Search Results (189)

Polymer composites are of considerable interest due to the possibility of improving the performance parameters of plastics. The filler is a component whose introduction into the rubber mixture can affect the physicochemical and functional properties of the composite. It is present in the largest quantity in the mixture, so its type is of significant importance in the polymer composite production process. Currently, much attention is being paid to the potential use of various materials as fillers to improve the properties of composites. These materials should, among other things, exhibit good adhesion to the polymer matrix and a high degree of dispersion. One example of such a material is dried plant material. In this group, dried leaves of two plants—sage (Salvia officinalis) and lucerne (Medicago sativa)—were introduced into a rubber mixture in several different content variants. The mixtures were subjected to durability and aging tests and the results were compared with a mixture without any plant additives. Of all the test variants with plant filler, the best results were obtained with the lowest proportion of dried plant material, which was 5 Parts per Hundred Rubber (PHR). In this case, most parameters remained at a level similar to the variant without additives. A slight improvement was observed in elongation at break for the mixture with sage (from 550% to 559%), while in the case of the mixture with lucerne, the color improved (from 1.21 to 0.94). Some parameters of vulcanization characteristics and tensile strength deteriorated. For the latter parameter, a decrease of 11% was noted for the mixture with sage (from 4.65 MPa to 4.13 MPa) and 18% for the mixture with lucerne (to 3.82 MPa). Interestingly, as a result of the ageing of the samples, a significant part of the mixtures with dried plants obtained better results in the case of tensile strength than before ageing. This applies especially to the following variants: 30 PHR for the mixture with sage (an increase of 48%) and 5 PHR for the mixture with alfalfa (an increase of 15%). In general, it should be noted that the functional parameters deteriorated with the increase in the proportion of plant additives. Full article

Piezoelectric polyvinylidene fluoride (PVDF) film sensors embedded in a tire can make the tire have a sense of tactile. Thus, PVDF strain sensors play an important role in smart tires. However, temperature tolerance of PVDF is a key issue limiting its application in smart tire as the embedding process needs high temperature vulcanization. This paper proposes a film repolarization method to treat PVDF film materials after high temperature vulcanization, which can be implemented to apply in smart tire. Variation in piezoelectric properties and its changing mechanism of PVDF film are analyzed with the methods of X-Ray Diffraction Spectroscopy (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). Vulcanization process that PVDF film sensors undergo in tire applications are simulated. Furthermore, properties of the PVDF sensors with different process stages are simulated based on finite element model. An experimental platform of the PVDF sensors is set up and the drop rod experiments are conducted. Results verify the performance improvement of the repolarization strategy on embedded PVDF sensors. The effectiveness of the repolarization in the PVDF film shows a great significance for the application of strain sensors in smart tire. Full article

Natural rubber is a widely used biological polymer material because of its excellent comprehensive performance. Nevertheless, the performance of domestic natural rubber cannot meet the requirements for high-end products such as aviation tires, which has become a constraint on the innovation and upgrading of high-end manufacturing enterprises and the enhancement of global competitiveness in China. To solve the bottleneck problem of natural rubber processing technology, this study systematically analyzed the effects of different varieties of fresh latex ratios on the processing and dynamic properties of bio-coagulated natural rubber. By mixing PR107 and Reyan72059 fresh latex with Reyan73397 fresh latex according to proportion, the fresh latex was coagulated by enzyme-assisted microbials, and the effects of the fresh latex ratio on physical and chemical indexes, molecular weight distribution, vulcanization characteristics, processing properties, cross-link density and physical and mechanical properties of the natural rubber were analyzed. The results showed that the aging resistance of natural rubber coagulated with enzyme-assisted microbial decreased, and the aging resistance of natural rubber increased with the increase in the mixing ratio of PR107 and Reyan72059 fresh latex. The proportion of high molecular weight of the natural rubber coagulated with the enzyme-assisted microbial increased, and the fresh latex mixing had little effect on the molecular weight distribution curve. Under the carbon black formulation, the CRI of the enzyme-assisted microbial coagulated natural rubber compound was relatively larger. Under the same strain conditions, the H-3 compound (PR107:Reyan72059:Reyan73397 = 1:1:3) had the best viscoelasticity and the least internal resistance of rubber molecules. In addition, the cross-link density, tensile strength, elongation at break, and tear strength of H-3 vulcanized rubber were the largest, improved by 23.08%, 5.32%, 12.45% and 3.70% compared with the same H-2 vulcanized rubber. In addition, the heat generation performance was reduced by 11.86%, and the wear resistance improved. Full article

