shifting cultural paradigms and spatial dynamics. This study emphasizes how mural painting, once integrated into sacred and imperial architecture, has become a tool for public participation, protests, and urban storytelling. Particular attention is paid to the evolving relationship between wall painting and the spaces it inhabits, highlighting the transition from permanence to ephemerality and from monumentality to immediacy. This article contributes to mural studies by offering a comprehensive framework for understanding the technical and symbolic transformations of the medium while proposing new directions for research in the context of digital urbanism and cultural memory. Full article

Preserving heritage sites is a complex challenge that requires multidisciplinary approaches, combining scientific accuracy with cultural and historical sensitivity. In alignment with UNESCO’s conservation guidelines, this study investigated the airflow dynamics and wind-induced structural effects within ancient architecture using advanced computational fluid dynamics (CFD). The study site was the Na Phra Meru Historical Temple in Ayutthaya, Thailand, where the shear stress transport $k-\omega$ turbulence model was applied to analyze distinctive airflow patterns. A high-precision 3D computational domain was developed using Faro focus laser scanning technology, with the CFD results being validated based on onsite experimental data. The findings provided critical insights into the temple’s ventilation behavior, revealing strong correlations between turbulence characteristics, wind speed, temperature, and relative humidity. Notably, the small slit windows generated complex flow mixing, producing a large internal recirculation zone spanning approximately 70% of the central interior space. In addition to airflow distribution, the study evaluated the aerodynamic forces and rotational moments acting on the structure based on five prevailing wind directions. Based on these results, winds from the east and northeast generated the highest aerodynamic loads and rotational stresses, particularly in the lateral and vertical directions. Overall, the findings highlighted the critical role of airflow and wind-induced forces in the deterioration and long-term stability of heritage buildings. The study demonstrated the value of integrating CFD, environmental data, and structural analysis to bridge the gap between conservation science and engineering practice. Future work will explore further the interactions between wall moisture and the multi-layered pigments in mural paintings to inform preservation practices. Full article

Debonding, especially in plastic materials, refers to the separation occurring at the interface within a bonded structure composed of two or more polymeric layers. Due to the great heterogeneity of materials and layering configurations, highly specialized expertise is often required to detect the presence and extent of such defects. This study presents a novel approach that leverages transfer learning techniques to improve the detection of debonding defects across different surface types using PICUS, an acoustic diagnostic device developed at Roma Tre University for the assessment of defects in heritage wall paintings. Our method leverages a pre-trained deep learning model, adapting it to new material conditions. We designed a planar test object embedded with controlled subsurface cavities to simulate the presence of defects of adhesion and air among the layers. This was rigorously evaluated using non-destructive testing using PICUS, augmented by artificial intelligence (AI). A convolutional neural network (CNN), initially trained on this mock-up, was then fine-tuned via transfer learning on a second test object with distinct geometry and material characteristics. This strategic adaptation to varying physical and acoustic properties led to a significant improvement in classification precision of defect class, from 88% to 95%, demonstrating the effectiveness of transfer learning for robust cross-domain defect detection in challenging diagnostic applications. Full article

This study aims to enhance the understanding of film cooling performance in an actual turbine vane by investigating influencing factors and developing more precise numerical prediction methods. Pressure sensitive paint (PSP) testing and Reynolds-Averaged Navier–Stokes (RANS) simulations were conducted. The findings indicate that the current design blowing ratio of S1 holes (0.89) is too high, resulting in poor film cooling effectiveness. However, the blowing ratios of P3 (0.78) and P4 (0.69) holes are relatively low, suggesting that increasing the coolant flow could improve the film cooling effectiveness. It is not recommended to design an excessively low blowing ratio on the suction surface, as this can lead to poor wall adherence downstream of the film holes. A slight increase in turbulence intensity enhances the film covering effect, particularly on the suction surface. Additionally, a novel superposition method for multirow fan-shaped film cooling holes on an actual turbine vane is proposed, exhibiting better agreement with experimental data. Compared with experimental results, the numerical predictions tend to underestimate the film cooling effectiveness with the examined k-ε-based viscosity turbulence models and Reynolds stress turbulence models, while the SST demonstrates relatively higher accuracy owing to its hybrid k-ω/k-ε formulation that better resolves near-wall physics and separation flows characteristic of turbine cooling configurations. This study contributes to the advancement of turbine vane thermal analysis and design in engineering applications. Full article

This research addresses the formula linking between Michael the Archangel and the Holy Virgin in the wall paintings from fourteenth-century parish churches in the Hungarian Kingdom. This starts from the murals that join together between the figure of St. Michael in the act of psychostasis, as the weigher of souls, and Mary, with the mantle, represented with her all-embracing cloak, and it investigates the spatial implications between St. Michael and Mary. Full article

The aim of this article is to analyse the material remains of the ancient miḥrāb of the Friday Mosque in Ronda (Malaga, Spain), preserved in the present-day church of Santa María de la Encarnación la Mayor, and to propose preservation and valorisation measures to bring these remains to light. After the Christian conquest of Ronda, the church of Santa María de la Encarnación la Mayor was built on the site of the former Friday Mosque. In the 16th century, an altarpiece featuring niches and wall paintings was built, covering the plasterworks of the ancient miḥrāb. The primitive altarpiece was replaced by a Baroque one in the 17th century (El Sagrario altarpiece). At the beginning of the 20th century, the remains of the ancient miḥrāb and the 16th-century altarpiece were discovered while preparing the space for burial sites. Since then, a section of the plasterworks was recovered, although part of them remains covered by the 17th-century altarpiece. In this article, we analyse in detail the remains of the Islamic plasterworks that covered the qibla wall and the ancient miḥrāb, and propose a series of preservation and valorisation measures aimed at restoring these remains, without damaging the 17th-century altarpiece. Full article