To address the issue of uneven temperature distribution during the tire vulcanization process based on electromagnetic heating, this study focuses on the hot plate of a tire vulcanizing machine. An octagonal hot plate with dimensions of 1380 mm × 1380 mm × 60 mm was adopted, and temperature sensors were installed to monitor temperature changes in real time. Through electromagnetic simulation, the effects of current intensity, frequency, and coil-to-hot-plate distance on temperature uniformity were studied. The simulation results show that the temperature difference increases with current intensity and current frequency, while the temperature difference decreases with the increase in coil-to-hot-plate distance. To minimize the temperature gradient, the coil layout was structurally optimized based on the geometric features of the hot plate to improve magnetic field distribution. Several coil arrangements were designed and compared, including uniform, dual-ring, multi-ring, and the newly proposed flower-shaped configuration. It shows that the multi-ring circular coil has the best uniformity when heating a circular hot plate, and the flower-shaped coil has best temperature uniformity when heating an octagonal hot plate. Experimental validation using an industrial-scale prototype confirmed that the optimized design reduced temperature variation to within ±2 degrees Celsius. This work contributes a practical and geometrically informed coil design strategy for improving the temperature uniformity and energy efficiency of electromagnetic heating systems in industrial tire vulcanization. Full article

This study presents the results of an investigation into the potential use of the DiagBelt+ magnetic diagnostic system for assessing the quality of conveyor belt splices. Splices in conveyor belts are susceptible to damage and irregularities resulting from assembly errors, improper vulcanization parameters, or unfavorable operational conditions. Detecting geometric deviations from the reference standard after splice fabrication can serve as a component of QA/QC systems. Later deviations may indicate material or fabrication defects. To date, applications of the DiagBelt+ system have been limited to locating damage within the belt and its splices. Recently, efforts have been made to extend the system’s functionality to include splice diagnostics. This study was conducted under laboratory conditions on an ST2500 belt featuring five splices (three bias and two straight splices). Data acquisition was performed under various configurations of measurement parameters, including sensor-to-belt distance, belt travel speed, and system sensitivity threshold. For each splice, the signal width was measured and analyzed as a potential indicator of splice geometry and quality. The results indicate that the DiagBelt+ system can be effectively used for splice diagnostics. Work has commenced on automating the splice quality assessment process. Full article

The article examines the possibility of using ophthalmic lens waste (OLW) as a filler in styrene–butadiene rubber (SBR) composites in varying proportions. It analyzes the impact of OLW on the composites’ rheological, structural, morphological, mechanical, and thermal properties. Results show that OLW addition does not significantly alter vulcanization time, leading to thermal savings during processing. The crosslink densities, determined by the swelling method in an organic solvent and the mechanical behavior of the elastomers, increased with the incorporation of OLW, suggesting a filler/polymeric matrix interaction. The Lorenz–Parks model confirmed matrix–filler interaction, although it was insufficient to substantially improve mechanical reinforcement, with OLW mainly acting as a filler. Thermogravimetric tests revealed good thermal stability, but dynamic mechanical analysis indicated reduced damping properties. Spectroscopic analysis indicated the lack of molecular bonding between the polymer and the OLW filler. The study suggests that the optimal OLW content is between 10 and 20 phr, enabling the production of a new composite. Overall, incorporating OLW into vulcanized SBR composites offers a sustainable and cost-effective approach to reusing industrial waste in polymer production, providing an environmentally friendly alternative for the polymer industry. Full article

The importance of sustainable polymers has increased greatly in the last years since most polymers are derived from non-renewable sources. Sustainable polymers (i.e., biopolymers) such as natural rubber (NR) are proposed as a solution for this concern. A comparative study between NR and deproteinized NR (DPNR) was carried out to elucidate the role of proteins on the network formation and degradation of peroxide cross-linked NR using time-domain NMR experiments. The ¹H multiple-quantum (MQ) NMR experiments provided information on the cross-link density and its spatial distribution, while the actual fraction of non-coupled network defects was obtained by exploiting the Hahn echo approach measured on swollen samples. The results showed that proteins influenced the network formation during the vulcanization process of NR, leading to a higher number of non-elastic network defects and promoting the creation of additional cross-links with a broader spatial distribution. The formation of network heterogeneities in different length scales deeply influences the mechanical properties of NR samples. On the other hand, the proteins showed a pro-oxidant activity on the degradation behavior by accelerating the degradation process of peroxide cross-linked NR. Full article

To address the challenges of unclear thermo-mechanical coupling mechanisms and unpredictable multi-field synergistic effects in segmented tire molds during vulcanization, this study focuses on segmented tire molds and proposes a multi-physics coupling numerical model. This model integrates fluid flow dynamics into heat transfer mechanisms. It systematically reveals molds’ heat transfer characteristics, stress distribution and deformation behavior under combined high-temperature and mechanical loading. Based on a fluid-solid-thermal coupling framework and experimental validations, simulations indicate that the internal temperature field of the mold is highly uniform. The global temperature difference is less than 0.13%. The temperature load has a significant dominant effect on the deformation of key components such as the guide ring and installation ring. Molding forces play a secondary role in total stress. The error between multi-field coupling simulation results and experimental results is controlled within 6%, verifying the model’s reliability. This research not only provides a universally applicable multi-field coupling analysis method for complex mold design but also highlights the critical role of temperature fields in stress distribution and deformation analysis. This lays a theoretical foundation for the intelligent design and process optimization of high-temperature, high-pressure forming equipment. Full article

The growing interest in renewable resource-based materials has driven efforts to develop elastomeric biocomposites using biomass, phyto-ash, and biochar as fillers. These bio-additives, derived from beech wood through various processing methods, were incorporated into natural rubber (NR) at varying weight ratios. The primary objective of this study was to assess how the type and content of each bio-filler influence the structural, processing, and performance properties of the biocomposites. Mechanical properties, including tensile strength and hardness, were evaluated, while crosslink density of the vulcanizates was determined using equilibrium swelling in solvents. Additionally, the composites underwent thermogravimetric analysis (TGA) to determine the decomposition temperature of individual components within the polymer matrix. Bio-fillers influenced rheological and mechanical properties, with phyto-ash reducing viscosity and cross-linking density, and biochar and biomass increasing stiffness and maximum torque. Biochar extended curing time due to the absorption of curing agents, whereas phyto-ash accelerated vulcanization. Mechanical tests showed that all bio-filled composites were stiffer than the reference, with biochar and biomass (30 phr) exhibiting the highest hardness (45.8 °ShA and 49.1 °ShA, respectively) and cross-link density (2.68 × 10⁻⁵ mol/cm³ and 2.77 × 10⁻⁵ mol/cm³, respectively), contributing to improved tensile strength, in particular in the case of biochar, where the TS was 17.6 MPa. The study also examined the effects of thermal-oxidative aging on the samples, providing insights into the changes in the mechanical properties of the biocomposites under simulated aging conditions. Full article

Calcium lignosulfonate was incorporated into rubber compounds based on styrene–butadiene rubber (SBR) and acrylonitrile–butadiene rubber (NBR) in amounts ranging from 10 to 60 phr. A sulfur-based curing system and a peroxide curing system consisting of dicumyl peroxide in combination with methacrylic acid zinc salt were used for cross-linking of the compounds. The aim of the work was to investigate the influence of lignosulfonate and curing system composition of the cross-linking process, morphology, physical–mechanical and dynamic–mechanical characteristics of the composites. The achieved results showed that peroxide cured composites demonstrated higher cross-link density, which was found not to be influenced by the content of lignosulfonate. The cross-link density of sulfur-cured composites was lower and showed a decreasing tendency with increasing amounts of the biopolymer. A lower cross-linking degree was reflected in a higher elongation at break and higher increase in the elongation at break of the corresponding composites. On the other hand, peroxide-cured composites exhibited a higher modulus M100 and higher hardness. The microscopic analysis revealed that co-agent in peroxide vulcanization contributed to the improvement of adhesion between the biopolymer and the rubber resulting in higher tensile strength of the equivalent composites. The higher cross-link density of peroxide-cured composites caused higher restriction of the chain segments’ mobility, due to which these composites exhibited a higher glass transition temperature. Full article

In the tire manufacturing process, rubber compounds are vulcanized in volcanic presses. The vulcanization technology is carried out at temperatures above 150 °C, i.e., at a temperature potential that causes heat losses if the containers are not sufficiently insulated. The paper describes the mathematical model developed to detect the heat fluxes from the container walls to the surroundings. The calculation is carried out strictly in the SI system. With the help of the developed model, the back-relations of heat losses through the vertical and horizontal walls of the container enclosure were obtained as a function of the thickness of the insulation without and with a radiation shield on the inside of the enclosure. Numerical modeling using the finite volume method was used to verify the results obtained. In the numerical simulation, a 2D and a 3D model were created, and the same input conditions as in the mathematical model were simulated. Using the obtained results, an energy-energy balance of the tire vulcanization technology was performed by comparing the heat loss fraction as a function of the external temperature of the container cover and as a function of the insulation thickness. Full article