In the central Mesa Verde region, rock art occurs on canyon walls and on boulders that are frequently associated with other archaeological remains. Moreover, rock art, together with architecture and pottery, is actually a primary source of archaeological information about the presence of various cultures in the area. It includes paintings and petroglyphs of Ancestral Pueblo farming communities, images and inscriptions made by post-contact Ute and possibly Diné (Navajo) people as well as historical inscriptions of the early Euro-Americans in this area. This paper presents the results of archaeological investigations at four large rock art sites from Sandstone Canyon, southwestern Colorado, within the Canyons of the Ancients National Monument (CANM). Methods of rock art recording included advanced digital photography, photogrammetry, terrestrial laser scanning (TLS), hand tracing, and consultations with members of indigenous societies and rock art scholars. Geophysics and sondage excavations were conducted at one site revealed important information about archaeology, environment, and geology of the area. Analysis of rock art and other material evidence aims to help reconstruct and understand the mechanisms and nature of cultural changes, migrations, and human–environmental interactions and later cross-cultural contacts between indigenous peoples and Anglo-American ranchers and settlers in southwestern Colorado and the US Southwest. Full article

Rock imagery in the Puebloan region of the American Southwest often combines elements from different animal, human, plant, and natural sources. Blended elements may depict or refer to other-wordly states of existence or to creation narratives. Beings with combined elements can shift from shapes familiar in the present world and transport the viewer’s frame of reference to the spirit world. Puebloan belief in layering worlds below and above the present world is an important underlying social construct. Other worlds, especially those below, refer to past mythical times when animals and humans existed in primordial forms or were not fully formed, or may refer to the land of the dead or the underworld. Certain animal forms may have been selected because they are spirit guides, have specific powers, or were guardian-gods of cardinal directions. Some animals, such as birds, were chosen as messengers of prayers or offerings, while others (such as bears) had healing powers. The placement of images on the landscape or in relation to natural features imparts added power to the imagery. Ambiguity and multiple meanings also enhance these powers and incorporate concepts of emergence and transformation. Some images refer to the transformation that occurs when dancers wear kachina masks and then assume the attributes of those kachinas. Examples will be presented from images dating to the pre-European contact period (1300 to 1540 AD) found at Petroglyph National Monument, in the central Rio Grande valley of New Mexico. Comparisons to painted wall murals in kivas (ceremonial rooms) made during the same time period are presented. Full article

Wood is often used as an interior surface finish in buildings, including exposed cross-laminated timber panels and other structural mass timber members. Building occupants generally have a positive reaction to visible wood elements used in building interiors due to the visual qualities associated with wood being a natural material. This study aims to identify any thermal comfort impacts of wood interior environments using subjective occupant-reported perceived thermal sensation during two experiments conducted in a climate chamber fitted with either white-painted gypsum wallboard or unfinished laminated Douglas Fir wall panels. In the first experiment, the thermal environment was continually varied while the visual stimulus of the wall type remained constant. Irrespective of wood or white wall treatment type, thermal history played a significant role in the perceived thermal comfort of participants under continually modulating temperatures. In the second experiment, a slightly warm steady-state thermal environment was maintained while one of the two wall treatments was revealed from behind a black curtain. While the shift in thermal sensation toward neutral was greater with wood walls than with white walls, the difference was not found to be statistically significant and appears to diminish after 15 min of exposure to the new visual surroundings. Full article

This paper presents numerical studies of the viscous droplet impact on dry and wetted solid walls for spray painting applications, focusing on air entrapment, film structure, and flake (flat pigment) orientation. The results were compared with experimental observations using various high-speed camera arrangements. For paint droplet impact on dry substrates, a dynamic contact angle model was developed and used in numerical simulations. This contact angle model was verified with experimental observations. For the droplet impact on wet surfaces, characteristic crater sizes (diameter and depth) were defined considering also the effect of the film thickness. A strong correlation with the droplet impact Reynolds number was observed. In addition, a user-defined 6DOF (6-degrees-of-freedom) solver was implemented in a CFD program to perform calculations of rigid body motions within the impacting droplet, technically relevant for the resulting effect of flakes in metallic effect paints. The developed models were applied in parameter studies to further clarify the existing dependencies on application and fluid parameters more quantitatively. The simulation results are helpful to understand and to improve painting processes with respect to the final quality parameters. Full article

The conservation of cultural heritage requires advanced analytical tools to assess historic materials. In the context of the IPERION-CH project, a mobile multi-spectroscopic characterisation system for the analysis of cultural heritage materials, designated SYSPECTRAL, has been developed. This system integrates Laser-Induced Breakdown Spectroscopy (LIBS), Laser-Induced Fluorescence, Raman spectroscopy, and reflectance spectroscopy. The first application of SYSPECTRAL in a real-world setting was carried out at Müstair Monastery (UNESCO World Heritage Site since 1983) for wall paintings. In this study, stratigraphic analysis using LIBS revealed lead- and iron-based pigments in black and red hues, suggesting pigment degradation and restoration interventions. The presence of titanium in white hues indicated possible retouching. Furthermore, the presence of Egyptian blue in blue hues was identified through a combination of elemental and reflectance spectral analysis, underscoring the potential of SYSPECTRAL for heritage conservation. This approach offers comprehensive material characterization with minimal impact, a finding that is of particular significance in the context of heritage conservation. The subsequent phase of research will extend the application of SYSPECTRAL to a wider range of heritage sites, with the objective of enhancing the spectral databases and refining the analytical techniques for the purpose of improving cultural heritage conservation. Full article