The damping performance of chlorinated butyl rubber (CIIR) is exceptional; however, its poor processability during vulcanization can lead to numerous defects. Natural rubber (NR) and ethylene propylene diene monomer rubber (EPDM) were selected to blend with CIIR for improving its processing performance. Their effects on the vulcanization characteristics, mechanical properties, and damping performance were investigated. Blending CIIR with NR can considerably increase the vulcanization speed of the rubber compound and improve production efficiency. The tensile strength of the vulcanizate first increases with an increase in the dosage of NR in NR/CIIR, and subsequently, it decreases before increasing again. The tensile strength first increases and then decreases with an increase in the EPDM dosage in EPDM/CIIR vulcanizate. The tensile strength increases by 15.6%when the EPDM dosage is 60 and 80 phr. EPDM and NR have similar effects on the damping performance of CIIR, which were evaluated by fitting the data of loss factor (∆tanδ) versus NR or EPDM dosage. Therefore, the quantity of NR or EPDM can be conveniently calculated based on performance requirements when designing the formula of the CIIR matrix materials. Full article

Geochemical data serve as crucial references for prospecting, and the effective extraction of prospecting information from such data determines the success rate of exploration. In the era of big data, novel prospecting methods based on geochemical data offer new ideas for exploring various ore deposits. By employing advanced data analysis techniques like machine learning and artificial intelligence, it becomes possible to identify elusive patterns and trends that are challenging to detect using traditional approaches, thereby significantly enhancing the success rate of prospecting endeavors. In this study, we selected drainage sediment geochemical data (Au, Ba, Mo, Sb, V, W, Zn) in the Jinya-Mingshan area to explore potential Carlin-type gold deposits. Traditional geochemical processing methods along with an association rule algorithm were employed for conducting comprehensive data mining analysis. The results demonstrate that the element combinations within the study area can be categorized into strong positive associations and enrichments (Mo, Sb, Zn) associated with vulcanization, strong negative associations, and decarbonation-related migration elements (Ba), as well as strong positive associations and weakly enriched elements (W) and weak positive associations and weakly enriched elements (V) not significantly related to mineralization. In comparison to Mo and Sb, which are closely linked to Au as revealed by cluster analysis and factor analysis, the association rule algorithm also reveals a relatively close correlation between Ba, Zn, and Au. Based on the element correlations obtained through the association rule algorithm, a new prospecting index was constructed for the study area. This new index is more reasonable than traditional indices. In conclusion, the association rule algorithm possesses unique advantages in information mining of geochemical data and holds promising applications in geological exploration. Full article

The microstructure and properties of a new type of carbon black produced by a domestic company through a new process were systematically characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Raman spectroscopy, and X-ray diffraction (XRD). The vulcanization properties, mechanical properties, and electrical conductivity of the new carbon black with different filler amounts were investigated in styrene butadiene rubber (SBR), using the traditional reinforcing filler N660 carbon black as a control. The experimental results demonstrate that the new carbon black exhibits a stratified structure with a specific surface area of 345.96 m²/g, and its particle size distribution is primarily concentrated within the 0.1–1 μm range. When the filling ratio was 30 phr/100 phr, the tensile strength of SBR composites filled with the new carbon black increased by 12.3% and the tear strength increased by 9.6% compared with those filled with N660 carbon black. In summary, the new carbon black can significantly improve the comprehensive performance of SBR composites and reduce the production cost. This provides a new type of material for the rubber industry that takes into account both economy and performance while also providing reference data for basic research in the field of SBR. Full article

Zinc oxide (ZnO) particles were successfully synthesized through the green method using aloe vera extract and zinc nitrate (1:1). The structure, morphology and properties of the biosynthesized ZnO (bioZnO) particles were analyzed by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), time of flight secondary ion mass spectrometry (TOF-SIMS) and thermogravimetry (TG). The morphology and the size of ZnO particles were elucidated by scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS). Then, the ability of bioZnO to activate sulfur curing of natural rubber (NR) was tested and compared to commercial ZnO traditionally used as vulcanization activator. The bioZnO showed similar activity in the vulcanization process to commercial ZnO. NR composites containing bioZnO were pro-ecological in nature and exhibited better mechanical characteristics and durability against thermo-oxidative aging than NR with commonly used micrometric ZnO. Moreover, NR vulcanizates containing bioZnO showed good mechanical properties in dynamic conditions and satisfactory thermal stability. The present research is new and in addition to the analysis of biosynthesized ZnO particles, the effect of the activator in the vulcanization process of the NR elastomer and its influence on the properties of the final products were additionally discussed. Full article